Energy Balance: During Switching: For G1: Adsorption (Mac*Cpac+Mac*Cpm*(dx1/dt)+Mal*Cpal+Mcu*Cpcu)dTads1/dt= Mac*Qst*(dx1/dt)+Mcw*Cpw*(Tci- Tco) The left side represents metallic

part of bed and carbon. The 1st part of left side term represents the heat the required sensible cooling of methanol, the methanol amount absorbed by activated represents the adsorption heat. The 2 nd transfer by cooling water

(Mac*Cpac+Mac*Cpm*(dx1/dt)+40.4)dTads/dt= Mac*Qst*(dx1/dt*(dx1/dt)+Mcw*Cpw*(Tci- Tco) Tco=Tads+(Tci-Tads)*exp(-(Ub*Ab)/(Mcw*Cpw))

For G2: Desorption (Mac*Cpac+Mac*Cpm*(dx2/dt)+Mal*Cpal+Mcu*Cpcu)dTdes2/dt= Mac*Qst*(dx2/dt)+Mhw*Cpw*(Thi- Tho) The left side represents metallic part of bed and carbon. The 1st part of left side term represents the heat the required sensible heating of methanol, the methanol amount absorbed by activated represents the adsorption heat. The 2 nd transfer by heating water

(Mac*Cpac+Mac*Cpm*(dx2/dt)+40.4)dTdes2/dt= Mac*Qst*(dx1/dt*(dx1/dt)+Mcw*Cpw*(Tci- Tco) Tho=Tdes2+(Thi-Tdes2)*exp(-(Ub*Ab)/(Mhw*Cpw)) For G3: Desorption (Mac*Cpac+Mac*Cpm*(dx2/dt)+Mal*Cpal+Mcu*Cpcu)dTdes3/dt= Mac*Qst*(dx2/dt)+Mhw*Cpw*(Thi- Tho) The left side represents the required sensible heating of methanol, metallic part of bed and the methanol amount absorbed by activated carbon.

The 1st part of left side represents the adsorption heat. The 2 nd term represents the heat transfer by heating water (Mac*Cpac+Mac*Cpm*(dx2/dt)+Mal*Cpal+Mcu*Cpcu)dTdes3/dt= Mac*Qst*(dx2/dt)+Mhw*Cpw*(Thi- Tho) Tho=Tdes3+(Thi-Tdes3)*exp(-(Ub*Ab)/(Mhw*Cpw)) For G4: Adsorption (Mac*Cpac+Mac*Cpm*(dx1/dt)+Mal*Cpal+Mcu*Cpcu)dTads4/dt= Mac*Qst*(dx1/dt)+Mcw*Cpw*(Tci- Tco) The left side represents metallic part of bed and carbon. The 1st part of left side term represents the heat the required sensible cooling of methanol, the methanol amount absorbed by activated represents the adsorption heat. The 2 nd transfer by cooling water

(Mac*Cpac+Mac*Cpm*(dx1/dt)+40.4)dTads4/dt= Mac*Qst*(dx1/dt)*(dx1/dt)+Mcw*Cpw*(Tci- Tco) Tco=Tads4+(Tci-Tads)*exp(-(Ub*Ab)/(Mcw*Cpw))

For Evaporator (-Mac*((dx1/dt)+(dx2/dt))*Cpm+Meva*Cpeva)dTeva/dt= Mac*hfg*(dx1/dt)+ Mch*Cpw*(Tchi-Tcho) The left side represents the required sensible heat transfer of methanol, metallic part of evaporator heat exchanger. The 1st part of left side represents latent heat. The 2nd term represents the heat transfer by chilled water Tcho=Teva+(Tchi-Teva)* exp(-(Ueva*Aeva)/(Meva*Cpw))

For Condenser (-Mac*((dx1/dt)+(dx2/dt))*Cpm+Mcon*Cpcon)dTcon/dt= -Mac*hfg*(dx2/dt)+ Mcon*Cpw*(Tconi-Tcono) The left side represents the required sensible heat transfer of methanol, metallic part of condenser heat exchanger. The 1st part of left side represents latent. The 2nd term represents the heat transfer by cooling water Tcono=Tcon+(Tconi-Tcon)* exp(-(Ucon*Acon)/(Mcon*Cpw))
For Air Cooled Condenser: ((Mconm*Cpm+Mcon*Cpcon)*dTcon/dt)=-Mac*hfg*dx2/dt+Ucon*Acon(Tcon-Tair)

During Operation For G1: Adsorption (Mac*Cpac+Mac*Cpm*(dx1/dt)+Mal*Cpal+Mcu*Cpcu)dTads1/dt= Mac*Qst*(dx1/dt)-Mac*Cpm*(Tads-Teva)*(dx1/dt)+Mcw*Cpw*(Tci- Tco) The left side represents the required sensible heat transfer of methanol, metallic part of bed and the methanol amount absorbed by activated carbon. The 1st part of left side represents the adsorption heat. The 2 nd term represents heat flow from condenser to evaporator. 3rd term represents the heat transfer by cooling water. (Mac*Cpac+Mac*Cpm*(dx1/dt)+40.4)dTads1/dt= Mac*Qst*(dx1/dt)Mac*Cpm*(Tads-Teva)*(dx1/dt)+Mcw*Cpw*(Tci- Tco) Tco=Tads1+(Tci-Tads1)*exp(-(Ub*Ab)/(Mcw*Cpw)) For G2: Desorption (Mac*Cpac+Mac*Cpm*(dx2/dt)+Mal*Cpal+Mcu*Cpcu)dTdes2/dt= Mac*Qst*(dx2/dt)+Mhw*Cpw*(Thi- Tho)

The left side represents metallic part of bed and carbon. The 1st part of left side term represents the heat

the required sensible heating of methanol, the methanol amount absorbed by activated represents the adsorption heat. The 2 nd transfer by heating water.

Tho=Tdes2+(Thi-Tdes2)*exp(-(Ub*Ab)/(Mhw*Cpw))

For G3: Desorption (Mac*Cpac+Mac*Cpm*(dx2/dt)+Mal*Cpal+Mcu*Cpcu)dTdes3/dt= Mac*Qst*(dx2/dt)+Mhw*Cpw*(Thi- Tho) The left side represents the required sensible heating of methanol, metallic part of bed and the methanol amount absorbed by activated carbon. The 1st part of left side represents the adsorption heat. The 2 nd term represents the heat transfer by heating water. Tho=Tdes3+(Thi-Tdes3)*exp(-(Ub*Ab)/(Mhw*Cpw))

For G4: Adsorption (Mac*Cpac+Mac*Cpm*(dx1/dt)+Mal*Cpal+Mcu*Cpcu)dTad4/dt= Mac*Qst*(dx1/dt)-Mac*Cpm*(Tads4-Tm)*(dx1/dt)+Mcw*Cpw*(Tci- Tco) The left side represents the required sensible cooling of methanol, metallic part of bed and the methanol amount absorbed by activated carbon. The 1st part of left side represents the adsorption heat. The 2 nd term represents the sensible heat of methanol and 3rd term represents the heat transfer by cooling water. (Mac*Cpac+Mac*Cpm*(dx1/dt)+40.4)dTads4/dt= Mac*Qst*(dx1/dt)Mac*Cpm*(Tads4-Tm)*(dx1/dt)+Mcw*Cpw*(Tci- Tco) Tco=Tads4+(Tci-Tads4)*exp(-(Ub*Ab)/(Mcw*Cpw))

For Evaporator (-Mac*((dx1/dt)+(dx2/dt))*Cpm+Meva*Cpeva)dTeva/dt= Mac*hfg*(dx1/dt)-Mac*Cpm*(Tcon-Teva)*(dx2/dt)+ Mch*Cpw*(Tchi-Tcho) The left side represents the required sensible heat transfer of methanol, metallic part of evaporator heat exchanger. The 1st part of left side represents latent heat. The 2nd term represents the heat flow from condenser to evaporator and 3rd term represents the heat transfer by chilled water. Tcho=Teva+(Tchi-Teva)* exp(-(Ueva*Aeva)/(Meva*Cpw))

For Condenser (-Mac*((dx1/dt)+(dx2/dt))*Cpm+Mcon*Cpcon)dTcon/dt= -Mac*hfg*(dx2/dt)-Mac*Cpm*(Tads-Tcon)*(dx2/dt)+ Mcon*Cpw*(TconiTcono. The left side represents the required sensible heat transfer of methanol, metallic part of condenser heat exchanger. The 1st part of left side represents latent heat. The 2nd term represents the heat flow from adsorption bed and 3rd term represents the heat transfer by cooling water. Tcono=Tcon+(Tconi-Tcon)* exp(-(Ucon*Acon)/(Mcon*Cpw))
For Air Cooled Condenser: ((Mconm*Cpm+Mcon*Cpcon)*dTcon/dt)=-Mac*hfg*dx2/dt-Mac*Cpm*(TdesTcon)*dx2/dt+Ucon*Acon(Tcon-Tair)

Reverse Cycle

For G1: Adsorption----Desorption (Mac*Cpac+Mac*Cpm*(dx1/dt)+Mal*Cpal+Mcu*Cpcu)dTdes1/dt= Mac*Qst*(dx1/dt)+Mhw*Cpw*(Thi- Tho) (Mac*Cpac+Mac*Cpm*(dx1/dt)+40.4)dTdes1/dt= Mac*Qst*(dx1/dt*(dx1/dt)+Mhw*Cpw*(Thi- Tho) Tho=Tdes1+(Thi-Tdes1)*exp(-(Ub*Ab)/(Mhw*Cpw)) For G2: Desorption------ Adsorption (Mac*Cpac+Mac*Cpm*(dx2/dt)+Mal*Cpal+Mcu*Cpcu)dTads2/dt= Mac*Qst*(dx2/dt)+Mcw*Cpw*(Tci- Tco) Tco=Tads2+(Tci-Tads2)*exp(-(Ub*Ab)/(Mcw*Cpw))

For G3: Desorption------ Adsorption

(Mac*Cpac+Mac*Cpm*(dx2/dt)+Mal*Cpal+Mcu*Cpcu)dTads3/dt= Mac*Qst*(dx2/dt)+Mcw*Cpw*(Tci- Tco) Tco=Tads3+(Tci-Tads3)*exp(-(Ub*Ab)/(Mcw*Cpw)) For G4: Adsorption------Desorption (Mac*Cpac+Mac*Cpm*(dx1/dt)+Mal*Cpal+Mcu*Cpcu)dTdes4/dt= Mac*Qst*(dx1/dt)+Mhw*Cpw*(Thi- Tho) (Mac*Cpac+Mac*Cpm*(dx1/dt)+40.4)dy/dt= Mac*Qst*(dx1/dt)*(dx1/dt)+Mhw*Cpw*(Thi- Tho) Tho=Tdes4+(Tci-Tdes4)*exp(-(Ub*Ab)/(Mhw*Cpw))

For Evaporator (-Mac*((dx1/dt)+(dx2/dt))*Cpm+Meva*Cpeva)dTeva/dt= Mac*hfg*(dx1/dt)+ Mch*Cpw*(Tchi-Tcho) Tcho=Teva+(Tchi-Teva)* exp(-(Ueva*Aeva)/(Meva*Cpw)) For Condenser (-Mac*((dx1/dt)+(dx2/dt))*Cpm+Mcon*Cpcon)dTcon/dt= -Mac*hfg*(dx2/dt)+ Mcon*Cpw*(Tconi-Tcono) Tcono=Tcon+(Tconi-Tcon)* exp(-(Ucon*Acon)/(Mcon*Cpw))
For Air Cooled Condenser: ((Mconm*Cpm+Mcon*Cpcon)*dTcon/dt)=-Mac*hfg*dx2/dt+Ucon*Acon(Tcon-Tair)

During Operation

For G1: Desorption (Mac*Cpac+Mac*Cpm*(dx2/dt)+Mal*Cpal+Mcu*Cpcu)dTdes1/dt= Mac*Qst*(dx1/dt)+Mhw*Cpw*(Thi- Tho) Tho=Tdes1+(Thi-Tdes1)*exp(-(Ub*Ab)/(Mhw*Cpw)) For G2: Adsorption (Mac*Cpac+Mac*Cpm*(dx1/dt)+Mal*Cpal+Mcu*Cpcu)dTads2/dt= Mac*Qst*(dx2/dt)-Mac*Cpm*(Tads2-Tdes1)*(dx2/dt)+Mcw*Cpw*(Tci- Tco) (Mac*Cpac+Mac*Cpm*(dx1/dt)+40.4)dTads2/dt= Mac*Qst*(dx2/dt)Mac*Cpm*(Tads2-Tdes1)*(dx2/dt)+Mcw*Cpw*(Tci- Tco) Tco=Tads2+(Tci-Tads2)*exp(-(Ub*Ab)/(Mcw*Cpw))

For G3: Adsorption

(Mac*Cpac+Mac*Cpm*(dx2/dt)+Mal*Cpal+Mcu*Cpcu)dTads3/dt= Mac*Qst*(dx2/dt)- Mac*Cpm*(Tads3-Teva)*dx1+Mcw*Cpw*(Tci- Tco) Tco=Tads3+(Tci-Tads3)*exp(-(Ub*Ab)/(Mcw*Cpw)) For G4: Desorption (Mac*Cpac+Mac*Cpm*(dx2/dt)+Mal*Cpal+Mcu*Cpcu)dTdes4/dt= Mac*Qst*(dx1/dt)+Mhw*Cpw*(Thi- Tho) Tho=Tdes4+(Thi-Tdes4)*exp(-(Ub*Ab)/(Mhw*Cpw))

For Evaporator

(-Mac*((dx1/dt)+(dx2/dt))*Cpm+Meva*Cpeva)dTeva/dt= Mac*hfg*(dx1/dt)-Mac*Cpm*(Tcon-Teva)*(dx2/dt)+ Mch*Cpw*(Tchi-Tcho) Tcho=Teva+(Tchi-Teva)* exp(-(Ueva*Aeva)/(Meva*Cpw)) For Condenser (-Mac*((dx1/dt)+(dx2/dt))*Cpm+Mcon*Cpcon)dTcon/dt= -Mac*hfg*(dx2/dt)-Mac*Cpm*(Tdes1-Tcon)*(dx2/dt)+ Mcon*Cpw*(TconiTcono) Tcono=Tcon+(Tconi-Tcon)* exp(-(Ucon*Acon)/(Mcon*Cpw))
For Air Cooled Condenser: ((Mconm*Cpm+Mcon*Cpcon)*dTcon/dt)=-Mac*hfg*dx2/dt-Mac*Cpm*(Tdes1Tcon)*dx2/dt+Ucon*Acon (Tcon-Tair)

Mass Balance

dMevam/dt= =-Mac*(dx1/dt+dx2/dt) Cooling Capacity and COP CC=Mchw*Cpw* COP=Mchw*Cpw* /Mhw*Cpw* dt

Saturation Pressure for Methanol Ps= exp (1-(2/T)) 1=20.84 2=4696 Isotherm
% xo1=a*exp(-k((T(1)/Ts)-1))^n % DS1=DSo*exp(-Ea/R*T(1)) % dx1/dt=15*((DS1/(RP^2))*(xo1-x1) % xo2=a*exp(-k((T(2)/Ts)-1))^n % DS2=DSo*exp(-Ea/R*T(2)) % dx2/dt=15*((DS2/(RP^2))*(xo2-x2)

% Ps=133.32*exp(18.3-(3820/(T-46.1)

Ea=3000 R=8.314 RP=0.0045 a=0.284 n=1.39 k=10.21 Ub=1 Ab=1 Ueva=1 Ucon=1 Cpeva=3 Cpcon=3 Aeva=2 Acon=2 Mhw=1 Mcw=1

Mchw=2 Mcon=2 Meva=30 Mcon=30 Cpw=4.18 DSo=1*10^-6 Mac=15 Qst=2000 Cpac=1 Cpm=0.75 hfg=1100 Thi=80 Tci=30 Tchi=7 Tconi=30 Tair=30