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Clariant Mining

Non-Sulfide ores

Clariant Mining
Ore Type Metal/Element Values Major Minerals

Non-Sulfide Ores
Barite
Ba Barite Direct flotation of barite FLOTINOR FS-100 If gangue material makes selective flotation of Barite difficult FLOTINOR FS-2 Flotation of coarse particles For varying or specific conditions (tailor-made frother blends) To regulate pH To depress gangue For a depressant for fluorspar To activate Barite
Ore Type Metal/Element Values Major Minerals Applications Applications Applications clariant Collectors Product

FLOTANOL 7026

Clariant Frothers Product

fatty acids fatty acids

Class of Actives

FLOTANOL grades
Modifiers Product

fraction of terpene alcohols polypropylene glycol and polypropylene glycol methyl ether Na2CO3 Na2SiO3 C6H8O7 BaCl2
Class of Actives

Class of Actives

soda water glass citric acid barium chloride

Calamine

Zn

Smithsonite, Hemimorphite, Willemite, Hydrozinkite

To enhance performance used in combination with xanthate over just xanthate


Applications

Applications

Clariant Collectors Product

FLOTIGAM 2835, FLOTIGAM 2835-2, FLOTIGAM 2835-2L


Clariant Frothers Product

Class of Actives

alkyl ether di-amine


Class of Actives

Flotation of coarse particles


Applications

Additives to be used as a co-collector with xanthates To regulate pH For a sulfidizing agent for calamine ("activator") For a dispersant, depressant for gangue material
Ore Type Metal/Element Values Major Minerals Applications Applications

Clariant Additives Product

FLOTANOL 7026 FLOTANOL M MONTANOL 800 FLOTIGAM 2835

fraction of terpene alcohols MIBC mixture of aliphatic alcohols, ethers and esters alkyl ether di-amine NaOH Na2S Na2SiO3
Class of Actives

caustic soda sodium sulfide water glass

Modifiers Product

Class of Actives

clariant Collectors Product

Ca, Mg Calcite, Magnesite

Calcite, Magnesite

For reverse calcite flotation


Applications

quaternary alkyl amine FLOTIGAM K2C FLOTINOR 4815 quaternary alkyl amine formulation FLOTIGAM ITU, FLOTIGAM 7079 imidazoline FLOTANOL 7026 MONTANOL 88 MONTANOL 800
Clariant Frothers Product

Class of Actives

For flotation of graphite out of calcite

FLOTANOL D-25

Modifier not typically used


Ore Type Metal/Element Values Major Minerals

Applications

Modifiers Product

fraction of terpene alcohols polypropylene glycol and polypropylene glycol methyl ether alcohol formulation mixture of aliphatic alcohols, ethers and esters
Class of Actives

Class of Actives

Applications

clariant Collectors Product

Cassiterite

Sn

Cassiterite

For a very selective cassiterite collector; add in several portions to enhance selectivity
Applications

HOSTAPHAT 7053 FLOTINOR 3635 FLOTINOR 1682 FLOTANOL C 07 FLOTANOL 7026

Clariant Frothers Product

alkane phosphonic acid alkyl sulphosuccinate phosphoric acid ester

Class of Actives

Flotation of coarse particles Flotation of fine particles


Applications

FLOTANOL D-25 MONTANOL 88 MONTANOL 800 sulfuric acid

To regulate pH
Ore Type Metal/Element Values Major Minerals

Modifiers Product

polypropylene glycol fraction of terpene alcohols polypropylene glycol and polypropylene glycol methyl ether alcohol formulation mixture of aliphatic alcohols, ethers and esters H2SO4
Class of Actives

Class of Actives

Coal

Coal

Applications

fatty acids, fuel oil, kerosene MONTANOL grades


Clariant Frothers Product Modifiers Product

Collectors Product

Class of Actives

Applications

mixture of aliphatic alcohol, ethers and esters


Class of Actives

Class of Actives

Modifier not typically used


Ore Type Metal/Element Values Major Minerals

Applications

Feldspar
Al, Si Orthoklase, Albite, Anorthite

For the flotation of fine grained feldspar to enhance selectivity For a liquid feldspar collector with very high flash point (> 100 C) Direct flotation
Applications

Applications

clariant Collectors Product

FLOTIGAM 2835, FLOTIGAM 2835-2, FLOTIGAM 2835-2L FLOTIGAM 4343 FLOTIGAM 7034 FLOTIGAM DAT FLOTIGAM EDA FLOTANOL 7026
Clariant Frothers Product Modifiers Product

Class of Actives

alkyl ether di-amine alkyl di-amine primary amine alkyl di-amine alkyl ether amine fraction of terpene alcohols
Class of Actives

Flotation of coarse particles To regulate pH To activate feldspar


Ore Type Metal/Element Values Major Minerals

Applications

sulfuric acid H2SO4 hydrofluoric acid or sodium fluoride HF or NaF


clariant Collectors Product

Class of Actives

Fluorite (Fluorspar)

Fluorite

To be used with other anionic collectors to enhance performance depending on the application Collectors recommended for use in combination with Flotinor FS-types Direct flotation Flotation of coarse particles Flotation of fine particles For very selective fluorite flotation, use frother in combination with FLOTINOR 2818 To regulate pH For a dispersant, depressant for gangue material For a depressant for gangue material
Applications Applications

Applications

FLOTINOR FS-2, FLOTINOR FS-100 FLOTINOR SM 15, FLOTINOR V 2711 FLOTINOR 2818 FLOTIGAM 5806
Clariant Frothers Product

Class of Actives

fatty acids phosphoric acid esters modified sodium carboxylate fatty acid formulation
Class of Actives

FLOTANOL C 07, FLOTANOL D-25 polypropylene glycol MONTANOL 800 mixture of aliphatic alcohols, ethers and esters FLOTANOL D 14
Modifiers Product

polypropylene glycol methyl ether


Class of Actives

soda water glass quebracho tannin

Na2CO3 Na2SiO3 -

Ore Type

Metal/Element Values

Major Minerals

Glass Sand
Si, Al, K, Na, Ca, Fe, Ti Quartz, Feldspar, Heavy Metal Oxides, Mica

For biotite flotation. Combining with FLOTINOR FStypes can be beneficial Collector recommended for use in combination with FLOTINOR FS-types or/and FLOTINOR SM 15 Depending on the case of application, these collectors in combination with FLOTINOR 3635 or/and FLOTINOR SM 15 can be beneficial For muscovite flotation

Applications

clariant Collectors Product

Class of Actives

FLOTINOR SM 15 FLOTINOR 3635 FLOTINOR FS-2, FLOTINOR FS-100

phosphoric acid ester sulphosuccinic acid ester fatty acids alkyl ether amine alkyl ether di-amine alkyl di-amine fraction of terpene alcohols polypropylene glycol and plypropylene glycol methyl ether H2SO4
Class of Actives Class of Actives

FLOTIGAM EDA, FLOTIGAM EDA C, FLOTIGAM EDA 3, FLOTIGAM EDA 3C For the flotation of fine grained feldspar to enhance FLOTIGAM 2835, FLOTIGAM 2835-2, FLOTIGAM 2835-2L selectivity For a liquid feldspar collector with very high flash point (> 100 C) FLOTIGAM 4343
Applications

Flotation of coarse particles


Applications

FLOTANOL 7026

Clariant Frothers Product

FLOTANOL D-25
Modifiers Product

To regulate pH
Ore Type Metal/Element Values Major Minerals

sulfuric acid

Graphite

Graphite

Applications

kerosene

Collectors Product

Class of Actives

Applications

Flotation of coarse particles Flotation of fine particles


Applications

FLOTANOL 7026 FLOTANOL D-25 MONTANOL 88 MONTANOL 800 caustic soda

Clariant Frothers Product

To regulate pH
Ore Type Metal/Element Values Major Minerals

Modifiers Product

fraction of terpene alcohols polypropylene glycol and polypropylene glycol methyl ether alcohol formulation mixture of aliphatic alcohols, ethers and esters NaOH
Class of Actives

Class of Actives

Heavy Metal Oxides

Fe, Ti

Biotite, Ilmenite, Rutile

Collector to be used in combination with Flotinor FStypes or/and Flotinor SM 15 recommended Depending on the case of application, these collectors in combination with FLOTINOR 3635 or/and FLOTINOR SM 15 can be beneficial For biotite flotation; combining with FLOTINOR FStypes can be beneficial Frother not typically used To regulate pH
Applications

Applications

clariant Collectors Product

Class of Actives

FLOTINOR 3635 FLOTINOR FS-2, FLOTINOR FS-100 FLOTINOR SM-15


Frothers Product Modifiers Product

sulphosuccinic acid ester fatty acids phosphoric acid ester


Class of Actives

Applications

sulfuric acid

H2SO4

Class of Actives

Ore Type

Metal/Element Values

Major Minerals

Applications

clariant Collectors Product

Iron Ores
Fe Hematite, Magnetite

For reverse hematite flotation For direct hematite flotation For reverse magnetite flotation
Applications

FLOTIGAM EDA, FLOTIGAM EDA-C FLOTIGAM V 5444 FLOTIGAM 5806 FLOTINOR FS-2 FLOTINOR 1682 FLOTIGAM 3135, FLOTIGAM 2835-2L FLOTIGAM 2835, FLOTIGAM 2835-2 MONTANOL 88 MONTANOL 800
Clariant Frothers Product

Class of Actives

alkyl ether amine alkyl ether mono-amine blend fatty acid formulation fatty acids phosphoric acid ester alkyl ether di-amine
Class of Actives

To support flotation of non quartz silicates


Applications

To regulate pH For a depressant for hematite


Ore Type Metal/Element Values Major Minerals

caustic soda caustic corn starch

Modifiers Product

alcohol formulation mixture of aliphatic alcohols, ethers and esters NaOH Class of Actives

Kaolin Clay

Al, Si

Kaolinite

Flotation of coarse particles Frother not typically used

Applications

clariant Collectors Product

FLOTIGAM 7034

Applications

Frothers Product

alkyl amine

Class of Actives

Class of Actives

To regulate pH To activate feldspar For a coagulant for kaolinite


Ore Type Metal/Element Values Major Minerals

Applications

sulfuric acid H2SO4 hydrofluoric acid or sodium fluoride HF or NaF Alumina sulfate Al2(SO4)3
clariant Collectors Product

Modifiers Product

Class of Actives

Phosphate

Apatite, Phosphorite

FLOTIGAM EDA, FLOTIGAM EDA 3, FLOTIGAM EDA-C, For reverse flotation of coarse silica particles FLOTIGAM EDA 3C FLOTIGAM V 5444 FLOTIGAM 3135, FLOTIGAM For reverse flotation of fine silica particles and high 2835, FLOTIGAM 2835-2L, selectivity is required FLOTIGAM 2835-2, FLOTINOR 5442 For direct apatite flotation; combination with FLOTINOR FLOTINOR FS-2, FLOTINOR FS-5, 2818 can be beneficial FLOTINOR FS-100 For reverse phosphorite flotation; usage in combination with FLOTINOR SM 15, FLOTIGAM 3135, EDA-types and 2835 types recommended FLOTINOR V 2711 For direct apatite flotation; combination with Flotinor FLOTINOR 2818 FS-types recommended Direct apatite flotation FLOTIGAM 5806 Flotation of fine particles
Applications

Applications

Class of Actives

alkyl ether amine alkyl ether amine blend alkyl ether di-amine fatty acid phosphoric acid ester modified sodium carboxylate fatty acid formulation mixture of aliphatic alcohol, ethers and esters nonyl phenol polyglycolether
Class of Actives Class of Actives

MONTANOL 800

Clariant Frothers Product

A depressant for carbonate minerals


Ore Type Metal/Element Values Major Minerals

Applications

FLOTICOR AD 7013

Clariant additives Product

Potash

Sylvite

For very warm brine temperatures (> 40 C); Flotigam V 5070 used in particular Flotation of coarse particles For a specialized frother for potash flotation Flotation of coarse particles Flotation of fine particles
Applications Applications

Applications

clariant Collectors Product

FLOTIGAM S FLOTIGAM V 5070

alkyl amines alkyl amines

Class of Actives

FLOTANOL C 07 FLOTANOL F FLOTANOL 7026 MONTANOL 88 MONTANOL 800 guar

Clariant Frothers Product

For a depressant for clay


Ore Type Metal/Element Values Major Minerals

Modifiers Product

polypropylene glycol alkyl polyglycol ether fraction of terpene alcohols alcohol formulation mixture of aliphatic alcohols, ethers and esters Class of Actives

Class of Actives

Pyrochlore

Nb

Pyrochlore

For a collector where no desliming may be necessary Flotation of pyrochlore Frother not typically used
Applications

Applications

clariant Collectors Product

FLOTIGAM 7033 FLOTIGAM 7014

Frothers Product

alkylenetriamine alkylenetriamine formulation

Class of Actives

Class of Actives

For flotation of pyrochlore; Especially used in combination FLOTICOR AD 7031, with FLOTIGAM 7014 FLOTICOR WA 7032
Ore Type Metal/Element Values Major Minerals Applications

Applications

Clariant additives Product

Class of Actives

fatty acid polyglycol ester

Scheelite W

Scheelite

Recommended collector to be used in combination with FLOTINOR 2818 To increase selectivity use in combination with FLOTINOR FS-types
Applications

clariant Collectors Product

FLOTINOR FS-2, FLOTINOR FS-100 FLOTINOR 2818

Class of Actives

fatty acids modified sodium carboxylate


Class of Actives

Flotation of coarse particles Flotation of fine particles


Applications

FLOTANOL 7026

Clariant Frothers Product

FLOTANOL D-25 MONTANOL 88 MONTANOL 800 soda ash water glass


clariant Collectors Product

Modifiers Product

fraction of terpene alcohols polypropylene glycol and polypropylene glycol methyl ether alcohol formulation mixture of aliphatic alcohols, ethers and esters
Class of Actives

To regulate pH Dispersant and depressant


Ore Type Metal/Element Values Major Minerals Applications

Na2CO3 Na2SiO3
Class of Actives

Talc

Mg

Talc

To enhance recovery

FLOTIGAM 7034

Applications

Flotation of coarse particles Flotation of fine particles


Applications

FLOTANOL 7026

Clariant Frothers Product

alkyl amine

FLOTANOL D-25 MONTANOL 88 MONTANOL 800 sulfuric acid

Modifiers Product

fraction of terpene alcohols polypropylene glycol and polypropylene glycol methyl ether alcohol formulation mixture of aliphatic alcohols, ethers and esters
Class of Actives

Class of Actives

For improving selectivity use to regulate pH

H2SO4

Clariant MINING

2645 Technology Forest Blvd. The Woodlands, Texas 77381 Tel: +1 281-465-9100 Fax: +1 281-465-9200
www.MINING.clariant.com

Contact your local Clariant representative for a solution that is tailored to meet your specific needs.

Clariant MINING

2645 Technology Forest Blvd. The Woodlands, Texas 77381 Tel: +1 281-465-9100 Fax: +1 281-465-9200
www.MINING.clariant.com

This information corresponds to the present state of our knowledge and is intended as a general description of our products and their possible applications. Clariant makes no warranties, express or implied, as to the informations accuracy, adequacy, sufficiency or freedom from defect and assumes no liability in connection with any use of this information. Any user of this product is responsible for determining the suitability of Clariants products for its particular application. * Nothing included in this information waives any of Clariants General Terms and Conditions of Sale, which control unless it agrees otherwise in writing. Any existing intellectual/industrial property rights must be observed. Due to possible changes in our products and applicable national and international regulations and laws, the status of our products could change. Material Safety Data Sheets providing safety precautions, that should be observed when handling or storing Clariant products, are available upon request and are provided in compliance with applicable law. You should obtain and review the applicable Material Safety Data Sheet information before handling any of these products. For additional information, please contact Clariant. Trademark of Clariant registered in numerous countries. * For sales to customers located within the United States and Canada the following applies in addition: NO EXPRESS OR IMPLIED WARRANTY IS MADE OF THE MERCHANTABILITY, SUITABILITY, FITNESS FOR A PARTICULAR PURPOSE OR OTHERWISE OF ANY PRODUCT OR SERVICE.  2012 Clariant International AG, Rothausstrasse 61, 4132 Muttenz, Schweiz  Product and service marks protected by Clariant

CM-012013

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