CLASS TEST - 8

Q.1

(PHYSICAL)

CHEMISTRY

IIT-JEE

P. JOY

Of the graphs below, the one that best illustrates the relationship between [H3O+(aq)] and [OH(aq)] in a solution is]
(a q ) +
+ (a q )

Q.6

(A)

(B)
[OH (a q ) ]

[O H ( a q ) ]
(aq)

(C)

[H 3 O

(D)
[O H
(aq)

[H 3 O

A weak monoprotic acid (25.0 mL of a 0.10 M solution) is titrated to a phenolphthalein end-point with a 0.10 M solution of NaOH. Which statement about this titration is true? (A) The volume required will be less than 25.0 mL (B) The pH at the equivalence point will be less than 7. (C) The solution will be colourless after 27.0 mL of NaOH have been added. (D) The [H+] = [OH] at the equivalence point (E) The pH at the equivalence point will be above 7. An indicator that ionized as shown below for which its Ka = 1.0 104

[H 3 O

(a q )

[H 3 O

[O H (aq) ]

Q.7

Q.2

In the Hall-Heroult process, aluminum is produced by the electrolysis of molten Al2O3(l). The half reactions that occur are : C(s) + 2O2(l) CO2(g) + 4e Al3+(l) + 3e Al(l) The mass of Al(l) produced for each 1.00 kg of C(s) consumed is(A) 1.69 kg (B) 2.45 kg (C) 3.00 kg (D) 6.00 kg Methane gas can be prepared by reacting water with solid aluminum carbide, according to the following balanced reaction : Al4C3(s) + 12H2O(l) 4Al(OH)3(s) + 3CH4(g) In the above reaction, 75.0 g of Al4C3 (M.W. = 90.03 g/mol) reacted with 100.0 g of H2O (M.W. = 18.02 g/mole), and a student obtains 20.0 g of CH4 (M.W. = 16.04 g/mole). The student's percent yield is : (A) 39.8% (B) 71.4% (C) 79.7% (D) 90.0% Q.8

Q.3

HIn + H2O l H3O+ + In yellow red Select the answer that has all of the true statements. I. The predominant color in its acid range is yellow. II. In the middle of the pH range of its color change a solution containing the indicator will probably be orange. III. At pH = 7.00, a solution containing this indicator will be red. IV. At pH = 7.00, most of the indicator is unionized. V. The pH at which the indicator changes colour is pH = 4. (A) I, III, V (B) II, IV (C) III, IV, V (D) I, II, III, V A sample contains 3.01 1020 molecules of SFn and its mass is 54 mg. What is the value of n ? (A) 1 (B) 2 (C) 4 (D) 6 (E) 8 The molar mass of a gas with a density of 5.8 g L1 at 25C and 740 mm Hg is closest to(B) 150 g mol1 (A) 190 g mol 1 (C) 20 g mol 1 (D) 10 g mol1 1 (E) 5 g mol If 1.50 g of H2C2O4.2H2O were heated to drive off the water of hydration, how much anhydrous H2C2O4 would remain ? (A) 0.34 g (B) 0.43 g (C) 0.92 g (D) 1.07 g (E) 1.50 g What is the conjugate acid of HPO42 ? (A) H3PO4(aq) (B) H2PO4(aq) (E) PO43(aq) (C) H3O+(aq) (D) H+(aq) If the percentage of water of crystallization in CuSO4.xH2O is 36.1%, what is the value of x ? (A) 1 (B) 3 (C) 4 (D) 5 (E) 6

Q.9

Q.4

A 100 gram sample of CaCO3 was heated until 3.33 L of CO2 was collected at 50.0C and 742 torr. What percentage of the CaCO3 had decomposed ? R = 0.08206 L atm/mol K. 760 torr = 1 atm. (A) 6.84% (B) 9.10% (C) 12.3% (D) 15.8% Carbon dioxide reacts with water to form carbonic acid (H2CO3) and is called the acid anhydride of that acid. The anhydrides of sulfurous and nitric acids are : (B) SO2 and N2O5 (A) SO3 and NO2 (C) SO3 and N2O5 (D) SO2 and NO2 (E) SO42 and NO2

Q.10

Q.5

Q.11

Q.12

&
Name : .......................................................................................................... 1 2 3 4 A B C D E 5 6 7 8 A B C D E

&
Roll No. : .................................. 9 10 11 12 A B C D E

CHEMISTRY IIT JEE (CLASS TEST - 8) (PHYSICAL) A N S W E R K E Y

ANSWER KEY (PHYSICAL TEST - 8)

Que. Ans. 1 A 2 C 3 D 4 C 5 B 6 E 7 D 8 C 9 B 10 D 11 B 12 D