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Safety data sheet

According to 1907/2006 EEC Article 31
Printing date: 03.03.2011 * Version: 5 Revision: 03.03.2011

1 Identification of the substance/mixture and of the company/undertaking

Product identifier Trade name: LOCTITE MULTISPRAY Relevant identified uses of the substance or mixture and uses advised against Sector of Use SU21 Consumer uses: Private households / general public / consumers Application of the substance / the preparation Lubricant Details of the supplier of the safety data sheet Manufacturer/Supplier: Mobacc/Pharmaspray/Eurofill 9640 AH Veendam The Netherlands Tel: +31(0)598 626666 Fax: +31(0)598 625976 E-mail: j.sleumer@mobacc.com Further information obtainable from: Research & Development / E-mail: j.sleumer@mobacc.com Emergency telephone number: During normal opening hours: Tel: +31(0)598 626666

2 Hazards identification
Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008 GHS02 flame Flam. Aerosol 1 H222 Extremely flammable aerosol. Classification according to Directive 67/548/EEC or Directive 1999/45/EC R66: Repeated exposure may cause skin dryness or cracking. Information concerning particular hazards for human and environment: The product has to be labelled due to the calculation procedure of the "General Classification guideline for preparations of the EU" in the latest valid version. At long or repeated contact with skin it may cause dermatitis due to the degreasing effect of the solvent. Warning! Pressurized container. Classification system: The classification is according to the latest editions of the EU-lists, and extended by company and literature data. Label elements Labelling according to EU guidelines: The product has been classified and marked in accordance with EU Directives / Ordinance on Hazardous Materials. Code letter and hazard designation of product: F Flammable

Risk phrases: 66 Repeated exposure may cause skin dryness or cracking. Safety phrases: 2 Keep out of the reach of children. 16 Keep away from sources of ignition - No smoking. 23 Do not breathe fumes/aerosol. 24 Avoid contact with skin. 46 If swallowed, seek medical advice immediately and show this container or label. 51 Use only in well-ventilated areas.
(Contd. on page 2)
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Safety data sheet

According to 1907/2006 EEC Article 31
Printing date: 03.03.2011 Trade name: LOCTITE MULTISPRAY
(Contd. of page 1)

Version: 5

Revision: 03.03.2011

Special labelling of certain preparations: Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50C. Do not pierce or burn, even after use. Do not spray on a naked flame or any incandescent material. Buildup of explosive mixtures possible without sufficient ventilation. Classification in accordance with Directive 75/324/EEC: Flammable Other hazards Results of PBT and vPvB assessment PBT: Not applicable. vPvB: Not applicable.

3 Composition/information on ingredients
Chemical characterization: Mixtures Description: Active substance with propellant Dangerous components: CAS: 64742-48-9 Naphtha (petroleum), hydrotreated heavy Benzene <0.1% EINECS: 265-150-3 Xn R65 R66 GHS08 Asp. Tox. 1, H304 CAS: 124-38-9 carbon dioxide EINECS: 204-696-9 GHS04 Press. Gas, H280 CAS: 64742-95-6 Solvent naphtha (petroleum), light arom. Benzene<0.1% EINECS: 265-199-0 Xn R65; Xi R37; N R51/53 R10-66-67 GHS08 Asp. Tox. 1, H304 Alkaryl polyether Xi R36/38; N R51/53 GHS09 Aquatic Chronic 2, H411; GHS07 Skin Irrit. 2, H315; Eye Irrit. 2, H319

50-100%

1.0-<2.5% 0.1-<1.0%

0.1-<1.0%

4 First aid measures

Description of first aid measures After inhalation: Supply fresh air; consult doctor in case of complaints. After skin contact: Generally the product does not irritate the skin. After eye contact: Rinse opened eye for several minutes under running water. After swallowing: Do not induce vomiting; call for medical help immediately. Information for doctor: Most important symptoms and effects, both acute and delayed No further relevant information available. Indication of any immediate medical attention and special treatment needed No further relevant information available.

5 Firefighting measures
Extinguishing media Suitable extinguishing agents: Water haze Fire-extinguishing powder Carbon dioxide Alcohol resistant foam Special hazards arising from the substance or mixture No further relevant information available.
(Contd. on page 3)
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Safety data sheet

According to 1907/2006 EEC Article 31
Printing date: 03.03.2011 Trade name: LOCTITE MULTISPRAY
(Contd. of page 2)

Version: 5

Revision: 03.03.2011

Advice for firefighters Protective equipment: Mount respiratory protective device. *

6 Accidental release measures

Personal precautions, protective equipment and emergency procedures Wear protective equipment. Keep unprotected persons away. Environmental precautions: Do not allow to enter sewers/ surface or ground water. Methods and material for containment and cleaning up: Ensure adequate ventilation. Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information.

7 Handling and storage

Handling: Precautions for safe handling Ensure good ventilation/exhaustion at the workplace. Information about fire - and explosion protection: Do not spray onto a naked flame or any incandescent material. Keep ignition sources away - Do not smoke. Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50C, i.e. electric lights. Do not pierce or burn, even after use. Conditions for safe storage, including any incompatibilities Storage: Requirements to be met by storerooms and receptacles: Observe official regulations on storing packagings with pressurized containers. Information about storage in one common storage facility: Observe official regulations on storing packagings with pressurized containers. Further information about storage conditions: Keep receptacle tightly sealed. Specific end use(s) No further relevant information available.

8 Exposure controls/personal protection

Additional information about design of technical facilities: No further data; see item 7. Control parameters Ingredients with limit values that require monitoring at the workplace: 124-38-9 carbon dioxide WEL Short-term value: 27400 mg/m, 15000 ppm Long-term value: 9150 mg/m, 5000 ppm Additional information: The lists valid during the making were used as basis. Exposure controls Personal protective equipment: General protective and hygienic measures: Wash hands before breaks and at the end of work. Do not inhale gases / fumes / aerosols. Respiratory protection: In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use self-contained respiratory protective device. Filter AX/P2
(Contd. on page 4)
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Safety data sheet

According to 1907/2006 EEC Article 31
Printing date: 03.03.2011 Trade name: LOCTITE MULTISPRAY
(Contd. of page 3)

Version: 5

Revision: 03.03.2011

Protection of hands: Protective gloves Solvent resistant gloves Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation Material of gloves Nitrile rubber, NBR Penetration time of glove material The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed. Eye protection: Not required. Body protection: Use protective suit. *

9 Physical and chemical properties

Information on basic physical and chemical properties General Information Appearance: Aerosol Form: According to product specification Colour: Characteristic Odour: Not determined. Odour threshold: pH-value: Change in condition Melting point/Melting range: Boiling point/Boiling range: Flash point: Flammability (solid, gaseous): Ignition temperature: Decomposition temperature: Self-igniting: Danger of explosion: Explosion limits: Lower: Upper: Vapour pressure at 20C: Density at 20C: Relative density Vapour density Evaporation rate Solubility in / Miscibility with water: Viscosity: Dynamic: Kinematic: Not determined. Undetermined. 187C 62C Not applicable. 236C Not determined. Product is not selfigniting. Product is not explosive. However, formation of explosive air/ vapour mixtures are possible. 0.7 Vol % 6.0 Vol % 4 Bar 0.836 g/cm Not determined. Not determined. Not applicable. Not miscible or difficult to mix.

Segregation coefficient (n-octanol/water): Not determined. Not determined. Not determined.

(Contd. on page 5)
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Safety data sheet

According to 1907/2006 EEC Article 31
Printing date: 03.03.2011 Trade name: LOCTITE MULTISPRAY
(Contd. of page 4)

Version: 5

Revision: 03.03.2011

Solvent content: Organic solvents: Solids content: Other information

65.9 % 2.3 % No further relevant information available.

10 Stability and reactivity

Reactivity Chemical stability Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. Possibility of hazardous reactions No dangerous reactions known. Conditions to avoid No further relevant information available. Incompatible materials: No further relevant information available. Hazardous decomposition products: No dangerous decomposition products known. *

11 Toxicological information
Information on toxicological effects Acute toxicity: LD/LC50 values relevant for classification: 64742-48-9 Naphtha (petroleum), hydrotreated heavy Benzene <0.1% Oral LD50 >5000 mg/kg (rat) Dermal LD50 >3000 mg/kg (rabbit) Primary irritant effect: on the skin: No irritant effect. on the eye: No irritating effect. Sensitization: No sensitizing effects known.

12 Ecological information
Toxicity Acquatic toxicity: No further relevant information available. Persistence and degradability Easily biodegradable Behaviour in environmental systems: Bioaccumulative potential No further relevant information available. Mobility in soil No further relevant information available. Additional ecological information: General notes: Water danger class 3 (German Regulation) (Self-assessment): extremely hazardous for water Do not allow product to reach ground water, water course or sewage system, even in small quantities. Danger to drinking water if even extremely small quantities leak into the ground. Results of PBT and vPvB assessment PBT: Not applicable. vPvB: Not applicable. Other adverse effects No further relevant information available.

13 Disposal considerations
Waste treatment methods Recommendation Must not be disposed together with household garbage. Do not allow product to reach sewage system.
(Contd. on page 6)
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Safety data sheet

According to 1907/2006 EEC Article 31
Printing date: 03.03.2011 Trade name: LOCTITE MULTISPRAY
(Contd. of page 5)

Version: 5

Revision: 03.03.2011

Uncleaned packaging: Recommendation: Disposal must be made according to official regulations. *

14 Transport information
Land transport ADR/RID (cross-border)

2 5F Gases. ADR/RID class: Danger code (Kemler): 1950 UN-Number: Packaging group: 2.1 Hazard label UN proper shipping name: 1950 AEROSOLS LQ2 Limited quantities (LQ) 2 Transport category D Tunnel restriction code Maritime transport IMDG:

IMDG Class: UN Number: Label Packaging group: EMS Number: Marine pollutant: Proper shipping name:

2.1 1950 2.1 F-D,S-U No AEROSOLS

Air transport ICAO-TI and IATA-DGR:

ICAO/IATA Class: UN/ID Number: Label Packaging group: Proper shipping name:

2.1 1950 2.1 AEROSOLS, flammable

UN "Model Regulation": UN1950, AEROSOLS, 2.1 Special precautions for user Warning: Gases. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Not applicable. *

15 Regulatory information
Safety, health and environmental regulations/legislation specific for the substance or mixture Labelling according to EU guidelines: The product has been classified and marked in accordance with EU Directives / Ordinance on Hazardous Materials.
(Contd. on page 7)
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Safety data sheet

According to 1907/2006 EEC Article 31
Printing date: 03.03.2011 Trade name: LOCTITE MULTISPRAY
(Contd. of page 6)

Version: 5

Revision: 03.03.2011

Code letter and hazard designation of product: F Flammable

Risk phrases: 66 Repeated exposure may cause skin dryness or cracking. Safety phrases: 2 Keep out of the reach of children. 16 Keep away from sources of ignition - No smoking. 23 Do not breathe fumes/aerosol. 24 Avoid contact with skin. 46 If swallowed, seek medical advice immediately and show this container or label. 51 Use only in well-ventilated areas. Special labelling of certain preparations: Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50C. Do not pierce or burn, even after use. Do not spray on a naked flame or any incandescent material. Buildup of explosive mixtures possible without sufficient ventilation. Classification in accordance with Directive 75/324/EEC: Flammable National regulations: Technical instructions (air): Class Share in % NK 50-100 VOC-CH 65.91 % VOC-EU 551.0 g/l Danish MAL Code 5-3 Chemical safety assessment: A Chemical Safety Assessment has not been carried out.

16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. Relevant phrases H280 Contains gas under pressure; may explode if heated. H304 May be fatal if swallowed and enters airways. H315 Causes skin irritation. H319 Causes serious eye irritation. H411 Toxic to aquatic life with long lasting effects. R10 Flammable. R36/38 Irritating to eyes and skin. R37 Irritating to respiratory system. R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R65 Harmful: may cause lung damage if swallowed. R66 Repeated exposure may cause skin dryness or cracking. R67 Vapours may cause drowsiness and dizziness. Department issuing MSDS: Research & Development Contact: Ing. J. Sleumer Abbreviations and acronyms:
ADR: Accord europen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) RID: Rglement international concernant le transport des marchandises dangereuses par chemin de fer (Regulations Concerning the International Transport of Dangerous Goods by Rail) IMDG: International Maritime Code for Dangerous Goods (Contd. on page 8)
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Safety data sheet

According to 1907/2006 EEC Article 31
Printing date: 03.03.2011 Trade name: LOCTITE MULTISPRAY
(Contd. of page 7) IATA: International Air Transport Association IATA-DGR: Dangerous Goods Regulations by the "International Air Transport Association" (IATA) ICAO: International Civil Aviation Organization ICAO-TI: Technical Instructions by the "International Civil Aviation Organization" (ICAO) GHS: Globally Harmonized System of Classification and Labelling of Chemicals MAL-Code: Mleteknisk Arbejdshygiejnisk Luftbehov (Regulation for the labeling concerning inhalation hazards, Denmark) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent

Version: 5

Revision: 03.03.2011

* Data compared to the previous version altered. *

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