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1.

The equilibrium between nitrogen dioxide, NO2, and dinitrogen tetroxide, N2O4, is shown
below.
2NO2(g)

N2O4(g)

Kc = 0.01

What happens when the volume of a mixture at equilibrium is decreased at a constant


temperature?
I.

The value of Kc increases

II.

More N2O4 is formed

III.

[ NO 2 ]
The ratio of [ N 2 O 4 ] decreases

A.

I and II only

B.

I and III only

C.

II and III only

D.

I, II and III
(Total 1 mark)

2.

Which statement about chemical equilibria implies they are dynamic?


A.

The position of equilibrium constantly changes.

B.

The rates of forward and backward reactions change.

C.

The reactants and products continue to react.

D.

The concentrations of the reactants and products continue to change.


(Total 1 mark)

3.

Methanol may be produced by the exothermic reaction of carbon monoxide gas and hydrogen
gas.
CO(g) + 2H2(g)

IB Questionbank Chemistry

CH3OH(g)

HO = 103 kJ

(a)

State the equilibrium constant expression, Kc, for the production of methanol.
......................................................................................................................................
......................................................................................................................................
(1)

(b)

State and explain the effect of changing the following conditions on the amount of
methanol present at equilibrium:
(i)

increasing the temperature of the reaction at constant pressure.


...........................................................................................................................
...........................................................................................................................
...........................................................................................................................
...........................................................................................................................
(2)

(ii)

increasing the pressure of the reaction at constant temperature.


...........................................................................................................................
...........................................................................................................................
...........................................................................................................................
...........................................................................................................................
(2)

(c)

The conditions used in industry during the production of methanol are a temperature of
450 C and pressure of up to 220 atm. Explain why these conditions are used rather than
those that could give an even greater amount of methanol.
......................................................................................................................................
......................................................................................................................................
......................................................................................................................................
......................................................................................................................................
(2)

IB Questionbank Chemistry

(d)

A catalyst of copper mixed with zinc oxide and alumina is used in industry for this
production of methanol. Explain the function of the catalyst.
......................................................................................................................................
......................................................................................................................................
(1)
(Total 8 marks)

4.

Which is the correct relationship between enthalpy of vaporization, intermolecular forces and
boiling point?
Enthalpy of
vaporization

Intermolecular
forces

Boiling point

A.

small

weak

high

B.

small

strong

low

C.

large

weak

high

D.

large

strong

high
(Total 1 mark)

...........................................................................................................................
...........................................................................................................................
...........................................................................................................................
(2)

IB Questionbank Chemistry

(c)

The conditions used in industry during the production of methanol are a temperature of
450 C and pressure of up to 220 atm. Explain why these conditions are used rather than
those that could give an even greater amount of methanol.
......................................................................................................................................
......................................................................................................................................
......................................................................................................................................
......................................................................................................................................
(2)

(d)

A catalyst of copper mixed with zinc oxide and alumina is used in industry for this
production of methanol. Explain the function of the catalyst.
......................................................................................................................................
......................................................................................................................................
(1)
(Total 8 marks)

5.

For the following reaction Kc = 1.0 105 at 30 C.


2NOCl(g)

2NO(g) + Cl2(g)

Which relationship is correct at equilibrium at this temperature?


A.

The concentration of NO equals the concentration of NOCl.

B.

The concentration of NOCl is double the concentration of Cl 2.

C.

The concentration of NOCl is much greater than the concentration of Cl 2.

D.

The concentration of NO is much greater than the concentration of NOCl.


(Total 1 mark)

IB Questionbank Chemistry

6.

The reaction below represents the Haber process for the industrial production of ammonia.
N2(g) + 3H2(g)

2NH3(g)

HO = 92 kJ

The optimum conditions of temperature and pressure are chosen as a compromise between those
that favour a high yield of ammonia and those that favour a fast rate of production. Economic
considerations are also important.
Which statement is correct?
A.

A higher temperature would ensure higher yield and a faster rate.

B.

A lower pressure would ensure a higher yield at a lower cost.

C.

A lower temperature would ensure a higher yield and a faster rate.

D.

A higher pressure would ensure a higher yield at a higher cost.


(Total 1 mark)

7.

An example of a homogeneous reversible reaction is the reaction between hydrogen and iodine.
H2(g) + I2(g)
(i)

2HI(g)

Outline the characteristics of a homogeneous chemical system that is in a state of


equilibrium.
......................................................................................................................................
......................................................................................................................................
......................................................................................................................................
......................................................................................................................................
(2)

(ii)

Deduce the expression for the equilibrium constant, Kc.


......................................................................................................................................
......................................................................................................................................
(1)

IB Questionbank Chemistry

(iii)

Predict what would happen to the position of equilibrium and the value of Kc if the
pressure is increased from 1 atm to 2 atm.
......................................................................................................................................
......................................................................................................................................
......................................................................................................................................
......................................................................................................................................
(2)

(iv)

The value of Kc at 500 K is 160 and the value of Kc at 700 K is 54. Deduce what this
information tells us about the enthalpy change of the forward reaction.
......................................................................................................................................
......................................................................................................................................
(1)

(v)

The reaction can be catalysed by adding platinum metal. State and explain what effect the
addition of platinum would have on the value of the equilibrium constant.
......................................................................................................................................
......................................................................................................................................
......................................................................................................................................
......................................................................................................................................
(2)
(Total 8 marks)

IB Questionbank Chemistry

8.

Which statement is correct for a crystal of iron(II) sulfate in a state of equilibrium with a
saturated solution of iron(II) sulfate?

A.

The colour of the solution darkens as the crystal continues to dissolve.

B.

The concentration of the iron(II) sulfate solution increases as the water evaporates.

C.

The shape of the iron(II) sulfate crystal does not change.

D.

The colour of the solution does not change but the shape of the crystal may change.
(Total 1 mark)

9.

(i)

A state of equilibrium can exist when a piece of copper metal is placed in a solution of
copper(II) sulfate. Outline the characteristics of a chemical system in dynamic
equilibrium.
(2)

(ii)

For an exothermic reaction state how an increase in temperature would affect both Kc and
the position of equilibrium.
(2)
(Total 4 marks)

IB Questionbank Chemistry

10.

Consider the equilibrium between methanol, CH3OH(l), and methanol vapour, CH3OH(g).
CH3OH(l)

CH3OH(g)

What happens to the position of equilibrium and the value of Kc as the temperature decreases?
Position of equilibrium

Value of Kc

A.

shifts to the left

decreases

B.

shifts to the left

increases

C.

shifts to the right

decreases

D.

shifts to the right

increases
(Total 1 mark)

11.

(a)

The production of ammonia is an important industrial process.


N2(g) + 3H2(g)

(i)

2NH3(g)

Using the average bond enthalpy values in Table 10 of the Data Booklet, determine
the standard enthalpy change for this reaction.
(3)

(ii)

The standard entropy values, S, at 298 K for N2(g), H2(g) and NH3(g) are 193, 131
and 192 JK1 mol1 respectively. Calculate SO for the reaction and with reference
to the equation above, explain the sign of SO.
(4)

(iii)

Calculate GO for the reaction at 298 K.


(1)

(iv)

Describe and explain the effect of increasing temperature on the spontaneity of the
reaction.
(2)

(b)

The reaction used in the production of ammonia is an equilibrium reaction. Outline the
characteristics of a system at equilibrium.
(2)

IB Questionbank Chemistry

(c)

Deduce the equilibrium constant expression, Kc, for the production of ammonia.
(1)

(d)

(i)

0.20 mol of N2(g) and 0.20 mol of H2(g) were allowed to reach equilibrium in a
1 dm3 closed container. At equilibrium the concentration of NH 3(g) was
0.060 mol dm3. Determine the equilibrium concentrations of N2(g) and H2(g) and
calculate the value of Kc.
(3)

(ii)

Predict and explain how increasing the temperature will affect the value of Kc.
(2)

(e)

Describe how increasing the pressure affects the yield of ammonia.


(2)

(f)

In practice, typical conditions used in the Haber process are a temperature of 500 C and
a pressure of 200 atmospheres. Outline why these conditions are used rather than those
that give the highest yield.
(2)

(g)

A catalyst of iron is used in the Haber process. State and explain how the catalyst affects
Kc and the position of equilibrium.
(3)
(Total 25 marks)

IB Questionbank Chemistry

12.

What is the equilibrium constant expression, Kc, for the following reaction?
N2O4(g)

A.

[NO 2 ]
Kc = [N 2 O 4 ]

B.

[NO 2 ] 2
Kc = [N 2 O 4 ]

2NO2(g)

[NO 2 ]
C.

2
Kc = [N 2 O 4 ]

D.

Kc = [NO2][N2O4]2
(Total 1 mark)

? ?800(ii)

Predict and explain how increasing the temperature will affect the value of Kc.
(2)

(e)

Describe how increasing the pressure affects the yield of ammonia.


(2)

(f)

In practice, typical conditions used in the Haber process are a temperature of 500 C and
a pressure of 200 atmospheres. Outline why these conditions are used rather than those
that give the highest yield.
(2)

(g)

A catalyst of iron is used in the Haber process. State and explain how the catalyst affects
Kc and the position of equilibrium.
(3)
(Total 25 marks)

IB Questionbank Chemistry

10

13.

Consider the endothermic reaction below.


5CO(g) + I2O5(g)

5CO2(g) + I2(g)

According to Le Chateliers principle, which change would result in an increase in the amount
of CO2?
A.

Increasing the temperature

B.

Decreasing the temperature

C.

Increasing the pressure

D.

Decreasing the pressure


(Total 1 mark)

[NO 2 ] 2 [NO 2 ]
2
Kc = [N 2 O 4 ] [N 2 O 4 ] ? ?800(ii)

B.

Predict and explain how increasing the

temperature will affect the value of Kc.


(2)

(e)

Describe how increasing the pressure affects the yield of ammonia.


(2)

(f)

In practice, typical conditions used in the Haber process are a temperature of 500 C and
a pressure of 200 atmospheres. Outline why these conditions are used rather than those
that give the highest yield.
(2)

(g)

A catalyst of iron is used in the Haber process. State and explain how the catalyst affects
Kc and the position of equilibrium.
(3)
(Total 25 marks)

IB Questionbank Chemistry

11

14.

In carbonated drinks containing dissolved carbon dioxide under high pressure, the following
dynamic equilibrium exists.
CO2(aq)

CO2(g)

Describe the effect of opening a carbonated drink container and outline how this equilibrium is
affected.
(Total 2 marks)

15.

0.50 mol of I2(g) and 0.50 mol of Br2(g) are placed in a closed flask. The following equilibrium
is established.
I2(g) + Br2(g)

IBr(g)

The equilibrium mixture contains 0.80 mol of IBr(g). What is the value of Kc?
A.

0.64

B.

1.3

C.

2.6

D.

64
(Total 1 mark)

IB Questionbank Chemistry

12

008 T
000320a4d01e003010000005d4e09000000320a4d019f00030000005b4e4f651c000000fb0220ff000
0000000009001000000000402001054696d6573204e657720526f6d616e0058b1f37761b1f3772040
f577881566a6040000002d01020004000000f001010008000000320aae03920301000000344e08000
000320aae03dd0101000000324e08000000320aa501340301000000324e0a00000026060f000a00ffff
ffff0100000000001c000000fb021000070000000000bc02000000000102022253797374656d00a688
1566a600000a0021008a01000000000100000054f31300040000002d01010004000000f0010200030
000000000

B.

[NO 2 ] 2
Kc = [N 2 O 4 ]

16.

The Haber process enables the large-

scale production of ammonia needed to make fertilizers.


The equation for the Haber process is given below.
N2(g) + 3H2

2NH3(g)

The percentage of ammonia in the equilibrium mixture varies with temperature.

(i)

Use the graph to deduce whether the forward reaction is exothermic or endothermic and
explain your choice.
(2)

(ii)

State and explain the effect of increasing the pressure on the yield of ammonia.
(2)

IB Questionbank Chemistry

13

(iii)

Explain the effect of increasing the temperature on the rate of reaction.


(2)
(Total 6 marks)

17.

What is the effect of an increase of temperature on the yield and the equilibrium constant for the
following reaction?
2H2(g) + CO(g)
Yield

Equilibrium
constant

A.

Increases

Increases

B.

Increases

Decreases

C.

Decreases

Increases

D.

Decreases

Decreases

CH3OH(l)

HO = 128 kJ

(Total 1 mark)

18.

Which statements about a liquid are correct?


I.

When the temperature of a liquid in a closed container increases, its vapour


pressure increases.

II.

When the pressure on a liquid increases, its boiling point increases.

III.

When the pressure on a liquid increases, its vapour pressure increases.

A.

I and II only

B.

I and III only

C.

II and III only

D.

I, II and III
(Total 1 mark)

IB Questionbank Chemistry

14

19.

Consider the following equilibrium reaction.


2SO2(g) + O2(g)

2SO3(g)

Ho = 197 kJ

Which change in conditions will increase the amount of SO3 present when equilibrium is reestablished?
A.

Decreasing the concentration of SO2

B.

Increasing the volume

C.

Decreasing the temperature

D.

Adding a catalyst
(Total 1 mark)

20.

Biodiesel makes use of plants ability to fix atmospheric carbon by photosynthesis.


Many companies and individuals are now using biodiesel as a fuel in order to reduce their
carbon footprint. Biodiesel can be synthesized from vegetable oil according to the following
reaction.

(a)

Identify the organic functional group present in both vegetable oil and biodiesel.
......................................................................................................................................
(1)

IB Questionbank Chemistry

15

(b)

For part of her extended essay investigation into the efficiency of the process, a student
reacted a pure sample of a vegetable oil (where R = C 17H33) with methanol.
The raw data recorded for the reaction is below.
Mass of oil
Mass of methanol
Mass of sodium hydroxide
Mass of biodiesel produced

= 1013.0 g
= 200.0 g
=
3.5 g
= 811.0 g

The relative molecular mass of the oil used by the student is 885.6. Calculate the amount
(in moles) of the oil and the methanol used, and hence the amount (in moles) of excess
methanol.
......................................................................................................................................
......................................................................................................................................
......................................................................................................................................
......................................................................................................................................
......................................................................................................................................
(3)

(c)

The reversible arrows in the equation indicate that the production of biodiesel is an
equilibrium process.
(i)

State what is meant by the term dynamic equilibrium.


...........................................................................................................................
...........................................................................................................................
(1)

(ii)

Using the abbreviations [vegetable oil], [methanol], [glycerol] and [biodiesel]


deduce the equilibrium constant expression (Kc) for this reaction.

(1)

(iii)

Suggest a reason why excess methanol is used in this process.


...........................................................................................................................
...........................................................................................................................
(1)

IB Questionbank Chemistry

16

(iv)

State and explain the effect that the addition of the sodium hydroxide catalyst will
have on the position of equilibrium.
...........................................................................................................................
...........................................................................................................................
...........................................................................................................................
(2)

(d)

The reactants had to be stirred vigorously because they formed two distinct layers in the
reaction vessel. Explain why they form two distinct layers and why stirring increases the
rate of reaction.
......................................................................................................................................
......................................................................................................................................
......................................................................................................................................
......................................................................................................................................
(2)

(e)

Calculate the percentage yield of biodiesel obtained in this process.


......................................................................................................................................
......................................................................................................................................
......................................................................................................................................
......................................................................................................................................
(2)

(f)

When biodiesel is combusted it produces carbon dioxide. Explain why the use of
biodiesel as a fuel does not significantly contribute to global warming.
......................................................................................................................................
......................................................................................................................................
(1)
(Total 14 marks)

IB Questionbank Chemistry

17

21.

Consider the following reversible reaction.


Cr2O72(aq) + H2O(l)

2CrO42(aq) + 2H+(aq)

What will happen to the position of equilibrium and the value of Kc when more H+ ions are
added at constant temperature?
Position of equilibrium

Value of Kc

A.

shifts to the left

decreases

B.

shifts to the right

increases

C.

shifts to the right

does not change

D.

shifts to the left

does not change


(Total 1 mark)

22.

Consider this equilibrium reaction in a sealed container:


H2O(g)

H2O(l)

What will be the effect on the equilibrium of increasing the temperature from 20 C to 30 C?
A.

More of the water will be in the gaseous state at equilibrium.

B.

More of the water will be in the liquid state at equilibrium.

C.

At equilibrium the rate of condensation will be greater than the rate of evaporation.

D.

At equilibrium the rate of evaporation will be greater than the rate of condensation.
(Total 1 mark)

IB Questionbank Chemistry

18

23.

What effect will an increase in temperature have on the Kc value and the position of equilibrium
in the following reaction?
N2(g) + 3H2(g)

2NH3(g)

Kc

Equilibrium position

A.

increases

shifts to the right

B.

decreases

shifts to the left

C.

increases

shifts to the left

D.

decreases

shifts to the right

H = 92 kJ

(Total 1 mark)

24.

Which statement is always correct for a chemical reaction at equilibrium?


A.

The rate of the forward reaction equals the rate of the reverse reaction.

B.

The amounts of reactants and products are equal.

C.

The concentration of the reactants and products are constantly changing.

D.

The forward reaction occurs to a greater extent than the reverse reaction.
(Total 1 mark)

25.

Consider the following equilibrium.


2SO2(g) + O2(g)

(i)

2SO3(g)

Ho = 198 kJ mol1

Deduce the equilibrium constant expression, Kc, for the reaction.


(1)

(ii)

State and explain the effect of increasing the temperature on the yield of sulfur trioxide.
(2)

(iii)

State the effect of a catalyst on the value of Kc.


(1)

IB Questionbank Chemistry

19

(iv)

State and explain the effect of a catalyst on the position of equilibrium.


(2)
(Total 6 marks)

26.

Which statement is correct for the equilibrium H 2O(l)

H2O(g) in a closed system at

100 C?
A.

All the H2O(l) molecules have been converted to H2O(g).

B.

The rate of the forward reaction is greater than the rate of the reverse reaction.

C.

The rate of the forward reaction is less than the rate of the reverse reaction.

D.

The pressure remains constant.


(Total 1 mark)

(ii)

State and explain the effect of increasing the temperature on the yield of sulfur trioxide.
(2)

(iii)

State the effect of a catalyst on the value of Kc.


(1)

(iv)

State and explain the effect of a catalyst on the position of equilibrium.


(2)
(Total 6 marks)

IB Questionbank Chemistry

20

27.

When a mixture of 0.100 mol NO, 0.051 mol H2 and 0.100 mol H2O were placed in a 1.0 dm3
flask at 300 K, the following equilibrium was established.
2NO(g) + 2H2(g)

N2(g) + H2O(g)

At equilibrium, the concentration of NO was found to be 0.062 mol dm 3. Determine the


equilibrium constant, Kc, of the reaction at this temperature.
(Total 4 marks)

28.

An increase in temperature increases the amount of chlorine present in the following


equilibrium.
PCl5(s)

PCl3(l) + Cl2(g)

What is the best explanation for this?


A.

The higher temperature increases the rate of the forward reaction only.

B.

The higher temperature increases the rate of the reverse reaction only.

C.

The higher temperature increases the rate of both reactions but the forward reaction is
affected more than the reverse.

D.

The higher temperature increases the rate of both reactions but the reverse reaction is
affected more than the forward.
(Total 1 mark)

29.

What will happen when at a constant temperature, more iodide ions, I , are added to the
equilibrium below?
I2(s) + I(aq)

I3(aq)

A.

The amount of solid iodine decreases and the equilibrium constant increases.

B.

The amount of solid iodine decreases and the equilibrium constant remains unchanged.

C.

The amount of solid iodine increases and the equilibrium constant decreases.

D.

The amount of solid iodine increases and the equilibrium constant remains unchanged.
(Total 1 mark)

IB Questionbank Chemistry

21

30.

Consider the following reaction taking place at 375 C in a 1.00 dm 3 closed container.
Cl2(g) + SO2(g)

(i)

SO2Cl2(g)

HO = 84.5 kJ

Deduce the equilibrium constant expression, Kc, for the reaction.


(1)

(ii)

If the temperature of the reaction is changed to 300 C, predict, stating a reason in each
case, whether the equilibrium concentration of SO2Cl2 and the value of Kc will increase
or decrease.
(3)

(iii)

If the volume of the container is changed to 1.50 dm 3, predict, stating a reason in each
case, how this will affect the equilibrium concentration of SO2Cl2 and the value of Kc.
(3)

(iv)

Suggest, stating a reason, how the addition of a catalyst at constant pressure and
temperature will affect the equilibrium concentration of SO 2Cl2.
(2)
(Total 9 marks)

31.

Which affects the equilibrium vapour pressure of a liquid in a sealed container, assuming that
there is always some of the liquid present?
A.

The temperature of the liquid

B.

The surface area of the liquid

C.

The volume of the liquid

D.

The volume of the container


(Total 1 mark)

IB Questionbank Chemistry

22

32.

Consider the following equilibrium reaction.


Cl2(g) + SO2(g)

SO2Cl2(g)

HO = 84.5 kJ

In a 1.00 dm3 closed container, at 375 C, 8.60 103 mol of SO2 and 8.60 103 mol of Cl2
were introduced. At equilibrium, 7.65 104 mol of SO2Cl2 was formed.

(i)

Deduce the equilibrium constant expression, Kc, for the reaction.


(1)

(ii)

Determine the value of the equilibrium constant, Kc.


(3)

(iii)

If the temperature of the reaction is changed to 300 C, predict, stating a reason in each
case, whether the equilibrium concentration of SO2Cl2 and the value of Kc will increase
or decrease.
(3)

(iv)

If the volume of the container is changed to 1.50 dm 3, predict, stating a reason in each
case, how this will affect the equilibrium concentration of SO2Cl2 and the value of Kc.
(3)

(v)

Suggest, stating a reason, how the addition of a catalyst at constant pressure and
temperature will affect the equilibrium concentration of SO 2Cl2.
(2)
(Total 12 marks)

IB Questionbank Chemistry

23

33.

The sequence of diagrams represents the system as time passes for a gas phase reaction in which
reactant X is converted to product Y.

D ia g ra m 1
t = 7 seconds

D ia g ra m 2
t = 5 m in u te s

D ia g ra m
t = 1 0 m in u te s

D ia g ra m 4
t = 5 days

T im e , t
X =
Y =

Which statement is correct?


A.

At t = 5 days the rate of the forward reaction is greater than the rate of the backward
reaction.

B.

At t = 7 seconds the reaction has reached completion.

C.

At t = 10 minutes the system has reached a state of equilibrium.

D.

At t = 5 days the rate of the forward reaction is less than the rate of the backward
reaction.
(Total 1 mark)

IB Questionbank Chemistry

24

34.

What changes occur when the temperature is increased in the following reaction at equilibrium?
Br2(g) + Cl2(g)

2BrCl(g)

H = +14 kJ mol1

Position of equilibrium

Value of equilibrium constant

A.

Shifts towards the reactants

Decreases

B.

Shifts towards the reactants

Increases

C.

Shifts towards the products

Decreases

D.

Shifts towards the products

Increases
(Total 1 mark)

35.

The diagrams below represent equilibrium mixtures for the reaction Y + X 2

XY + X at

350 K and 550 K respectively. Deduce and explain whether the reaction is exothermic or
endothermic.

X =

350 K

550 K

Y =
(Total 2 marks)

36.

The equation for the main reaction in the Haber process is:
N2(g) + 3H2(g)

IB Questionbank Chemistry

2NH3(g)

H is negative

25

(i)

Determine the equilibrium constant expression for this reaction.


(1)

(ii)

State and explain the effect on the equilibrium yield of ammonia with increasing the
pressure and the temperature.
(4)

(iii)

In practice, typical conditions used in the Haber process involve a temperature of 500 C
and a pressure of 200 atm. Explain why these conditions are used rather than those that
give the highest yield.
(2)

(iv)

At a certain temperature and pressure, 1.1 dm 3 of N2(g) reacts with 3.3 dm3 of H2(g).
Calculate the volume of NH3(g), that will be produced.
(1)

(v)

Suggest why this reaction is important for humanity.


(1)

(vi)

A chemist claims to have developed a new catalyst for the Haber process, which increases
the yield of ammonia. State the catalyst normally used for the Haber process, and
comment on the claim made by this chemist.
(2)
(Total 11 marks)

IB Questionbank Chemistry

26

37.

For the reaction below:


H2(g) + I2(g)

2HI(g)

at a certain temperature, the equilibrium concentrations, in mol dm 3, are


[H2(g)] = 0.30, [I2(g)] = 0.30, [HI(g)] = 3.0
What is the value of Kc?
A.

1.0102

B.

10

C.

33

D.

1.0102
(Total 1 mark)

38.

A liquid and its vapour are at equilibrium inside a sealed container. Which change will alter the
equilibrium vapour pressure of the liquid in the container?
A.

Adding more liquid

B.

Adding more vapour

C.

Decreasing the volume of the container

D.

Decreasing the temperature


(Total 1 mark)

IB Questionbank Chemistry

27

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