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The rate of Heat transfer is
*
1 2
Q
Q
Time
[ ]
2
* *
1 2
1
* *
1 2
varies
constant
Now if Q with time then Q Qdt
Now if Q is then Q Q time
T
2
T
1
T
P
The system undergoes the
path as shown and as a result
of the process the state of the
system changes. The process
will stop when system
achieves temperature of the
surroundings.
MODES OF HEAT TRANSFER : There are three methods by
which Heat Transfer takes place. These are Conduction,
Convection and Radiation.
CONDUCTION is the transfer of energy from high energy particles
to low energy particles. It takes place in Solids,Liquids, and Gases.
It is predominant in Solids and less dominant in Liquids and
Gases. It is governed by FOURIER LAW
*
cross sectional area
Cond
dT
Q kA where k Thermal Conductivity
dx
A
dT
Temperature Gradient in flow direction
dx
Surr
System
Piston
moving
Moving Boundary
Work
System
Shaft Work
R I
Electrical Work
System
Q= -ve
Q= +ve
W = -ve
W = +ve Heat and work
interactions imply a
change of state of
system
Heat and Work Interactions
They are
a. Interactions which cross boundaries
b. They are not properties.
c. They are associated with a process and occur because
of change of state.
d. Both are path functions , and thus the value of W and
Q depend upon the path taken.
2
1 2
1
2 1
det min W W and we have to er e the Inexact Differential and
and it is not equal to W W as Work is not a property
2
2 1
1
2 1
V dV V V This is an exact differential because
V and V are properties
1 2 1 2
Q and W are never written as W
We will always have to specify the path.
A
B
C
2
1
A B C
A B C
W W W
Q Q Q
Lets look at a few examples of how work and heat can be
assessed considering the system and its surroundings
FORMS OF WORK
System is room which is completely
insulated.
Candle located in room.
Q=0 and W=0
Isolated system
200
o
C
System is potato at 25
o
C which is
located in an oven having T=200
o
C
Q= +ve and W=0
Potato
Room
Oven
-ve +ve
System is oven and element. The
system is completely insulated.
Q= 0 and W=-ve
Work is Electrical work
Electrons
cross
boundary
Element
Heat
Given
Oven
Oven
System is oven and is not insulated.
Q= +ve0 and W= 0
Heat given by fire.
Electrical Work: When electrons cross the from the system
boundary then electrical work is done by the system. If electrons
cross into the system then electrical work is done on system
W
e
= V(N) where V=voltage and N = Coulombs of electron
Now
*
( ) e
N
Current I soW V I Power
Time
and thus power is expressed in Watts.
( ) ( )
( ) ( ) ( )
2
1
e
e
If V and I are functions of time then W V I dT
If V and I are not functions of time then W V I t
MECHANICAL WORK
From Physics we know that W = Force X Distance = F(s)
Insulated
Ice Water
at 0
o
C
Oil at 0
o
C
10 kJ Initially Oil ( System A) and
Ice Water (System B) are at
0
o
C.
When 10 kJ of electrical work is given to system A , it converts to
heat and increases temperature of Oil and it rises.
Now as oil gets heated it gives heat to ice water and some ice
melts.
Eventually both systems go to 0
o
C.
System A gets 10 kJ of Work and gives 10 kJ of Heat to ice water
and comes back to its original state.
System B gets 10 kJ of Heat from system A
For the combined System A+B
W
in
= 10kJ and Q
out
= 0
We should be sure about our system definition and the
interactions
If force is not constant then
2
1
W Fds
The area under the path of process 1-2 is the PdV work as
2
1
W PdV Moving Boundary Work
This is how most engines work by operating in a cycle and getting
positive work.
We can also have shaft work in that we use the net work of the
cycle to rotate a shaft ( Car Engine)
The boundary can also be made to expand by heating it to get
positive work. ( Baloon rising)
Basically Mechanical work is mostly due to PdV work and Shaft
work. We represent shaft work by W
X
.We will later learn how to
evaluate the value of shaft work as it requires information about
Torque and RPM.
We shall now look at a few examples.
2
1
P
V
2 1
PROCESSES IN THERMODYNAMICS AND WORK
EVALUATION
Ideal Gas Polytropic Process:- For Ideal gases generally we have
a process where P,V and T change together. This is called a
POLYTROPIC PROCESS. It is represented by the equation
( )
2 2 1 1
2 1
b
1 1
1 1 2 2
2 2 2
b
Constant=C where n is an index depending
upon the type of polytropic process. But n 1
So for such a process the PdV work can be
W
1
W
n
n n
n
n n
n
PV
V V
PdV CV dV C
n
but C PV PV
PV V
+ +
1
+
]
( )
( ) ( )
( )
1 1
1 1 1
2 2 1 1
1 1 1 1 2 2 2 2
2 2 1 1
b
2 1
b
1 1
W tan
1
W
1
n n n
PV V
PV PV
n n
But PV mRT and PV m RT so
m RT mRT
and if m cons t
n
mR T T
n
+ +
1
1
+
1
]
GRAVITATIONAL WORK
Work done by or against a Gravitational Filed. In such work the
force acting on a body is its weight.
F = mg where g = acceleration due to gravity so
2
2 1
1
( )
g
W Fdz mg z z
SPRING WORK
Spring Work is produced by change in length of Spring.
For any spring its force is given by F = k (x) where
k = spring constant and x is the distance length changes
( )
( )
2 2
1 1
2 2
2 1
1
2
x x
Spring
x x
W Fdx kx dx k x x
WORK OF ELASTIC SOLID BAR behaves like a spring and hence
2
1
/
x
Elastic n n
x
F
W Adx where A c s area and
A
+
+ + +
+
2 2
1 1
P v
or Ideal gases h C dt and u C dt
U,H AND C
P
AND C
V
FOR SOLIDS AND LIQUIDS
Solids and Liquids are in-compressible and their density does not
change significantly with Pressure or Temperature. For them
C
P
= C
v
= C. Values are given in Table A-3
[ ]
[ ] [ ]
2 1 2 1
2 1 2 1 2 1
2 1 2 1 2 1
0
0
. .
. .
v av
av
here du C dt so u u C T T
and for enthalpy changes h u Pv
so dh du Pdv vdP du vdP as dv
so h h C T T v P P
For solids P P so h h u u
For Liquids a if pressure is const then h u
b If const temperature h v P
+
+ + +
+
[ ]
( )
@ , @
@
2 1 2 1
@ ,
@ ,
0
1 2
P T T
T
P T f f Sat at T
P T f
as u
so for this case if we have a process from
h h v P P
so to find h h v P P
or h nearly equal to h