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What do know about Molecular chromic acid Guidechem, chromic acid,7738-94-5 Chromic acid is an intermediate in chromium plating, and is also used in ceramic glazes, and colored glass. Because a solution of chromic acid in sulfuric acid (also known as a sulfochromic mixture or chromosulfuric acid) is a powerful oxidizing agent, it can be used to clean laboratory glassware, particularly of otherwise insoluble organic residues. This application has declined due to environmental concerns. Furthermore the acid leaves trace amounts of paramagnetic chromic ions Cr(III) that can interfere with certain applications, such as NMR spectroscopy. This is especially the case for NMR tubes. Chromic acid(CAS:7738-94-5)was widely used in the instrument repair industry, due to its ability to "brighten" raw brass. A chromic acid dip leaves behind a bright yellow patina on the brass. Due to growing health and environmental concerns, many have discontinued use of this chemical in their repair shops. In this article, we can talk something about the properties of Molecular chromic acid. Molecular chromic acid, H2CrO4, has much in common with sulfuric acid, H2SO4. Both are classified as strong acids, though only the first proton is lost easily. H2CrO4 in equilibrium with [HCrO4] + H+ The pKa for the equilibrium is not well characterized. Reported values vary between about 0.8 to 1.6. The value at zero ionic strength is difficult to determine because half dissociation only occurs in very acidic solution, at about pH zero, that is, with an acid concentration of about 1 mol dm 3. A further complication is that the ion [HCrO4] has a marked tendency to dimerize, with the loss of a water molecule, to form the dichromate ion, [Cr2O7]2: 2 [HCrO4] in equilibrium with [Cr2O7]2 + H2O, log KD = 2.05 Furthermore, the dichromate can be protonated: [HCr2O7] in equilibrium with [Cr2O7]2 + H+, pK = 1.8[2] The pK value for this reaction shows that it can be ignored at pH > 4. Loss of the second proton occurs in the pH range 48, making the ion [HCrO4] a weak acid. Molecular chromic acid could in principle be made by adding chromium trioxide to water (cf. manufacture of sulfuric acid).

CrO3 + H2O in equilibrium with H2CrO4 but in practice the reverse reaction occurs when molecular chromic acid is dehydrated. This is what happens when concentrated sulfuric acid is added to a dichromate solution. At first the colour changes from orange (dichromate) to red (chromic acid) and then deep red crystals of chromium trioxide precipitate from the mixture, without further colour change. The colours are due to LMCT charge transfer transitions. Chromium trioxide is the anhydride of molecular chromic acid. It is a Lewis acid and can react with a Lewis base, such as pyridine in a non-aqueous medium such as dichloromethane (Collins reagent). Dichromic acid, H2Cr2O7, (structure illustrated top right) is the fully protonated form of the dichromate ion and also can be seen as the product of adding chromium trioxide to molecular chromic acid. [Cr2O7]2 + 2H+ in equilibrium with H2Cr2O7 in equilibrium with H2CrO4 + CrO3 It is probably present in chromic acid cleaning mixtures along with the mixed chromic-sulfuric acid H2CrSO7 Want to learn more information about Chromic acid, you can access the guidechem.com. Guidechem.com is just a place for you to look for some chemicals. Guidechem provide the most convenient conditions for the international buyers and let these leads benefit all the business people.