SULIT

4541/3(PP)

1
MARKING SCHEME PEPERIKSAAN PERCUBAAN SPM 2012 4541/3 CHEMISTRY Paper 3

Question

Rubric Able to record the pH value accurately with one decimal place. Answer : Set I : 9.0 Set II : 8.7 Set III : 8.5 Set IV : 8.0 Able to record any three pH value accurately with one decimal place // All pH value correctly Sample answer : Set I : 9 // 9.00 Set II : 8.68 Set III : 8.53 Set IV : 8.01 Able to record any two pH value correctly No response or wrong response

Score

1(a)

1 0 Score

Question

Rubric Able to construct a table to record the data that contain: 1. Correct titles 2. Correct pH value // ecf from 1(a) 3. Unit Sample answer: Set // Concentration (mol dm-3) I // 0.10 II // 0.01 III // 0.001 IV // 0.0001 pH value 9.0 8.7 8.5 8.0

1(b)

Able to construct a less accurate table that contains: 1. Titles 2. pH value Able to construct a table with at least one title / pH value No response or wrong response

2 1 0

Peperiksaan Percubaan SPM 2012

MARKING SCHEME

SULIT

4541/3(PP)

Question

Rubric Able to state the relationship correctly Sample answers: The higher the concentration of hydroxide ion, OH-, the higher the pH value // vice versa // The lower the pH value, the lower the concentration of hydroxide ion, OH// vice versa Able to state the relationship less accurately. Sample answer: The higher the concentration, the higher the pH value // vice versa // The lower the pH value, the lower the concentration // vice versa Able to give an idea of relationship Sample answer: Different concentration, different pH // Concentration affect the pH value No response given / wrong response

Score

1(c)

1 0 Score 3

Question

Rubric Able to predict the pH value correctly Sample answer: Higher than 9.0 but less than or equal to 14 // 9.0 < pH value 14.0

1(d)

Able to predict the pH value less accurately Sample answer: Higher than 9.0 Able to state an idea of pH value of acid. Sample answer: Lower than 14.0 // 7.0 < pH value 9.0 No response given / wrong response 2

1 0

Peperiksaan Percubaan SPM 2012

MARKING SCHEME

SULIT Question

4541/3(PP)

3
Score

Rubric Able to classify all the chemical substances correctly Answer: Acidic substance Vinegar Soft drinks Alkaline substance Toothpaste Baking powder

1(e) Able to classify any three chemical substances correctly Able to classify any two chemical substances correctly or give opposite answers Sample answer: Alkaline substance Vinegar Soft drinks No response or wrong response Acidic substance Toothpaste Baking powder 1 2

Peperiksaan Percubaan SPM 2012

MARKING SCHEME

SULIT Question

4541/3(PP)

4
Score

Rubric Able to state one observation correctly Sample answer:

2(a)

Experiment I II III

Observation Brown solid is formed. Iron wool burns brightly/ vigorously Iron wool glows dimly/ faintly

Able to state any two observations correctly Able to state any one observation correctly No response given / wrong response Question Able to state inference correctly Sample answer: Chlorine most/very reactive halogen //Iron(III) chloride is formed. Able to state inference less correctly Sample answer: Chlorine reacts with iron wool //Iron chloride is formed. Able to state any idea of inference Rubric

2 1 0 Score 3 2

2(b)

1 Sample answer: Reaction occurred. No response or wrong response Question Rubric Able to state All variables correctly Sample answer : Manipulated variable : Halogen // Chlorine, bromine and iodine Responding variable : Reactivity // Brightness of the flame Constant variable : Iron wool Able to state any two variables correctly Able to state any one variable correctly No response or wrong response 0 Score

2(c)

2 1 0

Peperiksaan Percubaan SPM 2012

MARKING SCHEME

SULIT Question

4541/3(PP)

5
Score

Rubric Able to give the hypothesis correctly Sample answers : Going down the Group 17, the reactivity with iron wool decreases // Going down the Group 17, the brightness of flame with iron wool decreases. Able to give the hypothesis almost correct Sample answers : The reactivity with iron wool decreases when going down Group 17// Chlorine is the most reactive halogen when reacts with iron wool. Able to state an idea of the hypothesis Sample answer : Different halogen, different reactivity. No response or wrong response

2(d)

1 0 Score 3

Question

Rubric Able to state the operational definition correctly. Sample answer: The brightness of flame when halogens flow to hot iron. Able to state the operational definition less correctly. Sample answer: The brightness of flame when halogens react with iron. Able to give an idea of reactivity. Sample answer: Different brightness/ flame/glow No response given / wrong response

2(e)

1 0 Score

Question

Rubric Able to arrange all three halogens in descending order of reactivity correctly Sample answer : Chlorine, Bromine, Iodine // Cl2, Br2, I2

2(f)

Able to arrange all two halogens in descending order of reactivity correctly Sample answer : Bromine, Iodine, Chlorine // Br2, I2, Cl2 // Iodine , Chlorine, Bromine // I2, Cl2, Br2 Able to arrange either chlorine or iodine in the correct place Sample answer : Chlorine, Iodine, Bromine // Cl2, I2, Br2 Bromine, Chlorine, Iodine // Br2, Cl2, I2 No response given / wrong response 2

1 0

Peperiksaan Percubaan SPM 2012

MARKING SCHEME

SULIT Question

4541/3(PP)

6
Score 3

Rubric Able to give the statement of the problem correctly Sample answer : How does the temperature of sodium thiosulphate solution affect the rate of reaction? Able to give the statement of the problem incorrectly

3(a)

Sample answer : How does the temperature of solution affect the rate of reaction? Able to give an idea of statement of the problem Sample answer : To determine the rate of reaction by the temperature of solution No response or wrong response

1 0 Score

Question

Rubric Able to state all variables correctly Sample answer : Manipulated variable :The temperature of sodium thiosulphate solution Responding variable : Rate of reaction//The time taken for the X mark to disappear Constant variable : Volume and concentration (sodium thiosulphate) / (hydrochloric acid) // sodium thiosulphate // acid// size of conical flask Able to state any two variables correctly Able to state any one variable correctly No response or wrong response Rubric Able to state the relationship between the manipulated variable and the responding variable correctly Sample answer : The higher the temperature of sodium thiosulphate solution , the higher the rate of reaction Able to state the relationship between the manipulated variable and the responding variable incorrectly Sample answer : The rate of reaction increases when the temperature of solution increase Able to state an idea of hypothesis Sample answer : The temperature of reactant affect the rate of reaction No response or wrong response

3(b)

2 1 0 Score

Question

3(c)

1 0

Peperiksaan Percubaan SPM 2012

MARKING SCHEME

SULIT Question

4541/3(PP)

7
Rubric Score

Able to give the list of the apparatus and materials correctly and completely Answer: Apparatus: conical flask, measuring cylinder, thermometer, stopwatch, white paper, wire gauze, tripod stand, Bunsen bunner Material: [0.1 1.0] mol dm-3 sodium thiosulphate solution, [ 0.1-1.0] mol dm-3 hydrochloric acid Able to give the list of the apparatus and materials correctly but not completely 3(d) Answer: 2 Apparatus: conical flask, thermometer, stopwatch, white paper, Bunsen bunner Material: Sodium thiosulphate solution, hydrochloric acid Able to give two materials and at least one apparatus Sample answer : Material: Sodium thiosulphate solution, hydrochloric acid Apparatus: [container] No response or wrong response 1 3

Peperiksaan Percubaan SPM 2012

MARKING SCHEME

SULIT Question

4541/3(PP)

8
Score

Rubric Able to state all procedures correctly Sample answer : 1. Draw an X on a white paper. 2. Pour [20-100] cm3 of [0.1 1.0] mol dm-3 sodium thiosulphate solution into a conical flask. 3. Record the temperature of solution. 4. Place the conical flask on the X. 5. Pour [5 10] cm3 of [0.1 1.0] mol dm-3 hydrochloric acid solution. 6. Swirl the conical flask and start the stopwatch immediately. 7. Stop the stopwatch when the X is no longer visible. Record the time taken. 8. Repeat steps 2 to 7 using 35oC, 40oC, 45oC and 50oC temperature of sodium thiosulphate solution. Able to state four steps of procedures correctly Steps 2, 4, 5, 8 Able to state two steps of procedures correctly

3(e)

1 Steps 2, 5 No response or wrong response Question Rubric Able to exhibit the tabulation of data that includes the following information. 1. Headings 2. With unit Sample answer : Temperature/ oC Time/s 30 35 40 45 50 Able to tabulate the data incompletely 1. Titles without unit Sample answer : Temperature Time 1 2 0 Score

3(f)

No response given / wrong response END OF MARKING SCHEME

Peperiksaan Percubaan SPM 2012

MARKING SCHEME