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1500 TPD Ammonia

Natural Gas Composition (mol%)


Methane
Ethane
Propane
Butane
Nitrogen
Carbondioxide
Total

92%
2%
2%
1%
2%
1%
100%

Pressure
Temperature
Basis
Desired Production Rate

4743
1500

psig
F
kgmol/hr Mixed
Tonnes/day

Stream Factor
Operating hours

345
8280

days
hours

Max. Hydrocarbon conc. in Steam reformer


0.50%outlet gas
Steam to hydrocarbon ratio in Primary Reformer
3.3

Natural gas Flow rate

Naphtha

4743

mmonia production via Dual feed Ste


Naptha composition (mol%)
Naphtha
Carbon
46
100%
Hydrogen(H2)
53.9
Sulphur
0.17 8.06

Total

100
8.06
C

kgmol/hr Mixed Feed


Tonnes/day

H
46 53.9
1.17

hours
552 108

5.44 665

feed Steam reforming


N.Gas
0%

551.8 108 5.44 665


6.65
6.65

6.649

Pre Reformer
Naphtha
Temperature
Pressure
Pressure Drop
HC to Steam Ratio

Reaction 1
Reaction 2
Reaction 3
Selectivity

4743
763 K
psig
psig
3.5

CnHm + n H2O ---> nCO + (2n+m)/2 H2


CO + H2O --> CO2 + H2
CO + 3H2--> CH4 + H2O
100 mol CH4 / mol of CO2
Stream 1 (Naphtha)

Components

Carbon
Hydrogen(H2)
Hydrogen gas
Carbon monoxide
Carbon dioxide
Methane
Steam
Total

Steam Consumed
Steam un reacted
CO produced

Mol. Wt

12
2
2
28
44
16
18

2193.57
6713.29
2180.831

Mole Flow Mass Flow


Mol%
(kgmol/hr)
(kg/hr)
44.61479 2180.8314 26169.977
52.25112 2554.1055 5108.211
3.134097 153.19890 306.3978
100

4888.1358 31584.586
47.43

Co consumed
CO 2 produced.
Ch4 Produced

Components
Methane
Ethane
Propane
Butane
Nitrogen
Carbon dioxide
Carbon monoxide
Hydrogen
Oxygen
Steam
Naphtha

1286.691
894.1409
12.73951
1273.951

0.00

Heat of Formations & Cp coefficients


Heat of
Mol. Wt
Formatio
ns
A
B
16
-74520
1.702
0.009081
30
-83820
1.131
0.019225
44
-104680
1.213
0.028785
58
-125790
1.935
0.036915
28
0
3.28
0.000593
44
-393509
5.457
0.001045
28
-110525
3.376
0.000557
2
0
3.249
0.000422
32
0
3.639
0.000506
18
-241818
3.47
0.00145
659.46 -1840303 -

Pre- Ref
Components

Methane
Ethane
Propane
Butane
Nitrogen

Mol. Wt

16
30
44
58
28

Mol%
0.00%
0.00%
0.00%
0.00%
0.00%

Mol%
Mole Flow accomodat
(kgmol/hr)
ed
0.00
0.00%
0.00
0.00%
0.00
0.00%
0.00
0.00%
0.00%

Carbon dioxide
Carbon monoxide
Hydrogen
Oxygen
Steam
Naphtha

44
28
2
32
18
659.46

KJ/Kmol
Del H specific
-37716.9
Del H
-3E+08
Heat of Formation Summation
Heat Supply required

0.00%
0.00%
3.13%
0.00%
0.00%
0.00%

0.00
153.20
0.00
7632.91
47.43
7833.54

0.00%
0.00%
1.96%
0.00%
97.44%
0.61%
100.00%

Gjoules/hr
-295.457
-1933.06
0.024047

rxn heat

1
Pre reformer
2

Excess steam is used to ensure all naphtha converted


60% based on CO
0.59
100

Stream 2 (Steam)
Mole
Mass
Flow
Flow
Mol% (mol/hr) (kg/hr)
100
100

7632.91 1E+05
7632.91 1E+05

Stream 3(Raw syn gas)


Mole
Flow
(kgmol/ Mass Flow
Mol%
hr)
(kg/hr)
10.82 1079.02
2158.04
8.97
894.14
25035.94
0.13
12.74
560.54
12.77 1273.95
20383.22
67.31 6713.29 120839.2201
100
9973.14
168976.96
0.00

& Cp coefficients

D
API Gravity 74.7682
Sp. Gravity
0.686
Heating value17924.2 BTU/Lb
41602 J/kg
27434.8 kj/mol
n
m
45.98
53.85
M.wat
659.46
Heat of Formation
-1840303.279

-0
0
-0
0
-0
0
-0
0
0
4000
0 -115700
0
-3100
0
8300
0 -22700
0 12100
Pre- Reformer Inlet

T
initial
1036
1036
1036
1036
1036

T final
298.00
298.00
298.00
298.00
298.00

Tau
0.288
0.288
0.288
0.288
0.288

Cp
55.6878
93.3467
133.742
174.321
30.5673

<Cp>
0
0
0
0
0

H0f
0.00
0.00
0.00
0.00
0.00

1036
1036
1036
1036
1036
1405
763
763

110.9

298.00
298.00
298.00
298.00
298.00
77.00
1405.4

0.288
0.288
0.288
0.288
0.288
-

50.9067
0
31.15
0
29.3709 0.5744
33.0101
0
36.9174 35.9719
2404.84 14.5607
51.107

0.00
0.00
0.00
0.00
-235624.67
-11142.55
-246767.22

H2 for Hyderotreating (a)161.3 kgmol/hr


#####

Pre-Reformer Outlet

Mol%
0.00%
0.00%
0.00%
0.00%
0.00%

Mole
Flow
Mol%
(kgmol/hr accomod
T
)
ated
initial
1273.95 12.77% 298
0.00
0.00%
298
0.00
0.00%
298
0.00
0.00%
298
0.00
0.00%
298

T final
783.00
783.00
783.00
783.00
783.00

Tau
2.628
2.628
2.628
2.628
2.628

Cp <Cp>
49.35 6.304
81.38
0
116.6
0
152.4
0
30.92
0

0.00%
0.00%
100.00%
0.00%
100.00%
200.00%

12.74
894.14
1079.02
6713.29

0.13%
8.97%
10.82%
0.00%
67.31%

298
298
298
298
298

783.00
783.00
783.00
783.00
783.00

2.628
2.628
2.628
2.628
2.628

21.6
29.81
30.95
26.94
38.34

9973.14 100.00%

KJ/Kmol Gjoules/hr
Del H specific
18508.49
Del H
1.85E+08 184.588
Heat of Formation Summation
-1822.17

0.028
2.672
3.349
0
25.81
38.16

510.00 Temp C

Heat Exchange from Flue Gas Conve


0.02405

H0f
-9519.05
0.00
0.00
0.00
0.00

Mol%
0.00%
0.00%
0.00%
0.00%
0.00%

Stream 10 (SR OUTLET) Heat Exchange from Convec


Mole
Flow
Mol%
(kgmol/h accomo
T
r)
dated
initial T final
Tau
1273.95 12.77% 783.00 973.00 1.243
0.00
0.00%
783
973.00 1.243
0.00
0.00%
783
973.00 1.243
0.00
0.00%
783
973.00 1.243
0.00
0.00%
783
973.00 1.243

-502.66
-9909.10
0.00
0.00
-162776.59

0.00%
0.00%
0.00%
0.00%
0.00%

-182707.41 0.00%

12.74
0.13%
894.14
8.97%
1079.02 10.82%
0.00
0.00%
6713.29 67.31%
0.00
9973.14 100.00%

KJ/Kmol Gjoules/hr
Del H specific
7864.26
lue Gas Convection section
Del H
7.8E+07 78.4313

783
783
783
783
783

973.00
973.00
973.00
973.00
973.00

1.243
1.243
1.243
1.243
1.243

ge from Convection section

Cp <Cp>
66.52 8.497
114
0
163.4
0
212.2
0
31.67
0

H0f
-9519.05
0.00
0.00
0.00
0.00

51.05
32.08
30.23
33.57
39.64

0.065
2.876
3.271
0
26.68
41.39

-502.66
-9909.10
0.00
0.00
-162776.59
0.00
-182707.41

N.Gas

Primary Reformer Inlet

0%

Naphtha
100.0%

Primary Reformer Outlet


700 C
Temperature
575 psig
Pressure
10 psig
Pressure Drop
3
HC to Steam Ratio
0
Mixed with N.Gas

Temperature
Pressure
Pressure Drop
HC to Steam Ratio
N.Gas Flow rate

Steam

Reaction 1
Reaction 2
Reaction 3
Reaction 4
Reaction 5

750
575
10
3
4

Reactions in Primary Reformer


CH4 + H2O = CO + 3H2
C2H6 + 2H2O = 2CO + 5H2
C3H8 + 3H2O = 3CO + 7H2
C4H10 + 4H2O = 4CO + 9H2
CO+H2O = CO2 + H2

75%
100%
100%
100%
40%

Total

Stream 4 (Mixed stream withNatural Gas)


Mass Flow
Mol%
Mole Flow (kgmol/hr)
(kg/hr)
12.77381594
1273.95
20383.21625
0
0
0
0
0
0
0
0
0
0
0
0
0.127738159
12.73951016
560.538447
8.965486749
894.14
25035.94447
10.81927924
1079.02
2158.044525
67.31367991
6713.29
120839.2201
100
9973.14
168976.9638

Total Primary Reformer Inlet

165214.7057 kg/hr

Components

Methane
Ethane
Propane
Butane
Nitrogen
Carbon dioxide
Carbon monoxide
Hydrogen
Oxygen
Steam
Argon

CO Production
Reaction 1
Reaction 2
Reaction 3
Reaction 4
Total
CO Consume

Mol. Wt
16
30
44
58
28
44
28
2
32
18
40

Del H Rxn
955.46
0
0
0
1849.60

kgmol/hr
kgmol/hr
kgmol/hr
kgmol/hr

1.96647E+11
0
0
0

Reaction 5

739.841654 kgmol/hr

CO2 Produced
Reaction 5

739.841654 kgmol/hr

H2 Produced
Reaction 1
Reaction 2
Reaction 3
Reaction 4
Reaction 5
Total

2866.38979
0
0
0
739.841654
4685.25

-30456321543

kgmol/hr
kgmol/hr
kgmol/hr
kgmol/hr
kgmol/hr
kgmol/hr

Steam consumption
Reaction 1
955.463262 kgmol/hr
Reaction 2
0 kgmol/hr
Reaction 3
0 kgmol/hr
Reaction 4
0 kgmol/hr
Reaction 5
739.841654 kgmol/hr
Total
1695.30492 kgmol/hr
1.6619E+11

166.1904388

Equilibrium Shift Conversion


1849.60
4654.67
CO

6504.28
H20

1849.60
a

4654.67
b

-0.3
CO conc eqlib

-8498.41
17412.14
-29020.236

Keq
Conv.
CO2
H2
12.73951016
c
6026509.804
CO conc. Eq

0.7
37.43%
3945.41

-415.3315507
692.2192511
Heat of Formations & Cp coefficients

Components

Methane
Ethane
Propane
Butane
Nitrogen
Carbon dioxide
Carbon monoxide

Mol. Wt
16
30
44
58
28
44
28

Heat of
Formations
-74520
-83820
-104680
-125790
0
-393509
-110525

A
1.702
1.131
1.213
1.935
3.28
5.457
3.376

B
0.009081
0.019225
0.028785
0.036915
0.000593
0.001045
0.000557

Hydrogen
Oxygen
Steam

2
32
18

0
0
-241818

3.249
3.639
3.47

0.000422
0.000506
0.00145

Primary Reforme
Components

Mol. Wt

Methane
Ethane
Propane
Butane
Nitrogen
Carbon dioxide
Carbon monoxide
Hydrogen
Oxygen
Steam

16
30
44
58
28
44
28
2
32
18

Mol%
12.77%
0.00%
0.00%
0.00%
0.00%
0.13%
8.97%
10.82%
0.00%
67.31%
100.00%

Mol%
accomodate
Mole Flow (kgmol/hr)
d
1273.95
13.05%
0.00
0.00%
0.00
0.00%
0.00
0.00%
0.00
0.00%
12.74
0.13%
894.14
9.16%
1079.02
11.05%
0.00
0.00%
6504.28
66.61%
9764.13

KJ/Kmol
Gjoules/hr
-25346.966
Del H
-247491055 -247.491055
Heat of Formation Summation
-1771.6238
Heat Supply required
245.3708166
3.926253962 Gjoules per ton Ammonia

Del H specific

Compressor Section

Pin
14.7

Gamma
r-1/r

Del H specific
Del H

Pout
298

589.7

1.43
0.3006993

Pre Heating Air required

Oxygen
Nitrogen

T in

M.Wt
32
28

Tin
904
Mol %
21.00%
79.00%

Tf

Del H required
1023.00
510.74
1921.37
2432.11

mol%
21.00%
79.00%

KJ/Kmol
Gjoules/hr
3854.43525
9374411.56 9.374411561

Heat of Formations & Cp coefficients


Components

Mol. Wt

Components

Methane
Ethane
Propane
Butane
Nitrogen
Carbon dioxide
Carbon monoxide
Hydrogen
Oxygen
Steam

Mol. Wt
16
30
44
58
28
44
28
2
32
18

Heat of
Formations
-74520
-83820
-104680
-125790
0
-393509
-110525
0
0
-241818

B
0.009081
0.019225
0.028785
0.036915
0.000593
0.001045
0.000557
0.000422
0.000506
0.00145

1.702
1.131
1.213
1.935
3.28
5.457
3.376
3.249
3.639
3.47

Secondary Reform
Components

Methane
Ethane
Propane
Butane
Nitrogen
Carbon dioxide
Carbon monoxide
Hydrogen
Oxygen
Steam

Mol. Wt
16
30
44
58
28
44
28
2
32
18

KJ/Kmol
Del H specific
-23503.703
Del H
-324983283
Heat of Formation Summation
Heat Requirement

Mol%
2.73%
0.00%
0.00%
0.00%
0.00%
6.45%
9.51%
40.13%
0.00%
41.19%
100.00%
Gjoules/hr
-324.983283
-1584.54769
15.24551817

Furnace Firing Fuel Consumption


Heat of Combustion required
Heating value Of Fuel
Fuel required

Mol%
accomodate
Mole Flow (kgmol/hr)
d
38.22
0.28%
0.00
0.00%
0.00
0.00%
0.00
0.00%
1921.37
13.90%
752.58
5.44%
1109.76
8.03%
4685.25
33.89%
510.74
0.00%
4808.97
34.78%
13826.90

reax

60%
408.951361
8015
0.03355079
12189.0233
195.0403136

Heat Provided by Radiation


GJ/hr
kcal/m3
Gjoules/m3
m3
m3/ TonAmmonia

Naphtha
Heating value Of Fuel

Fuel required

10556
44187.416
0.044187416
9254.928168
9.254928168
0.148090954

kcal/kg
Kj/kg
Gj/kg
kg/hr
Tons/hr
Tons/Ton Ammonia

Secondary Reformer
C
psig
psig

1200.80 C
565 psig
10 psig

Exit Temperature
Pressure
Pressure Drop
6

Primary Reformer
7

based CH4
based C2H6
based C3H8
based C4H10
based on CO

Mol%
100
100

Secondary
Reformer
Air

205813
3464061
498559
650962
-41166

Stream 5 (Steam)
Mole Flow
Mass Flow
(mol/hr)
(kg/hr)
-209.014336 -3762.25805
-209.014336 -3762.25805

Reaction 1
Reaction 2
Reaction 3
Reaction 4

Reactions in Secondary Reformer


CH4 + H2O = CO + 3H2
CH4 + 2O2 = CO2 + 2H2O
2CO + O2 = 2CO2
2CO + 2.5O2 +H2= 2CO2 + H2O

Mol%
2.73
0.00
0.00
0.00
0.00
6.45
9.51
40.13
41.19

Stream 6
Mole Flow
(kgmol/hr)
318.49
0.00
0.00
0.00
0.00
752.58
1109.76
4685.25
4808.97

Mass Flow
(kg/hr)
5095.80
0.00
0.00
0.00
0.00
33113.57
31073.35
9370.51
86561.47356

100

11675.05586

165214.7057

Total Secondary Reformer Inlet


Total Secondary Reformer Outlet
Nitrogen in
1921.37 kgmol/hr
Total air
2432.11 kgmol/hr
O2 with Air
510.74 kgmol/hr
Argon with Air
0.00 kgmol/hr
CH4 Consumption
Reaction 2
63.70 kgmol/hr
Reaction 1
216.57 kgmol/hr

CO Production
Reaction 1

216.57 kgmol/hr

CO Consumption
Reaction 4

511.13 kgmol/hr

CO2 Production
Reaction 2
63.70
Reaction 4
511.13
H2 production
Reaction 1
649.72
H2 Consumed
Reaction4
255.57
Steam Consumption
1800
1192
1474 Reaction 1
216.57
982.2222222 644.4444444 801.1111111
Steam Production
Reaction 4
255.57
Reaction 2
127.40
O2 Consumption
GJ
Reaction 2
127.40
Reaction 4
383.35

s & Cp coefficients
C
-0.000002164
-0.000005561
-0.000008824
-0.000011402
0
0
0

D
0
0
0
0
4000
-115700
-3100

kgmol/hr

kgmol/hr
kgmol/hr
kgmol/hr

kgmol/hr

0
0
0

8300
-22700
12100

Primary Reformer Inlet

T initial
973
973
973
973
973
973
973
973
973
973

T final
298.00
298.00
298.00
298.00
298.00
298.00
298.00
298.00
298.00
298.00

Tau
0.30626927
0.30626927
0.30626927
0.30626927
0.30626927
0.30626927
0.30626927
0.30626927
0.30626927
0.30626927

Cp
54.18115362
90.55173505
129.7579981
169.2460049
30.41382177
50.57961785
31.00266192
29.26416652
32.86706685
36.54326732

<Cp>
7.069154181
0
0
0
0
0.065992526
2.839039333
3.233948066
0
24.34292669
37.55106079

H0f
-9722.82
0.00
0.00
0.00
0.00
-513.42
-10121.22
0.00
0.00
-161084.61
-181442.07

Tout
904 K
631 0C

H required
Tin
904
904

s & Cp coefficients

T required
1023.00
1023.00

Tau
Cp
1.131212078 34.04764749 7.150005973
1.131212078 32.0670063 25.33293498
Cp
32.48294095

0.00
0.00

C
-0.000002164
-0.000005561
-0.000008824
-0.000011402
0
0
0
0
0
0

D
0
0
0
0
4000
-115700
-3100
8300
-22700
12100

Secondary Reformer Inlet

T initial
1023.00
1023.00
1023
1023
1023
1023
1023
1023
1023
1023

T final
298.00
298.00
298.00
298.00
298.00
298.00
298.00
298.00
298.00
298.00

-233.8797714 Gj/hr

at Provided by Radiation

TonAmmonia

Tau
0.291300098
0.291300098
0.291300098
0.291300098
0.291300098
0.291300098
0.291300098
0.291300098
0.291300098
0.291300098

Cp
55.38076461
92.77996548
132.9360584
173.2944119
30.53557519
50.84025585
31.11959813
29.34876333
32.98076072
36.84010737

<Cp>
0.153076388
0
0
0
4.243182714
2.76717323
2.497694363
9.944849017
0
12.81292543
32.41890114

H0f
-205.98
0.00
0.00
0.00
0.00
-21418.22
-8870.86
0.00
0.00
-84103.88
-114598.94

ns/Ton Ammonia

Ammonia Production

62.49489181 TPH

39.62414966

econdary Reformer
2O = CO + 3H2
2 = CO2 + 2H2O
O2 = 2CO2
+H2= 2CO2 + H2O

Mol%
79
21
0
100

85% based on remaining CH4 after Reaction 4


20%
100% based on O2

Stream 7 (Air)
Mole Flow
(kgmol/hr)
1921.37
510.74
0
2432.11

Mass Flow
(kg/hr)
53798.27914
16343.78
-

Mol%
0.27
13.57
9.38
5.76
35.88
0.00
35.14

Stream 8
Mole Flow
(kgmol/hr)
38.22
1921.37
1327.41
815.20
5079.40
0.00
4975.36

70142.06

100

14156.96

235356.77 kg/hr
235356.77 kg/hr
N2:H2 Ratio

3.0000379
2.4385

3
0.999987356
2.438469167
2.4577876 For mix feed
2.462481 For 100% n.gas
2.4385 For 100% naphtha

Primary Reformer Outlet

Mol%
2.73%
0.00%
0.00%
0.00%
0.00%
6.45%
9.51%
40.13%
0.00%
41.19%
100.00%

Mole Flow
(kgmol/hr)
38.22
0.00
0.00
0.00
0.00
752.58
1109.76
4685.25
4808.97
11394.79

KJ/Kmol
25286.27402
Del H
288131697.2
Heat of Formation Summation

Mol%
accomodated
2.73%
0.00%
0.00%
0.00%
0.00%
6.45%
9.51%
40.13%
0.00%
41.19%

Gjoules/hr

Del H specific

288.1316972
-1566.893622

T initial
298
298
298
298
298
298
298
298
298
298

T final
1023.00
1023.00
1023.00
1023.00
1023.00
1023.00
1023.00
1023.00
1023.00
1023.00

Secondary Reformer Outlet

Mol%
0.00%
0.00%
0.00%
0.00%
0.00%
0.00%
0.00%
0.00%
0.00%
0.00%
0.00%

Mole Flow
(kgmol/hr)
38.22
0.00
0.00
0.00
1921.37
1327.41
815.20
5079.40
0.00
4975.36
14156.96

Mol%
accomodated
0.27%
0.00%
0.00%
0.00%
13.57%
9.38%
5.76%
35.88%
0.00%
35.14%

T initial
298
298
298
298
298
298
298
298
298
298

T final
1473.80
1473.80
1473.80
1473.80
1473.80
1473.80
1473.80
1473.80
1473.80
1473.80
1200.80

KJ/Kmol
Del H specific 40553.09296
Del H
574108572.3
Heat of Formation Summation

Gjoules/hr
574.1085723
-1818.427466

15.24551817

m8
Mass Flow
(kg/hr)
611.50
53798.28
58406.02
22825.70
10158.81
0.00
89556.47
235356.77

Mol%
92%
2%
2%
1%
2%
1%
0
0
0
0
0
100.00%

Natural Gas
Mole Flow
(kgmol/hr)
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00

Mass Flow
(kg/hr)
0
0
0
0
0
0
0
0
0
0
168976.96

0.00
0.00

r Outlet

Tau
3.432885906
3.432885906
3.432885906
3.432885906
3.432885906
3.432885906
3.432885906
3.432885906
3.432885906
3.432885906

Cp
55.38076461
92.77996548
132.9360584
173.2944119
31.81189175
13.92279939
30.1304528
31.99712019
25.73766425
40.70096496

<Cp>
1.510750402
0
0
0
0
0.897472073
2.864024505
12.84059174
0
16.76478062
34.87761934

H0f
-2032.86
0.00
0.00
0.00
0.00
-25365.83
-10505.86
0.00
0.00
-99605.15
-137509.69

er Outlet

Tau
4.945637584
4.945637584
4.945637584
4.945637584
4.945637584
4.945637584
4.945637584
4.945637584
4.945637584
4.945637584

Cp
64.84253338
109.390407
156.0686441
202.6610967
33.48966608
-0.50510527
30.73521444
33.9634395
23.47096982
45.13191265

<Cp>
0.175050723
0
0
0
4.545180361
-0.04736055
1.769832595
12.18580763
0
15.86127744
34.48978819

H0f
-201.18
0.00
0.00
0.00
0.00
-36896.87
-6364.39
0.00
0.00
-84985.15
-128447.58

High Temperature Shift Converter


315 C
565 psig
10 psig

Temperature
Pressure
Pressure Drop

599
38.43537415

SR outlet stream
HTS

9
Reactions in HTS
CO+H2O = CO2 + H2

Reaction 1

Components

Methane
Nitrogen
Carbon dioxide
Carbon monoxide
Hydrogen
Steam

Mol. Wt
Mol%
0.27
13.57
9.38
5.76
35.88
35.14
100

16
28
44
28
2
18

Total
CO Consume
Reaction 1
CO2 Produced
Reaction 1
H2 Produced
Reaction 1
Steam Consume
Reaction 1

Components

Methane
Ethane
Propane
Butane

80% based on CO

Stream 9 (SR outlet)


Mole Flow
Mass Flow
(kgmol/hr)
(kg/hr)
38.22
611.50
1921.37
53798.28
1327.41
58406.02
815.20
22825.70
5079.40
10158.81
4975.36
89556.47
14157.0
235356.8

Stream 10 (HTS out


Mol%
0.27
13.57
13.98
1.15
40.49
30.54
100

652.16 kgmol/hr
652.16 kgmol/hr
652.16 kgmol/hr
652.16 kgmol/hr

Mol. Wt
16
30
44
58

Heat of
Formations
-74520
-83820
-104680
-125790

Heat of Formations & Cp coefficients


A
B
C
1.702
0.009081
-2.164E-06
1.131
0.019225
-5.561E-06
1.213
0.028785
-8.824E-06
1.935
0.036915 -1.1402E-05

Nitrogen
Carbon dioxide
Carbon monoxide
Hydrogen
Oxygen
Steam

Components

Methane
Ethane
Propane
Butane
Nitrogen
Carbon dioxide
Carbon monoxide
Hydrogen
Oxygen
Steam

28
44
28
2
32
18

0
-393509
-110525
0
0
-241818

Mol. Wt
16
30
44
58
28
44
28
2
32
18

Mol%
0.27%
0.00%
0.00%
0.00%
13.57%
9.38%
5.76%
35.88%
0.00%
35.14%
100.00%

3.28
5.457
3.376
3.249
3.639
3.47

Mole Flow
(kgmol/hr)
38.22
0.00
0.00
0.00
1921.37
1327.41
815.20
5079.40
0.00
4975.36
14156.96

0.000593
0.001045
0.000557
0.000422
0.000506
0.00145

0
0
0
0
0
0

Stream 9 (SR Inlet) Cool down to


Mol%
accomodate
d
T initial
0.27%
1473.80
0.00%
1473.8
0.00%
1473.8
0.00%
1473.8
13.57%
1473.8
9.38%
1473.8
5.76%
1473.8
35.88%
1473.8
0.00%
1473.8
35.14%
1473.8
315
1200.8

KJ/Kmol
Gjoules/hr
Del H specific
-32828.16852
Del H
-464747115 -464.747115
Heat of Formation Summation
0
Heat Supply required
-464.747115

rxn heat

Heat of Formations & Cp coefficients


Components

Methane
Ethane
Propane
Butane
Nitrogen
Carbon dioxide
Carbon monoxide
Hydrogen
Oxygen
Steam

Mol. Wt
16
30
44
58
28
44
28
2
32
18

Heat of
Formations
-74520
-83820
-104680
-125790
0
-393509
-110525
0
0
-241818

A
1.702
1.131
1.213
1.935
3.28
5.457
3.376
3.249
3.639
3.47

B
C
0.009081
-2.164E-06
0.019225
-5.561E-06
0.028785
-8.824E-06
0.036915 -1.1402E-05
0.000593
0
0.001045
0
0.000557
0
0.000422
0
0.000506
0
0.00145
0

Stream 9 (SR Inle


Components

Methane
Ethane
Propane
Butane
Nitrogen
Carbon dioxide
Carbon monoxide
Hydrogen
Oxygen
Steam

Mol. Wt
16
30
44
58
28
44
28
2
32
18

Mol%
0.27%
0.00%
0.00%
0.00%
13.57%
9.38%
5.76%
35.88%
0.00%
35.14%
100.00%

Mole Flow
(kgmol/hr)
38.22
0.00
0.00
0.00
1921.37
1327.41
815.20
5079.40
0.00
4975.36
14156.96

Mol%
accomodate
d
0.27%
0.00%
0.00%
0.00%
13.57%
9.38%
5.76%
35.88%
0.00%
35.14%

T initial
588
588
588
588
588
588
588
588
588
588
315
315

KJ/Kmol
Gjoules/hr
-9480.381971
Del H
-134213401.8 -134.213402
Heat of Formation Summation
-1818.42747
Heat Supply required
-0.48060121

Del H specific

rxn heat

-26.846931

Heat of Formations & Cp coefficients


Components

Methane
Ethane
Propane
Butane
Nitrogen
Carbon dioxide
Carbon monoxide
Hydrogen
Oxygen
Steam

Mol. Wt
16
30
44
58
28
44
28
2
32
18

Heat of
Formations
-74520
-83820
-104680
-125790
0
-393509
-110525
0
0
-241818

A
1.702
1.131
1.213
1.935
3.28
5.457
3.376
3.249
3.639
3.47

B
C
0.009081
-2.164E-06
0.019225
-5.561E-06
0.028785
-8.824E-06
0.036915 -1.1402E-05
0.000593
0
0.001045
0
0.000557
0
0.000422
0
0.000506
0
0.00145
0

Stream 10 (HTSC ou
Components

Methane
Ethane
Propane
Butane
Nitrogen

Mol. Wt
16
30
44
58
28

Mol%
0.27%
0.00%
0.00%
0.00%
13.57%

Mole Flow
(kgmol/hr)
38.22
0.00
0.00
0.00
1921.37

Mol%
accomodate
d
0.27%
0.00%
0.00%
0.00%
13.57%

T initial
543
543
543
543
543

Carbon dioxide
Carbon monoxide
Hydrogen
Oxygen
Steam

44
28
2
32
18

13.98%
1.15%
40.49%
0.00%
30.54%
100.00%

KJ/Kmol
Gjoules/hr
Del H specific
-8098.750514
Del H
-114653698.5 -114.653699
Heat of Formation Summation
-1845.2744
Heat Supply required
-1.20079189

1979.57
163.04
5731.57
0.00
4323.20
14156.96

13.98%
1.15%
40.49%
0.00%
30.54%

543
543
543
543
543
270
270

rxn heat

-5.3693862

Low Temperature Shift converter


200 C
555 psig
10 psig

Exit Temperature
Pressure
Pressure Drop

10

11
LTS

Reactions in LTS
Reaction 1
CO+H2O = CO2 + H2

Stream 10 (HTS outlet)


Mole Flow
Mass Flow
(kgmol/hr)
(kg/hr)
38.22
611.50
1921.37
53798.28
1979.57
87101.18
163.04
4565.14
5731.57
11463.13
4323.20
77817.54
14156.96
235356.77
CO Consume
Reaction 1
CO2 Produced
Reaction 1
H2 Produced
Reaction 1
Steam Consume
Reaction 1

fficients
D
0
0
0
0

80% based on CO

Stream 11(LTS outlet)


Mole Flow
Mass Flow
Mol%
(kgmol/hr)
(kg/hr)
0.27
38.22
611.50
13.57
1921.37
53798.28
14.90
2110.00
92840.21
0.23
32.61
913.03
41.41
5862.00
11724.00
29.62
4192.76
75469.75693
100
14156.96
235356.77

130.43 kgmol/hr
130.43 kgmol/hr
130.43 kgmol/hr
130.43 kgmol/hr

4000
-115700
-3100
8300
-22700
12100
(SR Inlet) Cool down to reactor Inlet temp

T final
588.00
588.00
588.00
588.00
588.00
588.00
588.00
588.00
588.00
588.00
599

fficients
D
0
0
0
0
4000
-115700
-3100
8300
-22700
12100

Tau
0.398968652
0.398968652
0.398968652
0.398968652
0.398968652
0.398968652
0.398968652
0.398968652
0.398968652
0.398968652

Cp
71.68583919
122.0200634
174.034758
225.5388899
32.3585737
54.14940403
32.83732269
30.64178195
34.55685721
41.29586686

<Cp>
0.193525104
0
0
0
4.391669757
5.077249898
1.890878756
10.99402374
0
14.51312747
37.06047473

H0f
-201.18
0.00
0.00
0.00
0.00
-36896.87
-6364.39
0.00
0.00
-84985.15
-128447.58

Stream 9 (SR Inlet)

T final
298.00
298.00
298.00
298.00
298.00
298.00
298.00
298.00
298.00
298.00

Tau
0.506802721
0.506802721
0.506802721
0.506802721
0.506802721
0.506802721
0.506802721
0.506802721
0.506802721
0.506802721

Cp
43.93977376
70.8133391
101.191459
132.7812718
29.5027472
47.80831182
30.08177233
28.66760656
31.84165231
34.33753975

<Cp>
0.118621047
0
0
0
4.004080151
4.482685464
1.732205295
10.28570557
0
12.06767479
32.69097231

H0f
-201.18
0.00
0.00
0.00
0.00
-36896.87
-6364.39
0.00
0.00
-84985.15
-128447.58

Mol%
0.27%
0.00%
0.00%
0.00%
13.57%
13.98%
1.15%
40.49%
0.00%
30.54%
100.00%

Mole Flow
(kgmol/hr)
38.22
0.00
0.00
0.00
1921.37
1979.57
163.04
5731.57
0.00
4323.20
14156.96

599
KJ/Kmol

Del H specific11342.81057
Del H
160579731.6
Heat of Formation Summation

fficients
D
0
0
0
0
4000
-115700
-3100
8300
-22700
12100
Stream 10 (HTSC outlet)

T final
298.00
298.00
298.00
298.00
298.00

Tau
0.548802947
0.548802947
0.548802947
0.548802947
0.548802947

Cp
<Cp>
42.62668421 0.115076193
68.20804357
0
97.37932321
0
127.9077245
0
29.40496939 3.990809854

H0f
-201.18
0.00
0.00
0.00
0.00

Mol%
0.27%
0.00%
0.00%
0.00%
13.57%

Mole Flow
(kgmol/hr)
38.22
0.00
0.00
0.00
1921.37

298.00
298.00
298.00
298.00
298.00

0.548802947
0.548802947
0.548802947
0.548802947
0.548802947

47.23241509
29.96738454
28.61595497
31.67236135
34.10607948

6.604522854
0.345123695
11.58541244
0
10.41517951
33.05612455

-55024.48
-1272.88
0.00
0.00
-73845.42
-130343.96

14.90%
0.23%
41.41%
0.00%
29.62%
100.00%

2110.00
32.61
5862.00
0.00
4192.76
14156.96

518
KJ/Kmol
Del H specific8393.205954
Del H
118822292.8
Heat of Formation Summation

Stream 10 (SR OUTLET)


Mol%
accomodate
d
0.27%
0.00%
0.00%
0.00%
13.57%
13.98%
1.15%
40.49%
0.00%
30.54%

T initial
298
298
298
298
298
298
298
298
298
298

Gjoules/hr

T final
654.48
654.48
654.48
654.48
654.48
654.48
654.48
654.48
654.48
654.48

Tau
2.196241611
2.196241611
2.196241611
2.196241611
2.196241611
2.196241611
2.196241611
2.196241611
2.196241611
2.196241611

Cp
45.83519859
74.54801233
106.6420192
139.7469414
30.44034473
25.71732341
29.63607223
30.38969341
27.5906417
37.07875369

<Cp>
0.123737989
0
0
0
4.131329847
3.596061093
0.34130809
12.30352551
0
11.32296298
31.81892552

H0f
-201.18
0.00
0.00
0.00
0.00
-55024.48
-1272.88
0.00
0.00
-73845.42
-130343.96

381.48 Temp C

160.5797316
-1845.2744

-0.48060121

LTSC Stream 11 (LTSC OUT)


Mol%
accomodate
d
0.27%
0.00%
0.00%
0.00%
13.57%

T initial
298
298
298
298
298

T final
563.00
563.00
563.00
563.00
563.00

Tau
1.889261745
1.889261745
1.889261745
1.889261745
1.889261745

Cp
<Cp>
43.21327815 0.116659779
69.37365838
0
99.0858329
0
130.0895449
0
30.09987713 4.085121961

H0f
-201.18
0.00
0.00
0.00
0.00

14.90%
0.23%
41.41%
0.00%
29.62%

Gjoules/hr
118.8222928
-1850.64378

298
298
298
298
298

563.00
563.00
563.00
563.00
563.00

1.889261745
1.889261745
1.889261745
1.889261745
1.889261745

290.00 Temp C

-1.20079189

28.64515109
29.51334909
29.99067191
28.05061776
36.17958977

4.269376924
0.067978946
12.41829178
0
10.71504591
31.6724753

-58650.00
-254.58
0.00
0.00
-71617.48
-130723.23

COOL Down HTSC OUTLET

Mol%
0.27%
0.00%
0.00%
0.00%
13.57%
13.98%
1.15%
40.49%
0.00%
30.54%
100.00%

Mole Flow
(kgmol/hr)
38.22
0.00
0.00
0.00
1921.37
1979.57
163.04
5731.57
0.00
4323.20
14156.96
KJ/Kmol

Mol%
accomodate
d
0.27%
0.00%
0.00%
0.00%
13.57%
13.98%
1.15%
40.49%
0.00%
30.54%

T initial
654.48
654.48
654.48
654.48
654.48
654.48
654.48
654.48
654.48
654.48

Gjoules/hr

Del H specific-3827.45032
Del H
-54185066.6 -54.1850666 Heat Surplus
Heat of Formation Summation -1845.2744

T final
543.00
543.00
543.00
543.00
543.00
543.00
543.00
543.00
543.00
543.00

Tau
0.8296663
0.8296663
0.8296663
0.8296663
0.8296663
0.8296663
0.8296663
0.8296663
0.8296663
0.8296663

Cp
52.88656225
88.48138466
126.9986797
165.7660314
30.28624321
48.70825215
30.79084697
29.24652926
32.40792591
36.26242287

<Cp>
0.142774048
0
0
0
4.11041536
6.810889596
0.354607219
11.8407058
0
11.07367511
34.33306713

H0f
-201.18
0.00
0.00
0.00
0.00
-55024.48
-1272.88
0.00
0.00
-73845.42
-130343.96

Cooler Separator
C
555 psig
psig

Temperature
Pressure
Pressure Drop
Assumptions:
Water Condensed
CO2 Solubility in Water

Components

LTS outlet stream


11

100%
0%

Mol. Wt

Methane
Nitrogen
Carbon dioxide
Carbon monoxide
Hydrogen
Steam

16
28
44
28
2
18

Total

Mol%
0.27
13.57
14.90
0.23
41.41
29.62
100

Stream 11 (LTS outlet)


Mole Flow
(kgmol/hr)
Mass Flow (kg/hr)
38.22
611.50
1921.37
53798.28
2110.00
92840.21
32.61
913.03
5862.00
11724.00
4192.76
75469.76
14157.0
235356.8

CO2 Removal
C
555 psig
10 psig

Temperature
Pressure
Pressure Drop

Stream from
Cooler Separator
Lean Solvent

Assumptions:
Solvent Used
Rich Solvent Loading
Lean Solvent Loading
Solution Strength

12
14

MDEA

Total

0.55 mol of Acid gas /mol of pure solvent


0.10 mol of Acid gas /mol of pure solvent
50% by weight
Stream 12 (Feed Gas)
Mole Flow
Mol. Wt
Mol%
(kgmol/hr)
Mass Flow (kg/hr)
16
0.38
38.22
611.50
28
19.28
1921.37
53798.28
44
21.18
2110.00
92840.21
28
0.33
32.61
913.03
2
58.83
5862.00
11724.00
119.12
0.00
0.00
0.00
18
0.00
0
0.00
100.00
9964.2
159887.0

Total Mass in

1297601.56 kg/hr

Components

Methane
Nitrogen
Carbon dioxide
Carbon monoxide
Hydrogen
MDEA
Water

Total Mass out

1297601.56 kg/hr

Circulation rate of MDEA solution

Vap pressure of Water at 314 K


Vap pressure of Water at 311 K

1104.577235 m3 /hr
Partial pressure at Top of Abs.
Total pressure bar g
H2O condensed
16.87
9.81

Components

Methane
Ethane
Propane
Butane
Nitrogen
Carbon dioxide
Carbon monoxide
Hydrogen
Oxygen
Steam
Components

Methane
Ethane
Propane
Butane
Nitrogen
Carbon dioxide
Carbon monoxide
Hydrogen
Oxygen
Steam

Heat of
Formations
-74520
-83820
-104680
-125790
0
-393509
-110525
0
0
-241818

Mol. Wt
16
30
44
58
28
44
28
2
32
18
Mol. Wt

Mol%
0.38%
0.00%
0.00%
0.00%
19.28%
21.18%
0.33%
58.83%
0.00%
0.00%
100.00%

16
30
44
58
28
44
28
2
32
18

KJ/Kmol
Gjoules/hr
Del H specific
489.8471763
Del H kjoules/hr
4880933.833 4.880933833
Heat of Formation Summation
0
Heat Supply required
0
BTU/lb
Heat of Absorption

577

Heat of Formations & Cp coefficients


A
B
1.702
0.009081
1.131
0.019225
1.213
0.028785
1.935
0.036915
3.28
0.000593
5.457
0.001045
3.376
0.000557
3.249
0.000422
3.639
0.000506
3.47
0.00145
Mole Flow
(kgmol/hr)
38.22
0.00
0.00
0.00
1921.37
2110.00
32.61
5862.00
0.00
0.00
9964.20

Mol%
accomodated
0.38%
0.00%
0.00%
0.00%
19.28%
21.18%
0.33%
58.83%
0.00%
0.00%

Kwatt
1355.81

Kj/kg
Kj/hr
1339.217

Kwatt

Strea

Heat of Absorption
Enthalpy of Lean

34536.99588
15488.7195

124333185.2
55759390.19

K
Temp of Rich solution out 298.0108983

Heat Exchanger
Flow rate
Lean MDEA sol. From Stripper
Rich MDEA sol. From Absorber
Cooler
Lean MDEA sol. From Stripper
Water

T in
K

1137714.6
1230554.8

389.0
298.0

1137714.6
4303529.0

353.0
303.0

Heat of Formations & Cp coefficients


Components

Methane
Ethane
Propane
Butane
Nitrogen
Carbon dioxide
Carbon monoxide
Hydrogen
Oxygen
Steam

Mol. Wt
16
30
44
58
28
44
28
2
32
18

Heat of
Formations
-74520
-83820
-104680
-125790
0
-393509
-110525
0
0
-241818

A
1.702
1.131
1.213
1.935
3.28
5.457
3.376
3.249
3.639
3.47

B
0.009081
0.019225
0.028785
0.036915
0.000593
0.001045
0.000557
0.000422
0.000506
0.00145

COOLER SEPERA
Components

Methane
Ethane
Propane
Butane
Nitrogen
Carbon dioxide
Carbon monoxide
Hydrogen
Oxygen

Mol. Wt
16
30
44
58
28
44
28
2
32

Mol%
-

Mole Flow
(kgmol/hr)
38.22
0.00
0.00
0.00
1921.37
2110.00
32.61
5862.00
0.00

Mol%
accomodated
0.27%
0.00%
0.00%
0.00%
13.57%
14.90%
0.23%
41.41%
0.00%

Steam

18

0.00%

4192.76
14156.96

KJ/Kmol
Gjoules/hr
-3523.913277
Del H
-49887904.29 -49.8879043
Heat of Formation Summation
0

29.62%
100.00%

Del H specific

Latent Heat of Condensation

Boiler Feed Water


Total heat Surplus

Gjoules/hr
-255.5087114

rxn heat
Sat. steam
sat. water

2801.9425
959.86
-1842.0825

1
13
3

Cooler
Condenser
12

Mol%
0.38
19.28
21.18
0.33
58.83
0.00
100

Stream 12
Mole Flow
(kgmol/hr)
38.22
1921.37
2110.00
32.61
5862.00
0.00
9964.20

Mass Flow
(kg/hr)
611.50
53798.28
92840.21
913.03
11724.00
0.00
159887.01

Stream 13 (Condensed Water)


Mole Flow
Mass Flow
Mol%
(kgmol/hr)
(kg/hr)
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
100.00
4192.76
75469.75693
100
4192.76
75469.76

235356.77

15

Treated Gas

CO2 Removal

Stripper
16

Rich Solvent

MDEA M.wt
119.7
H20
18
CO2
44
Stream 14 (Lean Solvent)
Mole Flow
Mass Flow
Mol%
(kgmol/hr)
(kg/hr)
0.00
0.00
0.00
0.00
0.00
0.00
0.00
468.89
20631.16
0.00
0.00
0.00
0.00
0.00
0.00
0.00
4688.90
558541.70
0.00
31030.09
558541.70
36187.88
1137714.55
kpa

Mol%
0.49
24.46
0.00
0.42
74.64
0.00
0.00
100

Stream 15 (Treated Gas)


Mole Flow
Mass Flow
(kgmol/hr)
(kg/hr)
38.22
611.50
1921.37
53798.28
0.00
0.00
32.61
913.03
5862.00
11724.00
0.00
0.00
0
0
7854.19
67046.80

Mol Fract. Of water in MDEA solution

sure of Water at 314 K


sure of Water at 311 K

essure at Top of Abs.


ssure bar g

& Cp coefficients
C
-2.164E-06
-5.561E-06
-8.824E-06
-1.1402E-05
0
0
0
0
0
0

7.777
6.624

0.868728121

5.754455076
4601.3
7.06 127.0079625

Avg. Cp of Rich & lean solution


3.77

D
0
0
0
0
4000
-115700
-3100
8300
-22700
12100

Stream Sour Gas


T initial
T final
Tau
298
314.00
1.053691275
298
314.00
1.053691275
298
314.00
1.053691275
298
314.00
1.053691275
298
314.00
1.053691275
298
314.00
1.053691275
298
314.00
1.053691275
298
314.00
1.053691275
298
314.00
1.053691275
298
314.00
1.053691275
315.5555556
25

600

Cp
35.56821927
53.98298133
76.44538172
101.1240889
29.17315617
36.61442408
29.17930816
28.90457273
29.30262954
33.73214972

<Cp>
0.136424948
0
0
0
5.625374731
7.753420272
0.095490169
17.0047384
0
0
30.61544852

H0f
-285.83
0.00
0.00
0.00
0.00
-83328.93
-361.70
0.00
0.00
0.00
-83976.45

T out
K

Heat Transfer Radiation loss


Kj/hr
353.0 154410619.0
2.0%
330.6 151322406.6
311.0 180145722.2
313.0 180145722.2

0.0%

& Cp coefficients
C
-2.164E-06
-5.561E-06
-8.824E-06
-1.1402E-05
0
0
0
0
0
0

D
0
0
0
0
4000
-115700
-3100
8300
-22700
12100

COOLER SEPERATOR WATER LET DOWN

T initial
563.00
563
563
563
563
563
563
563
563

T final
458.60
458.60
458.60
458.60
458.60
458.60
458.60
458.60
458.60

Tau
0.814564831
0.814564831
0.814564831
0.814564831
0.814564831
0.814564831
0.814564831
0.814564831
0.814564831

Cp
48.00491689
78.94244115
113.1205742
148.0378723
29.87373033
47.3353733
30.36729276
28.98166792
31.91851899

<Cp>
0.129595421
0
0
0
4.054429569
7.055035241
0.069945859
12.00049167
0

H0f
-201.18
0.00
0.00
0.00
0.00
-58650.00
-254.58
0.00
0.00

563

458.60
200
290

0.814564831 35.26595326

10.44446083
33.75395859

392

0
Heat of Condensation

J/mol
-33157.485

-1.39022E+11
-139.0215185

-71617.48
-130723.23

Stream 16 (Rich Solvent)


CO2 Out
Mole Flow
Mass Flow
Mol%
(kgmol/hr)
(kg/hr)
0.00%
0.00
0.00
0.00%
0.00
0.00
6.73%
2578.89
113471.37
2110.00 92840.20825
0.00%
0.00
0.00
0.00%
0.00
0.00
12.24%
4688.90
558541.70
81.02%
31030.09
558541.70
1.00
38297.89
1230554.76

Mol%
0.49%
0.00%
0.00%
0.00%
24.46%
0.00%
0.42%
74.64%
0.00%
0.00%
100.00%

Mole Flow
Mol%
(kgmol/hr) accomodate
38.22
0.49%
0.00
0.00%
0.00
0.00%
0.00
0.00%
1921.37
24.46%
0.00
0.00%
32.61
0.42%
5862.00
74.64%
0.00
0.00%
0.00
0.00%
7854.19
100.00%

Stream Treated gas


T initial
T final
Tau
298.00
311.00
1.043624161
298.00
311.00
1.043624161
298.00
311.00
1.043624161
298.00
311.00
1.043624161
298.00
311.00
1.043624161
298.00
311.00
1.043624161
298.00
311.00
1.043624161
298.00
311.00
1.043624161
298.00
311.00
1.043624161
298.00
311.00
1.043624161

KJ/Kmol
Gjoules/hr
Del H specific376.8811455
kwatt
Del H
2960097.032 2.960097032 822.2491754
Heat of Formation Summation
0

Cp
35.47157627
53.78590048
76.15411779
100.7512189
29.16199085
36.71043942
29.17528357
28.8914872
29.31771402
33.70266249

329.88 Temp C

Steam Requirment in Reboiler


Cp

Flow rate
kg/hr

T oprational T ref
K
K

Rich Sol. Entering from Abs.


Lean solution leaving
CO2 gas leaving Stripper
Enthalpy of Desorption
Steam Enthalpy required
Latent heat 4 bar abs.
Steam required
174.4016235 TPH

3.77
3.77
0.878863636
kj/kg

Mole Flow
(kgmol/hr)
38.22
0.00
0.00
0.00
1921.37
2110.00
32.61
5862.00
0.00

330.6
389.0
367.8
-

298.0
298.0
298
-

2133 174401.6235
-

psi
System pressure
164.4 temp
8498.056974
Vapor pressure
A
8.14019

Mol%
-

1230554.8
1137714.6
92840.21

Mol%
accomodate
d
0.27%
0.00%
0.00%
0.00%
13.57%
14.90%
0.23%
41.41%
0.00%

Deg C

K
185.6

458.6
C

1810.94

244.485

Vap. Pressure
8502.251881

T initial
458.60
458.6
458.6
458.6
458.6
458.6
458.6
458.6
458.6

T final
315.22
315.22
315.22
315.22
315.22
315.22
315.22
315.22
315.22

Tau
0.687357659
0.687357659
0.687357659
0.687357659
0.687357659
0.687357659
0.687357659
0.687357659
0.687357659

164

Cp
40.63784599
64.2452437
91.57177042
120.4815756
29.28615871
45.58720927
29.77557609
28.59519593
31.26552737

0.00%

4192.76
14156.96
KJ/Kmol

29.62%

Gjoules/hr

458.6

315.22

0.687357659 33.84269306

42.22 Temp C

Del H specific -4704.3491


Del H
-66599288.6 -66.5992886
Heat of Formation Summation-1850.64378

32

<Cp>
0.172604827
0
0
0
7.133883057
0
0.121126601
21.56324286
0
0
28.99085734

Enthalpy
Kj/hr

H0f
-362.61
0.00
0.00
0.00
0.00
0.00
-458.87
0.00
0.00
0.00
-821.48

Kwatt

2% radiation loss

151372965.9
390315731.4
5695253.0
124333185.2

42048.04608
108421.0365
1582.014732
34536.99588

371998663 103332.9619

K
1.000493631

<Cp>
0.10970707
0
0
0
3.974685
6.794482552
0.068582941
11.84046452
0

H0f
-201.18
0.00
0.00
0.00
0.00
-58650.00
-254.58
0.00
0.00

98%

10.02294421
32.81086629

-71617.48
-130723.23

Methanator
400 C
460 psig
10 psig

Temperature
Pressure
Pressure Drop

From CO2 Removal Unit


15
Reactions in Methanator
CO+3H2 = CH4 +H2O

Reaction 1

Components

Methane
Nitrogen
Carbon monoxide
Hydrogen
Steam

Stream 15 (CO2 Removal outlet)


Mole Flow
Mass Flow
Mol%
(mol/hr)
(kg/hr)
0.49
38.22
611.50
24.46
1921.37
53798.28
0.42
32.61
913.03
74.64
5862.00
11724.00
0.00
0.00
0.00
100
7854.2
67046.8

Mol. Wt
16
28
28
2
18

Total
CO Consume
Reaction 1
H2 Consume
Reaction 1
CH4 Produced
Reaction 1
Steam Produced
Reaction 1

Components

Methane
Ethane
Propane
Butane
Nitrogen
Carbon dioxide
Carbon monoxide
Hydrogen

100%

32.61 kgmol/hr
97.82 kgmol/hr
32.61 kgmol/hr
32.61 kgmol/hr

Mol. Wt
16
30
44
58
28
44
28
2

Heat of Formations & Cp coefficients


Heat of Formations
A
B
-74520
1.702
0.009081
-83820
1.131
0.019225
-104680
1.213
0.028785
-125790
1.935
0.036915
0
3.28
0.000593
-393509
5.457
0.001045
-110525
3.376
0.000557
0
3.249
0.000422

Oxygen
Steam
Components

Methane
Ethane
Propane
Butane
Nitrogen
Carbon dioxide
Carbon monoxide
Hydrogen
Oxygen
Steam

32
18
Mol. Wt
16
30
44
58
28
44
28
2
32
18

KJ/Kmol
-8412.4524
Del H
-66073020
Heat of Formation Summation
Heat Supply required

0
-241818

Mol%
0.49%
0.00%
0.00%
0.00%
24.46%
0.00%
0.42%
74.64%
0.00%
0.00%
100.00%

3.639
3.47

0.000506
0.00145

Mole Flow
Mol%
(kgmol/hr) accomodate
38.22
0.49%
0.00
0.00%
0.00
0.00%
0.00
0.00%
1921.37
24.46%
0.00
0.00%
32.61
0.42%
5862.00
74.64%
0.00
0.00%
0.00
0.00%
7854.19

Gjoules/hr

Del H specific

Components

Methane
Ethane
Propane
Butane
Nitrogen
Carbon dioxide
Carbon monoxide
Hydrogen
Oxygen
Steam

Components

Methane
Ethane
Propane
Butane
Nitrogen
Carbon dioxide

Mol. Wt
16
30
44
58
28
44
28
2
32
18

-66.07302011
-6.452059187
-0.209185006

Heat of Formations & Cp coefficients


Heat of Formations
A
B
-74520
1.702
0.009081
-83820
1.131
0.019225
-104680
1.213
0.028785
-125790
1.935
0.036915
0
3.28
0.000593
-393509
5.457
0.001045
-110525
3.376
0.000557
0
3.249
0.000422
0
3.639
0.000506
-241818
3.47
0.00145

Mol. Wt
16
30
44
58
28
44

rxn heat

Mol%
0.91%
0.00%
0.00%
0.00%
24.67%
0.00%

Mole Flow
(kgmol/hr)
70.83
0.00
0.00
0.00
1921.37
0.00

Mol%
accomodate
d
0.91%
0.00%
0.00%
0.00%
24.67%
0.00%

Carbon monoxide
Hydrogen
Oxygen
Steam

28
2
32
18

KJ/Kmol
Del H specific
-8923.3681
Del H
-69503901
Heat of Formation Summation
Latent Heat of Condensation

Boiler Feed Water


Total heat Surplus

Gjoules/hr
-66.687284

0.00%
74.00%
0.00%
0.42%
100.00%

0.00
5764.17
0.00
32.61
7788.98

0.00%
74.00%
0.00%
0.42%

Gjoules/hr
-69.50390139
-13.1632376
Sat. steam
sat. water
Enthalpy of condensation

rxn heat
2801.9425
959.86
-1842.0825

17
Methanator

Cooler and
Separator

18

Knock out water

19
based on CO
Stream 17 (Methanator outlet)
Mole Flow
Mass Flow
Mol%
(mol/hr)
(kg/hr)
0.91
70.83
1133.23
24.67
1921.37
53798.28
0.00
0.00
0.00
74.00
5764.17
11528.35
0.42
32.61
586.95
100
7788.98
67046.80

Cp coefficients
C
-2.164E-06
-5.561E-06
-8.824E-06
-1.1402E-05
0
0
0
0

D
0
0
0
0
4000
-115700
-3100
8300

Mol%
0.91
24.77
0.00
74.32
0.00
100.00

Stream 18
Mole Flow
(mol/hr)
70.83
1921.37
0.00
5764.17
0.00
7756.37

Stream 19 (Knock o
Mass Flow
(kg/hr)
1133.23
53798.28
0.00
11528.35
0
66459.85

Mol%
0.00
0.00
0.00
0.00
100.00
100

0
0

T initial
588.5555556
588.5555556
588.5555556
588.5555556
588.5555556
588.5555556
588.5555556
588.5555556
588.5555556
588.5555556

-22700
12100

T final
298.00
298.00
298.00
298.00
298.00
298.00
298.00
298.00
298.00
298.00

315.5555556
315.5555556

Tau
0.506324335
0.506324335
0.506324335
0.506324335
0.506324335
0.506324335
0.506324335
0.506324335
0.506324335
0.506324335

Cp
43.95583296
70.8451132
101.2379035
132.8406393
29.50397879
47.81471433
30.08316558
28.66829498
31.84360354
34.34047126

<Cp>
0.213889252
0
0
0
7.217543394
0
0.124895842
21.39666271
0
0
28.9529912

H0f
-362.61
0.00
0.00
0.00
0.00
0.00
-458.87
0.00
0.00
0.00
-821.48

Mol%
0.91%
0.00%
0.00%
0.00%
24.67%
0.00%
0.00%
74.00%
0.00%
0.42%
100.00%

600

Del H specific

Del H
Heat of Formation Summa

-6.71117841

Cp coefficients
C
-2.164E-06
-5.561E-06
-8.824E-06
-1.1402E-05
0
0
0
0
0
0

T initial
605.00
605
605
605
605
605

D
0
0
0
0
4000
-115700
-3100
8300
-22700
12100

T final
298.00
298.00
298.00
298.00
298.00
298.00

System pressure
Vapor pressure

Tau
0.492561983
0.492561983
0.492561983
0.492561983
0.492561983
0.492561983

Cp
<Cp>
44.4295088 0.40400612
71.78131826
0
102.6058244
0
134.5890846
0
29.540659 7.287023311
47.99771414
0

H0f
-677.62
0.00
0.00
0.00
0.00
0.00

Mol%
0.91%
0.00%
0.00%
0.00%
24.67%
0.00%

605
605
605
605

298.00
298.00
298.00
298.00
200
332

0.492561983
0.492561983
0.492561983
0.492561983

30.12423103
0
28.68913941 21.23118557
31.90008202
0
34.42792515 0.144130688
29.06634569

0.00
0.00
0.00
-1012.36
-1689.98

0.00%
74.00%
0.00%
0.42%
100.00%

392

Del H specific

Del H
Heat of Formation Summa

0
Heat of Condensation

J/mol
-33157.485 -1081203800
-1.0812038

Stream 19 (Knock out Water)


Mole Flow
Mass Flow
(mol/hr)
(kg/hr)
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
32.61
586.95
32.61
586.95

Input
Out put

67046.8
67046.80

Mole Flow
Mol%
(kgmol/hr) accomodate
70.83
0.91%
0.00
0.00%
0.00
0.00%
0.00
0.00%
1921.37
24.67%
0.00
0.00%
0.00
0.00%
5764.17
74.00%
0.00
0.00%
32.61
0.42%
7788.98
100.00%

T initial
298.00
298.00
298.00
298.00
298.00
298.00
298.00
298.00
298.00
298.00

T final
605.00
605.00
605.00
605.00
605.00
605.00
605.00
605.00
605.00
605.00

KJ/Kmol
Gjoules/hr
9317.657708
72575013.52 72.57501352
at of Formation Summation-13.1632376

psi
192.5765668 temp
9956.339507
por pressure
A
8.14019

Mole Flow
(kgmol/hr)
70.83
0.00
0.00
0.00
1921.37
0.00

Mol%
accomodate
d
0.91%
0.00%
0.00%
0.00%
24.67%
0.00%

Tau
2.030201342
2.030201342
2.030201342
2.030201342
2.030201342
2.030201342
2.030201342
2.030201342
2.030201342
2.030201342

Cp
44.4295088
71.78131826
102.6058244
134.5890846
30.2561915
27.30093637
29.56969334
30.17386936
27.83943504
36.59241098

332.00 Temp C

-0.20918501

Deg C
25
B

298
C

1810.94

244.485

Vap. Pressure
26.31400976 0.508968347

T initial
298.00
298
298
298
298
298

T final
315.22
315.22
315.22
315.22
315.22
315.22

Tau
1.057792692
1.057792692
1.057792692
1.057792692
1.057792692
1.057792692

Cp
35.60756139
54.063194
76.56391861
101.2758359
29.177705
36.57530672

0.00
5764.17
0.00
32.61
7788.98

0.00%
74.00%
0.00%
0.42%

KJ/Kmol
Gjoules/hr
500.4279353
3897821.245 3.897821245
at of Formation Summation-13.1632376

298
298
298
298

315.22
315.22
315.22
315.22

1.057792692
1.057792692
1.057792692
1.057792692

29.18094781
28.90990388
29.29648401
33.74416304

42.22 Temp C

629.6

<Cp>
0.40400612
0
0
0
7.46352926
0
0
22.329949
0
0.153192193
30.35067657

H0f
-677.62
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
-1012.36
-1689.98

K
0.00264294

<Cp>
0.323786445
0
0
0
7.197490635
0

H0f
-677.62
0.00
0.00
0.00
0.00
0.00

0
21.39456069
0
0.141268154
29.05710592

0.00
0.00
0.00
-1012.36
-1689.98

Ammonia Conversion Loop


400 C
2000 psig
10 psig

Temperature
Pressure
Pressure Drop

24
From Methanator

Ammonia
Converter

18

Reaction 1

Reactions in Ammonia Converter


N2+3H2 = 2NH3

25% based onN2

Iteration No. 1
Components

Methane
Nitrogen
Hydrogen
Ammonia

Mol. Wt
16
28
2
17

Total

Stream 18 (Methanator Outlet)


Mole Flow
Mass Flow
Mol%
(kgmol/hr)
(kg/hr)
0.91%
70.83
1133.23
24.77%
1921.37
53798.28
74.32%
5764.17
11528.35
0.00%
0.00
0.00
100.00%
7756.4
66459.9

H2 Consume
Reaction 1
N2 Consume
Reaction 1

NH3 Produced
Reaction 1

Stream 20 (Converter outl


Mol%
16.66%
16.61%
49.82%
16.91%
100.00%

Calculations for Purge stream 20 Rate


5552.32 kgmol/hr
5552.39
1850.77 kgmol/hr
1850.77

3701.55 kgmol/hr
3701.55

Feed Stream Flow


Feed Stream Inert
Required Inert Conc.

Purge Stream 20 flow


Recycle Stream 21 Flow
66459.9
66458.27

R /F

7756.4
0.01
15%

378.65
29380.98

3.787982016

Note: This indicates that at the start-up, until the system get stabilized, recycle is required after that all the stream s

Scale up Factor Calculations


NH3 production based on 100 kgmol/hr ofNaphthas Feed
Scale up Factor
All the stream flow should be multiplied by this factor to get the desired production rate.

ammonia price
dollar
Total Input

23

Recycle Stream

Ammonia
Converter

20

Cooler and
Ammonia
Separator

21

Liquid Ammonia

22
Sep. Efficiency 65%

Stream 20 (Converter outlet)


Mole Flow
Mass Flow
(kgmol/hr)
(kg/hr)
5570.60
89129.64
5552.32
155464.92
16657.17
33314.33
5655.65
96145.99
33435.80
374054.89

kgmol/hr
mol%
mol%

Methane
Nitrogen
Hydrogen
NH3

kgmol/hr
kgmol/hr

N2 :H2

Stream (25) (Mixed feed)


Mole Flow
Mass Flow
Mol%
(kgmol/hr)
(kg/hr)
15.00%
5570.60
89129.64
19.93%
7403.09
207286.57
59.80%
22209.56
44419.11
5.26%
1954.10
33219.70838
100.00%
37137.35
374055.03

Mol%
18.72%
18.66%
55.97%
6.65%
100.00%

Purge Stream 23
Mole Flow
Mass Flow
(kgmol/hr)
(kg/hr)
70.83
1133.23
70.65
1978.09
211.94
423.88
25.19
428.18
378.65

66459.85
66458.27
7756.4
4054.82
quired after that all the stream should be purged.

62494.89 kg/hr
1499.9 Tonnes/day
1.0
e desired production rate.

Purge Stream

62.49489181 TPH

1.59

3963.37

Stream 22 (Liquid A
Mol%
0.00%
0.00%
0.00%
100.00%
100.00%

Recycle Stream
Mol%
18.72%
18.66%
55.97%
6.65%
100.00%

Required
4743.387682

31538.7847

1.981525046

31.5387847

Nh3/ton naphtha

Put Basis
2265.2595

756.9308328
1.981525046
0.504661802

792.6100185
287.9482168

504.6618017
145.3164659

Stream 22 (Liquid Ammonia)


Stream 21 (after seperatorLiquid Ammonia)
Mole Flow
Mole Flow
Mass Flow
(kgmol/hr) Mass Flow (kg/hr)
Mol%
(kgmol/hr)
(kg/hr)
0.00
0.00
18.72%
5570.60
89129.64
0.00
0.00
18.66%
5552.32
155464.92
0.00
0.00
55.97%
16657.17
33314.33
3676.17
62494.89
6.65%
1979.48
33651.10
3676.17
62494.89
100.00%
29759.56
311560.00
Recycle Stream 24
Mole Flow
(kgmol/hr) Mass Flow (kg/hr)
5499.78
87996.41
5481.67
153486.84
16445.23
32890.45
1954.29
33222.91
29380.96
29380.98
307596.62

1133.23
1.447523411

311560.00

-0.14

Over All composition


Pre- Reformer
Components

Stream 1 (Pre-R1)

Mol. Wt

Carbon
H2

Stream 2 (Pre-R2)

306.3978 -

26169.9768
5108.211

Methane
Ethane
Propane
Butane
Nitrogen
Carbon dioxide
Carbon monoxide
Hydrogen
Oxygen
Steam/Water
Argon
MDEA sol.

16
30
44
58
28
44
28
2
32
18
40

Ammonia
Total

Stream 3 (Pre-R3)

20383.22
560.54
25035.94
2158.04
137392.3782

31584.5856

120839.2201
-

137392.3782

168976.9638
0

Total Input
235356.8
Total output 235356.8

Input
St 1
St 5
St 2
N.gas input

output
31584.5856
-3762.258051
137392.3782
0

co2 out
st 13
st 19
st 23

92840.20825
75469.75693
586.9464585
3963.374505

St 7

70142.06014 st 22
235356.7659

62494.89181
1.587933805

235356.7659
235.3567659

235356.7659

Reformer Primary & Secondary


Stream 4 (P-R4)
20383.21625
0
0
0
0
560.538447
25035.94447
2158.044525
-

Stream 5 (P-R5)
-

120839.2201
-

5095.80
0.00
0.00
0.00
0.00
33113.57
31073.35
9370.51

Stream 7 (S-R7)

53798.27914
-

-3762.258051

16343.781
86561.47 -

168976.9638

kg/hr
kg/hr

Stream 6 (P-R6)

-3762.258051

165214.7057
0

70142.06014

0.000674692

Shift Convertors
Stream 8 (S-R8)

Stream 9 (S-C9)

611.50

Stream 10 (S-C10)

Stream 11 (S-C11)

611.50

611.50

611.50

53798.28
58406.02
22825.70
10158.81
0.00
89556.47

53798.28
58406.02
22825.70
10158.81
0.00
89556.47

53798.28
87101.18
4565.14
11463.13

53798.28
92840.21
913.03
11724.00

77817.54

75469.75693

235356.7659
0

235356.7659

235356.7659

235356.7659

Water Seperator
Stream 12 (C-S12)

CO2 Absorption Stripping

Stream 13 (C-S13)

Stream 14 (C-S14)

Stream 15 (C-A15)

611.50

611.50

53798.28
92840.21
913.03
11724.00

53798.28

20631.16
913.03
11724.00
75469.75693

558541.70
558541.70

159887.009

75469.75693
0

1137714.552
1297601.561

67046.80071

ion Stripping

Methanator
Stream 16 (C-A16)

Stream 17 (M-R17)

Stream 18 (M-R18)

1133.23

1133.23

53798.28

53798.28

11528.35

11528.35

Stream 19 (M-R18)

113471.37

558541.70

586.95

586.95

558541.70
1230554.76
1297601.561
0

67046.80071

66459.85425

586.9464585
0.00

Input

Stream 20 (S-L20)

Stream 21 (S-L21)

Stream 22 (S-L22)

Stream 23 (S-L23)

89129.64

89129.64

1133.23

155464.92

155464.92

1978.09

33314.33

33314.33

423.88

96145.99
374054.8868

33651.10
311559.995

62494.89
62494.89181

428.18
3963.374505

Stream 24 (S-L24)

Stream 25 (S-L25)

87996.41

89129.64

153486.84

207286.57

32890.45

44419.11

33222.91
307596.6205

33219.70838
374055.0273

235355.2

Pre Reformer
Del H
Tin
T out
Pin
Pout

Adiabetic

Primary reformer
Gj/hr
245.3708166
490
700
510.00
750