SYLLABY School Name Subject Class/Semester Year Competency Standard : SMA NEGERI 1 PALEMBANG : Chemistry : XI/1 : 2013 / 2014

: 3. Understanding the reaction kinetics, chemical equilibrium, and the factors that influence it, as well as its application in life daily and industry

Basic Competence

Materials

Indicator

Learning Activity

Assessment

Time Allocation 2x 45 minutes

Source /Apparatus/ Material Source : Hermanto, Ari. And Ruminten, 2009, Buku Sekolah Elektronik (BSE): Kimia 2 untuk SMA/MA Kelas XI, Jakarta : Pusat Perbukuan Departemen Pendidikan Nasional Apparatus : Instrument laboratory Material worksheet

3.1 Describe understanding The reaction rate Defining what it is the reaction Discuss what the students Evaluation type: the reaction rate by order know about the reaction Written Test conducting experiments on Explaining the definition of reaction order and factors that affect the factors that affect the Instrument form: the order of the reaction. order rate of reaction. Understand the reaction rate Multiple Choice, Essay Some factors that affect the order of the Explaining some factors that affect by the experiment reaction the order of the reaction

3.2 Understanding the theory `The collision theory of collision (collision) to explain the determinants of the rate and the order of the reaction and its application in daily life The reaction order

Explaining the factors to Discuss what the students Evaluation type: determining the rate of reaction know about collision theory to Written Test based on the collision theory explain the factors of determining the rate of Instrument form: Multiple Choice, reaction Calculate the reaction order Calculate and determine the order and reaction of time based on the result of experiment through class discussion. Practicing determine the order of the reaction, the reaction of rate equations and reaction of time

1x15 minutes

Source : Hermanto, Ari. And Ruminten, 2009, Buku Sekolah Elektronik (BSE): Kimia 2 untuk SMA/MA Kelas XI, Jakarta : Pusat Perbukuan Departemen Pendidikan Nasional Apparatus : Black Marker White board Stick

Evaluation type: Explaining the collision theory in Discuss the role of the Written Test daily life collision theory in daily life Instrument form: Multiple Choice, 3.3 Explain the equilibrium and Dynamic equilibrium Defining what it is the dynamic Understand the dynamic Evaluation type: factors affecting equilibrium equilibrium by the experiment Quiz, written test equilibrium friction toward Explaining the definition of dynamic the experiment. equilibrium Discuss what the students Instrument form: know about the Dynamic Multiple Choice, The factors that influence the direction of Explaining some factors that equilibrium and factors that Essay the equilibrium friction affecting equilibrium friction toward influence the direction of the equilibrium friction the experiment The role of the collision theory

2x 45 minutes

Material Worksheet

2 x 45 mintutes

Source : Hermanto, Ari. And Ruminten, 2009, Buku Sekolah Elektronik (BSE): Kimia 2 untuk SMA/MA Kelas XI, Jakarta : Pusat Perbukuan Departemen Pendidikan Nasional Apparatus : Instrument laboratory Material worksheet

3.4Determine the quantitative Quantitative relationship between Calculate the value of Kc, Kp and Practicing to calculate the relationship between reactants of the reaction equilibrium the degree of dissociation value of Kc, Kp and the reactants with the reaction (decomposition) through degree of dissociation product of an equilibrium discussion. (decomposition) through reaction. Exercise to calculate the value of discussion and calculate the value Kc by Kp or otherwise Kc, Kp. Exercise to calculate the value Kc by Kp or otherwise

Evaluation type: Written test, Quiz Instrument form: Multiple Choice, Essay

4 x 45 minutes

Source : Hermanto, Ari. And Ruminten, 2009, Buku Sekolah Elektronik (BSE): Kimia 2 untuk SMA/MA Kelas XI, Jakarta : Pusat Perbukuan Departemen Pendidikan Nasional Apparatus : Laptop, LCD projector White board Black marker Material Worksheet Powerpoint presentation Source : Hermanto, Ari. And Ruminten, 2009, Buku Sekolah Elektronik (BSE): Kimia 2 untuk SMA/MA Kelas XI, Jakarta : Pusat Perbukuan Departemen Pendidikan Nasional Apparatus : Laptop, LCD projector White board Black marker Material Worksheet Powerpoint presentation

3.5 Explain the application of Haber Bosch process and contact Assess the optimum conditions for Discuss the application of the the principle of equilibrium process the production of chemicals in principle of equilibrium in in daily life and industrial industries that are based on daily life and industrial equilibrium reaction.

Evaluation type: Written test Instrument form: Multiple Choice, Essay

2 x 45 minutes

LESSON PLAN
School Name Subject Class/Semester Meeting Year Time Allocation I. : SMA NEGERI 1 PALEMBANG : Chemistry : XI/1 : First meeting : 2013 / 2014 : 1 x 15 minutes

Competency Standard : 3. Understanding the reaction kinetics, chemical equilibrium, and the factors that influence it, as well as its application in life daily and industry.

II.

Basic Competence : 3.2 Understanding the theory of collision (collision) to explain the determinants of the rate and the order of the reaction and its application in daily life

III.

Indicator : 1. Explaining the factors to determining the rate of reaction based on the collision theory 2. Calculate the reaction order

IV.

Learning Objectives : 1.1 Through group discussions, students are able to explain the factors to determining the rate of reaction based on the collision theory. 2.1 Students can calculate the reaction order based on the results of the experiment

V.

Learning Materials : 1. Collision theory 2. The reaction order

VI.

Materials/Teaching points Reaction Rate Reaction rate theory Based on collision theory, the reaction will be happen if there is collision between particles. If there are many collision, the reaction will be fast. But not all collisions can be produce reactions, only some particles that have enough energy and has a good positioned to react.

Some Factors that affect the rate of reaction : 1. Surface area 2. Concentration of reactants 3. Pressure 4. Temperature 5. Catalytic

Reaction rate equation V = k. [A]x. [B]y which : v = Reaction rate equation k = Constants of reactions x = Reaction order A y = Reaction order B

VII.

Approaches and Methods : Approaches Methods : Cooperative learning type talking stick : Question and answer

VIII.

Apparatus and Materials : Apparatus Materials : Stick/pen : Reading materials

IX.

Teaching and Learning Process : Learning Activities Opening Section Checking student attendance before activites begin. Opens the lesson and motivates students: What are the factors that affect the rate of reaction? Main Section Teacher giving the reading material to students Teacher giving instruction to students to reading the materials which is will be used for talking stick activities. Teacher explained the rules of the talking stick model Randomly, the teacher give the stick to student then give a questions. Closing Section The students and teacher discussion about conclusion Teachers give some home work to students 3 10 2 Time

X.

Learning Resources Hermanto, Ari. And Ruminten, 2009, Buku Sekolah Elektronik (BSE): Kimia 2 untuk SMA/MA Kelas XI, Jakarta : Pusat Perbukuan Departemen Pendidikan Nasional Internet

XI.

Assessment : Learning Assessment Procedure: Techniques : Written Test Types : Multiple choice

XII.
No 1.

Instrument
Indicator Explaining the factors to determining the rate of reaction based on the collision theory Assessment 1. Which does not affect the rate of reaction is .... A. catalyst B. temperature C. surface area D. particle motion E. concentration 2. The function of catalyst in the reaction is...... A. to change the balance B. to increase or decrease the rate of reaction C. form solution D. as a major component of the reaction E. lower the activation energy of substances 3. Reaction between H2 and O2 gas at a temperature of 25 C is very slow, but when the Pt powder was added, the reaction becomes faster. This suggests that the reaction rate is influenced by .... A. temperature B. catalytic C. properties D. concentration E. surface area 4. For the reaction A + B C + D obtained the following data. Rate reaction (mol.liter-1det.-1) Data [A] (mol/liter) [B] (mol/liter) 1 0,1 0,1 x 2 0,2 0,2 8x 3 0,1 0,3 9x The Reaction order B is . . . A. 1 B. 2 C. 3 D. 4 E. 5 5. From this data Score 1 Key answer D

2.

Calculate the reaction order

No 1 2 3 4

[P] (M) [Q] (M) 0,10 0,10 0,10 0,10 0,10 0,20 0,20 0,20 Rate equation for the reaction is .... A. v = k [P]2[Q] B. v = k [P]2[Q][R] C. v = k [P][Q][R] D. v = k [P][Q]2[R] E. v = k [P][Q][R]2

[R] (M) 0,10 0,05 0,05 0,10

Laju reaksi (M/detik) 0,100 0,025 0,050 0,400

Scoring Score : Sum of the correct answer _____________________ Sum of sample x 100

Palembang, 20 Juli 2013 Mengetahui Headmaster of SMA Negeri 1 Palembang Chemistry Teacher

Drs. EFFENDI NAWAWI, M.Si NIP. 19601006 198803 1 002

SUCI FERALIA RATIKASESHA. NIP. 06101010021

EXERCISE
Name : Class : choose the correct answer

1. Which does not affect the rate of reaction is .... A. catalyst B. temperature C. surface area D. particle motion E. concentration 2. The function of catalyst in the reaction is......
A. to change the balance B. to increase or decrease the rate of reaction C. form solution D. as a major component of the reaction E. lower the activation energy of substances

3. Reaction between H2 and O2 gas at a temperature of 25 C is very slow, but when the Pt powder was added, the reaction becomes faster. This suggests that the reaction rate is influenced by .... A. temperature B. catalytic C. properties D. concentration E. surface area 4. For the reaction A + B C + D obtained the following data.
Data 1 2 3 [A] (mol/liter) 0,1 0,2 0,1 [B] (mol/liter) 0,1 0,2 0,3
Laju reaksi (mol.liter-1det.-1)

x 8x 9x

The Reaction order B is . . . A. 1 B. 2 C. 3 D. 4 E. 5 5. From this data

No 1 2 3 4 [P] (M) 0,10 0,10 0,10 0,20 [Q] (M) 0,10 0,10 0,20 0,20 [R] (M) 0,10 0,05 0,05 0,10 Laju reaksi (M/detik) 0,100 0,025 0,050 0,400

Rate equation for the reaction is .... A. v = k [P]2[Q] B. v = k [P]2[Q][R] C. v = k [P][Q][R] D. v = k [P][Q]2[R] E. v = k [P][Q][R]2

Materials/Teaching points

Reaction Rate

Reaction rate theory Based on collision theory, the reaction will be happen if there is collision between particles. If there are many collision, the reaction will be fast. But not all collisions can be produce reactions, only some particles that have enough energy and has a good positioned to react. Some Factors that affect the rate of reaction : 1. Surface area 2. Concentration of reactants 3. Pressure 4. Temperature 5. Catalytic Reaction rate equation Reaction : mA + nB pC + qD so the reaction rate equation is :

v = k. [A]x. [B]y

where : v = Reaction rate equation k = Constants of reactions x = Reaction order A y = Reaction order B example : from experiment, get some data which is shown in below [NO] (mol/L) [H2](mol/L) Rate reaction (mol/L.s) 0,6 0,1 3,2 0,6 0,3 9,6 0,2 0,5 1,0 0,4 0,5 4,0 determine the reaction rate equation based on the data Solution : to determine the order of the reaction to NO then we use the data in tabel which the concentration of [H2] has the same value (data 3 and 4) so : V3 = ( ). ( ) V4 1,0 = ( ) . ( ) 4,0 1 = ( ). ( ) 4 X=2 to determine the order of the reaction to H2 then we use the data in tabel which the concentration of [NO] has the same value (data 1 and 2) V1 = ( ). ( ) V2 3,2 = ( ) . ( ) 9,6 1 =( ).( ) 3 y =1 So the reaction rate equation is v = k. [NO]2. [H2]

Exercise : experimental data the rate of reaction 2CO(g) + O2 (g) 2CO2(g) is [CO] [O2] Rate reaction 0,2 0,1 x 0,2 0,3 3x 0,4 0,1 4x The orde reaction of [CO] is ...