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Material Safety Data Sheet

Cola®Mine 1-76
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Colonial Chemical, Inc. Emergency Telephone #
225 Colonial Drive 423/837-8800
S.Pittsburg, TN 37380 Chemtrec 800/424-9300
SECTION I – PRODUCT INFORMATION
Product Name: Cola®Mine 1-76 File: 1-76
C.A.S. No.: Proprietary Blend
Product Class: Alkanolamide
Hazard Rating: Health: 1 Flammability: 1 Reactivity: 0

Direct Phone: 423/837-8800

THE CHEMTREC NUMBER IS TO BE CALLED ONLY IN THE EVENT OF CHEMICAL


EMERGENCIES INVOLVING A SPILL, LEAK, FIRE, EXPOSURE OR ACCIDENT
INVOLVING CHEMICALS.

Emergency Overview: May cause moderate eye and skin irritation.


SECTION II – HAZARDOUS INGREDIENTS
Ingredients CAS # Weight % PEL (ppm) TLV (ppm)

DIETHANOLAMINE 111-42-2 18

*** All ingredients in this product are listed in the TSCA Inventory.
SECTION III – PHYSICAL DATA
Appearance: Clear light amber liquid
Boiling Point (°F): 150° F
% Volatile: NIL
Vapor Pressure: Not determined
Vapor Density: Estimated heavier than air
Evaporation Rate: Estimated slower than ethyl ether
pH (10% AQ.): 9.0
Specific Gravity @25°C: 0.99
SECTION IV – FIRE AND EXPLOSION HAZARD DATA
Flash Point: 201°F
Extinguishing Media: CO2, foam, dry chemical, BC/ABC extinguishers
Special Fire Fighting Procedures: Firefighters should wear full protective clothing
including self-contained breathing apparatus
Unusual Fire and Explosion Hazards: None
SECTION V – REACTIVITY DATA
Stability: Stable under normal conditions
Hazardous Polymerization: Will not occur
Incompatibility (Materials to avoid): Strong-oxidizing agents.
Hazardous Decomposition Products: Oxides of carbon and nitrogen
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SECTION VI – HEALTH HAZARD DATA
EMERGENCY OVERVIEW: May cause irritation to the eyes, skin, and respiratory system.

HEALTH EFFECTS:
Eyes – May cause irritation
Skin – Prolonged and/or repeated skin contact with this product may cause
irritation/dermatitis
Inhalation – Vapors or mists may be irritating to respiratory system

FIRST AID:
Eye Contact - Immediately flush with copious amounts of water for at least 15
minutes while holding eyelids open. Consult physician.
Skin Contact- Immediately flush with copious amounts of soap and water for at
least 5 minutes. Remove contaminated clothing. If irritation
persists, contact physician. Launder contaminated clothing
before reuse.
Ingestion- If patient is conscious and can swallow, give 2 glasses of water.
Call a physician or Poison Control Center immediately. Induce
vomiting as directed by medical personnel.
Inhalation- Remove to fresh air – if necessary give oxygen, artificial
respiration. Contact physician.
Ingestion - If material is swallowed, get medical attention immediately.
SECTION VII – SPECIAL PROTECTION INFORMATION
Occupational Exposure Limits
ACGIH TLV ACGIH TLV-C ACGIH STEL OSHA STEL OSHA PEL
DIETHANOLAMINE
0.46 PPM N/est N/est N/est 3.00 PPM

Respiratory Protection: If vapors are present, use a NIOSH approved respirator


for ammoniacal vapors, air-line respirator, or a self-contained
breathing apparatus.
Ventilation: Provide adequate local exhaust ventilation to maintain worker
exposure below exposure limits. Local exhaust is suggested
for use, where possible, in enclosed or confined spaces.
Eye Protection: Chemical goggles
Protective Gloves: Impervious
Other Protection: Wear protective clothing to prevent skin contact. Eye wash
stations and safety showers are recommended.
SECTION VIII – SPECIAL PRECAUTIONS
HANDLING PROCEDURES: Wash thoroughly after handling.
STORAGE PROCEDURES: Avoid freezing or excessive heat.
OTHER PRECAUTIONS: Spilled material is quite slippery.

SPILL OR LEAK PROCEDURES: Absorb spill with inert material. Shovel material into
appropriate container for disposal. Flush area with water to remove trace residue. Do not allow
the spilled product to enter public drainage system or open watercourses. Ventilate the
contaminated area.
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SECTION IX – REGULATORY INFORMATION
TSCA: Listed in TSCA inventory.
SARA TITLE III – Section 313: Diethanolamine, See Section II
SECTION X – WASTE DISPOSAL
Waste Disposal Method: In accordance with local, state and federal regulations.
SECTION XI – TOXICOLOGICAL INFORMATION
CARCINOGENICITY: No carcinogenicity data available for this product.
OTHER TOXICOLOGICAL INFORMATION: Do not use nitrosating agents with this product
since nitrosamines may form. Some nitrosamines have been shown to be carcinogenic tests with
laboratory animals.
NIOSH – SELECTED LD50s AND LC50s:
Diethanolamine CAS #: 111-42-2 Oral LD50 Rat: 620 uL/kg; Oral LD50 Mouse:
3300 mg/kg; Dermal LD50 Rabbit: 7640 uL/kg
SECTION XII – TRANSPORTATION INFORMATION
Proper Shipping Name: Environmentally Hazardous Substance, liquid N.O.S.
(contains Diethanolamine)
DOT Hazard Class: 9
UN Number: UN3082
Packing Group: III

***This item contains Diethanolamine, which has an RQ amount of 100 pounds. Any container
that holds an equal or greater amount is a DOT hazardous substance and is shipped as stated
above.
***Any container containing a lesser amount is non-regulated.

HEALTH 1
FLAMMABILITY 1
REACTIVITY 0
PERSONAL PROTECTION B

The above data is for information purposes only and is accurate to the best of Colonial Chemical,
Inc.’s knowledge. No guarantees or liabilities are expressed or implied.

REVISED: 06-16-2006 J.STAFFORD