ADVANCED ANALYTICAL CHEMISTRY QUIZ 5 Name: ___________________________Date: ________ 1.

Any current in an electrochemical cell due to an oxidation or reduction reaction is called A.charging current B.non-faradaic current C. faradaic current D. overpotential current 2. The current in an electrochemical cell that is present even in the absence of the analyte is called A. cathodic current B. anodic current C.residual current D. faradaic current 3. Which of the following is an example of non-faradaic current? A. cathodic current B. anodic current C. charging current D. i1/2 current 4. Voltammetric techniques that include convection by stirring are called A. polarography B.hydrodynamic voltammetry C.differential pulse polarography D. coulometry 5. A form of voltammetry using a dropping mercury electrode or a static mercury drop electrode in which the potential is linearly scanned is called A. hydrodynamic voltammetry B. normal polarography C. differential pulse polarography D.square-wave polarography 6. The relationship between the limiting current and concentration of the analyte in polarography is called A. Ilkovic equation B. Ohms law C.Randles-Sevcik equation D. Lingane equation 7. A form of voltammetry in which we measure current as a function of time while maintaining a constant potential is called A.normal polarography B. amperometry C. cyclic votammetry D. square-wave polarography 8. In controlled-potential coulometry, the potential of the ______electrode is maintained constant. A. reference B. auxiliary C. counter D. working 9. An electronic device that maintains the potential of a working electrode at constant level is called A. potentiostat B. galvanostat C. amperostat D. potentiometer 10. Faradays law relates the number of moles of the analyte to the A. voltage B. charge C. current D. volume 11. In coulometric tritration, a constant _____generates the titrant electrolytically. A. charge B. voltage C. current D. volume 12. Polarography and hydrodynamic voltammetry use what signal excitation? A. square wave B. triangular C. linear scan D. differential pulse 13. The potential at iL/2 is called A. middle potential B. half-wave potential C. reference potential C. overpotential 14. Negative current is called A. anodic B. cathodic C. electrons D. holes 15. Reduction reaction produces_____current A. constant B. cathodic C. anodic D. controlled 16. In hydrodynamic voltammetry, the first reduction product of oxygen present in the solution is A. OH B. H2O2 C. H2O D. H3O+ 17. Amperometric titration is an application of A. potentiometry B. coulmetry C. electrogravimetry D. voltammetry 18. The following are used for disk electrode in hydrodynamic voltammetry EXCEPT A. gold B. Pt C. carbon D. Hg 19. In polarography, the limiting current is controlled by A. migration B. diffusion C. forced convection D. natural convection 20. In polarography, at -0.4 V mercury drop begins to expand while the reading of the current is zero, this current responsible for the expansion is called A. faradaic B. Non-faradaic C. cathodic D. anodic

ADVANCED ANALYTICAL CHEMISTRY QUIZ 5 Name: ___________________________Date: ________ 1.Any current in an electrochemical cell due to an oxidation or reduction reaction is called A.charging current B.non-faradaic current C. faradaic current D. overpotential current 2. The current in an electrochemical cell that is present even in the absence of the analyte is called A. cathodic current B. anodic current C.residual current D. faradaic current 3. Which of the following is an example of non-faradaic current? A. cathodic current B. anodic current C. charging current D. i1/2 current 4. Voltammetric techniques that include convection by stirring are called A. polarography B.hydrodynamic voltammetry C.differential pulse polarography D. coulometry 5. A form of voltammetry using a dropping mercury electrode or a static mercury drop electrode in which the potential is linearly scanned is called A. hydrodynamic voltammetry B. normal polarography C. differential pulse polarography D.square-wave polarography 6. The relationship between the limiting current and concentration of the analyte in polarography is called A. Ilkovic equation B. Ohms law C.Randles-Sevcik equation D. Lingane equation 7. A form of voltammetry in which we measure current as a function of time while maintaining a constant potential is called A.normal polarography B. amperometry C. cyclic votammetry D. square-wave polarography 8. In controlled-potential coulometry, the potential of the ______electrode is maintained constant. A. reference B. auxiliary C. counter D. working 9. An electronic device that maintains the potential of a working electrode at constant level is called A. potentiostat B. galvanostat C. amperostat D. potentiometer 10. Faradays law relates the number of moles of the analyte to the A. voltage B. charge C. current D. volume 11. In coulometric tritration, a constant _____generates the titrant electrolytically. A. charge B. voltage C. current D. volume 12. Polarography and hydrodynamic voltammetry use what signal excitation? A. square wave B. triangular C. linear scan D. differential pulse 13. The potential at iL/2 is called A. middle potential B. half-wave potential C. reference potential C. overpotential 14. Negative current is called A. anodic B. cathodic C. electrons D. holes 15. Reduction reaction produces_____current A. constant B. cathodic C. anodic D. controlled 16. In hydrodynamic voltammetry, the first reduction product of oxygen present in the solution is A. OH B. H2O2 C. H2O D. H3O+ 17. Amperometric titration is an application of A. potentiometry B. coulmetry C. electrogravimetry D. voltammetry 18. The following are used for disk electrode in hydrodynamic voltammetry EXCEPT A. gold B. Pt C. carbon D. Hg 19. In polarography, the limiting current is controlled by A. migration B. diffusion C. forced convection D. natural convection 20. In polarography, at -0.4 V mercury drop begins to expand while the reading of the current is zero, this current responsible for the expansion is called A. faradaic B. Non-faradaic C. cathodic D. anodic

ADVANCED ANALYTICAL CHEMISTRY QUIZ 5 Name: ___________________________Date: ________ 1.Any current in an electrochemical cell due to an oxidation or reduction reaction is called A.charging current B.non-faradaic current C. faradaic current D. overpotential current 2. The current in an electrochemical cell that is present even in the absence of the analyte is called A. cathodic current B. anodic current C.residual current D. faradaic current 3. Which of the following is an example of non-faradaic current? A. cathodic current B. anodic current C. charging current D. i1/2 current 4. Voltammetric techniques that include convection by stirring are called A. polarography B.hydrodynamic voltammetry C.differential pulse polarography D. coulometry 5. A form of voltammetry using a dropping mercury electrode or a static mercury drop electrode in which the potential is linearly scanned is called A. hydrodynamic voltammetry B. normal polarography C. differential pulse polarography D.square-wave polarography 6. The relationship between the limiting current and concentration of the analyte in polarography is called A. Ilkovic equation B. Ohms law C.Randles-Sevcik equation D. Lingane equation 7. A form of voltammetry in which we measure current as a function of time while maintaining a constant potential is called A.normal polarography B. amperometry C. cyclic votammetry D. square-wave polarography 8. In controlled-potential coulometry, the potential of the ______electrode is maintained constant. A. reference B. auxiliary C. counter D. working 9. An electronic device that maintains the potential of a working electrode at constant level is called A. potentiostat B. galvanostat C. amperostat D. potentiometer 10. Faradays law relates the number of moles of the analyte to the A. voltage B. charge C. current D. volume 11. In coulometric tritration, a constant _____generates the titrant electrolytically. A. charge B. voltage C. current D. volume 12. Polarography and hydrodynamic voltammetry use what signal excitation? A. square wave B. triangular C. linear scan D. differential pulse 13. The potential at iL/2 is called A. middle potential B. half-wave potential C. reference potential C. overpotential 14. Negative current is called A. anodic B. cathodic C. electrons D. holes 15. Reduction reaction produces_____current A. constant B. cathodic C. anodic D. controlled 16. In hydrodynamic voltammetry, the first reduction product of oxygen present in the solution is A. OH B. H2O2 C. H2O D. H3O+ 17. Amperometric titration is an application of A. potentiometry B. coulmetry C. electrogravimetry D. voltammetry 18. The following are used for disk electrode in hydrodynamic voltammetry EXCEPT A. gold B. Pt C. carbon D. Hg 19. In polarography, the limiting current is controlled by A. migration B. diffusion C. forced convection D. natural convection 20. In polarography, at -0.4 V mercury drop begins to expand while the reading of the current is zero, this current responsible for the expansion is called A. faradaic B. Non-faradaic C. cathodic D. anodic