Académique Documents
Professionnel Documents
Culture Documents
Chapter 10 (Sperling)
Thirion Relaxation
Remember, all physical reasons for stress relaxation and creep are related to molecular motion (strain) induced by stress, therefore, must be related to conformational changes.
Springs store energy and respond instantaneously. Dashpots dissipate energy in the form of heat, characterizes retarded nature of response. Spring Dashpot
Creep Experiments
Maxwell Model
Developed to explain the behavior of pitch and tar. Maxwell assumed that such materials can undergo viscous flow and also respond elastically. Combine Hookes and Newtons laws and assume that the strains are additive (both elements feel the same stress).
Serial Combination
= elast + visc Assume the stress is constant. (t) = /G + t/ This is a creep experiment. Note, that the first term is the instantaneous elastic response, while the second term is the viscous retarded response.
Creep Experiments
Kelvin-Voigt Model
Material can undergo viscous flow but can also respond elastically. Combine Hookes and Newtons laws, assuming that the same strain is felt by both elements and that the stresses are additive. = elast + visc = + d/dt Assume overall stress is constant (t) = 0 J [1 - exp(-t /J)] This is a Creep Experiment. The strain reaches a limiting value at very long times. Retarded Elastic behavior. 2 = 1 / J is the Retardation Time
Parallel Combination
This is a Stress Relaxation Experiment. The quantity 1 = /G has units of time and is called the Relaxation Time.
Note that the recovery is not complete. One says that there is a permanent set, or a partial recovery.
Time-Temperature Superposition
The Stress relaxation modulus depends on temperature and time.
First: Choose an arbitrary reference temperature T0. Second: Shift, along the time axis, the stress relaxation modulus curve recorded at T just above or below T0, so that these two curves superpose partially. Third: Repeat the procedure until all curves have been shifted to be partially superposed with the previous ones. Four: Keep track of aT, the amount a curve recorded at T is shifted. No shift for curve recorded at T0.
Time-Temperature Superposition
The shift factor, aT, is defined mathematically by: log10 [aT] = log10 [t] log10 [t0] = log10 [t/t0]
The temperature dependence of the shift factor, aT, is given by the WLF equation. This relates to the fact that there is a specific relationship between the times (t and t0) and the temperatures (T and T0), for which E(T, t) = E(T0, t0). If the reference temperature, T0, is chosen to be Tg, then we can write: log10 [aT] = -[C1 (T-Tg)]/[C2+T-Tg]
Time-Temperature Superposition
Similar master curves can be obtained with dielectric data. When superposition does not work, it implies that more than one relaxation mechanism is at work in the temperature range investigated. The system is said to be rheologically complex (as opposed to simple).
Time-Temperature Superposition
Applications: Prediction of viscosity at different temperatures Prediction of mechanical properties: E(T,t), G(T,t), D(T,t), J(T,t) Accelerated Aging Issues: The WLF parameters , C1g, C2g depend slightly on the measurement technique. WHY ? WLF equation works better for intrapolation than for extrapolation.