SPM Trial 2012 Chemistry Qa Kedah

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PROGRAII PENINGKATAN PRESTASI AKADEMIK

SPM
TAHUN 2412
CHEMISTRY
Kertas
Satu jam dan lima belas minit

JANGAN BUKA KERTAS SOATAN INI SEHINGGA DIBERITAHU
1. 2. 3.
Kertas soalan ini adalah dalam dwibahasa Soalan dalam bahasa lnggeris mendahului soalan yang sepadan dalam bahasa Melayu Calon dikehendakimembaca maklumat dihalaman belakang kertas soalan ini.
Kertas soalan ini mengandvngi
24 halaman bercetak
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INFOR]VIATION T'OR CANDIDATES MAKLUMAT T'NTUK CALON
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This question paper consists of 50 questions, Kertas soalan ini mengandungi 50 soalm.
questions. Jawab semuo soalan.
2. Answerall
3. Each question is followed by four alternative answers, AP.C and D. For each question, choose one answer only. Blacken your answer on the objective answer
sheet provided.
TiaVtiap soalan diih.ti aleh emqtat pililnniawapan. iaitu A,8,C dan D. Bagi set@ s(xrl(m, pilih saUjan'apan sahaia. Hitamkanin+,apan mda pada kertas jawqan objektf ymg disediakan.
4.
If you wish to change your answer,
eras the blackened mark that you have made.
Then blacken the new answer. Setiranyo onda lrendak menulmriawapan, padamkan tanda yang telah dibuat. Ikmtiian httankan iov' apm yang baru.
6. The
diagrams in ths questions provided are not drawn to scale unless stated. Rajah yang mengiringi soalan tidak dilukis mengihtt skola kecuali dinyaalcan
7. You may us a non-programmable scientific calculator. Atdo dihenarkan nengunakan kalhiator saintiJikyang tidak boleh diprogram.
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Diagram I shows a stnrcfuie ofammonia molecule, NH3. Ralah I nrenunjukkan satu stntVur molefutl ammonia"NHz
H
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Diagram I
How many atoms of hydrogen alr there in one molecule ofammonia, NHr? Berapakah atom hidrogen yog terdapat dalam suu molekal ammonia, NHI?
A2 B3 c4 D5
Which of the following are anions? Manakah antara beriha adalah anion?
A Li*,H*
Al3*,
cr
crzor'-
c G' ,
D
MnO+-, NHa*
Diagram
shows the elernents in the Periodic Table.
Rajah 2 menunjuA:ftan unsar-unsur dalam Jadual Berksla
Diagram 2 Which element is a halogen? Unsur manakah adalah suatu halogen?
AP Ba CR DS
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What type of chemical bond exist in water, HzO ? Apakah jenis ilmtan kimia yang wajud dalam air , H2a ?
A B C D
Covalent bond Ikntan kovalen lonic bond Ikatan ionik Metallic bond Ifutan logam Single bond Ikatan tunggal
Rajah3 rnemnjukkan
Diagram 3 shows the apparatus set-up for an experiment. susururn radas untuk suatu ekspertmen
Anode
And
Cathode Kotod
Electrolyte Elektrolit Diagram 3 Which ofthe following substances could be used as an electrolyte? Antara bahon yotg berilst, yang manakah boleh digunakan sebagai elektrcli{!
A B C D 6
Solid naphthalene Pepejal nofialena Hydrochloric acid Asid hidroHorik Molten glucose I*buran glukosa Pure ethanol
Etmol nlen Which of the following is true about an acid? Auara pernyataan berilal yang manaf,ah bewr tentang suatu asid ?
A B C D
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An acid is not conosive Asid tidak mengkakis A strong acid has a low pH value Asid hnt memputyai nilai pHyang rendah A weak acid has a high degree of ionisation Asid lemah mempnyai kadar pengionanyemg tinggi An acid is a chEmical compound that is soluble in water to produce OH- ion Asid ialah sebdian kimia ywry lantt dalom air menghmilkan ion Abf
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Which of the following substances is a soluble salt? Aruara balnn berilwt , yang monakah goram terlarutkan ?
Sodium chloride, NaCl Natrium Horida,NaCl Barium sulphate, BaSO+ Barium sulat, BaSOI Potassium nitrate, KNO3 Kalium nitru, KNOr tf,ad 0I) carbonate, PbCO3 P I u mb u m(Il) ka rb o nat, PbCOr I and I and tII II and III II and IV
il
III
IV
A
B C D
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Diagram 4 shows a type of material used to make buildings. Rajah4 merunjukkan sejenis untuk membina bangtnan
bahanyang
Cement
Simen
Steelwires Wayar keluli
Diagram 4
What arr the characteristics of the material? Apakah ciri<iri bahon tersebuf?
A B C D
High tensile snength hratan re gang(m yang t inggi Hard and brittle Keras dan rapuh High boiling point and melting point Takat didih dan takat lebur yang tingi Capable to conduct electricity Ke bo le hm me ngla nduks i kan el e Hri k
Ke
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Which ofthe following explains the meaning of effective collision? Antqra berihtt, yang manakah mererangkan maksud perlanggaran berkesan?
A B C D l0
The coltision where its energy is less than the activation energJ yang mempwryai tenaga kurang daripada tenaga pengalctifan The collision that has a low energy Perlongaranyang mempunyat terurya yang rendah The collision which takes place before a reaction Perlangaranyang berlaka sebelum tindak balas The collision that causes a rcaction Perlanggaran yang menghasilkan tindak balas
P erlanggaran
Which of the homologous series is a saturated hydrocarbon? Antara siri homolog berikat, yang manakah hidrokarbon tepu?
A B C D
Alcohol Alkohol Alkenes Alkena Alkanes Alkana Carboxylic acid Asid ksrbokcilik
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The following information is about the effect of magnesium towards the rusting of iron. MaHumat berikut adalah tentang kesan magnesiarn terhadap pengaralan besi.
Magnesium that is in contact with iron will protect iron from rusting Magnesium yang bersennhan dengan besi aknn melindungi besi daripada berkarol
Which of the following explains the statement? Antara berihut, yang monakah merupakan perrersngan bagi pernyataan itu?
A B C D
Magnesium is softer than iron Magnesium lebih lembut doripada besi Magnesium is a good heat conducfor Magnesium adalah kandufuor luboyang baik Magnesium has a lower melting point Magnesium mempunyai nkat lebur yang lebih rendoh Magnesium is more tendency to release electrons Magnesium lehih cenderzng untuk membebaskon elelaron
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Which statement is correct about exothermic reaction?

P e rny at asn m anakah y utg be t aI me nge nai I i ndak
b a I ac e ks o t e rm
ik ?
A B C D
The reaction absorbs heat from the surrounding Tindah balas menyerap haba dari persekitaran The surrounding temperature decreases Suhu pe rse kitaran rnenarun In this reaction, heat energy is converted to chemical energy Di dalam ttndak balas ini, terwga laba diubah kepada tenaga kimia. llhe products contain less enerry than the reactants Hasil tindok balas mengandungi htrang tewrya daripada bahan tindak balas
13 Which of the following medicines
is an antibiotic?
Anara ubat berikul, yang manakah suatu antibiotiV?
A B C D
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Insulin Insulin Aspirin Aspirin Streptomycin Streptomisin Paracetamol Parasetamol
Diagram 5 shows the change of state of matter. Rajah 5 menunjukkan sata penrbalwn keadaanjirim.
Ice cube .-_-..} Kiub ais
Water
Air
Diagram 5 What is the name of this process? Apakah ruma proses yang terlibafl
A B C D
Sublimation Pemejalwapan
Boiling Pendidilnn
Freezing
Pembehnn Melting Peleburan
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15 firc molecular formula of hexene is CeHrz.

Which of the following has the same empirical formula as hexene? Formula molehtl bagi hekseno adalah Cellrz. Ma*ah antara berifut mempunyaiformula empirikyang sama dengan heksena?
A B C D
CsHro
CsHrz
CeHo
C6FI1a
16 Potassium is situated in the same group as sodium in the Periodic Table.

Which of the following statements is true abut the element potassium? Kalium beroda di dalam htmpulot yang sama dengan ruilrium di dalam Jahsl Berkala. Anlffo pernyalaon berihtt, yangmaru, benar ten angunsur kalium?
A B C D
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Reacts with waler to produce acidic solution Bertindak balas dengan air menglnsilkan lanttan berasid. React with chlorine gas to produce a black solid. Bertirdok balas dengan gas Horin menglnsilkan Fpej al hitam. Potassium has several oxidation numbers. Kal ium me mpunyai be berapa wmbor pengo ksidaan Potassium has low melting point and boiling point. Kalium mempunyai takat lebur don takat didihyang rendah.
Which of the following are the properties of sodium oxide? Antara berihtt , yarg manakah sifu-sifu Mtium oksida?
I ll tII ry
Low melting point Mempwryai takat lebur rendah Insoluble in water Tidak urlarutkmt dalatn air lnsoluble in organic solvent Tidak terlarutlwn dalanr pelarut organik Decomposes to its constituent element by electrolysis in molten stale Terurai kepada unsur juzubtya melalui elektrolisis dalan bentuk leburan
A landll B IandIV C ll and tII D III and IV
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Diagram 6 shows the apparatus set-up for an electrolyic cell. Rajah 6 menunjukkan susundn radas bagi sebuah sel elektrolisis.
Carbon electrode
Elektrod karbon
Carbon electrode Elehrod karbon
Copper(ll) sulphate solution

Laru t an kup ru m(ll)
su
Ifu t
Diagram 6 Which of the following ions are atkacted to anods and cathode? Yang manakah antara ion-ion berilut tertarilc ke anod dan karcd Anode Anod
Cathode
c
D
SOa'Cu2*
Kolod Cu'
OH
SO,'-. 0H-
lu'-.
Cu'-, FlSO4'-, OH-
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Which ofthe following is not a chemical properfy of acids? Antarayang berilcut, yang manakah bu*an sifat kimia bagi asid?
A B C D
Reacts with magnesium carbonate to produce salt, water and carbon dioxide Bertindak balas dengan magrresium karbonat untuk menghasilkan garern, air dan karbon dioksida Reacts with copper metal to produce salt and hydrogen gas Bertindak balas dengan logam kupram untuk menghasillean garam dan hidrogen Reacts with zinc oxide to ploduce salt and water Bertindalc balas &ngan zink oksido antuh menghasilkan garam dan air Reacts with alkali to produce salt and water Bertindak balas dengan alkali untuk menghasilkan garam dan air
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The following information shows the properties of salt X. MaHumat berikut menu4iukkan s@-sifct goramX.
Releases brown gas and a gas which tights up glowing splinter when heated
strongly
Membebasksn gos perang dipanaskan dengan lant
dot
gas
ytmg menyalakan kayu uji berbara apabila
is hot and yellow when it is cold Baki yang berwarna perang semasa panos dan hming semasa seiuk
Residue after heating is brown when
it
What is salt X? Apakah garomX?
A B C D
Zinc nitrate Zink nitrat Zinc carbonate Zink karbonat Lead(II) nitrate Plumbum(Il) nitrat Lead (II)carbonate Plumbum(ll) karbonat
2t Diagram
7 shows the arrangement$ of atoms in three substances. RajahT menuniukkan susunun otorn-alom dalam tigaienis bahan-
Diagram 7 Arrange the substances from the most ductile to the least ductileSus un b afran- b ahan te rs e but dari paling mulur ke karang mulw.
A B c D
P,R,Q Q,P,R Q,R,P
&P,Q
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22 The following equation
shows the reaction between calcium carbonate, CaCO: and hydrochloric acid" HCl. Persomaan berikul menunjukkon tindak balas antarq serbuk kalsium karbonal, CaCOr dan a.sid hidroHorik, HCl.
CaCOn'y
ZHCl1"qy
CaClqay +COz@
HzQu
Which of the following is the suitable method to determine the rate of rcaction? Antara yang berikut, yang nanakah merupakan lraedah yang sesuai urduk meneuuksn kadar tindak bslas?
A B C D
23
Change in the temperature of the solution with time Perubahan suhu larutan dengan masa Change in the volume ofcarbon dioxide gas with time Perubahan isipadu gas lmrbon dioksida dengan masa Change in the mass of water with time Perubahon jisim air dengan masa Change in the concrntration ofhydrochloric acid with time Perubahan kepekaton asid hidroHorik dengan rnasa
Alkane can bs produced from the hydrogenation of alkene. Name the catalyst used in this reaction. Alkana dapat dihasitkan daripado tindak balas penghidrogenan alkerw Narnakan mangfrinyang digunakan di dalam tindak balan ini.
A B C D
Nickel Niksl
Phosphoric acid
Asidfosforik
Sulphuric acid Asid sulfurik
Aluminium oxide Aluminium oksido
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Antora berilat yang nstahah
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24 Which of the following are oxidisingagents?

agen pengoksidaon?
I il til ry
Magnesium Magnesium
Chlorine water
Air Horin
Potassium iodide solution Larutan kalium iodida Acidified potassium manganat{Vll) solution Larutan kalium msngg@at (WI) berasid
A I and II only B lI and IV only C I,II and III only D I, II and IV only
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The following equation shows the reaction between silver nitrate solution , AgNO3 and sodium chloride solution, NaCl. Persamaan berihat mew4iuF,kan tindak bala.t antara lat*an argentum nitrd, AgNO3 dan larutan rwriun Horida,NaCl AB],rOr (aq)
NaCl
(aq) -.+ AgCl
(s) +
NaNQ
(aq) AH:-
80.64 kJ mol-3
Which ofthe following is true ebout thc heat change and type ofreaction for&e chemical equation? Antara berilad yang monakoh beno nengenai perubahan lwba danjenis tindok balas bagi Wrsamcum kimia ini ?
Heat change Type of reaction Jenis tinda* balas
Perubahsthaba
c
D
Heat is released Haba dibebaslwn Heat is released Haba dibebaskmr Heat is absorbed Haba disero Heat is absorH Haba diseran
Endothermic Exothermic Exothermic Endothermic
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Which quation rcpresents a rcaction of saponification? Persam.aan manakah tnewakili tindak balas saponifrkasi ?
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Acid + Alkali -+ salt + wster
Alcohol + Carbo:rylic acid ---r ester + water Alkolwl + Asid kobsilih+ ester * air Fats + Alkali -' Fatty acid salt + Glycerol Lemak + Alkoli 4 garcm, asid lemak + gliserol Yeast + Glucose -'-r alcohol + carbon dioxide Yis + Glukosa + alkolpl + kabon dioksida [Lihatsebelah STJLIT
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in four different elements. the of particles. The letter used is not the asatral symbol Jadual I merunjuk*antwmbor prolon dan bilangan elekron dolam empat zarah. Hunrf yang digurukan bakan simbol yang sebens. Tablc
Element Unsur
P
I shows the proton number and the number of electrons
Proton number Nombor oroton
Number of electron Bilansan elebron
t7
t7
t7
a
R
l8
t0
t2
8
I
Table I
Which is an anion? Yang manakah suatu qion?
AP
Ba
CR DS
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Which substance contains the same number of atoms as in 12 g ofcarbon? : [Relative atomic mlss: He = 4, C = l2,O = l6n lfr/rg= 24, Al 27, I mole ofany
gas occupies 24 dm3 at room conditionJ
Balnn moukah mengandangi biloryan atam yang sama dengan *24, Al=27| lJisim atomrelatif: He = 4, C: l2,A - 16, Mg
12
g karbon?
A B C D
24
24
dm3
dmi
of helium gas gas lretium
12 g of magnesium 12 gmagnesium
16gofoxygen 16 goksigen
54 g ofaluminium 54 galuminiurn
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Proton number of element Zis}}.Element T has the same chemical property as element Z. Which of the following is the electron arrangement for atom Nombor proton unsur Z ialah 20. Unsur T mempunyai sifat kimia yang sama dengan iû, Z. Manakah ontdro beribtt adalah susunan elektron bagi atomT ?
fi
A2 B 2.8 c 2.8.2
D
2.8.8
30 Diagram I show the electron arrengement of elements X and Y.

Rajah
8 di
bawah memmiukkan Ewutl(m elektron bagi unsur
x dany.
Diagram 8
Which of the fiollowing is true about the formula and type of bond formed by elements X and Y? Antara berilrut yeng msnkah benar mengenai formula danienis ikatm yang terbenUk &ltara unsurXdanY ?
Formulae Type ofbond Jenis ikatan
Formula
A
B
XY,
XzY
lonic Ionic
Covalent
Covalent
c
D
XY
XYz
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Diagram 9 shows the apparatus set-up used to elechoplate iron spoon with silver. Rajah 9 menunjukkan susunan radas untuk menyadur sudu besi dengan orgentum.
Iron spoon
Sudu besi
Silver ptrate
Plat argentum
Diagram 9
Silver nitrate solution Ltutqn argentum nitral
What is observed at the anode and cathode after 30 minutes? Apakah pemerlwtian di anod dan di tatad selepas 30 minit? Anode Anod Silver plate becomes thinner Plat arsentum semakin niois Silvery deposit formed Mendakon berw arna perak terbentuk plate becomes thinner Silver Plat arsentum semakin nipis Gas bubbles released Gelembuns sas terbebas
Cathode
A
B
Katod Silvery deposit fonned Mendakan berwarna perak terbewuk Gas bubbles released Gelembung gas terbebas
Cas bubbles released Gelembuns sas terbebas Gas bubbles released Gelembuns. src terbebos
C D
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Alkali Y of concentration I mol dm-3 has a pH of 8. Which statement is true abut alkali Y? Atkati Y dengan kepekatan I mol dm'3 m empunyai pH 8.
Pernyataan manahah yang benar tentong alkali Y2
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A
B
lnsoluble in water
Tidsklsut dalamair Reacs with a weak acid

Bertindak balas dengan asid lemah The degree of ionisation in water is higlr Darjah pengionan dalam air adalah tinggi Has a low concentralion of hydroxide ions Mempurzyai kepfutan ion hi&oksidayang rendoh
c
D
I and II II and III I and tV II and IV
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l0 shows some reastion of zinc compounds. Which changes is made by adding an acid? Rajah lA menwjukkan sebahogian tirdak balas ymg melibatkan sebatian zink Antara perubahan lersebut yang manakah berlafu dengat penanbahan asid 2 '
Zinc carbonate
Zink karbonat
Zinc sulphate Zink sulfat
Zinc oxide
Zink oksida
)--.
Zinc
Zink
Diagram 10
34 The fcllowing equation is a reaction to prepare a synthethic

Ammonia
fertilissr, Z. Persamasn beriktt adatah tindakbslas untuk menyediafum baja sintelih Z.
+Y +
Which ofthe following is Y? Manakah antara berikut adalahY?
A B C D
Urea
Urea
Nitric acid Asid nitric

Ammonium nitrate Ammonium nitat Ammonium hydroxide Ammonium hidroksida
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In an experiment,25 cm3 of 0.2 mol dm-3 hydrogen peroxide solution decomposes to produce oxygen gas. Graph of volume of oxygen gas against time is sketched and curve R is obtained as shown in Diagram I I Dalam satu eksperimen, 25 cm3 0.2 mol dm'3 larutan hidrogm peroluida terurai menghasilkan gos olcsigen. Graf isipadu gas oksigen melmsan masa dilakarkan dan lenglangR terhasil seperti ditunjukkan dalarn Rajah
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Volume of oxygen gaV cm3 kipadu gas oksigen / cm3
Time/
Masal
s
s
Diagram I I Which ofthe following solution will produce curve S? herika okan menghasilkan lengkung S?
20 cm3 0.1 mol dm-3 hydrogen peroxide 20 cm3 0.1 mol dm-3 hidragen peroksida 30 cm3 0.2 mol drn-3 hydrogen peroxide 30 cm3 0.2 mol dm'3 hidrogen peroksida
cm3 0.3 mol dm-3 hydrogen peroxide 20 cm3 0.3 mol dm-3 hidrogen peroksida
Yang manakah di antara larutan
A B c D
20
l0 lo
cm3 0.3 mol dmj hydrogen peroxide cm3 0.3 mol dm-3 hidrogen peroksida
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Ester is a carbon compound that can be derived from the reaction between alcohol and carboxylic acid. Diagram 12 shows the structure of an ester. Ester ialah satu sebatior karbon yang diterbitkan dtrii;da tindak balas antara alkphol dan asid karholsilik. Rajah 12 menunjukkan struktur suatu ester.
o
CHr-CHz-C-O-CHg
Diagnm
12
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Which of the alcohol and carboxylic acid used to form the ester? Yang manakah allcohal dan asid karboksilik yang digunolmn bagi membentuk ester inr2
A
B
Alcohol Alcohol Methanol Metanol

Ethanol
Etanal
c
D
Ethanol
Etarai
Methanol Metanal
Carboxylic Acid Asid korbosilik Ethanoic Acid Asid etanoik Ethanoic acid Asid Etonoik Propanoic acid Asid Propanoik Propanoic acid Asid Propanoik
37
Diagram 13 shows the set up of the apparatus of a simple chemical cell. Rajoh 13 menunjukkan susurwn radas bogi sotu sel kimia ringkas.
Zinc plate PIat zink
Silver plare Plat argentum Silver nitrate solution Lorutan argentum nitral Diagram
13
Which half equations represent rcaction @curs at silver plate? Antara berikut, setengah per.iamctan manakah mewakili tindak balas yong berlaku di kepingan argentum?
A Zn --) Znzn + 2e BAg --+ Ag* +e C Ag*+ e -' D 2H* + 2e ;

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33 Hot packs contain chemicals that react to produce heat.

Which substance is used in hot packs?
Pek parws mengandungi bahan kimia yang bertindah balas untuk membebaskan
haba.
Bahon manakahycng digunakan dalam pek panas?
A B
c
Sodium carbonate
Natium karbonat
Ammonium nitrate
Ammonium nitrat Magnesium sulphate Magnesiumsulfut
Calsium carbonate Kalsium ksrbonat
39
Which of the following is aot true about soap? Antarc yang berikut, yang manakah ldok benar tentang sabun?
A B C D
Soap forms when fats react with an alkali Sabun terbentuk apabila lemak bertindak balas dengan Soap forms scum in soft water Sabun membentuk kekat dengan air lembul
alkoli
Scum decreases the effectiveness of the cleansing action of a soap Kekat mengarangkan keberkcsanon tindakan peneucian sahun The presence of magnesium ions and calcium ions in soap forms scums Kehadiran ion magrcsium dan ion kalsium dalam sabun menghasilkan kekat
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Table 2 shows the subatomic particles of P and Q. Jadual2 menu4jukhan zarah-zarah subatom bagi P danQ Neutron
P 6
5
Proton
5
5
a
It shows that P and Q Ini menunjuk*an? danQ
Table2
I II Iil IV A B C D 4l
are both positively charged
acblah bercas po,ritif have the same nusleon number mempunyai nombor rruHeonyang sama have the same number of elechons mempunyai bilangan elektran yang sama are particles of the same elements adalah unsur yang sama
I and II only II and III only II and lV only III and IV only
The following equation shows the reaction between magnesium and hydrochloric acid. Persamaan berikut menunjukkan tindak balas antara magnesium fun asid hidroHorilc
M&rl +
2HCl tuql )
MgCl2("ol
HzGl
What is the volume of hydrogetr gff, H2 prroduced if 0.05 mol of hydrochloric acid rpact with excess magnesium ribbon at standard temperature and pressurc (srP)? :22.4 dm3mol-r] [Molar volume of gas at STP Apakah isipadu gas hidrogen,H2 yang terhasil jika 0.05 mol asid hidroHorik bertindakbalas dengan pita magnesium berlebilnn pada suha dan tekanqt piawai (STP)? lMolar volune of gas at STP :22.4 dm3 mol-r]
A B C D
56 cm3 60 cm3
l12cm3
120 cm3
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2l X is used in airships and weather balloons X is

because of its low density.
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Gas Gas
Gas X diganakan dala n kapal udara dan belon kajicuaca disebabkan ketumpatannya yang rendah. Gas Xadalah
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Helium Neon Argon Krypton
The following equation shows the formation of magnesium oxide. Persamaan berikut men unj ukkan pem bentukan magnesi um oksida.
2Mg
Apakah jisim formula
'1Oz
2MgO
What is the relative formula mass ofthe compound, magnesium oxide? relatd bagi sebatiut magnesium oksida tersebut ? atomic mass : Mg=24; O :16] [Relative
D16
U
Table 3 shows information about two voltaic cells. Jadual 3 memmjufr*an maHumat tentang dua sel kimia .
Pairs of metal Pasangan logom Q and Copper Potential difference / V
Beza keupoyaan/Y
832 c24
Â. 4A
Negative terminal
Terminol negatif
Qdan Kuprum
R and Copper
t.7a
0.53
a
Cu
Rdan Kuprum
Table 3 What is the potential diflbrence between metal Q and R?

Apafra], bezo kcupayaan di urtara logatn Q danR?
A B
0.97 V
2.t4Y
2.23 V
2.67
c D
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22
4$4t/t
The equation shows the reaction between sulphuric acid and potassium hydroxide. Persanaan di bawah menunjuft:lcon tindafi:balas antara asid sulfurik dan kalium hidroksida.
HISO* + 2KOH -'* trGSOr + 2I12O

What is the volume of 0.1 mol dmi potassium hydroxide solution which can neutralise 20.0 cm3 of 0.1 mol dm-3 sulphuric acid? Berqakah isipadu larutan kalium hidroksida 0.i mol dm'3 yang diperlakan unnk meneutralkar 20.0 cm3 0.1 mol dn-3 asid sutfurik'l
A B C D
46
10.0 cm3
20.0 cm3 40.0 cm3 80.0 cm3
The following equation shows a double decomposition reaction.

Persamaan berikut menunjuk*an tindak balas pengwaian ganda dua.
Pb{NO3)2 +
2KI --' PbI2 + 2KNO3
The ionic equation for this reaction is Personaan ion untuk tindak balas ini adalah
A Pb 2* + l- --+ PbI: B Pb2* + 2l' -' Pblz C K** +NOr'---'KNO: D 2K + No3- --* 2KNor
47 A compound FeXs is formed from the reaction between
0.1 mol of iron and 10.65 g of element X. What is the relative atomic mass of element X? [Relative atomic mass : Fe:56] Suau sebaticm FeX3 terbentuk dori tindakbalas antara 0.1mol besi dengan 1A.65 g
unsur
Apakahjisim atom relatf bagi unsurX? frJisim atom relatif : Fe = 56J
c D
A B
35.5
35.0
32.5
32.A
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48
Table 3 shows the total volume of gas collected at regular intervals in a reaction. Jadud 3 menuniukkan jumlah isipadu gas yang dikumpul pada sela masayang sekata dalam suatu tindak balas.
Time/ s Masa/ s Total volume ofgaV cm' Jamlah isipadu gas/ cm3
0 0
30 2.A
60 3.7
90
t2a
6.4
r50
7.3
180
zta
8.5
<)
8.6
Table 3 What is the average rate of reaction in the second minute? Berapakah kadar tindak balas purata dalmn minit kedudl
A B C D
0.040 cm3s-' 0.045 cm's-t 0.053 cm3s-r
0.O62cm's-r
49 A glass of wine becomes acidic if it is left in the air in certain time.

Which of the following equation reprcsents these changes? wain bertukar menjadi berasid apabila ditinggalkan untilk beherapa kettka Antra persamaan berikat yang manakah mewabli perubalun infl
Segelas
A 2C:HsOH + 2COz ---+ B CzllsOH + 3Q C CzHsOH + Oz --------) D CzHsOH + CO ------|
2CzHsCOOH
ZCAz
02
3HzO
CHICOOH
CzHsCOOH
HzO
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24
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50
Diagram 15 shows the apparatus set-up to investigate a redox reaction. Rajah 15 menunjukkot su;uwu radas untukmengkaji satu tindakbalas redoks.
gradute elactrode
elck*td karbon
X soLd:n Iarlatart]{
Dilute su$hric acid
U- tube
nub U
Asrd
su{ur* catr
Diagram
15
The colourless potassium iodide solution becomes a brown solution. Which of the following is X solution? Larutan kalium idida tanpa wama menjadi loutan perang. Antara berikut, yangmanakah larutanX?
A
B
Chlorine water Air klorin
Iron(II) sulphate Ferum(ll) sulfar

Hydrogen sulphide
Hidrogen sulJida
Sodium chloride
Natrium Horida
QUESTTONS END FIERE
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PROGRAM PENINGKATAN PRESTASI AKADEMIK SPM TAHUN 2012 PERATURAN PEMARKAHAN
CHEMISTRY
PAPER Paper 1 Paper 2 Paper 3 Total MARKS 50 100 50 200
Jumlah markah diskalakan kepada 100%

CHEMISTRY Paper 1 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 B C D A B B B A D C D D C D A D D C B C A B A B B
A = 12 ; B = 13 ;
26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50
C = 12 ;
C B A C D A D D B D D C C B D A A A C C B A B C A
D = 13
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Nama:
Tingkatan:
PROGRAM PENINGKATAN PRESTASI AKADEMIK SPM
CHEMISTRY
Paper 2
Two hours and thirty minutes
JANGAN BUI(A KERTAS SOATAN INI SEHINGGA DIBERITAHU
1.
Kertas soalan ini adalah dalam dwibahasa. Soalan dalam Eahasa lnggeris mendahului soalan yang sepadan dalam Bahasa
2.
Untuk Kegunaan Pemeriksa Markah Markah Bahagian Soalan Penuh Dioeroleh

1
Melayu.
Calon dibenarkan menjawab keseluruhan atau sebahagian soalan sama ada dalam Bahasa lnggeris atau Bahasa Melayu.
10 10 10
2 3 A
4
5 6 7
B
10
10 10
4.
Calon dikehendaki membaca maklumat di halaman belakang kertas soalan ini.
20 20 20 20
8 9
c
10 Jumlah Kertas soalan inimengandungi
27 halaman bercetak
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INFORJ}'ATION FOR CA}I DI DATES MAKLUMAT UNTUKCALON
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l. 2.
This question paper consists of three sections: Sections A, B and C. Kertas soalan tni mengandmgi tiga bahagian: Bohaglan A,B dan C. Answer all guestions in Section ,A,. Write your answers for Section A in the spaces provided in the question paper. Jaw ab semua soalan dalam Bahagian A. Tul iskan j aw apan 6agz Sahegi an A da lam rucng yang disediakan dalam kertas soalan Answer one question from Section B and one question *om Section C. Write your answers for Section B and Section C on the 'writing paper' providd by the
3.
invigilaton.
Answer questions in Section B and Section C in detail. You may use equations, diagrams, tables, graphs and other suitable methods to explain your answer. Jswab sttu soalan daripada Bahagian B dan satu soslan dcripda Bahagian C. Tuliskan juwapan bagi Bahagian B dan Br.hagitn C pada haloman bergaris di bahagian akhir kertas soalan ini. Jawob Bahagian BdanBlthrgianC dengon terperinci. Anda boleh menggunakan perserrnean, gambar rqiah, jadual, grof dan cara lain yang sesuni untuk menjelasktn jawapan anda
4-
Show your working. It may help you to get marks. Tunjull<an kerja mengira.Ini membantu anda mendapatkan markah.
5. 6. 7. B.
If you wish to change your answer, neatly cross out the answer that you have done.
write down the newanswer.
Sekiranya anda hendak membatalkon sesuatu jswapan, buat garisan
T?ren
di
atas jawapan itu.
The diagrams in the questions ar not drawn to scale unless stated. Rajah yang mengiringi soalcn tidak diluhisksn mengikut skala kecaali dinyatakan
Marks allocated for each question or part question are shown in hackets. Markah yang dipenmakkan bagi setiap soalan atau cetaian saalan ditunjui*an dalam kurungan
The time suggested to answer Section A is 90 minutesn Section B is 30 minutes and Section C is 30 minutes. Masa yang dicadangkan untuk menjawcb Bahagian L ialah 90 minit, Bahagien B ialah 3O minit &tn Bahagian C ialah 30 minir
9.
You may use a non-programmable scientific calculalor Anda dibenarkan mengunakan kalkulator saintifkyang tidak baleh diprogramkan.
10. Hand in your answer sheets a the end of the examination. Serahkan semuo kertas jawapan anda di akhir peperikaan
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16A marksl Answer all'questions in tlris section
Jowob sernufr soalan dalam hahagian ini.
Figure I show the electron arrangetnent of three atoms of elernents P, Q and R Rajah I menunjuk*an susunan eleloron bagi tiga atom unsw P,Qdan R
Figure I
(a)
Write the electron &rangement for the atoms of element R.

Tuliskan susunctn elektron bagi atom unsur R.
{l
(b) Identify the position of element Q Kenol pasti kedudukan unsur Q.
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{l
mark}
(c)
(i)
Which element is chemically inert? Unsur yang manakah lengai dari segi kimia?
ll
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(ii)
Give one reason for the answer in c (i) Beri satu sebab bagi jawapan di c (i)
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(d)
Element Q dissolves in waterto form an acid and a strCIng bleaching agent. Write the chemical formulae of the bleaching agent. (Insur Q larut dalam air untuk membentuk satu asid dan satu agen pelwnr yang huu. Tuliskan formula kinia bagi ogen pelunhr ltu.
U markj
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(e)
Another element S has a proton number of 9. V/hich element shows similar chemical properties to element S? Uwur Inin, S mempunyai nombor proton9. Unsw yang manakah menunjuldran sifat kimia yang scna dengan unsur
S7
mark\
(g (i)
Which element. react vigorously with water?

Urcur yong manoftah benindak balas dengan cergcw dengan air?
$ nar*l
(ii)
Based on the answer in

Berdasarlcon jawapan
(i) ,write the chemical equation for the reaction" di fii) ,tulislnn perscrrflaan Hmia bagi tindak balas itu.
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(g)
Arrange the atomic size ofelements P, Q and R starting from the smallest. Sustmkon saiz atom unsur P,Q den R bermula daripada yang paling kecil-
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t Diagram 2 shows an experiment !o dctermine the empirical formula of copper (It) oxide. Rajah 2 menunjulr.kan satu ekperimen antuk menmtr*anfornula empirik kuprum(ll\ obida.
Combustion tube
Tabung pembakaran
Coppe(Il) oxide Kupnn(II) oksida

'Hydrogen flame
Nyalaan hidrogen
Dry hydrogen gas \ Gas hidrogen kering-
Heat
Ponaskon
Diagram 2
(a)
What is meant by empirical formula?

Apakah yang dimoksttdlcan dengot formula empiri k 2
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(b)
Before copper(Il) oxide powder is heate{ dry hydnrgen gas is flowed through the combustion tub for a while. Why? Sebelum serbuk hpram(ll) okida dipouskan, gas hidrogen kering dialirlcan melalut tiub pembakoran seloma beboapa ketiha. Mengapa?
ll
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(c)
State the observation that happens to copper(Il) oxide after heating.

Nyatukan pemerhaticn
lang berlahu kepada kuprun(Il) akida
selepas pemanosun.
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Table 2 shows the result obtained in tfte experiment: Jadaat 2 menunjrkkan keputusan yang diperolehi dalam eksperimen di atos
Mass of combustion tube + asbestos paper Jisim tiub pembakaran * kertas asbestos Mass of combustion tube + asbestcs paper + coppe(ll) oxide
Jisim tiab nembalcaren + kertas asbestos+ fuprw(ll\ olsida Mass of cornbustion tub + asbestos paper + copper Jisim tiub oembakaran + kertas asbestos* kuprwn
58.36 g 91.95 g 85.2a g
(i)
Table 2 Based on Table 2, Berdosarkan Jadual 2, Calculate the mass of coppr and the mass of oxygen that have reacted. Hitungkan jisim kuprum dan jisim oksigen yang telah bertindak balas. Mass of copper
Jisim kuprum: Mass of oxygen Jisim oksigen:
:
:
Ll markl
(ii)
Calculate the ratio of moles of coppr atoms to oxygsn atoms.
Hitungktn nisbah mol bagi atom kuprum kepada atom oksigen. I Relative atomic mass /Jisim atam relatd:0 = 16 ; Cu:64 ]
(iii)
12 marks]
Determine the empirical formula of copper (II) oxide.

Tentuksnformula empirift kuprum (Il) oksida-
fl narkl
(iv)
Write the chemical equation for the reaction in the experiment. Tulis persamaan bimia bagi tindakbalas dalau eksperimen tersebut'
[2 narksl
(v)
This method is not suitable to determine the empirical formula of magnesium oxide.
whv?
Kaedoh ini tidak sesusi untwk menentukanformula empirik bagi magnesium olcsida.
Kenapa?
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p and respectively' are industrial processes to manufrcture sulphuric acid and ammonia in Sufptrgic acid and ammonia are usd to manufacture ammonium sulphate as shown
Diagram 3.1 p ian Q adalah proses-proses indttspi untuk menghasilkan asid salfwik don anmonia maslng' ammcnium sulfat seperti dala*t masiing.)"sid sutfurik ioi *rirni" digwahan rmtik mengftasilkan Rajah3.l
Reaction R
Tinda*balasR
Ammonium sulPhate
Ammonium
sulf*
(NH4hSO4
Diasram 3.1 Name

(a)
Namakan
(i)
Process P:
Proses P
{ii}
Process Q
Proses Q
12 marksl
{b)
State one raw material needed for procsss Q? Nyvtakon satu bahan mennh yang dtperlukan mtuk proses Q?
U nork]
(c)
(i)
Write a balanced chemical equation for reaction R
Tulis persamaan Hmia yang seimbang bagi tindak balas R
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(i
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i)
State one use of ammonium sulphate Nyatakan satu kegunaan ammonium sulfat
(iii)
Calculate the percentage of nitrogen by mass in ammonium sulphate

Hi tung pe ratus nitrogen mengikut j is im bagi amnonium sulfat.
ll
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I Relative atomic mass / Jisim stom relatif: N
14 ; O
16; S = 32; H
=I
f 2 nartcl
(d) Diagram 3.2 shows the structuralformula of the polymer polyvinyl chloride Rajah 32 menunjuk*anformula struktur bagi polimer polivinil Horida
HCI
C
I I
Diagram 3.2 Draw the structural formula for its monorner LuVsformula struhur bagi monomer polimer tersebut
I I nark]
{e) The use of synthetic polyrners extensively in our daily life has become an issue
of environmental pol lution. Penggunaan poliwer sintetik secara berlebihan didalom kehidupan seharian telah menjadi isu kepada pencemaran alam sekitar.
Give one method to overcome this problem. Berikan salu kaedah untuk mengatasi masalah ini
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Diagram 4.I and 4.2 shows a set up apparatus to investigate the role of water for acid to show its acidic properties. Rojah 4.1 ond 4.2 menunjukkan radas wuk menglaji peranan air untuk asid menuniukJan sdat
keasidannya.
Dry hydrogen chloride gas Gas hidrogen Horida kcrW

Methylbenzene
Metilbewena
Diagram
4.1
Dry hydrogen chloride gas Gas hidrogen Horida kcring
Water
Air
Diagram 4.2
(a)
Write the chemical formula of hydrogen chloride Tulisformula kimia hagi hidrogen Horida
ll
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(b) (i)
Dry hydrogen chloride gas is bubbled in methylbernene for 5 minutes as shown in Diagram 4.1, then tssted with a piece of blue litrnus papr. State the observation. Gas hidrogen Horida kertng dialirkan masuk dalam metilbewena selama 5 minit seperti yang ditunjuW@n dalam Rnjah 4.1, kemudian diuji dengan sekeping kertas
Iitmus
b
iru.
Nyatakan pemerhatian.
ll
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(ii)
Jelaskan jawapan anda
Explain your answer in b(i) dalamVi)
{2 marksl
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(c)
Diagram 4.2 shows dry hydrrrgen chloride gas bubbled into water for 5 minutes. The solution is then divided into two parts, Part I and Parf II. Table 4 shows the observations of the two tests conducted on the two parts. Rajah 4.2 menunjukkan gas hidrogen Horida kering dialirtan masuk dalam air selama 5 minit . Larutan itu dibahagikan lepada dua bahagian, Bahogianl dan Bahoglaull.
Jadual 4 mentnjulckan pemerhatian bagi dua ujian yang dijalankan ke atas duo bahagian ita.
Part
Bahagian
Test
Ujian
Obseivation
Pemcrhorian
Add magnesium carbonate. Testgas given off with lime water

Tambahkon
m agn e s
Effervescence
Pembuakan
i*n
karbonat.
Uji gas yang terbebas dengon air kapw
Lime water turns chalky Air kapur menjadi luruh
II
Add magnesium ribbon. Test gas given offby pufting in lighted wooden spl inter
Tambahkan pit a ma gn es i wn. Uji gas terhasil dengan memasukkan Irayuuji menyala
(i)
Table 4 State the role of water that caused the produced gas turns lime water chalky. Nyatakan peranan air yang menyebabkan penghasilan gas yang menukarkan air kapur menjadi keruh.
mar*l
(ii)
Write an ionic equation to the reprsnt the production of gas in Part

Tulis persamaan ion unuk mewakili penghasilan gas dalam Bahagian
I
nnks]
12
(iii) (iv)
Complete the observations in Table 4. Lengkapkan pemerhatian dalom Jadual 4
[2 marksl
What is the conclusion drawn from the observation in both part? Apakah kesimpulan yong boleh dibuat daripada pemerhatian dalom keduoduo bahagian.2
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Diagram 5 shows the flow chart for dte reaction of propan-l-ol. Rajah 5 menunjukkan carta alir bagi tindak balas propan-l- ol . Reaction
SULIT
Tindak balorl Compound X

Sebatian
tll H-C-C-C-OH
HHH
Reaction
Tindalc
II
Compound Y SebatianY
balasll
alumina
Heated
Panaskan
trl HHII
-------------*
KMnOt
berasid
Acidified KMnOe
Propan-l-ol
Reaction III l+ CH3COOH findakbala-sfit + HzSOa f

Compound Z
Sebatian
Diagrarn 5
(a) State the molecular
formula of propan-l-ol. Nyatakanforrmrla molehi bagi propan-l- ol.
U ma*l
(b) The following
equation shows complete combustion of propan-l-ol. Persamaan berilat memrnjuklmn pembakarorc lengkap propan-l -ol.
C3H7OH + 9O2 -*+ 3COz + 4H2O

2
Calculate the volurne ofcarbon dioxide gas produced
if
0.1 mol of propan-l-ol is bumt
completely in air.
Ilinmgkan isipadu gas karbon dioksida yang terhasil jika A.l mol propan-l-al dibakar dengan
Iengkap dalam udara.
[Molar volume :24
dm3
mol-l at room condition]
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(c)
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Compound X is an unsaturatcd hydrocarbon. SebatianX adalah hidrokarbon tery.
(i)
What is the meaning of hydrocarbon?

Apakah yang dimaksudkm dengan hidrokarbon?
ll nmkJ
(ii)
Complete the following diagram to collect compound X in reaction I.

Lengkapkan rajah berihtt unluk mengutip sebatian X dalam ttudak balas
l.
hopan-l-ol
soaked
with glass wool
Alumina
warrn
(d) hopan-lol
12 marksJ
is addsd with acidified potassium marganate
(VIt) solution and heated in
reaction II. Propn-l- oI
ditambahhan dengan larutan kaliun mangout (Yl7) berasid dan dipanaskan dalan
tindak balas lL
(i)
What is the name of reaction II? Apakah nans tindak bolas ll?
(ii)
Name compound Y.
Namakan sebatian Y.
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(e) Compound Zhas the following properties:

SebatUn Z mempnyai stfat-stfat beri*at :
o r (i)
Float on water Terapwg otas oir
Fruity smell
Yangi bwh-buahan
Draw the sfuctural formula of oompound Z. L*is formula smrkur bagi sebatian Z.
(ii)
Concer*rated sulphuric acid is added in reaction lll. Explain why? Asid sulfurik pelcat ditambah dalmt tindak balas lll .
Teranglan mengapa?
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6 (a)
rection between Jdual
Table 6 shows the result ofan experimcnt to study the cffet oftemperafure on the rate 50 cm3 1.0 mol dm-3hydrochloric acid solution, HCI and 50 cm3 0.2 mol dm-3 sodium thiozulphate soluticiq NazSzOr.
of
6 memmjuk*an kepr.hrsan bagi satu elrspeimen unn* menglraji kesan guhu kcatas kadar 50 cm3 1.0 mol dmo t*uton asid sulfarih HzSOr dan 5A enf 0.2 mol &n'3 tindakbalas
*i*o
lorutan natlium tiosulfat, NazSzQ.
TemperaturefC SuhufC Timc taken for'X' mark to disappear fronr sight Masa tanda X' hilansdari pandoutt
Table 6
30
94.8
35 49.9
40
36.1
45
50
19.8
25.2
(a)
Balanced the ctremical equmion below for the reaction that occurs in this erperimenL &imbangk*t percomaail kimia dibov,ah bagi tindakbalas yang berlaht dqlan ekprimen ini.
mHCl+Na2S2O3t nNaCl+HzO + Soz+

m=
TI:
{2
narksl
(b)
Draw the set-up of apparatus used to measure the time taken for 'X' mark to disappear from sight. Lakis*an susunan radas yng digwakan untuk mengalatr maso tanda'X' hilang dti
Q marksl
(c)
Name the substance that is responsible for'X' mark to disappear from sight. Nama*mt bahan yvng menyebablcan tanda X' hilang dari pandangan-
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(d)
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'Flot a graph of temperature against time taken for'X' mark to disappear from sight. Iâkarkan graf suhu melasan masa tando'X' hilotg doi padmgan
14
mc:ksl
(e) Based on the graph in (d), sbte the relationship between temperature and time.
Berdasarkon
graf pada (d), nyatakm hubwgan qntara $rtu dan masa.
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Section B Answer any one question. Javtab m(rnt -rnsna sala soolan.
[20 rzr:ksl
Table 7 shows the proton numberofatom P, Q, Rand S. The letters used do not represent the actual symbols of the atoms. Jadual T mmwJulikan nombor proton untuk atom P, Q, R dcr S. Hun{yng diganakan tidak mewakili simbol sebens atom berkenaan.
Atom
P
Atom
Proton Number Nombor proton
a
12
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Table 7
{a) ,
Write the electron arrangement for the atom of element Q Determine the group for element Q Talis susunan elekron bagi atom rrrrrQ. Tentufun funpulan untuk msw Q.
pnarksl
O) (i) (ii)
7, sel*t two differpnt elemen8 that can form ionic compound. Berdasarkan Jaduol T, pilih dua unsur Malnan yang akan membentuk sebation ion.
Basd on Table
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Draw a diagram to show the compound tlrat will be formed in 7(b) (i) Lulris rajah untuk menunjul*an sebatiot yang terbentulc di 7(b) (i)
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(c)
Diagrarn 7 shows the molecule of carbon dioxide. The bond formed between carbon atom and oxygen atom are double covalent bond. Rajah 7 menunjuk*an molekul karbon dlokida. Ikatanyang terbentuk antara atom Iurbon dan atom olsigen ialah ilcatan kovalen ganda dua.
Dagram 7
Explain the formation of this compouod in terms of o Electron arrangement r Electrons involved o Particles involvod [Proton number :C:6, O: 8 J
Terangkan tentang pembmwkan sebatian ini dari segi: Susunan elehron
:
t o
Elektron yang terlibat
Zaroh-zorahyangterlibat.
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(d)
Compare the physical propcrties benpeen ionic compound and covalent compound. Your answer should consist of the following : Physical properties in roorn conditions
o o o r o
Melting point and boiling point Electricalconductivity Solubility in water and organic solvent Example ofcompound
Bandingkan sifat*ifutfizikal di utoa sebatian ion don sebatian kovalen. Dalamjawopan ando, perlu mengan&ngi perkara bertlatt : o Keadaon jirim pada kzadaan bilik" t Taknt lebw dan takst didih t Kekonduksiot elekrik
o o
Keterlanttan dalan air dan sebatian organic

Contoh sebatian
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Diagram 8.1 shows the apparatus set-up for the electrolysis of concentrated copper (II) chloride solution, 0.1 mol dm-' using carbon electrodes. Rajah 8.1 menunjulkan susur'rcm radcn untuk me4jalankan elekrolisis larutan larprum(ll) Hirida t pe kat, 0. l mol dm' me ngunokan ele ldrod-e lektrod knrbon.
concentrated coppe(I I)
chloride solution I arut an hprum{ll).

Wlcat
kl or i da
Carbon electrode X Elel*rod karbonX
Carbon elrctrode Etefuod korbonY
Diagram 8.1
(a)
Based on Diagram 8.1, sbte the factors that determine the products formed at electrode X and elwtode Y. Berdasarkan Rajah 8.1, nyatakanfakor-fahor yang menentufran hasil yang terbennk pada
elebrodXdan elekrodY.
.12,
morksl
(b)
Explain the reactions at electrodes, X and Y. Include the following in your explanation: Terangkan tindak batas pada elektod,X dan Y. Penerangan anda perla m
r r r . o
List the ions atttracted to each of elecfode, X and Y Senaraikan ion-ion yang tertarik ke setiap elekrad, X dan Y Name
of
the ions selectively discharged at each elechode
Nams ian'ian yang dipilih

Sebab ion-ion ini
wuk
dinyahcas di setiap
elekrd
The reason why the ions are selectively discharged
dipilih unuk dinyahcas
Half equations for each reaction

Setengah persomaan bagi setiap tindak balas
The observable changes ofthe solution Perubahan yang diperhatikon pada lanttan
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(c) '
Table I shows the incomplete results of a series ofexperiments carried out to c,onsmrct the electrochemical series of metals. W, X and Y are not the actual symbols of the metals.
Jadwl
W,
mmunjal4ran keputusan yang tidak lenglrap bagi satu siri eksperlmen yang telah
bulcan simbol sebenar logam-Iogam itu.
dijalanlwn antukmembina sin elebrokimia bagi logun.
XdanY
Pairs of metals
Pasangan lagan
Positive terminal
Terminal
Potential difference/ V
Beza keupayaan 3.1
positif
W' Copper
Copper
X,Y
Y X
0.3
wx
X, Copper
t.8
Table 8
(i)
Based on the values ofthe potential differences, arrange the metals in descending order in the elecbochemical series.
Berdasarkan niloi beza keupcyaan, susun logam-logan tersebut dalam tertib menuntn dalam siri elekrokimia.
lt ndf,
(iD
Predict the positive terminal and the value of potential difflerence for the pair metals X and Cu. Explain your answer.
Ramulkan terminal positif dan nilai
Jeloskan jawapan anda.
of
heza
bagf pasangan logom X dan
C*
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(d)
Diagram 8.2 shows a voltaic cell. Metal Q is situated below copper in the e leitroch em i stry series. dalam siri Rajah 8.7 menunjakkan saaru sel voltan. Lagam Q terletak di hawah kuprum
elelctrokimia.
Metal Q
Logam Q
Cu
Solution R LarutqnR
Copper${) nitrate Kaprum(ll) nitrut
Diagram 8.2
State the positive terminal and the negative lerminal ofthis cellm"tal Q and a solution that is suitable as solution Suggest a metal that is suitable
R.
Nyatalan terminal posilif dan tenninal negatif bagi sel ini' iaaanske, togam yani sesaai sebagai ligam Q dan larutan yang sesuai sebagai larutan
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Section C
[2A marks] Answer any one qrsstion.

Jawab masra-mana satu soalan,
Table 9 shows the heat of displacement of hvo diffe,rent metals P and Q with copper (II) sulphate solution. Jadual 9 menrmju?Jran luba penysarm bagi dua logam yong berlainan, P danQ dengan larut ot kuprunt{ll) s u lfat.
Experiment
Reactants Bahan Tlndalcbalas

50 cm" 0.2 rnoldm-'
Heat of Displecement I{*ba Penyesaran (kJ mol-I )

-336
coplxr gl)sulphate solution

+
metal P
50 crr3 0.2 moldm't larutan kupram {11'1sulfut
logamP
II
50 cm'0.2 moldm-' copper{U)sulphate solution metal Q 50 cm3 0.2 rnoldrn-t larutst kuprun (ll) sulfut + logam Q
-217
Table 9
(a)
Based on the information in Table 9,
(i) State one exanple which could be metal P and one ex{rmple which could be metai Q. Berdasarksn maftlunat dalam Ja&*al 9, Nyatalam ssta c{}ntoh ymg mwgkin bagi logrnnP dffi sdu contoh yang mungkin bagi
logamQ.
[2 marksl
(ii) Explain why there is a difference in the values of
the heat of displacement. Jelaskon mengapa terdaryt perbezool nilai lwba penyesran itu.
[4 marksl
O) Calculate the change in temperature
I:litang perubahsn sahu hagi campurcm dalam ehryterimen
of the rnixture in experiment I. og't {Specific heat capacity of solution: 4.2 Jg't ,
l-
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{c)
By using one of the metal in 9 (a) (D, describe one experiment to dstermine the heat of displaceinent. Your answer should consist of the following : o Procedure of the experiment
The method to calculate the heat of displacement
Dengan menggunakan satu daripda logam dalam menentukan hcba perqrcsaran.
(aXi), huraikan saw eksperimen tmtuk
Jawapan anda perlu mengandungi perkara berikut : Prosedur elsperim*t
c o
Kaedah untuk menghittmg haba penyesaron.
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24 (a)
SI]LTT
10
Diagram l0 shows an apparatus set-up, its observation and chemical equation to investigate the displacement of halogen from its halide solution by halogen P. Rajah ft menunjukkan susunan radas , pemerhatian dan prsamaan kimia'untuk mengkaii penyesaran hologen daripada larutsn halidanya oleh halogenP .
larutan
potassium A , P iodide
solution
\ \
kaliumiodida
\H_w
,{, I I
,/
shake
gonccrrg
lr{
t_J
\#-
purple
ungu
l, l, I -trichloroethane l,l,l-triHoroetana
Persamaan
Chemical equation: kimio :
zlf.l + Pz -'+ 2KP + Ie

Diagnm
10
(i) (i0
C adangkan
Suggest the identity of halogen P idmtiti halogen P
U markl
Write half equation for the oxidation or rduction prccess that has occuned. Tuliskon setengah persamaan unuk proses pengofuidaan atet penuntnan yng telah
berlalru. [2,
narlal
{iii)
Describe a chemical test to verifu the displaced halogen in the reaction. Huraikon sata ujian kimia unt* mengesahkan halogen y(mg tersesar dalom tindak balas ini. 13 marksT
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(b)
Table l0.l shows the result of two experiments to study the effect of metals M and N on the rusting of iron when coiled on iron nail. Jodual l0 .l fienunjukkan keputusan dua eksperimen untuk mengkaji kesan logam M dan N
ke atas pengaratan besi apabila dililitkan pada paku besi.
Experiment
Eksnerimen
0bservation
Pemerhatian
Experiment I Eloperimenl Blue spots formed in the Hot agar solution + potassium hexacyanoferrate (l l$ solution + phenolphthalein
agar
Tompok biru terbentuk dolam agar-sgar
larutan agar-cgar panas * kalium heksasianoferat {lllt. +
metal
fenolftalein
logamM Experiment
Eksperimen
ll
II
metal N lopamN
Hot agar solution + potassium hexacyanofurrate (l II) solution + phenolphthalein larutan agar-agar panas + kaliam helasasianoferat (lfl) + fenalftalein
Pink spots formed in the agar Tompak merch jambu

terbentuk dalam agar-
agar
Table
l0.l for Experiment I and II.

Il.
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(i)
Explain why there is a difference in observations
Terangkan mengopa terdapal perbezaan dalam pemerhalian bagi Eksperimenl dan
(ii)
Arrange in ascending order of metals M, N and iron based on the electropositivity of the metals. Susunkan secara menaik bagi togam M,N dan besi berdosarkan sifat
ke e I e laropo si tifan I o gam
.
I (c)
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A student carried out an experiment to construct a Reactivity Series based on the reactivity of metal with oxygen. Table 10.2 shows the observation obtained by the student. Seorang pelajar telah menjalankan satu eh;perimen unluk membina sant Siri Kereaktifan berdasarlcan kzreakdan logam dengan gas oksigen. Jadual 10.? menunjr*kan pemerhatian yang diperolehi oleh pelajar in. [Lihat sebel.rh SULIT
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Metal Logam
lron
Besi
Obscrvaiion
Pemerhatian
Iron glows brightly and prducing a brown residue

Besi membara dengon lerang dan rnenghasilkan baki berwarna perang
T
U
glows dimly and producing a black residue Lopam T membars densan ,nalan and menshasilkon boki berwarna hitam Metal U burns brightly and producing a white residue Log.am U terbakor densan terang dan menshasilkan bad berwarna putih
MetalT
Table 10.2
(i)
Write a balanced chemical equation when iron reacts with oxygen to form iron (III) oxide.
Tuliskan persamaan kimia yang seimbang apabila besi bertfndsk balas dengan olrsigen untuk membentuk ferum(lll) aksido .
12
marks)
(ii)
Table l0.J shows the appararus and materials to investigate the reactiviry of metals with oxygen. Jadual 10.3 menunjukkan radas dan bahon untuk mengkaji kereaktifan logam dengan
oksigen.
Solid potassium manganate (VIl), glass wool oasbestos WW1 bunsen burner, retort stand and clamp,
boiling iube
Pepejal lcolium manganat (Yll),wul koca ,kerlas asbestos , penuna bunsen koki retot dan pengapit, tabwg didih
Table 10.3
Based on Table 10.3, draw a labelled diagram to investigate the rcactiviqv of any given metal with oxygen in the school laboratory. Berdassrkan Ja&al 10.3, tukiskan sebuah rajah berlabel untuk menkaji kereaktifan
mana-tnana logam yang cliberi dengan oksigen di dslam malonal selcolah
[2 marks]
(iii)
Arrange in ascending order of metals ircn, T and U based on their reactivity towards oxygen. Explain how you construct this Reactivity Series. Susunkan secora menoik logam besi ,T danU herdasarkcn kereaktifan logam
terse but terhadap oksigen.
Terangkan bagaimana anda membina Siri Kereahtifan tersebut.
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END OS'Q{TESTTON PAPER
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PERIODIC TABLE OF THE I,LEMENTS

t
Li
Lithftm
1
Be
Scrytliunt
9
rn{ I f,i*+*SYmbol
I X**-Name
,-//Proton
number
5
He
Helium
of element atomic mass
B
Borfi
t1 t3
c
Carban
N
Nitroger
o
0lryS.rt
r
Flucine
l0
Ne
Nsr
?0
l2
l4
l4
t6
l9
17
ll Na
Sodium 23
It
\Relative
It
Mg
t{agneriu
m 24 20
AI
Alurni*ir
m
71
l6
si
Silicrlrt
P
Pllorphtr
l8
s
Sulphur
32 14
CI
Chlorit*
19 35
Ar
Argss
40 36
2t
Itt 3t
33
l9
2l
+t
23
K
Forascium 39 37
Ca
CalcfuE
40 38
Se
Scadium
45
39
Ti
Tironium
48
,lO
v
Vaaadiu
24
25
Cr
Chronium
52 42
Mn
Mrnpnx
c
26
27
?8
29
30
3l
Fe
Iron
56 44
Co
Cobolt
59 45
Ni
Nicktl
59 rl6
Cn
Copn6
64 47
Zn
Zirr
65
4E
Gn
Callium
?0 !t9
Ge
Carmaniu
m
71
'J
As
Ar$nic
75
Se
Schnium
79
Br
Bromine 80
Kr
Krygon
84
$
JI
5t
43
dl
l\ (t.l
Rb
Rutridiun
E6
Sr
$rontium
Y
Ytlriufi
89
51
Zr
Zircolium 9t
al
Nb
NiSium
Mo
Molybdcn
't*hoeliu
m
18
15
Tc
Ru
Rutheniu m
50
5t
5l
5{
R}
Rhodium
103
Pd
Palladiurn
106
?E
Ag
Sihtr
103
cd
Cadr,rium
In
lndirm
Sn
il9
82
Sb
Aatiuony t22
83
Te
Tellutlunr
I
lnlim
121 g5
Xe
Xmon
tt
9] 1t
uo
96 11
t0l
76
il2
EO
il5
8l
llt
l2t
8rl
t3t
86
JJ
56
Cs
Caesiun
r33 87
Ba
Berium
137
La
Laathanu m r39
TIf
llaftrium t79
104
Ta
Tanlalun
w
Tung5len
184
IUO
77
Re
Rheniun
186
0s
Omium
r90
108
Ir
lridiun
192 109
79
Pt
Plailusr
195
Att
Qold
197
Hg
Mdisury
?01
TI
Ttalliut
3(X
Pb
l8t
t0J
Ld
207
Bi
Bismulh 249
Po
fulonium
At
Aststinc
210
Rn
Rador
2t0
JJ''
t8
t9
107
Fr
Fnncium 723
Ra
Radium
2:16
Ac
&tinitrm
221
unq
Unnilquadium
251
unp
Unnil-
Unh
Unnil-hcr
Uns
Umilsc.pi
Uno
Unnilo$i
um
265
Uue
Unnil6nni
um 7n6
pct{inlr
260
um
161
un
262
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1 SULIT: Chemistry 2 4541/2 (PP) Sub Mark 1 1 1 1 1 1 1 2ROH 2LiOH + H2 + H2 1 1 1 Total Total Mark 1 1 1 1 1 1 1
Question No 1 (a) (b) (c) (i) (ii) (d) (e) (f) (i) (ii) // 2Li + 2H2O 2.1 // 2,1 Group 17, Period 2 P // Ne // Neon
Mark Scheme
Octet electron arrangement // 8 valence electrons HOQ // HOF Q // F // Fluorine R // Li // Lithium 2R + 2H2O
1. Correct reactants and products 2. Balanced equation (g) P,Q , R
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Question No 2 (a) (b) (c) (d) (i) (ii)
Mark Scheme Chemical formula that shows the simplest whole number ratio of atoms of each element in a compound To remove all oxygen / air Black solid turns brown Mass of copper = 26.88 g Mass of oxygen = 6.72 g ( unit compulsory )
Sub Mark 1 1 1 1 1 1 1
Total Mark 1 1 1 1
1. Number of mole of Cu = 26.88 /64 // 0.42 Number of mole of O = 6.72 /16 // 0.42 2. Ratio Cu : O = 1 : 1
2 1
(iii) (iv)
CuO CuO + H2 Cu + H2O 1. Correct reactants and products 2. Balanced equation
1 1
(e)
Magnesium is more reactive than hydrogen // Hydrogen is less reactive than magnesium // Hydrogen is below magnesiumin the reactivity series
1 Total
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3 Sub Mark 1 1 1 Total Mark 1 1 1
Question No 3 (a) (i) (ii) (b) (c) (i) 2NH3 + H2SO4 Contact process Haber process Nitrogen // Hydrogen
Mark Scheme
(NH4)2SO4 1 1 1 1 1 2 2 1
1. Correct reactants and product 2. Balanced equation (ii) (iii) Fertilizer 1. 28 X 100 % 132
2. 21.21% (d) H Cl | | C=C | | H H (e) Use biodegradable polymer. [ Accept: Any other correct answer ]
1 Total
1 10
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4 Sub Mark 1 1 1 1 1 2 Total Mark 1 1 1
Question No 4 (a) (b) (i) (ii) (c) (i) HCl
Mark Scheme
No changes // blue litmus paper remain unchanged Consist of molecule // no hydrogen ion / H+ 1. Helps acid to ionizes / dissociate 2. Produce hydrogen ion / H+ // HCl H+ + Cl[ award pt 2 if write correct equation]
(ii)
2H+ + CO32- CO2 + H2O 1. Correct reactants and products 2. Balanced equation 1 1 1 1 1 2 2 1
(iii) (iv)
1. Effervescence // bubbles of gas 2. `Pop` sound Acid only shows its acidic properties when dissolve in water // H+/ hydrogen ions are responsible for acid to show their properties.
Total
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5 Sub Mark 1 1 1 1 2 1 Total Mark 1
Question No 5 (a) (b) C3H8O [ r : C3H7OH ]
Mark Scheme
1. No. of mole of carbon dioxide = 0.1 X 3 // 0.3 2. Volume of carbon dioxide = 0.3 x 24 dm3 // 7.2 dm3 // 7200 cm3
(c)
(i) (ii)
Compound that contain carbon and hydrogen only
water 1. Functional diagram 2. Label : water (d) (i) (ii) Oxidation Propanoic acid [ r : formula ] (e) (i) H O H H H | || | | | HC COCCCH | | | | H H H H 1 [ a: CH3COOC3H7 ] (ii) To increase rate of reaction // As a catalyst 1 Total 1 10 1 1 1 1 1 2 1 1
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Question No (a) 6 (b)
Mark Scheme m=2 n=2 Eye
Sub Mark 1 1
Total Mark 2
mixture
1. Functional diagram 2. Label : Eye , X mark, hydrochloric acid and sodium thiosulphate solution // solution // mixture (c) (d) Sulphur 1. Labelled axis with units : ( temperature /oC, time /s) 2. Suitable scale : (cover 50% of graph paper) 3. All point are plotted correctly 4. Correct shape and smooth curve The higher the temperature, the less the time taken for X mark to disappear from sight // the temperature is inversely proportional to time
1 1 1 1 1 1 1
2 1
(e)
1 Total
1 10
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7 Sub Mark 1 1 1 Total Mark 2 1
Question No 7 (a) 1. 2.8.2 // 2,8,2 2. Group 2 // 2 (b) (i) (ii)
Mark Scheme
P and Q // Q and R // Cl and Mg // Mg and O [ a: names of elements ] +2
P 1 1 1 1 1 1 1 1 2
1. label nucleus with dot or symbol and correct shells 2. octet electron arrangement and correct charges [ a: actual elements] (c) 1. Electron arrangement of C : 2.4 2. O : 2.6 3. Carbon atom contributes 4 electrons for sharing with two oxygen atom. 4. One oxygen atom contributes 2 electrons for sharing. 5. both achieve the octet electron arrangement
Ionic compound Solid High Conducts electricity in molten / aqueous Soluble in water// Insouble in organic solvent Sodium chloride // other ionic compound Physical properties Physical state at room conditions Melting/ boiling pt Electrical conductivity Solubility in water and organic solvent Example of compound Covalent compound solid, liquid, gaseous Low Does not conduct electricity in all state. Insoluble in water// Soluble in organic solvent Tetrachloromethane // other organic compound
Max. 5
(d)
1+1 1+1 1+ 1 1+1
1+1 Total
10 20
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8 Sub Mark 1 1 Total Mark 2
Question No 8 (a) (b) Electrode Ions that are attracted Ions that are selectively discharged Reason (i)
Mark Scheme Electrode Y : the position of ions in electrochemical series Electrode X : concentration of ions / solution/electrolyte
Y Cu2+ , H+ Copper(II) ion Cu is lower than H+ in the electrochemical series Cu2+ + 2e Cu

2+
X Cl- , OHChloride ion Concentration of Cl- higher 2ClCl2 + 2e 1+1 1+1 1+1 2+2
Half equations Observable changes of the solution
Blue solution becomes paler
10 (c) (i) (ii) W, X, Y, Cu 1. Cu 2. 1.3 V 3. Metal X is more electropositive than metal Cu 1. Positif terminal :Q 2. Negative terminal : Cu 3. Suitable metal for Q : silver 4. Suitable solution for R : silver nitrate solution [ a: name of substance ] Total 10 1 1 1 1 3 (ii) 1 1 1 1 4 1
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9 Sub Mark 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1+ 1 Max 10 Total 20 4 Total Mark 2
Question No 9 (a) (i) (ii)
Mark Scheme 1. P : Mg // Magnesium 2. Q: Zn // Zinc 1. The value of heat of displacement for Expt I is more than Expt II. 2. The distance between P / Cu is bigger/ further 3. than Q/Cu 4. in the electrochemical series. 1. mol of CuSO4 = 0.2 x 50 // 0.01 1000 2. Heat = 0.01 x 336000 J // 3.36 kJ // 3360 J 3. Change in temperature = 3360 50 X 4.2 = 16 oC
(b)
(c)
1. Appratus: Polystyrene cup , thermometer, [spatula] measuring cylinder ( suitable volume) 2. Procedure: 1. Measure 50cm3 of copper(II) sulphate solution 2. Pour into a polystyrene cup. 3. Measure the initial temperature, T1 4. Add a spatula of P // Q powder 5. Stir 6. Record the highest temperature, T2 3. Calculations: 1. T2 T1 = T oC 2. Mol of copper(II) sulphate solution = n mol // 0.2 x 50 // 0.01 1000 3. Heat = mc (T) // 50 x c x T J 4. Heat of displacement = - 50 x c x T J mol-1 0.01 [ negative symbol and correct unit compulsory]
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10
10 (a) (i) (ii)
P = chlorine // bromine Accept : formula Oxidation = 2I- I2 + 2e or Reduction = P2 + 2e 2PNote : P is Cl / Br 1.Correct formula of reactant and product 2.Balanced equation
1 1 1 1 1 6
(iii) 1. Add slowly // Add drop by drop // Add by using dropper 2. starch solution to the product in a test tube 3. dark blue colouration/solution is formed r: precipitate (b) (i) Exp 1 1.Presence of iron(II) ion 2.Metal M is less electropositive than iron // metal M located lower than iron in Electrochemical Series 3.When metal M in contact with iron nail, Iron rust Exp 2 4. No iron (II) ion // presence of hydroxide ion 5. Metal N is more electropositive than iron //metal N located above iron in Electrochemical Series 6.When metal N in contact with iron nail, iron do not rust
1 1 1 1 1 1 Max 5
(ii) (c) (i)
M,iron,N 4Fe + 3O2 2 Fe2O3 1. formula of reactant and product correct 2. Balanced equation
1 1 1
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11 (ii)
Glass wool Solid potassium manganate(VII)
Metal
powder
Asbestos paper heat heat 1 1 1 1 1 1 4 20 2
1. functional diagram,shading,and both heat 2. label (iii) 1.T,iron,U 2.U is more reactive than T and iron so U is located above iron and T in the Reactivity Series 3.iron is more reactive than T but less reactive than U so iron is located above T and below U in the Reactivity Series 4.T is less reactive than U and iron so T is located below U and iron in the Reactivity Series.
END OF MARKING SCHEME
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Tingkatan:
PROGRAM PENINGKATAN PRESTASI AKADEIVTIK

SPM TAHUN 2OI2
CHEMISTRY Paper 3
One hour and thirty minutes
JANGAN BUKA KERTAS SOAL.AN INI SEHINGGA DIBERITAHU
1. 2.
Kertas soalan ini adalah dalam dwibahasa. Soalan dalam Bahasa lnggeris mendahului soalan yang sepadan dalam Bahasa Melayu. Calon dibenarkan menjawab keseluruhan atau sebahagian soalan sama ada dalam Bahasa lnggeris atau Bahasa Melayu. Calon dikehendaki rnembaca maklumat di halaman belakang kertas soalan ini.
Untuk Kegunaan Pemeriksa

Soalan
Markah penuh
24 9
Markah
diperoleh
3.
4.
t7
JUMLAH
Kertas soalan ini mengandungi
halaman bercetak
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INTORMATION FOR CANDIDTTES
l. This question paper consists of three questions. Answer all questions.

2. Write your answers for Question I and Question
question paper.
2 in the spaces provided in the
3. Write your answers fot Question 3 on the "helaian tambahan". You may use
equation, diagralns, tables, gfaphs and other suitable methods to explain your answer.
4. Show your working" it may help you to gt marks5. lf you wjsh to change your answef, neatly
Therr write down the new answer. cross out &e answer that you have done.
6. The diagrams in the q*estions are not drawn to scale 'tnless stated.
7. Mark allocated for each question orpart question are shown in brackets.
B. The time suggested to srxwers Que$tion
nnd Qucstion 2 is 45 minutes and
Question3h45minutes. 9. You may

use enon-programrnable scientific calculator'
10. Hand your atlswer sheets at the end of the examination.
Marks awarded:
Mark
3
Descrintion
t
0
Excellent Satisfactory Weak
: The best resPonse : An average response : An inaccrnate response
No response or wrong rsponse
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1 Diagram
fujah
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l.l
1.1 shows two experiments to deterrnine the heat of nzutnalization.

menunjukkan dua eksperimen tmtuft menentukan haba peneunalan
Experimerit
I
of
Reaction between 25 cm3 of sodium hydroxide solution , NaOH 1.0 mol dm-3 and 25 cm3 hydrochloric acid, HCI 1.0 mol dm-' Tinrlak bulus anturuZ5om3 letrutan fiatrium hi<Irol*idu, NaOH l-0 mol dm'3 elengtn 25cmi ucid hklxtWorik HCt 1.0 mol dm'3
Stirred ___--____4 dikacau

Polystyrene cups Cw'ot polistirena
hitial temperature of the mixture

Suhu awal campuran
OC
Higbest temperature ofthe mixtue:

Sahu
OC
tertingf cdrnpaftrn
OC
Change in temperanrre
Perubo.hnt suhu
454t/3
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sul,rT
Experiment
4
II
454U3
Reaction between 25 cm3 of sod.ium hydroxide solution , NaOH 2.0 mol dm-3 and 25 cm3 of ethanoic acid, CH3 COOH 2.0 mol dm-i l Tirutak balas antara 25 cml larutan natrium hidroksida, NaOH 2.0 mol dm'3 deng*t 25 cm asid et6noik2.0 mol dm-3
W#f, W
\
Polystyrene cups Cawan polistirena
il|fl
f}Il ilil
Inifial temperature of the rnixture

Suhu cwal campuran
: Tr oC
Tz
uC
Highest temperature of the Subu te r t inggi c amFar sn

Change in Perubahsn sulnt
mixture:
temperature
T3 "C
(a)
Wdte the initial and the highest temperature of the mixhne and change in tem.perafure for Experimeni I in Diagram 1.1 Tulis suhu crwal dan suhu tertinggi campuran serta perubahan suhu untuk Elxperitnenldalam Rajah l.l
13 marks)
(b)
Construct a table that can be used to record the data from both experiments. Bina satuja&nl ymg boleh dignakn wrtuk merekod data bagi kedua-daa eksperimen
13 marrs'l
454r/3
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sultT
(c)
4541t3
State one hypothesis for both experiments. Nyalakm satu hipotesis bagi kedaa-dua eh,sperimen
13
marbl
(d) .
Based on the temperatures in Experiment I, predict the change in temperature in
Experiment II Eerdasskot suhu dalsm Ehrperimenl, ramslkwt peruhahan
suhu bagi Eksperimen
Il
[3
marks]
these
{e}
Why must the initial temperature and the higlrest temperature be rscorded in
experiments?
Mengapakah suhu swal dwr suha tertinggi perlu direkodkan dalam ekrperimen ini?
[3
narfu]
(0
How can the value of the change of lenrperature be obtained? Bagaimwtakah nilai perubahan suhu diperoleh?
[3 wr.lesl
(g)
For this experimentstate

Bagi eksperimen ini , nyatakan
ti)
Manipulated Variable
P embol e hubah dimantpulas
(it
(iii)
RcspondingVariable
P em b a I e lubuh
beryerakbalus
ConstantVariable P e mbo I e la$ ah d i tzna,la r km
[ 3 marks]
454v3 http://www.chngtuition.blogspot.com
ll.ihat sebelah SULIT
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SULIT fri)
45411-\
for the Diagram 1.2 shows the calculation to determinc tlre heat of neutralisation reactions in Experiments I and II n";"n 1.2 menmju*kan perhitungan untah menentukm haba peneatralan bogi tiwlak balos daiam Ekperimenl dan Eksperimenll
Experiment
Experiment
II
Heat released I{aba yang dihebaskan
Heat released
Haba yang dibebaskan
: mcO
*xJ
=50Bx4.2Jgr x
Heat $f neutralisation
oc
: mc0
=yJ
= 50 8 x4.21
XT3oC
Heat of neutralisation
tr{aba peneutra}rm
Haba penedralan
xkJ
y-ki
number ol'mole of water Produced bilangan mol air.vang dihs$ilksn
numtrer of mole of water Produced bilangon mol air Yang dihusilkan
It *'as found that the value of x is greater than value of y' Explain why. Didapa{i nilai x lebih hesat dtnipada nilai y'
Teranglam mengsps.
t3
morksJ
454t13
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2 Table
1 shows
'7
454113
Experiment I, Experiment II and Experiment III which arc conducted to study the solubility of salts in water. Jadaal 1 menunjukkon Ekperimen [" Eksperimen {( don Eksperimen lll vang diljalankm untak
nengkqji keterlarulan gararn dalam air.
Experiment
Reaction
TindaL balas
Observations Penerhstian
Add water
Tambah
sir
Calcium
Kqlsium
nitrate nitrat
Colourless solution Larwan tak berwama
II
Add water Tsmbahair
-|} Copper(Il) sulphate

Kr,prrndll)
sulfat
Blue solufion Larutat biru
NI
Calcium carbonate Kalsium ka*anat Table I 454U3
[Lihat sebelab SULIT
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SULIT I (a) V/rite the observation for Experiment I. II and III in Table L
Tul is pemerlnt ian bagi Eksperimen
454t/3
l, ll don lll dalaw Jadaal
I. 13
marksl
(b)
Based on Experiment I and II, state the operational definition of soluble salt. Berdasskan Eksperimen I dmt fI" nyatakm definisi secaro operasi bagi garam terlarut.
f3 marks]
(c)
Classif the following
Kelaskon gsram-gmrofi, di bowuh
salts into solubl salts and insoluble salts. ke@a garom terlarw de, garam tak terlsrut.
$odium sulphate, Lead(II) sulphate, Barium sulphate, Magnesium sulphate

Natriam sulfat, Plumbum$l) sulfat, Borium sulfal, Magtesium sulfut
l3 marksl
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3
454v3
The distance between pnirs of different metals in the electrochemical serisr aflect the.voltnge produced. Jarak di antara pasangan logamyntg berlainon di dolam shi elehtto*imia mcnpengarahi voltan yrng lerhssil
Diagram 3 shows a voltaic cell which consist of two different metals dipped in an electrolyte. Rajah 3 newnjul*an salu sel voltan yang terdiri daripada dua logam yang berlainan di celup dalan satu elektolit.
Copper{Il) sulphate solution

Lar u t an kup r wn(ll)s u Ifu t
Diagranr 3
Based on Diagram 3, plan one laboratory experiment to investigate the efTect of the distance betwon two metals in the electrochemical series on the voltage produced. Berdacwksn Rcjah3, rancang sata ekryrimen mobtwl wtak mengkaji kescn jwuk di sntara dua logam dalam siri elektrokimis kE atas voltan yang terhasil.
Your planning should include the follorrying aspects:

Perancangan anda lendailah tnengqftdungi aspek-aspe k ber ikut:
Problem statement
Pernyataan masalah
AII the variables

Semua pemboleh ubah
Hypothesis
Hipotesis
List of materials and apparatus Senaai balmn danradas

Procedtrre
Prosedur
Tabulation of data Peqiadualan data

END OF QUESTION PAPER 4541/3
[17 marks]
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PAPER 3: CHEMISTRY
Question 1(a)
Mark Scheme Able to record all the temperature accurately Answer Initial temperature Highest temperature = 29.0 = 41.0
Marks 3
Change of temperature = 12.0 2 Able to record all the temperature correctly Sample answers Initial temperature Highest temperature = 29 = 41
Change of temperature = 12 Able to record one temperature correctly No response or wrong response 1(b) Able to construct table accurately with correct title and unit Sample answer TemperatureC I Initial temperature of mixture Highest temperature of mixture 29.0 41.0 T1 T2 Experiment II 1 0 3
Able to construct table correctly without unit
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Able to construct table less accurate with at least one experiment No response or wrong response 1(c ) Able to state the hypothesis accurately Sample answer The heat of neutralization of a weak acid and strong alkali is smaller than the heat of neutralization of strong acid by a strong alkali Able to state the hypothesis correctly Sample answer The heat of neutralization changes when different acids react with strong alkali Able to state the idea of hypothesis Sample answer The heat of neutralization changes No response or wrong response 1(d) Able to predict the change of temperature accurately 11C Able to predict the change of temperature correctly 9-10C Able to predict less correctly 7-8C No response or wrong answer 1(e) Able to explain with two correct reasons Sample answer *This is to enable the change in temperature to be measured. *The change of temperature is needed to calculate the heat of neutralization
1 0 3
0 3
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Able to explain at least one reason from the above Able to give an idea of explaining No response or wrong response 1(f) Able to state the formula accurately Sample answer Change in temperature= Highest temperature of mixture- initial temperature of mixture Able to state the formula correctly Sample answer Difference of temperature between highest and lowest Able to give an idea of calculating No response or wrong response 1(g) Able to state all the variables correctly Answer Manipulated Variable: The type of acid used // ethanoic acid, hydrochloric acid Responding Variable : The heat of neutralisation
2 1 0 3
1 0 3
Constant Variable : The concentration and the volume of acid and alkali // the type of container that is used to hold the mixture Able to state two variables correctly Able to state one variable correctly No response or wrong response 2 1 0
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1(h)
Able to explain with two reasons correctly Sample answer 1.Experiment I uses a strong acid whereas Experiment II uses a weak acid. The heat of neutralization of a weak acid by a strong alkali is less than the heat of neutralization of a strong acid by a strong alkali . 2 This is because during neutralization of a weak acid such as ethanoic acid , part of the heat is used to dissociate the acid molecules Able to explain with one of the reasons Able to give an idea Sample answer Ethanoic acid is a weak acid No response or wrong response
2 1
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Question
2 (a)
Mark Scheme Able to state all observation correctly Sample answer EXPERIMENT EXPT I Calcium nitrate dissolves // Colourless solution is formed. EXPT II Copper(II) sulphate dissolves// Blue solution is formed EXPT III . Calcium carbonate does not dissolve/remains unchanged // No change. Observation
Marks
Able to state any 2 observations correctly. Able to state any 1 observation correctly. No response or wrong response (b)
2 1 0 3
Able to state the operational definition of soluble salt correctly Sample answer: When a salt is added into water and dissolves to form a solution, it is a soluble sal t.// When a salt dissolves in water to form a solution, it is a soluble salt. Able to state the operational definition of soluble salt less correctly Sample answer When a salt is added into water and forms a solution, it is a soluble salt. When a salt dissolves to form a solution, it is a soluble salt. Salt dissolves in water to form a solution.
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Able to state any idea of operational definition of soluble salt Salt dissolves//Salt dissolves in water. Solution forms. No response or wrong response
(d)
0 3
Able to classify all the solutions correctly Sample answer Soluble salt Potassium sulphate Zinc sulphate
# Score 1 if state in the reverse
Insoluble salt Lead(II) sulphate Barium sulphate
Able to classify at least 3 salts correctly Able to classify any 2 salts correctly No response or wrong response
2 1 0
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Question
Mark Able to state the problem statement correctly Sample answer: How does the distance between two metals in the electrochemical series affect the voltage produced? Able to state the problem statement less correctly No response or wrong response
Score
3(a)
1 0
Question
Rubric Able to state the three variables correctly Sample answer: Manipulated: Pairs of metals Responding: Voltage // Voltmeter reading
Score
3(b)
Constant: Electrolyte // Copper(II) sulphate solution // Copper electrode//Concentration of electrolyte Able to state any two variables correctly Able to state any one variable correctly No response or wrong response 2 1 0
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Question
Rubric Able to state the hypothesis correctly and with direction Sample answer: Hypothesis: The further the distance of the pairs of metals in the electrochemical series, the greater the voltage produced Able to state the relationship between manipulated variable and responding variable but in the opposite direction // no direction Able to state an idea of the hypothesis
Score
3(c)
1 No response or wrong response Question Rubric Able to give complete list of substances and apparatus Sample answer: Substances Copper (II) sulphate solution, magnesium metal, zinc metal, iron metal, copper metal, sandpaper. 3(d) Apparatus Beaker, connecting wire, voltmeter Able to give at least two substances and at least two apparatus Able to give at least one substance and at least one apparatus No response or wrong response 2 1 0 3 0 Score
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Question
Rubric Able to list all the steps correctly Sample answer: 1. Clean the strips of magnesium and copper with sandpaper. 2. Measure 50 100 cm3 of copper(II)sulphate solution and pour into a beaker. 3. Dip the magnesium and copper strips into the copper(II) sulphate solution. 4. Complete the circuit // Connect the strips to the voltmeter. 5. Record the voltmeter reading. 6. Repeat steps 1 to 5 by replacing pairs of Mg/Cu with Zn/Cu, Al/Cu and Fe/Cu . Able to list down steps 2, 3, 4 and 5
Score
3(e)
2 1 Able to list down steps 3 and 4 No response or wrong response 0
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Question 2(f)
Marks Scheme Able to exhibit the tabulation of data that includes the following four information. 1. Heading for the manipulated variables 2.. Heading for responding variable 3. All Manipulated variables Sample answer: Pairs of metals Voltmeter reading // Voltage (V) Mg / Cu Al / Cu Fe / Cu Zn / Cu
Marks
Able to exhibit the tabulation of data that includes the following three information. 1. Heading for the manipulated variables 2.. Heading for responding variable 3. One Manipulated variable Sample answer: Pairs of metals Voltmeter reading // Voltage (V) Mg / Cu 2
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Able to exhibit the tabulation of data that includes the following two information. 1. Heading for the manipulated variables 2.. Heading for responding variable Sample answer: Pairs of metals Voltmeter reading // Voltage (V)
END OF MARKING SCHEME

SPM Trial 2012 Chemistry Qa Kedah

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PROGRAII PENINGKATAN PRESTASI AKADEMIK

Satu jam dan lima belas minit

Kertas soalan ini mengandvngi

[Lihat sebelah SULIT

If you wish to change your answer,

eras the blackened mark that you have made.

shows the elernents in the Periodic Table.

Rajah 2 menunjuA:ftan unsar-unsur dalam Jadual Berksla

Diagram 2 Which element is a halogen? Unsur manakah adalah suatu halogen?

[Lihet rebelah SULIT

Steelwires Wayar keluli

[Lihnt scbchh ST'LIT

Which statement is correct about exothermic reaction?

13 Which of the following medicines

Anara ubat berikul, yang manakah suatu antibiotiV?

Insulin Insulin Aspirin Aspirin Streptomycin Streptomisin Paracetamol Parasetamol

Pembehnn Melting Peleburan

15 firc molecular formula of hexene is CeHrz.

16 Potassium is situated in the same group as sodium in the Periodic Table.

A landll B IandIV C ll and tII D III and IV

[Lihat sebelah SULIT

Carbon electrode Elehrod karbon

Copper(ll) sulphate solution

Cu'-, FlSO4'-, OH-

ytmg menyalakan kayu uji berbara apabila

Residue after heating is brown when

What is salt X? Apakah garomX?

P,R,Q Q,P,R Q,R,P

[Lihat sebeleh SI.]LIT

22 The following equation

Aluminium oxide Aluminium oksido

[Lihat sebelah ST]LIT

24 Which of the following are oxidisingagents?

(aq) -.+ AgCl

Endothermic Exothermic Exothermic Endothermic

Acid + Alkali -+ salt + wster

I shows the proton number and the number of electrons

Proton number Nombor oroton

Number of electron Bilansan elebron

Which is an anion? Yang manakah suatu qion?

of helium gas gas lretium

30 Diagram I show the electron arrengement of elements X and Y.

bawah memmiukkan Ewutl(m elektron bagi unsur

Silver nitrate solution Ltutqn argentum nitral

Tidsklsut dalamair Reacs with a weak acid

I and II II and III I and tV II and IV

Zinc sulphate Zink sulfat

34 The fcllowing equation is a reaction to prepare a synthethic

fertilissr, Z. Persamasn beriktt adatah tindakbslas untuk menyediafum baja sintelih Z.

Which ofthe following is Y? Manakah antara berikut adalahY?

Nitric acid Asid nitric

[Lihat sebelah ST'LIT

Volume of oxygen gaV cm3 kipadu gas oksigen / cm3

Yang manakah di antara larutan

[Lihat sebelah SULIT

Alcohol Alcohol Methanol Metanol

Zinc plate PIat zink

A Zn --) Znzn + 2e BAg --+ Ag* +e C Ag*+ e -' D 2H* + 2e ;

33 Hot packs contain chemicals that react to produce heat.

Bahon manakahycng digunakan dalam pek panas?

Calsium carbonate Kalsium ksrbonat

A Zn --) Znzn + 2e BAg --+ Ag* +e C Ag+ e -' D 2H + 2e ;