CLASS-XI CHEMISTRY-ASSIGNMENT Chapter Thermodynamics CH !

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Q.1. Q.(. Q.3. If the enthalpy of combustion of diamond and graphite are 395.4KJ mole and !393." KJ mole. #hat is the enthalpy change for the c$graphite% &$diamond%' If )1 for a reaction has a negati*e *alue+ ho, ,ould you -no, the sign re.uirement of / for it so that the reaction is spontaneous at lo, temperatures' &alculate the heat of combustion of glucose from the follo,ing data0 &$graphite% ) 1($g% &1($g% 2 3 4 ! 395.1KJ 3($g% ) 5 1($g% 3(1$l%2 Q.4. 3 4 ! ("9.4 KJ "& $graphite% ) "3( $g% ) 1($g% &"31(1"$/%2 6lucose 4!11"9.7 KJ &alculate the standard free energy change 68 for the reaction. ( 3g1 $/% (3g $l% ) 1($g% 384 91 KJ mole at (97K+ /8$3g1%49(.:J K mol /8$3g% 4 99.4 J K mol and /8$1(% 4 (:5 JK!1 mol!1 at (97K. Q.5. Q.". ;or a re*ersible reaction ta-ing place at 1(98& and 1 atmospheric pressure+ 6 is (3.5 KJ mol for the for,ard reaction. &alculate the *alue of <.uilibrium constant for this reaction. &ompound ,ith carbon!carbon double bond+ such as ethylene &(34 and hydrogen in a reaction called hydrogenation. &(=y$g% ) 3( $g%&(3"$g% &alculate enthalpy change for the reaction+ using the follo,ing combustion data0! &(34$g% ) 31($g% (&1($g% )(3(13 4 ! 14:1KJ mol &(3"$g% ) 51($g% (&1($g% )33(1$l%3 4 ! 14:1KJ mol 3($g% ) 51($g% 3(1$l% 34!(7".1KJ mol. Q.9. Q.7. &alculate bond eneryg of &!3 bond if 3c of &34 is 791 KJ+ 3& of & $/% is 394 KJ+ 3c of 3( $g% is (7" KJ+ heat of sublimation of &$/% is 919KJ+ heat of dissociation of 3(is 43" KJ. 3o, is a change in free energy related to the spontaneity of a reaction' &alculate 68 of the follo,ing reaction 0 &1 $g% ) 5 1($g% &1($g% 84!(7(.74 KJ mole 6i*en /8&1( $g% 4 (13.7 JK!1 mol!1+ /8 $&1% $g%4 199.9JK!1 mol!1+ 58$1(%$g%4(:5.1JK!1mol!1 Q.9. >sing the data gi*en belo, calculate the *alue of e.uilibrium constant for the reaction at (97K. 3&3 &3$g% &"3" $g% assuming ideal gas beha*iour.

68f 3&&3$g% 4(.:9 1:5 J mole+ 68f$&"3"% Q.1:. &alculate bond energy of 3&l+ if bond energy of 3!3 bond is 43" KJ mole+&l!&l bond energy is (4( KJ mole and beat of formation of 3&l4 !9(.5 KJ mole. Q.11. ?t ":8&+ dinitrogen tetro@ide is 5:A. Bissociated &alculate the standard free energy at this temperature and at one atmosphere. ?ns. 684 ! 99:.1KK mole. Q.1(. ;or the reaction at (97 K (?$g% ) C $g% (B $g% >84 ! 1:.5 KJ and /8 4 ! 44!1 JK!1. &alculate 68 for the reaction and predict ,hether the reaction may occur spontaneous or not. Q.13. ?n e@othermic reaction D!E is spontaneous in the bac- direction. #hat is the sign of / for the for,ard direction' Q.14. Fhe standard enthalpies of formation of /1($g% and /13$g% are (9"." KJ and !395."KJ respecti*ely &alculate 3 for the reaction0 /1($g% ) 11( $g% /13$g% ( Q.15. =repare has the structure 33&&3(&33. &alculate the enthalpy change 38r for the reaction0 &337$g% ) 51( $g% 3&1( $g% ) 43(1$g% Fhe a*erage bond enthalpies of *arious bonds are & & $KJ mol% 349 & 3 414 141 497 &41 941 1 3 4"4

Q.1". It is planned to carry out the reaction 0 &a&13$/% &a1$/% ) &1($g% ?t 1(93K and 1 bar pressure 38419" KJ mole and /84159.( KJ mo2e $a% Is the reaction at this temp and pressure' $b% &alculate the *alue of Kp at 1(93 K for the reaction. Q.19. 38 and /8 for the reaction0 Cr($l% ) &l($g%

( Cr&l$g%

?t (97K are (9.3 KJ mole and 1:4.1 JK!1 mol!1 resp. &alculate the e.uilibrium constant for the follo,ing reaction at (97 K0 (3(1$l% (3($g% ) 1($g% f68$3(1% 4 ! (39.( KJ mole+ G4 7.314J mol K