PTL Introduction Laminated TFS ENG Nov12

Confidential
Laminated TFS
Nippon Steel & Sumitomo Metal Corporation
Production of Laminated TFS
Laminated TFS for TULC(canning process) has developed by TOYO SEIKAN group , and Nippon Steel sealed the license contract of this Laminated TFS in 1991. 1993 : No. 1 FLL came into operation. 1994 : Supply of materials for TULC started. 1997 : No. 2 FLL came on stream. 2001 : Supplies to users overseas started.
From the start of production of Laminated TFS in 1994, NSSMCs output totaled 1.6 million tons by 2011.
Confidential :2012.10.1:Laminared TFS
2012 NIPPON STEEL & SUMITOMO METAL CORPORATION All Rights Reserved.
Outline of Film Laminating Line
Specifications of Film Laminating Lines

Maximum Speed (m/min.) Capacity (tons/Year) Start of Operation October 1993 (During a stop) October 1997
No.1FLL
No.2FLL
200
200
120,000
120,000

Details of Film Laminating Equipment

Film Laminator Laminating Conditions
(ex. PET Film)
Film PET Polyethylene Terephthalate PP Polypropylene
Temperature Conditions: TL<<TM<TS

Cross-sectional Structure
PET Film Thickness(mm)
Inside
Clear White Gold 20 20
Outside
12 , 20 13 , 20 12
*1 : Base Metal: TFS Featuring Excellent Coat Adherence High-purity Chromium Oxide Layer *2 : Crystalline Layer Corrosion resistance *3 : Amorphous Layer Adhesionability Formability
5
Film TFS*1
Film

Applications for Domestic Market

Beverage cans
Food cans

Examples of PLT Applications (Overseas)

General Can
Salmon (Body)
Vegetable (End)
Tuna Salad (Body)
Ready meal (Body)
Tuna Sardine : 3piece Club Can (Body & EOE) (EOE & END) (Body, EOE)
Pet Food (Body)
Juice Can Cap

7
Manufacturable Range of Laminated TFS

Metal thickness of product (mm)
0.45 0.40 0.35 0.30 0.25 0.20 0.15 0.10 0.05 500 600 700 800 900 1000 1100 1200 1300 1400
Manufacturable range Range of regular manufacture
Width (mm)
As these ranges vary depending on degree of temper, type of annealing and others, we would appreciate being allowed to check and confirm with you detailed conditions involved on a case-by-case basis.
Defect Information
Classification of Defects
Class. Defect A (Serious Defect) Defect name Film joint Coil joint Base sheet hole Film width shortage Defect B (Slight Defect) Base sheet defect Visual insp. defect Base sheet pinhole Film pinhole *Our sales weight (selling weight) is the weight after subtraction of weights of defective portions (in cases where contracts are based on calculated weights).
Defect Information Sheet ( Attached to all coils )
Defective surface
Position from the outer turn of coil

9
Markings of Defective Portions
Markings are made in two types depending on the classification of defects. Defect
Marking to Defect Area Serious Defect Slight Defect
Edge of Sheet
Position of marking
Positions of markings may sometimes be 300 mm maximum off the defects.
* Some of the defects cannot be located by naked-eye observation, but since a marking means that there is some defect in the marked portion, please make sure to reject the portion.
10
Edge of Sheet
Label and Package Card
Label
In future, we plan to use codes that will show top- and bottom-side film type.
11
Package Card
In future, we plan to use codes that will show top- and bottom-side film type.
12
Films for Laminated materials

13
Film Types and Application Examples Film types
Color: Three colors (white, gold, and clear) are available. Thickness (mm): ( ): Consultation required
Type-A White Clear Gold 12, 16, 20 Type-B 13, (16), 20 16, 20, (28) 12 12 20 Type-C Type-D
*Films that meet the requirements for food products (stipulated by the FDA and others) are used.
14
Specification of the Film Resin
Type-A General PET resin is used. Type-B PET-IA type resin is used to improve forming workability. Type-C PBT resin is mixed into PET resin. *It reduces blushing that is liable to occur during heating (retort process) when Type-A or Type-B is used for the outside surface. Type-D It has a PET resin layer in the surface layer in which PE resin is dispersed. *It reduces unwanted adherence of the contents to the inside of the can when the contents are unskinned fish or some pet foods.

15
Basic Film Properties

Type Glass-transition temperature (C) *1 Tg 74 74 56 74
Melting point (C) *2 Tm1 245-258 226 218 229 Tm2 245 253
A B C D
*1 Point at which resin starts to soften *2 Films consisting of two or more resins may have two or more melting points. *3 The temperatures are all typical values.
16
Applications of Films (Example for Food Cans)

Application Printing Film type Outside NOE EOE DRD Applicable/ not applicable Not applicable Not applicable Applicable C C C C B (white) Inside A, B, C B, C A, B D B With meat-release property Film with white outside also serves as an alternative to base coating. Tab for EOE Normal lid Remarks
Tab
Not applicable
A, C
A, C
Film thickness: Outside of can: Use 12mm (13mm for white) in general. Inside of can: Choose the thickness suitable for the application and the contents.
17
Type-B (White Film)

18
Printing for PLT materials

No inside surface coating required Leading to less coating capacity requirement Decrease the waste gas

Printable as on tinplate, TFS, or aluminum Uniform appearance assured, free of uneven coating
19

Cleanliness Improvement
Original Coated Can Laminated Can
Products appear cleaner
Laminated Can
Coated
Laminated

20
Type-C : Blush-free Film

21
Measures against Blushing
PET films recrystallization is progressed by retort sterilization and other such heat treating. When this recrystallization of PET film does not progress uniformly, appearance imperfections called blushing (see the figure on the right hand) occur. Non-uniform recrystallization is liable to occur during heat-treating involving steam, such as retort sterilizing.
Fig. Appearance of blushing.

22
Improvement of Blushing
Blush-free Film has been established by the application of a film which recrystallizes at a fast rate. NSSMC has developed this technology by joint study.
10000
1/2 Crystallization Time (sec.)
1000
Type-A
Type-B Type-C
100
10
1 60 80 100 120 140 160 Temperature () 180 200 220

23
Ref. Comparison in Anti-Blushing Property

Comparison of NSSCMs and two other companies laminated materials
Dip in Boiled Water (10 min.)
NSSCM
Company A
Company B
In the boiling-water immersion test, color changes occur on the interface between the gas phase and the liquid phase in the other two companies materials, the NSSCM material is virtually free of such a phenomenon.
24

Type-D : Film for Meat Release

25
Meat Release Specification

Wax is added to the film layer in the coating.
The wax-bearing layer is about 2m thick.
Wax-bearing PET layer PET layer
(Clear)
New Film
TFS
Ordinary Film
Retort Treating
Salmon in Can
26
Commercialized products

27
Paper Labeled Drawn Cans

Fish Cans (Tuna, Sardine, etc.) Corn Can
1/4 CLUB CAN 307x113 DRD
Film
Fish Can (Tuna, Sardine) Salmon Can
83mmx86mm DRD Corn Can
Inside
Outside
C20A
G12C (blush-free type)
C20D (Meat release)

G12C (blush-free type)
W20B
C12C (blush-free type)
28

Pre-Printed Drawn Cans

Distortion-Printed Drawn Can
Film
Bowl Can Inside Outside W20B W13B DRD Can C20B W13B Club Can W20B W13B
29

Ends for Cans

200f Ends for 6 oz. Sardine Can 603f Ends for Fruits Can 307f Ends for Corn Can
Film
Inside Outside
Sardine G12C G12C
Fruits C12A or C12C C12C
Corn W13B C12C

30
Easy Open Ends & Tabs

Normal-Type Club Can End
Film
Round Can Non-Printed Inside Outside C12C or W13B G12C or C12C Printed C12C G12C or C12C Club Can Non-Printed G12C G12C Printed W13B W13B C12A C12A or G12C Tab

31
Conclusion
PLT is possible use in a various usage and has good performance. PLT is the material that does not include the regulation fears substance. (ex. BPA, BADGE, BFDGE, NOGE ) If PTL is used the discharge quantity cut of such as CO2 gas is produced. (ex. TULC by TOYO SEIKAN is the object of an ECO-LEAF mark in Japan (ISO14025). PLT is the material that has an excellent prospect. NSSMC can support the technology to the use of PLT by various experiences and evaluation equipment.
32


PTL Introduction Laminated TFS ENG Nov12

Transféré par

Informations du document

Description originale:

Copyright

Formats disponibles

Partager ce document

Partager ou intégrer le document

Options de partage

Avez-vous trouvé ce document utile ?

Ce contenu est-il inapproprié ?

Droits d'auteur :

Formats disponibles

PTL Introduction Laminated TFS ENG Nov12

Transféré par

Droits d'auteur :

Formats disponibles

Confidential

Nippon Steel & Sumitomo Metal Corporation

Production of Laminated TFS

Outline of Film Laminating Line

Specifications of Film Laminating Lines

Confidential :2012.10.1:Laminared TFS

Details of Film Laminating Equipment

Film PET Polyethylene Terephthalate PP Polypropylene

Temperature Conditions: TL<<TM<TS

Confidential :2012.10.1:Laminared TFS

Confidential :2012.10.1:Laminared TFS

Applications for Domestic Market

Confidential :2012.10.1:Laminared TFS

Examples of PLT Applications (Overseas)

Tuna Salad (Body)

Ready meal (Body)

Pet Food (Body)

Juice Can Cap

Manufacturable Range of Laminated TFS

Defect Information Sheet ( Attached to all coils )

Position from the outer turn of coil

Markings of Defective Portions

Marking to Defect Area Serious Defect Slight Defect

Positions of markings may sometimes be 300 mm maximum off the defects.

Label and Package Card

Films for Laminated materials

Confidential :2012.10.1:Laminared TFS

Film Types and Application Examples Film types

Specification of the Film Resin

Confidential :2012.10.1:Laminared TFS

Basic Film Properties

Applications of Films (Example for Food Cans)

Type-B (White Film)

Confidential :2012.10.1:Laminared TFS

Printing for PLT materials

Confidential :2012.10.1:Laminared TFS

Products appear cleaner

Confidential :2012.10.1:Laminared TFS

Type-C : Blush-free Film

Confidential :2012.10.1:Laminared TFS

Measures against Blushing

Fig. Appearance of blushing.

Confidential :2012.10.1:Laminared TFS

1/2 Crystallization Time (sec.)

1 60 80 100 120 140 160 Temperature () 180 200 220

Confidential :2012.10.1:Laminared TFS

Ref. Comparison in Anti-Blushing Property

Dip in Boiled Water (10 min.)

Confidential :2012.10.1:Laminared TFS

Type-D : Film for Meat Release

Confidential :2012.10.1:Laminared TFS

Meat Release Specification

Confidential :2012.10.1:Laminared TFS

Paper Labeled Drawn Cans

1/4 CLUB CAN 307x113 DRD

83mmx86mm DRD Corn Can

C20D (Meat release)

Confidential :2012.10.1:Laminared TFS

Pre-Printed Drawn Cans

Confidential :2012.10.1:Laminared TFS

Ends for Cans

Sardine G12C G12C

Fruits C12A or C12C C12C