OMEGA TUITION CENTRE

Students name : ____________________________________ Teachers Name : Mr Chew Chin Kuen Subject : Chemistry Form 5 Class Attend : 5 Chemistry 6 Chapter 2 : carbon compound lesson 14 (26 mac 2011) 2.30 4.30 pm

1.

Figure 3 shows a few conversions of organic compounds from one homologous series to another homologous series. Name the reaction in conversion I. hydrogenation [1] Write an equation for the reaction in conversion II. C4H8 + Br2 C4H8Br2 [1]

(a) (b)

(c) (d)

Name a reagent for the reaction in conversion III. Acidified potassium manganate (VII) [1] Draw the structural formula of 1,2-dibromobutane. [1]

(e)

But-1-ene and but-2-ene are isomers of butene. Draw the structural formula for one isomer of butene and name the isomer.

[2]

But-1-ene
(f) (i) (ii)

but-2-ene

2-methylpropene
alkene [1]

Name the homologous series of but-1-ene.

Compare the sootiness of the flame from burning but-1-ene with butane in air.[1] But-1-ene burn with more sootiness compare to butane

(iii) Explain your answer in (f)(i). [Relative molecular mass: but-1-ene, 56; butane, 58]

[2]

But-1-ene butane % of C = 4(12) / 56 x 100% = 85.7% % of C = 4(12) / 58 x 100% = 82.8% Since but-1-ene has higher percentage of carbon so it has more sootiness

(g) Butan-1-ol reacts ts with butanoic acid in the presence of concentrated sulphuric acid to produce an organic compound X. (i) Name X. butyl butanoate [1] (ii) Give one physical property of X. insoluble nsoluble in water / colourless liquid with sweet smell [1]

polyethene

2.

Figure 2 shows the conversion of an unsaturated hydrocarbon, J, to other compounds via processes I, II, III and complete combustion in air. What is meant by unsaturated hydrocarbon? Compound which contain only C and H in it with at a least one C=C [2]

(a)

(b)

Draw the structural formula of J.

H H C H C H

[1]

(c) (d)

Name process I.

polymerisation

[1] [1]

State the observation that occurs to bromine in process II. Brown colour of bromine water was decolourised by J

(e)

Describe how J can be converted to ethanol by process III. Write an equation for the reaction in process III.

[3]

J is passed through together with a flow of steam, catalysed by diluted sulphuric acid and form a colourless solution (f) (g) Name compound R. C2H4 + H2O C2H5OH [1]

carbon dioxide

Ethanol can be converted to J. Draw a diagram of the set-up set up of the apparatus to convert ethanol to J and to collect J produced. [3]

3.

Figure 4 shows reactions such as hydrogenation, polymerisation, conversion I and conversion II for propene, C3H6, to other compounds. (i) State the conditions for the hydrogenation of propene. hydrogen gas heated to 1800C and catalysed by nickel (ii) Compound R is a member of a homologous series. Write the general formula of this series. CnH2n+2 [1] [1]

(a)

(b)

Combustion of compound R and propene produce flames of different sootiness. (i) State why compound R and propene produce flames of different sootiness. Because they have different percentage of carbon (ii) Write an equation for the combustion of propene in air. 2 C3H6 + 9 O2 6 CO2 + 6 H2O [1] [1] [1]

(c) (d)

Name compound Q. polypropene The reaction in conversion I produces compound P. (i) State the observation in conversion I. Brown colour of bromine water is decolourised (ii) Name the type of reaction in conversion I. Additional reaction

[1]

[1]

(e)

In conversion II, propene is oxidised to compound with formula C3H6(OH)2 by substance Y. (i) Suggest a suitable substance for Y. Acidified potassium manganate (VII) (ii) Draw the structural formula of the compound with formula C3H6(OH)2. [1] [1]

4. (a)

Figure 4 shows a flow chart with a number of conversion reactions of alcohol Z with formula C3H8O. Draw the structural formula of alcohol Z. [1]

(b)

Write a chemical equation for the combustion of alcohol Z in conversion I. 2 C3H8O + 9 O2 6 CO2 + 8 H2O

[1]

(c)

Substance R is a colourless liquid. (i) (ii) State a characteristic property of R. produce sweet smell / insoluble in water [1] Name the organic compound Y used in conversion II. ethanoic acid [1]

(d)

(i)

Name the reaction in conversion III to produce substance Q. Oxidation reaction

[1]

(ii)

State the observation for the reaction in conversion III. Orange colour of solution turns green

[1]

(iii)

Name a suitable substance to replace the acidified potassium dichromate(VI) in conversion III. Acidified potassium manganate (VII) [1] [1]

(e)

(i)

Draw the structural formula of substance P.

(ii)

Name the product formed when substance P is shaken with tetrachloromethane[1] propene

(iii)

Draw a diagram for the set-up of the apparatus for an experiment to carry out conversion IV in the laboratory.

[2]

5. Figure 2 shows the stages in the conversion of X to butanoic acid, X to butene and butene to hydrocarbon Y.

(a) (b)

Write the molecular formula of butene. Draw two structural formulae of butene.

C4H8

[1] [2]

(c)

Give the steps for preparing butene from X.

[2]

X is passed though a hot porcerlain chips. Gas formed were collected under test tube filled with water which are placed upside down. (d) Write an equation for the hydrogenation of butene to hydrocarbon Y. C4H8 + H2 (e) C4H10 [1]

X can be converted to butanoic acid by oxidation when it is added to acidified potassium dichromate(VI). (i) State the observation in the above oxidation reaction. Orange solution turns green when added to X (ii) Write an equation for the oxidation reaction. C4H9OH + 2 [O] C3H7COOH + H2O [1] [1]

6.

Figure 4 shows the set-up of apparatus for the preparation of ethyl ethanoate from the reaction between ethanol and ethanoic acid.

(a) (b)

On the condenser mark X where water enters and Y where water flows out. Why is the mixture heated in a water bath?

[1] [2]

To ensure an even heating on the solution and to enhance the rate of reaction for esterification (c) (i) Name the reaction for preparing ethyl ethanoate. esterification (ii) Write an equation for the reaction in (c)(i). CH3COOH + C2H5OH (d) CH3COOC2H5 + H2O [1] [1]

The experiment is repeated by replacing ethanol with propanol. (i) (ii) Name the ester formed. Propyl ethanoate [1] [1]

Give a physical property of the ester. Have sweet smell / insoluble in water

(e)

The flow chart below shows the conversion of ethanol to ethene and ethanol to ethanoic acid.

Base on the chart, write a chemical equation for (i) (ii) process I process II C2H5OH C2H4 + H2O [1] [1]

C2H5OH + 2 [O]

CH3COOH + H2O

ethanoic acid / methanoic acid disulphur dichloride / sulphur catalysed by zinc oxide

rubber molecules were protected by a negative charged membrane. When these molecules collide, they will repel each other

rubber is inelastic since when pulled, the rubber stretched, but when the forces were lifted, it will not revert to original shape

disulphide linkage cross-linked between the rubber long chain

- rubber become harder and stronger / - rubber become more elastic / - rubber become more resistant to oxidation by air / - rubber can withstand high temperature and more stable

bacteria from surrounding decomposed to form acidic substance and neutralised the negatively charged membrane

HCOOH / CH3COOH NH3