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INNOVA JUNIOR COLLEGE JC 2 BLOCK TEST

in preparation for General Certificate of Education Advanced Level

Higher 2
CANDIDATE NAME CLASS INDEX NUMBER

CHEMISTRY
Paper 1 Multiple Choice Additional Materials: Data Booklet Multiple Choice Answer Sheet.

9647/01
22 March 2011 30 mins

READ THESE INSTRUCTIONS FIRST Write your name and class on all the work you hand in. Write in soft pencil. Do not use staples, paper clips, highlighters, glue or correction fluid. There are forty questions on this paper. Answer all questions. For each question there are four possible answers A, B, C and D. Choose the one you consider correct and record your choice in soft pencil on the separate Answer Sheet. Read the instructions on the Answer Sheet very carefully. Each correct answer will score one mark. A mark will not be deducted for a wrong answer. Any rough working should be done in this booklet.

This document consists of 8 printed pages.

Innova Junior College

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2 Section A
For each question there are four possible answers, A, B, C, and D. Choose the one you consider to be correct. 1 Which molecules have isomers that exhibit cis-trans isomerism? I C3H6BrI II C3H5I III C3H4I2 IV C3H4BrI

A B C D

II and IV only III and IV only I, II and III only II, III and IV only

Identify the number of sp2 and sp3 hybridised carbon atoms in the given structure:

sp2 A B C D 2 3 8 9

sp3 5 4 5 4

Reaction of ethene with bromine in the presence of aqueous sodium chloride gives a mixture of products. Which pair of products will be included in this mixture? A B C D CH2OHCH2Br CH2BrCH2Br CH2BrCH2Br CH2BrCH2Br CH2ClCH2OH CH2OHCH2Cl CH2ClCH2Br CH2ClCH2Cl

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4 During the halogenation of benzene, a halogen group substitutes at a carbon atom. Which one of the following gives the arrangement of the bonds at this carbon atom during the substitution reaction?
At the start of the reaction In the intermediate complex At the end of the reaction

A B C D Ans: (A) 5

planar planar planar tetrahedral

tetrahedral planar tetrahedral planar

planar planar tetrahedral tetrahedral

Which of the carbon atoms in the molecule below is most susceptible to the attack of an electrophile?

Ans: (D) 6 In the hydrolysis of C2H5X in aqueous solution: C2H5X + OH A B C D C2H5OH + X Why does the reaction take place more rapidly when X is iodine than when X is bromine? The I ion is a stronger nucleophile than the Br ion. The I ion is less hydrated in solution than the Br ion. The CBr bond is stronger than the C I bond. The CBr bond is more polar than the C I bond.

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7 Concentrated ammonia was heated in a sealed tube with excess bromoethane, C2H5Br. Which of the following products will not be formed? A B C D C4H11N C5H13N C6H15N C8H20NBr

Acarol is the active ingredient in many insecticides.

O HO C Br Acarol Br C O (CH3)3

Which of the following statements about Acarol is correct?

A B C D

It is able to rotate the plane of polarised light. It gives steamy white fumes with PCl5. It gives an orange precipitate with 2,4dintriophenylhydrazine. It gives brisk effervescence with aqueous sodium carbonate.

Compound Z

decolourises aqueous bromine gives brisk effervescence with metallic sodium changes the colour of acidified potassium dichromate(VI)

Which of the following could be the structure of Z?

OH

C
CH3

CH3 HO

B
OH

D
CH3

CH3

OH

CH3 CH3 O
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CH3 HO
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10

Nootkatone is one of the organic compounds found in grapefruit. Its structure is as shown below.

Which statement is correct about nootkatone?

A B C D

It reacts with hot acidified potassium manganate(VII) to form one organic product. It reacts with silver diammine complex to give a silver mirror. It reacts with potassium cyanide in ethanol to form a nitrile compound. It forms a pale yellow precipitate with alkaline I2(aq).

11

Pentan-2-one is treated with cold hydrogen cyanide in the presence of traces of sodium cyanide. The product X of this reaction is then boiled with hydrochloric acid to give Y. What are X and Y likely to be?
H OH C CN H H C H H CH3 H3C H C H H OH C H C CH3

H3C

C H H

OH C CN H H3C

COOH H H H

OH C H

H3C

C H H

C H H
C H OH C CN

C H OH
C CN

C H H

C H H
C H OH C

C H OH
C

COOH

H3C

C H H

CH3

H3C

C H H

CH3

COOH

H3C

C H

CH3

H3C

C H

CH3

COOH

12

P, Q and R are three different organic compounds. Both Q and R can react with P to form an ester each, but R reacts much less readily than Q.

Which of the following could be Q?

A B

propanoyl chloride propanoic acid

C D

propanamide propan2ol

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13

A small peptide X is hydrolysed according to the following equation.

X
hydrolysis

2NH2CH2CO2H + NH2CH(CH3)CO2H + 2NH2CH(CH2OH)CO2H (Mr = 75) (Mr = 89) (Mr = 105)

What is the Mr of X?
A B

359 377

C D

431 449

14

In the tertiary structure of a water-soluble globular protein extracted from barley grains, it was found that the types of amino acid residues present on the outer surface of the protein were different from those present on the inside. Which of the following amino acids is most likely to be incorporated into the outer surface of such proteins?
A
H H N H C COOH

B
H

H N

CH2COOH H
C COOH

C
H

H N

CH(CH3)2 H
C COOH

H H N

CH2SH H

COOH

Ans: A

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15 The use of Data Booklet is relevant to this question.

What is the standard e.m.f. of the cell shown in the following diagram?

V
Salt bridge

Lead 1.0 mol dm -3 Pb2+(aq)

Platinum 1.0 mol dm-3 Fe2+(aq) 1.0 mol dm-3 Fe3+(aq)

A B

+ 0.09 V + 0.31 V

C D

+ 0.64 V + 0.90 V

Section B

For each of the questions in this section, one or more of the three numbered statements 1 to 3 may be correct. The responses A to D should be selected on the basis of
A 1, 2 and 3 are correct B 1 and 2 only are correct C 2 and 3 only are correct D 1 only is correct.

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16

A species of termite produces a chemical defence secretion which contains the following molecule.
H3C C H3C H H C C H C C H H C H C CH2 H H

To help determine the structure of this compound it is treated with acidified hot concentrated manganate (VII) ions. Which compounds are produced in this reaction?
1 2 3

CO2 CH3COCH3 CH3CO2H

Answer: B 17

Which property of benzene is a result of the delocalisation of electrons in the benzene ring?
1 2 3

The carbon-carbon bond lengths are between those of C-C bonds and C=C bonds. It is susceptible to attack by electrophilic reagents. It is a good electrical conductor.

Ans: (B)
18

Iron filings were added to a solution containing equimolar quantities of methylbenzene and iodochloride, ICl. The mixture was immediately placed in the dark until no further change took place. Which of the following are likely to have been the main products?
CH3

I
1

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CH3

Cl
2

CH2Cl

19

Which reagents could be used to distinguish between compounds T and U?

CHO

CO2CH3

COCl
T 1 2 3
Ans: C Fehlings solution Tollens reagent aqueous silver nitrate

Cl
U

20

Methyl propanoate, CH3CH2COOCH3 , undergoes acid hydrolysis in the presence of H218O. Which of the following products are formed?

1 2 3
Ans: C

CH318OH CH3CH2CO18OH CH3OH

1 2 3 4 5 A: 5

D D C A D B: 5

C: 5

6 7 8 9 10 D: 5

C B B A A

11 12 13 14 15

C A B A D

16 17 18 19 20

B B D C C

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