Chemical Bonding and Molecular Structure: MCQs | Question Paper 2 Topic: Chemical Bonding and Molecular Structure, Test

t No.: 02, Total MCQs: 15

Please wait while the activity loads. If this activity does not load, try refreshing your browser. Also, this page requires javascript. Please visit using a browser with javascript enabled. If loading fails, click here to try again Question 1 The state of hybridization of the central atom and the number of lone pairs over the central atom in POCl3 are [WB JEE 2012] A sp, 0 B sp2, 0 C sp3, 0 D dsp2, 1 Question 2 NiCl2{P(C2H5)2(C6H5)}2 exhibits temperature dependent magnetic behaviour (paramagnetic/diamagnetic). The coordination geometries of Ni2+ in the paramagnetic and diamagnetic states are respectively [IIT JEE 2012] A tetrahedral and tetrahedral B square planar and square planar C tetrahedral and square planar D square planar and tetrahedral Question 3 When O2 is converted into O2+ [Karnataka CET 2011] A both paramagnetic character and bond order increase B bond order decreases C paramagnetic character increases D paramagnetic character decreases and the bond order increases Question 4 Which one of the following conversions involve change in both hybridization and shape? [Karnataka CET 2010] A NH3 NH4+ B CH4 C2H6 C H2O H3O+ D BF3 BF4 Question 5

Assuming that Hund's rule is violated, the bond order and magnetic nature of the diatomic molecule B2 is [IIT JEE 2010] A 1 and diamagnetic B 0 and diamagnetic C 1 and paramagnetic D 0 and paramagnetic Question 6 Based on VSEPR theory, the number of 90 degree F Br F angles in BrF5 is [IIT JEE 2010] A0 B2 C4 D8 Question 7 The species having pyramidal shape is [IIT JEE 2010] A SO3 B BrF3 C SiO32 D OSF2 Question 8 The value of n in the molecular formula BenAl2Si6O18 is [IIT JEE 2010] A3 B5 C7 D9 Question 9 Using MO theory predict which of the following species has the shortest bond length? [AIEEE 2009] A O2+ B O2 C O22 D O22+ Question 10 The number of nodal planes present in * s antibonding orbitals is [Karnataka CET 2008] A1 B2 C0 D3 Question 11

Which metal has a greater tendency to form metal oxide? [Karnataka CET 2008] A Cr B Fe C Al D Ca Question 12 Which one of the following constitutes a group of the isoelectronic species? [AIEEE 2008] A B C D Question 13 Which one of the following pairs of species have the same bond order? [AIEEE 2008] A CN and NO+ B CN and CN+ C O2 and CN D NO+ and CN+ Question 14 For a stable molecule the value of bond order must be [Karnataka CET 2007] A negative B positive C zero D there is no relationship between stability and bond order Question 15 In acetylene molecule, between the carbon atoms there are [Karnataka CET 2007] A three sigma bonds B two sigma and one pi bonds C one sigma and two pi bonds D three pi bonds Once you are finished, click the button below. Any items you have not completed will be marked incorrect.
1. The ion that isoelectronic with CO is a. CNb. O2+ c. O2-

d. N2+ (JEE 1982) ans: (a) isoelectronic means same number of electrons 2. carbon tetrachloride has no net dipole moment because of a. its planar structure b. its regular tetrahedral structure c. similar sizes of carbon and chlorine atoms d. similar electron affinities of carbon and chlorine (JEE 1983) ans (b) 3. which one among the following does not have the hydrogen bond? a. phenol b. liquid NH3 c. water d. liquid HCl (JEE 1983) Ans: (d) 4. the types of bonds present in CuSO4.5H2O are only a. electrovalent and covalent b. electrovalent and coordinate covalent c. electrovalent, covalent and coordinate covalent d. covalent and coordinate covalent 5. On hybridization of one s and one p orbitals we get: a.two mutually perpendicular orbitals b. two orbital at 180 c. four orbitals directed tetrahedrally d. three orbital in a plane (JEE 1984)

Answer: (b) 6. the molecule having one unpaired electron is: a. NO b. CO c. CNd. O2 (JEE 1985) Ans: (a) 7. The bond between two identical non-metal atoms has a pair of electrons: a. unequally shared between the two. b.transferred fully from one atom to another c. with identical spins d. equally shared between them (JEE 1986) Ans: (d) 8. the hydrogen bond is strongest in: a. O-HS b. S-HO c. F-HS d. F-H...O (JEE 1986) Answer: ( c ) 9. The hybridization of sulphur dioxide is: a. sp b. sp c. dsp d. sp (JEE 1986) answer (b) 10. The bonds present in N2O5 are ______

a. only ionic b. covalent and coordinate c. only covalent d. covalent and ionic (JEE 1986) ans: (b) Chemistry: MCQ question on Periodic table Labels: MCQ on Periodic Table 1. The modern periodic table is arranged based upon atomic (A) isotopes (B) number (C) density (D) radius (E) mass 2. In period 3 of the periodic table the atom with the largest atomic radius is located in group (A) 1 (B) 3 (C) 13 (D) 17 (E) 18 3. The elements that display the greatest nonmetallic character are located toward which corner of the periodic table? (A) Upper left (B) Dead center (C) Lower right (D) Lower left (E) Upper right 4. Which two elements will display the most similar chemical properties? (A) Aluminum and calcium (B) Nickel and phosphorus (C) Chlorine and sulfur (D) Carbon and sulfur (E) Lithium and potassium 5. Assuming the ground state, all of the elements located in group 13 of the periodic table will have the same number of

(A) nuclear particles (B) occupied principal energy levels (C) electrons (D) valence electrons (E) neutrons

6. Which group contains elements in the solid, liquid, and gas phases at 298 K and 1 atm? (A) 1 (B) 2 (C) 16 (D) 17 (E) 18 7. An element that has a high first ionization energy and is chemically inactive would most likely be (A) a noble gas (B) a transition element (C) an alkali metal (D) a halogen (E) an alkaline earth metal 8. Which salt solution is most likely to be colored? (A) KClO3 (aq) (B) KNO3 (aq) (C) K2CrO4 (aq) (D) K2SO4 (aq) (E) KCl (aq) 9. As the elements of period 2 are considered from left to right, there is generally a decrease in (A) ionization energy (B) electronegativity (C) metallic character (D) nonmetallic character (E) none of the above 10. Which element is a liquid at room temperature? (A) K (B) Hg (C) I2 (D) Mg (E) Kr

11. At STP, which element is most expected to exist as a monatomic gas? (A) Calcium (B) Hydrogen (C) Nitrogen (D) Neon (E) Bromine 12. Nonmetals are poor conductors of heat and they also tend to (A) be brittle (B) conduct an electrical current (C) have a shiny luster (D) be malleable (E) lose electrons 13. Which statement does not explain why elements in a group are placed together? (A) They tend to have the same number of valence electrons. (B) They tend to have a similar oxidation number. (C) They tend to have the same electronegativities. (D) They tend to have the same chemical reactivity. (E) They tend to have the same charge when they form ions. ANSWERS: 1. (B) 2. (A) 3. (E)4. (E) 5. (D) 6. (D)7. (A) 8. (C) 9. (C)10. (B) 11. (D) 12. (A) 13. (C)