Sri Chaitanya IITJEE Academy

IV GROUP

Single answer type questions : 1. 2. The dehydration of malenic acid CH2(COOH)2 with P4O10 and heat give 1) Carbon monoxide 2) Carbon sub oxide 3) Carbon dioxide 4) All three The oxides of carbon differ from those of other elements of the group because 1) Carbon is smaller atom 2) They contain pp pp multiple bonds 3) The bonds in them are very weak 4) The electronegativity of carbon is very low Sn(II) is a stronger reducing agent than Pb(II) because 1) Pb(II) is less stable than Sn(II) 2) Pb(II) is less stable than Pb(IV) 3) Sn(IV) forms more covalent compounds 4) Pb(II) forms covalent compounds Vessels plated with tin containg lead if used for cooking may contaminate the food with poisionous 1) Lead compounds 2) Tin compounds 3) Tin and lead compounds 4) Alloys PbCl2 is more ionic than PbO2 because 1) The radius of Pb2+ is more than that of Pb4+ 2) Of inert pair effect 3) Chlorine is more electronegative than oxygen 4) Chlorine atom is smaller than oxygen atom PbF4 is good fluorinating agent because 1) The Pb F bond is very weak 2) It is a fluoride of a heavy metal 3) It is unstable and dissociates on warm forming fluorine 4) Fluorine is highly electronegative A 0.1 M solution of certain cation will precipitate with 0.1 M solution of all these anions OH, CO32 and SO42. This discription is true for the cation 8. 9. 1) Fe2+ 2) Mg2+ 3) Ba2+ 4) Pb2+ The hydrolysis of dimethyl dichloro silane gives 1) Silicones 2) Silicates 3) SiO2 4) Silicic acid Lead and Tin are respectively extracted from their chief ore by 1) Carbon reduction and self reduction 2) Carbon reduction and electrolytic reduction 3) Self reduction and carbon reduction 4) Electrolytic reduction and carbon reduction Which of the following statements are correct 1) Lead salts are slow poisionous 2) Lead metal is used in accumulators 3) Plumbosolvancy increases in the presence of carbonates sulphates, phosphates etc. 4) Lead is a soft metal Identify the correct statements 1) Galena is the sulphide ore of lead 2) Red lead is a mixed oxide of lead 3) PbO2 is highly oxidizing 4) Pb3O4 is used in lead accumulators Which of the following statement(s) is/are correct 1) PbI4 is not known because of the oxidising power of Pb(+ IV) and the reducing power of I 2) SnCl2 does not hydrolyse 3) SnCl2 is reducing agent 4) Tin (II) chloride is linear in shape

3.

4. 5.

6.

7.

One or more than one answer type questions : 10.

11.

12.

13.

14.

15.

Which of the following statement(s) is/are correct 1) The only important ore of tin is cassiterite 2) SnO2 is reduced to the metal using carbon at 1200 13000C in an electric furnace 3) Galvanization of iron is done by tin 4) Pewter is an alloy of Sn with Sb and Cu Identify the correct statement(s) 1) Sn and Pb are amphoteric 2) Sn reacts with Cl2 on warming forms SnCl4 3) Pb dissolves in dilute H2SO4 liberating H2 gas 4) Sn reacts with water to give SnO2 and H2 Which of the following statement(s) is/are correct 1) Pb does not dissolve in conc. HCl 2) SnCl2 is used in the qualitative analysis of Hg22+ ion in group 1 3) Tin exists only in one metallic form 4) The formula of lead hydroxide is Pb(OH)4 Identify the correct statement(s) 1) Sn(+ IV) is covalent and stable 2) Pb(+ IV) is more common and stable than Pb(+ II) 3) Sn is attacked by hot alkali giving Na2[Sn(OH)6] 4) Tin exists in white and grey allotropic forms Which of the following statement(s) is/are correct 1) Lead is true metal with +2 electrovalency 2) Lead forms PbCl4 which is soluble in organic solvents 3) Lead reacts with conc. HCl producing PbCl2 4) Lead reacts with NaOH solution forming Pb(OH)4 Which of the following statement(s) regarding lead is/are correct 1) The solvent action of water on lead is known as plumbosolvency 2) The plumbosolvency is accelerated by the presence of NO3 and NH4+ salts in water 3) The plumbosolvency is accelerated by the presence of SO42 and PO43 in water 4) The plumbosolvency is retarded due to the formation of protective layer of basic carbonate Which of the following statements is/are correct 1) Trisilyl amine (SiH3)3 N is a weaker base than trimethyl amine (CH3)3N 2) Silicon has more tendency to form p bonds with oxygen than phosphorous 3) Structure of silicon is same as that of dimond 4) SiO2 is a high melting solid

16.

17.

18.

19.

CHEMISTRY TEST KEY

1. 2

2. 2

3. 3

4. 1 14. 1,2

5. 1 15. 1,2

6. 3

7. 4

8. 1

9. 3

10. 1,2

11.1,2,3 12.1,3 13. 1,2,4

16. 1,3,4 17. 1,2,4 18. 1,2,4

19. 1,3,4