The solid State Very Short Answer type Questions 1. 2. 3. 4. 5. Why are solids rigid?

Name two types in which solids are broadly classified. Give one example each for a crystalline and amorphous solid. How many atoms per unit cell are present in (i) hcp (ii) fcc (iii) bcc How many tetrahedral holes are present per unit cell in an (1)hcp structure and (2) fcc structure? 6. What type of coordination would you expect when (1)all the tetrahedral holes in an fcc structure of anions are occupied by cations, (2) half of the tetrahedral holes in an fcc structure of anions are occupied by cations and (3) all the octahedral holes of an fcc structure
MM : 25 TIME : 40 MIN. 1. Two liquids A and B boil at 145oC respectively and 190oc respectively . Which of them has a higher vapour pressure at 80oc ? 2. Why is freezing point depression of 0.1 M sodium chloride solution nearly twice that of 0.1M glucose solution ? 3. Define the term molarity of the solution . State one disadvantage in using the molarity as the unit of concentration. 4. Define the term osmotic pressure . What is advantage of using osmotic pressure as compared to other colligative properties for the determination of molar masses of solutes in the solutions ?. 5. Non ideal solutions exhibit either positive or negative deviation for Raoults law . What are these deviations and why are they caused ? 6. What mass of ethylene glycol (molar mass = 62g mol-1) must be added to 5.50 Kg of water to lower the freezing point of water to lower the freezing point of water from 00c to 10 .0 0c ? [Kf for water = 1.86 K Kg mol-1 ) 7. What concentration of nitrogen should be present in a glass of water at room temperature. Assume a temperature of 25oc a total pressure of 1 atmosphere and mole fraction of nitrogen in air of 0.78 (Kh for N2 = 8.42 x 10-7 M/mm Hg) . 8. The boiling point elevation of 0.30 g acetic acid in 100 g benzene is 0.0633 K . Calculate the molar mass of acetic acid from this data . What conclusion can you draw about the molecular state of the solute in the solution ? [Kb = 2.53 K Kg mol-1) 9. An antifreeze solution is prepared from 222.6 g of ethyleneglycol and 200 g of water . Calculate the molality of the solution . If density of this solution be 1.072gml-1 What will be the molarity of the solution? 10. Urea forms an ideal solution in water . Determine the vapour pressure of an aqueous solution containing 10% by mass of urea at 400c ( vapour pressure of water = 55.3 mm of Hg) 11. A 4% solution of sucrose is isotonic with 3% solution of an unknown organic substance . Calculate the molecular mass of unknown substance .

Surface Chemistry MM : 25 TIME : 40 MIN. 1. Name the catalyst used in the Ostwald process for the manufacture of nitric acid . 2. What happens when a colloidal sol of Fe(OH)3 is mixed with that of As2S3 ? 3. How does alum helps in the purification of water with suspended impurities ? 4. Define gold number . 5. Why sky appears blue in the colour ? 6. Write down the difference between sols and emulsions. 7. What does activity and selectivity of catalyst means ? Explain. 8. What is CMC and Kraft temperature with respect to Micelles formation? 9. What is the difference between adsorption isotherm and adsorption isobar ? 10.In which of the following does adsorption takes place (i) Silica gel placed in the atmosphere containing water . (ii) Anhydrous CaCl2 placed in the atmosphere containing water . 11.Differentiate between multimolecular, macromolecular and associated colloids ? 12.Write short note on (a) Electrophoresis (b) Peptization . 13.Differentiate between (a) Physical and chemical adsorption (b) Lyophillic and Lyophobic colloids . HALOALKANES AND HALOARENES MM : 25 TIME : 45 MIN. 1. Give IUPAC names of the following compounds: (a) CH2=CH-CH C=CH2 C2H5 Cl (b) CH3-CH2-CH-C6H5Br CH3 2. Write the structure of the following organic halogen compounds : (a) 4-tert-butyl-3-iodoheptane (b) 2-(2-chlorophenyl)-1-iodooctane 3. Explain the following reaction: (a) Friedel craft alkylation reaction. (b) Wurtz reaction (c) Sandmeyers reaction (d) Finkelstein reaction 4. Convert the following: (a) Ethane to bromoethene (b) But-1-ene to but-2-ene (c) Propene to propyne (d) Benzyl alcohol to 2-phenylethanoic acid (e) Aniline to chlorobenzene 5. Explain Markownikoffs rule with example. 6. Explain the following

(a) Vinyl chloride is hydrolysed more slowly than ethyl chloride (b) The treatment of alkyl chloride with aqueous KOH leads to the formation of alcohols but in the presence of alcoholic KOH , alkenes are the major products. 7. Distinguish between C2H5Br and C6H5Br through chemical test . 8. What are Enantiomers and Racemic mixtures ? 9. Predict the order of reactivity of the following compounds in SN1 reaction C6H5CH2Br , C6H5CH(C6H5)Br , C6H5CH(CH3)Br , C6H5C(CH3)(C6H5)Br 10. What is chemical name of D.D.T ? How it is prepared ?