1.

Instead of principal quantum number n, l and m, a set of new quantum numbers was introduced with similar logic but different values as defined below s = 1,2,3.....all +ive integral values t = (s1), (s3), (s5).... No negative value u = (t+1/2) to (t+1/2) in integral steps For each value of 'u' there will be three electrons. (i) Calculate the number of electrons in s = 1 shell? (ii) Corresponding to t = 0, 1, 2, 3..... a sub-shell is represented by s,p,d,f,g....respectively. Calculate the number of electrons in 3d subshell. (iii) (s + t) rule is defined similar to (n + l ) rule then write the principal quantum number and azimuthal quantum number of the last subshell for Fe. 2. In the Bohr's model, for unielectronic species following symbols are used rn,z Radius of nth orbit with atomic number "z" Un,z Potential energy of electron in nth orbit with atomic number "z" Kn,z Kinetic energy of electron in nth orbit with atomic number "z" vn,z Velocity of electron in nth orbit with atomic number "z" Tn,z Time period of revolution of electron in nth orbit with atomic number "z" Calculate z in all in cases. (i) U1, 2 : K1,z = 8 : 1 (ii) r1,z : r2, 1 = 1 : 8 (iii) v1, z : v3, 1 = 9 : 1 (iv) T1, 2 : T2, z = 9 : 32 3. The angular momentum of an electron in a Bohr's orbit of H-atom is 3.16521034 kg-m2/sec. Calculate the wavenumber in terms of Rydberg constant (R) of the spectral line emitted when an electron falls from this level to the ground state.[Use h = 6.626 1034 Js] 4. Electron present in single electron specie jumps from energy level 3 to 1. Emitted photons when passed through a sample containing excited He+ ion causes further excitation to some higher energy level (Given En = 13.6 ). Determine (i) Atomic number of single electron specie. (ii) principal quantum number of initial excited level & higher energy level of He+. 5. An alpha particle after passing through a potential difference of 2 106 volt falls on a silver foil. The atomic number of silver is 47. Calculate (i) the K.E. (in Joules) of the alpha-particle at the time of falling on the foil. (ii) K.E. (in Joules) of the particle at a distance of 5 1014m from the nucleus, (iii) the shortest distance (in meters) from the nucleus of silver to which the particle reaches. 6. A proton captures a free electron whose K.E. is zero & forms a hydrogen atom of lowest energy-level (n = 1). If a photon is emitted in this process, what will be the wavelength of radiation? (Ionisation potential of hydrogen = 13.6 volt, h = 6.6 1034K/s, c = 3.0 108 m/s) 7. Column I Column II (A) Orbital angular momentum of the (P) Principal quantum number electron in a hydrogen-like atomic orbital (B) (C) A hydrogen-like one-electron wave function obeying Pauli principle Shape, size and orientation of hydrogen atomic orbitals (Q) (R) Azimuthal quantum number Magnetic quantum number like

(D)

Probability density of electron at the nucleus (S) in hydrogen-like atom

Electron spin quantum number

8. The energy level of an atom for 1st, 2nd and third level are E, and 2E respectively. A photon of wavelength is emitted for a transition 3 to 1. What will be the wavelength of emission for transition 2 to 1. 9. Let 1 be the frequency of series limit of the Lyman series, 2 be the frequency of the first line of the Lyman series and 3 be the frequency of the series limit of the Balmer series then find the relationship between 1, 2 and 3.
Answers 1. 2. 3. 4. 5. 6. 7. 8. (i) 6 (ii) 18 (iii) s=3, t= 2 (i) 1 (ii) 2 (iii) 3 (iv) 3 8R/9 (i) 1 (ii) 2

(i) 6.410 13 J, (ii) 2.110 13 J, (iii) 3.410 14 m

910 (A)-Q,R (B)- P,Q,R,S (C)-P,Q,R (D)P,Q 3

9. 3 = 12