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Group
Formula
Graphical Formula
Prefix
Suffix
Example
Acyl halide
Haloformyl
RCOX
haloformyl-
Alcohol
Hydroxyl
OH
hydroxy-
-ol Methanol
Aldehyde
Aldehyde
RCHO
oxo-
Alkane
Alkyl
RHn
alkyl-
-ane
Methane
Alkene
Alkenyl
R2C=CR2
alkenyl-
Alkyne
Alkynyl
RCCR'
alkynyl-
-yne
Acetylene (Ethyne)
Amide
Carboxamide
RCONR2
carboxamido-
Amines
Primary amine
RNH2
amino-
Secondary amine
R2NH
amino-
-amine Dimethylamine
Tertiary amine
R3N
amino-
-amine Trimethylamine
4 ammonium ion
R4N+
ammonio-
-ammonium Choline
Azo compound
Azo (Diimide)
RN2R'
azo-
Toluene derivative
Benzyl
RCH2C6H5 RBn
benzyl-
Carbonate
Carbonate ester
ROCOOR
alkyl carbonate
Carboxylate
Carboxylate
RCOO
carboxy-
Carboxylic acid
Carboxyl
RCOOH
carboxy-
ROCN
cyanato-
alkyl cyanate
RSCN
thiocyanato-
alkyl thiocyanate
Ether
Ether
ROR'
alkoxy-
Ester
Ester
RCOOR'
-oate
Haloalkane
Halo
RX
halo-
Hydroperoxy
ROOH
hydroperoxy-
Primary ketimine
RC(=NH)R'
imino-
-imine
RC(=NR)R'
imino-
-imine
RC(=NH)H
imino-
-imine
Secondary aldimine
RC(=NR')H
imino-
-imine
Isocyanide
Isocyanide Isocyanate
RNC RNCO
isocyanoisocyanato-
Ketone
Ketone
RCOR'
keto-, oxo-
Nitrile
Nitrile
RCN
cyano-
Nitro compound
Nitro
RNO2
nitroNitromethane
Nitroso compound
Nitroso
RNO
nitrosoNitrosobenzene
Peroxide
Peroxy
ROOR
peroxy-
Benzene derivative
Phenyl
RC6H5
phenyl-
-benzene
Cumene (2-phenylpropane)
Phosphine
Phosphino
R3P
phosphino-
-phosphane Methylpropylphosphane
Phosphodiester
Phosphate
HOPO(OR)2
di(substituent) hydrogenphosphate
DNA
Phosphonic acid
Phosphono
RP(=O)(OH)2
phosphono-
Phosphate
Phosphate
ROP(=O)(OH)2
Pyridine derivative
Pyridyl
RC5H4N
3-pyridyl (pyridin-3-yl)
-pyridine Nicotine
Sulfone
Sulfonyl
RSO2R'
sulfonyl-
(Methylsulfonylmethane)
Sulfonic acid
Sulfo
RSO3H
sulfo-
Sulfoxide
Sulfinyl
RSOR'
sulfinyl-
Thiol
Sulfhydryl
RSH
mercapto-, sulfanyl-
-thiol
These are possible mnemonics for the common functional groups. Vowels: Remember the vowels "A", "E", and "Y" for Alkane, Alkene, and Alkyne. Alkanes have only single covalent bonds. Alkenes have at least one double bond. Alkynes have at least one triple bond. The letters "I", "O", and "U" are not used. Furthermore, "O" and "U" would result in awkward pronunciations. Alcohol: Look for the "C-O-H" in "Alcohol." Ether: Ethers were anesthetics used in the 1800s. Dr. Kellogg also lived at the same time. Corn Flakes are made by Kellogg's. A rooster or cock (C-O-C) is the cornflake mascot. Amine: Remember the "N" stands for nitrogen. Aldehyde: This sounds like "Adelaide," the Australian city. Australia is at the end of the Asian islands, and aldehydes are at the end of the hydrocarbon chain. The "Y" indicates a C=O double bond.
Ketone: Imagine the diagonal strokes of "K" forming the C=O double bond. Carboxylic Acid: "Box" stands for boxed wine or C-O-H, alcohol. The "Y" indicates a C=O double bond. Ester: This sounds like "Estelle" George Costanza's mother in the TV show Seinfeld. George's nickname was Koko or Coco. So think of O=C-OC. Amide: Amine with a "D". D for double.