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AIEEE 2009 CHEMISTRY

1.If 18 g of glucose is present in 1000g of a solvent it is said to be a) 1 molal b) 0.1 molal 1.1 molal c) 0.5 molal d)

2.The osmotic pressure of a solution is given by the relation a) =RTC b) =CTR c) =CRT d) C=RT

3. hich of the follo!ing has highest free"ing point# a) 0.1 $ %a&l 0.1 $ )e&l3 b) 0.1 $ 'ugar c) 0.1 $ (a&l2 d)

*. hich one of the follo!ing has highest boiling point a) 0.1 $ glucose b) 0.1 $ urea 0.1 $ (a&l2 c) 0.1 $ %a&l d)

5.%umber of moles of +2&r2,-reducedbyonemole'n2.ionsis a) 13 b) 3 c) 1/ d) /

/.The o0idation number of iron in )e3,*is a) .2 b) .3 c) 83 d) 23

-.In 12,2the o0idation state of o0ygen is a) 22 b) 21 c) 0 d) .*

8. hich of the follo!ing is not a redo0 reaction# a) &a&,33&a,.&,2 %a.12,3%a,1.1212 d) b) ,2.2123212, $n&l33$n&l2.12&l2 c)

4.The o0idation number of &12, is a) 52 b) .2 c) 0 d) .*

10.6 has an o0idation state of .3 in a) orthophosphoric acid metaphosphoric acid d) b) phosphorous acid pyrophosphoric acid c)

11.,0ygen has an o0idation state of .2 in a) 12,2 b) 12, c) ,)2 d) ',2

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12. hich of the follo!ing is the strongest o0idising agent a) )2 b) &l2 c) (r2 d) I2

13.,0idation number of ' in '2,325is a) 22 b) .2 c) ./ d) 0

1*.7 reducing agent is a substance !hich can a) protons d) accept electrons b) donate protons donate electrons c) accept

15.8n2.9a:).2e538n9s);this is a) o0idation none of these b) reduction c) redo0 reaction d)

1/.&orrosion is basically a a) c) metal 1-.7 smuggler could not carry gold by chemically depositing iron on the gold surface since a) gold is denser b) reduction potential than iron d) 18. hich of the follo!ing is a <e!is acid# a) &l5 b) %13 c) ()3 d) &215,1 iron rusts c) gold has higher gold has lo!er reduction potential than iron altered reaction in presence of 12, interaction d) b) electrochemical phenomenon union bet!een t!o light metals and a heavy

14.7t cathode; the electrolysis of a:ueous %a2',*gives a) %a b) 12 c) ',3 d) ',2

20.&onductivity 9unit = ') is directly proportional to the area of the vessel and the concentration of the solution in it and is inversely proportional to the length of the vessel; then the unit of constant of proportionality is a) ' mmol51 '2m2mol52 b) 'm2mol51 c) '52m2mol d)

21. hich of the follo!ing reaction is possible at the 7node# a) 2&r3..-12,3&r2,-25.1*1. b) )232)5 12,2.21.312, d) %one of these c)

22.For the reactions, C+O2CO2; a)

!="#$#%&, 2'n+O22'nO; !="()2%& d) ,0idation of carbon is not possible 8n can o0idise &arbon c)

&arbon can o0idise "inc b) ,0idation of 8n is not feasible

2#.Ca*cu*ate the amount of char+e f*owin+ in two minutes in a wire of resistance ),- when a .otentia* difference of 2, / is a..*ied a) 120 & b) 2*0 & c) 20 & d) *&

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2*.The specific conductance of 0.1$ %a&l solution is 1.0/>1052ohm51cm51.Its molar conductance is a) 1.0/>102 53 b) 1.0/>103 c) 1.0/>10* d)

25.In the cell reaction; &u9s).27g.9a:)3&u2.9a:).27g9s)?@0cellA0.*/B.(y doubling the concentration of &u2.;@&ellis a) doubledb) decreases by small fraction halved c) unchanged d)

2/.6revention of corrosion of iron by 8n coating is called a) d) Calvani"ation b) 6hotoelectrolysis &athodic protection c) @lectrolysis

2-.The e:uivalent conductance of %a&l; 1&l and &215&,,%a at infinite dilution are 12/.*5; *2/.1/ and 41 ohm51cm2respectively. The e:uivalent conductance of &215&,,1is a) 201.28 b) 340.-1 c) /48.28 d) 5*0.*8

28.. &horine cannot displace a) %a(r d) )luorine from %a) b) %one of these Iodine from %aI c) (romine from

24.In electrorefining of copper a minor percentage of gold accumulates in a) 7node mud &athode b) &athode mud c) @lectrolyte d)

30.The resistance of 1% solution of acetic acid is 250 ohm; !hen measured in a cell of cell constant 1.15cm51.The e:uivalent conductance of 1% acetic acid is a) *./ b) 4.2 c) 18.* d) 0.023

31.The standard @0Dedvalues of 7; (; & are 0./8 B; 22.5* B; 20.50 B respectively. The order of their reducing po!er is a) 7E(E& (E&E7 b) 7E&E( c) &E(E7 d)

32. hen electricity is passed through a solution of 7l&l3and13.5gof 7l are deposited; the number of faraday must be a) 0.5 b) 1.0 c) 1.5 d) 2.0

33.The reference &alomel electrode is made from !hich of the follo!ing a) 8n&l2 b) &u',* c) 1g2&l2 d) 1g&l2

3*. hich of the substances %a;1g;';6t and Craphite can be used as electrodes in electrolytic cells having a:ueous solutions# a) only d) %a; 6t and Craphite b) %a and ' only %a and 1g c) 6t and Craphite

35.@lectrolysis involves o0idation and reduction respectively at

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a) 7node and &athode b) the electrodes d) %one of the above &athode and 7node c) 7t both

3/.The one that is a good conductor of electricity in the follo!ing list of solids is a) d) 'odium &hloride 'ulphur b) Craphite c) Fiamond

3-.The solubility of 7g&l in 0.2 $ %a&lis 9+sp7g&lA1.8>10510) a) 1.8>10511$ 5./>10511$ b) 4>10510$ c) /.5>10512$ d)

38.7t 250&the p1 of a solution containing 0.1$ 'odium acetate and 0.03 $ acetic acid is 9p+a) of acetic acid A *.5-) a) 3.2* b) *.54 c) 5.04 d) /./-

34.Identify the indicator used to titrate %a2&,3!ith 1&l a) 6henolphthaleinb) %one Filute 12',* c) $ethyl ,range d)

*0. hich of the follo!ing on reaction !ith 12'does not produce metallic sulphide# a) &d&l2 b) 8n&l2 c) &,&l2 d) &u&l2

*1.The conGugate base of 16,*25 is a) 6,*35 b) 126,*5 c) 136,* d) 136,3

*2.7t 800;pure distilled !ater has H13,.I A1>105/mol<51;the value if +! at this temperature !ill be a) 1>105/ *3.7n a:ueous solution of &u',*is a) acidic b) basic c) neutral d) amphoteric hat is p1 of unpredictable 1>1058 b) 1>10512 c) 1>1051* d)

**.In decimolar solution; &13&,,1 acid is ionised to the e0tent of 1.3J if log 1.3 A 0.11; the solution# a) 3.84 b) 2.84 c) *.84 d)

*5.The p1 of a 1058$solution of 1&l in !ater is a) 8 b) (et!een / and 28 c) (et!een - an 8 d)

*/. hich of the follo!ing salts !hen dissolved in !ater hydrolyse# a) %a&l b) %1*&l c) +&l d) %a2',*

*-.6recipitation taKes place !hen the ionic product a) e:uals the solubility product b) is less than the solubility productd) e0ceeds the solubility product is almost "ero c)

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*8.The p1 of an a:ueous solution is /. The H,15Iof the solution !ill be a) 1058$ b) 105/$ c) 105-$ d) 108$

*4.The rate of for!ard reaction is t!o times that of the reverse reaction at a given temperature and identical concentration; + e:uilibrium is a) 0.5 b) 1.5 c) 2.5 d) 2.0

50.)or the reaction; &,9g).12,29g)0&,29g);+p+cis a) DT b) 9DT)51 c) 9DT)51L2 d) 9DT)1L2

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