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Practical Implementation of Renewable Hydrogen & Fuel Cell

Installations in the Built Environment

Paper prepared for Detail Design in Architecture 8 “Translating sustainable


design into sustainable construction”, 4th September 2009, Cardiff, UK. University
of Wales Institute Cardiff, Cardiff School of Art & Design.

Gavin D. J. Harpera*

Ross Gazeyb

a) The E.S.R.C. Centre for Business Relationships Accountability


Sustainability and Society (B.R.A.S.S.), Cardiff University,

b) Pure Energy® Centre

*- Corresponding Author

Abstract

There is significant interest in fuel cells for use in the built environment, as a
technology that has the potential to produce localised heat and power, with
increased efficiency and reduced carbon emissions which give it an advantage
over alternative technologies. Whilst fuel cell technology is easy to understand
on paper, there is a paucity of information on practical implementation of fuel
cell technology in the built environment for architects. This paper discusses some
of the practical aspects of implementing renewable hydrogen installations in the
United Kingdom, that is to say installations that produce their own hydrogen on-
site from renewable energy sources.

Introduction

There is a well articulated need to reduce the impact of energy consumption in


the built environment, on a local level initiatives such as the London Borough of
Merton’s Planning Guidance, which has since become known as “The Merton
Rule” (Harper, 2006), provide clear incentives for building developers to reduce
the energy use and carbon emissions of their building. On a national level, UK
Government consultation such as the Draft Climate Change Bill, and Building a
Greener Future: Towards Zero Carbon Development suggest a future trajectory
for the UK Built Environment where renewable energy systems and zero-carbon
technologies will play a vital role in the energy provision of our buildings.

Whilst the biggest challenge is making “better use of the technologies and
techniques for energy-efficient building design that are already available” (Pitts,
2008) there is clearly room for innovation, particularly in the field of energy
generation and transformation. Increasing penetration of renewables into the
grid will doubtless require extra storage capacity in order to help manage
fluctuation of supply and balance supply and demand.
According to Pitts (2008) the current UK building stock is characterised by a
reliance on grid-based electricity supply used by 99% of consumers and mains
gas in areas where it is available. Many energy commentators believe that there
will be a move towards more decentralised and embedded electricity generation
in the UK network, this will eventually necessitate a change in pricing structure
of electricity – ‘dynamic pricing’ of electricity is one option which looks likely
under a future “smart grid” scenario. This could make it economically
advantageous for ‘flexible’ users of electricity who are able to tailor their
demand to the prevailing supply conditions.

There is also the issue of land which is not cost-effectively accessible to


traditional utilities. If solutions are found to providing heat and electrical power in
remote locations at a cost effective price, then the value of this land increases.
This makes renewable hydrogen-based solutions particularly attractive to
‘islanded communities’ (Sovacool & Hirsh 2008; Gazey et.al 2006).

The Built-Environment has been identified as a fertile early-market for fuel cell
technologies as the fuel cell technology types that are well-suited to stationary
applications are reaching a level of maturity where for some applications they
are economically viable. This is a trend that is likely to increase. In some
projections, Hydrogen will be a major final end-use carrier in the Built
Environment by the end of the century, with some (Van Ruijven, 2007),
predicting it will provide 45% of residential energy by 2100.

Financing Hydrogen Projects

In the current economic climate, house building and construction has


experienced a massive downturn, meanwhile as a result of the international
focus on developing clean technologies that has been enthusiastically embraced
by politicians there is funding available for development of innovative, state-of-
the-art projects incorporating low-carbon building technologies that push the
envelope of design knowledge.

From experience gained working on a number of renewable hydrogen projects it


has been found that it is the financing of the building that is the biggest barrier,
not the technology. For example, in the Hydrogen Homes that the Pure Energy®
Centre has been developing in association with the Hjaltland Housing
Association, The credit crunch has changed the settlement agreement. Nationally
there has been a change in allocations for housing association financing. By
contrast the technology can be funded through different routes, although funding
for hydrogen and fuel cell projects is relatively small compared to other more
“traditional” fields of energy. Competition for the funding available for hydrogen
technology is very high.

Renewable Hydrogen Installations

There are fuel cell installations which take natural gas and reform it on-site to
produce hydrogen which in turn is used by a fuel cell to generate heat and
power. Whilst many of the points in this paper will also apply to this type of
installation, it is not expressly the subject of this paper.

A renewable hydrogen installation commonly contains the following components:

• Renewable Energy Device; this can be any renewable energy conversion


device, Solar, Wind, Micro Hydro e.t.c. which produces electricity from the
natural resource. Energy from this device may form part of a metering
agreement with the National Grid where extra electricity is sold to the grid
when there is excess.

• Electrolyser; the electrolyser takes electricity and water, and uses the
former to disassociate the latter into Hydrogen and Oxygen. It produces
hydrogen “on site”.

• Compressor; this is an optional stage. It is used to compress hydrogen to a


level whereby it can be used to refuel hydrogen vehicles (which tend to
require hydrogen gas in the region 350-700 bar pressure). By pressurising
the hydrogen gas, more gas can be stored in a smaller volume reducing
the space requirements for hydrogen storage. In the Pure Energy® Centre
HyPod® system a compressor is eliminated by using a specially developed
high-pressure electrolyser. It should be noted that the inclusion of a
compressor stage, whilst affording amenity in the hydrogen installation,
will also consume energy reducing the overall energy balance of the
system.

• Storage; storage is used onsite to store hydrogen which has been


produced for later use. This stored hydrogen can be used for heat and
power in the building, using a Combined Heat and Power fuel cell, or for
refuelling external devices such as hydrogen vehicles.

• Fuel Cell; the fuel cell itself takes Hydrogen from the storage and converts
this into electrical and thermal energy.

Figure 1:
Block Diagram of the Hydrogen System at the Energy & Environment Technology
Centre, Yorkshire

At the moment, the fuel cell in this installation has been optimised for electrical
generation and the waste heat has not been used at the present time, this exists
as an upgrade path in the future.
Electrolyser Technology

Electrolysers take an input of electricity and water to produce renewable


hydrogen, and oxygen which can be vented to atmosphere or used for other
processes. Electrolyser technology has the potential to take surplus renewable
electricity from stand-alone installations and turn it into hydrogen which can be
stored for later use. For grid-connected installations, in a future scenario where
energy is priced dynamically based on a “real-time” commodity price, buildings
that integrate electrolyser technology would have the potential to generate their
own hydrogen overnight or in periods where electricity was plentiful and the
spot-price was cheap – this stored energy could then be used by the building
during periods when the cost of grid electricity increased beyond a set-point.

Fuel Cell Technology

Experience from a range of installations has tended to lean toward Solid Oxide
Fuel Cell technology being selected as the technology of choice for stand-alone
installations. Proton Exchange Membrane fuel cells have been used with varying
degrees of success, however, the membrane assemblies are particularly fragile
and have been prone to cracking.

Experience with Solid Oxide Technology has also encountered issues of durability
and robustness with the ceramics used in the cell stack. Whilst SOFC technology
works well if run up to a steady state it performs less favourably with cyclical
operation as ceramic materials deteriorate when heated and cooled in cycle. This
is due to the cell technology and issues with thermal cycling deteriorating the
cell stack. The lifetime of a continuously run SOFC should in theory run (in
excess of 10,000 hours). This is to say for a year and a half. The life of the cell
will be far exceeded by the balance of plant and support equipment, therefore it
is necessarily to periodically rebuild the system and stack. For this reason,
building design should anticipate easy access for service and repair to the fuel
cell stack. Solid Oxide Fuel Cells are a high temperature fuel cell technology and
rely on a high temperature for their electrochemical conversion process.
However, from cold-starting the temperature is not there to start the chemical
reaction, as a result, the cell must be slowly heated at a rate that is compatible
with the ceramic materials co-efficient of expansion. Heating beyond this rate
will cause degradation of the ceramic material – and ultimately if it is too fast,
the stack will fail.

Systems Integration

Whilst the individual components of Hydrogen and Fuel Cell installations are
reaching the point where they are shown to have acceptable reliability and
service life, this is usually measured under optimum conditions. The challenge
remains to integrate the components of renewable fuel cell installations to
ensure that all components within the installation work at their optimum in order
to ensure long service life and the longevity of the installation.
As an example, Gammon (2006) discusses the limitations of an electrolyser unit,
whose performance would degrade appreciably after 2500 on/off cycles, this was
mitigated by including a battery back-up to reduce the degree to which on/off
switching was necessary. As more modern electrolysis techniques are developed,
electrolyser technology will become more resilient and the balance of plant can
be reduced. Through developing specialist electrode coatings and optimising the
electrode technology – a combination of advanced control and materials science
techniques, this phenomenon can be reduced to a negligible level. By way of
contrast, the electrolyser at the Pure Energy® Centre site in Baltasound, has
recorded in excess of 19000 on/off cycles without noticeable degradation of
stack performance.

To some extent, this can be solved with “packaged” hydrogen systems. Off-site
prefabrication is now extensively used within the construction industry in order
to concentrate skilled labour and maintain high levels of quality. The Pure
Energy® Centre produces a “HyPod®”, in the first generation HyPod® the fuel
cell is external to the container (pictured in Figures 2 & 3) however, depending
on the type and certification constraints there is potential for integrating a fuel
cell installation within a trans-modal shipping container, to allow simple shipping
of the solution to site.

Experience within other domains in the construction industry has shown that off-
site fabrication reduces the need for a skilled workforce on site – allows for
increased quality control as components are assembled in a central factory
location by a skilled workforce. Modular renewable hydrogen systems fabricated
off-site and moved to the site of installation as a complete unit could present one
blueprint for the development of renewable hydrogen in the built environment.

Figure 2 (Left): PURE Energy Centre’s HyPod™ System Showing red Hydrogen
Storage Cylinders and Stationary P.E.M. Fuel Cell.

Figure 3 (Right): PURE Energy Centre’s HyPod™ weather monitoring equipment is


clearly visible.

Integration of Renewable Hydrogen Technologies with Existing Building


Systems
Integrating hydrogen and fuel cells into building systems should present no more
of a challenge than any other building services, if space requirements are taken
into consideration. As hydrogen services are still under development, they may
take up more space and require more generous room for access and service than
well-established technologies.

A consideration for the architect is that hydrogen, as a gas that is lighter than air
rises, to provide passive-safety designers should ensure that in service areas the
highest point of the building envelope is ventilated, and that the envelope of the
service area is designed in such a way that any hydrogen that is accidentally
vented can rise upwards to this point. Good passive ventilation of the area will
ensure that any hydrogen leaks can be safely dispersed.

Sizing Fuel Cell Installations

Where the installation is a grid-connected installation in common with other CHP


technologies, it is wise to size the fuel cell in accordance with the maximum heat
demand, as electrical power can easily be imported and exported to and from
the grid.

At the moment as this technology is still expensive and used in a limited number
of installations, it is common practice to use fuel cell technology in concert with
other more conventional technologies, with the fuel cell providing a portion of
demand. This has the advantage that there is a back-up system in place to
provide heat and power during fuel cell service intervals e.t.c.

Using Fuel Cells with other Low Carbon Technologies

Fuel Cells with GSHP

In the installation at the “Hydrogen Office” in Methil, for which the Pure Energy®
Centre provided the hydrogen installation, the Fuel cell is used in concert with a
ground source heat pump to meet the buildings heating needs. The heat pump
takes thermal energy from the surrounding ground area and concentrates it into
the building envelope. For every unit of electrical energy used to drive the
heating system it is anticipated that up to 3 units of equivalent thermal energy
are recovered from the ground. This is known as the Coefficient of Performance
(CoP)

Fuel Cells for Cooling

It is possible to use fuel cells in concert with absorption chillers to provide


building cooling. Where additional cooling is required, however, for good low-
energy design, passive cooling techniques should be adopted first where possible
to reduce building energy demand.

Safety in Hydrogen Installations


Safety is imperative in hydrogen installations, both for the imperative of
protecting people and property; ensuring duty of care to members of the public
who may use and come into contact with such installations, but also to protect
“nascent technologies at a critical time in their emergence into the wider
consciousness” (Gammon, 2004)

“ …we don’t know much about it at all, other than we used to make bombs out
of this stuff.”
-Local Hornchurch resident, Mike Dyer Romford Recorder May 2003.

“My feelings are rather strong on this, I think it must be dangerous.”


-Local Hornchurch resident, Stephen Kelly, Romford Recorder May 2003.

Quotes excepted from Garrity (2004)

There is a lack of understanding about the genuine safety implications of using


hydrogen. Urban myths persist about the “dangerous nature of hydrogen”,
largely founded on a mistaken understanding of the Hindenberg Disaster (1937)
and the Hydrogen bomb. When polled (Garrity, 2004) 17% of all respondents
associated “the hydrogen bomb” with the word hydrogen, whilst 2% of all
respondents associated the word Hindenburg with hydrogen (These results could
be possibly explained by the fact this survey was conducted in Australia, it is
believed that a poll in Europe would most likely show a greater awareness of the
Hindenburg disaster.)

There is a body of best-practise information that can be learned from industry,


indeed companies such as BOC have a long experience of safely working with
industrial gases, and much of the best-practise they have learned from industry

In particular HAZOP Analysis – Hazard and operability studies; are a useful tool in
refining process and procedure to ensure safe-working practise.

In addition to the safety concerns surrounding the use of hydrogen itself,


consideration should also be given to the strong alkali which is used in
electrolyser systems, its storage and use should be done in accordance with the
COSHH regulations.

Contemporary developments in electrolysis and fuel cell technology take account


of ATEX, COSHH and PED to fully design in and automate all material handling
internally. This removes the need for user intervention in order to create services
with a lighter maintenance requirement.

Repair and maintenance would be conducted by trained service engineers, much


the same way as how a mains gas boiler is used, operated and maintained at this
present time. With this in mind, modern products will be more akin to ‘plug and
play’ to the user and the risks and dangers associated with the fuel and internal
process are fully controlled and automated under a “fail to safe” design
methodology. By way of example, modern flat screen plasma televisions contain
within them lethal voltages within, tens of thousands of volts, but the technology
is packaged in such a way that the user is protected – and if there is a problem or
a fault, trained personnel are able to effect a repair.

Relevant Legislation
One of the frustrations in developing this innovative building technology is that
there is lack of clarity as far as legislation and safety codes. As there are only a
limited number of hydrogen installations in settings other than industrial
installation, there are limited examples of best-practice to learn from.

There is not yet a standard for hydrogen installations in the same way that there
is the GasSafe (Formerly CORGI) quality mark for domestic and commercial gas
installations. The United Kingdom Hydrogen Association is working to address
this. As there is a lack of guidance for domestic / commercial small scale
hydrogen standards, at present guidance is taken from the statutory industrial
regulations listed below, and projects are assessed on a case-by-case basis, this
adds significant expense to hydrogen installations due to the extra work of
performing due-diligence and is an area where the cost of a hydrogen installation
can be reduced as proper standards are developed. Ideally, the hydrogen
community will work towards a standard that can be signed off by a competent
person.

Pressure Equipment Directive EU standard

The pressure equipment directive covers vessels, piping, valves and associated
accessories for safety and managing pressure, where the installation contains
pressure running at greater than 0.5bar, this is the case for renewable hydrogen
installations, with the Pure Energy® Centre’s HyPod® running at 38-42bar as an
example, whilst next-generation hydrogen vehicles will require refuelling at
between 300-750bar.

• Pressure Equipment Directive 97/23/EC

ATEX directive

The ATEX directive in fact consists of two directives, from the European Union,
one which applies to the manufacture of equipment and their associated
protective systems for use in explosive environments, and the other which
applies to the operation and use of equipment in explosive environment. They
are:

• ATEX 95 equipment directive 94/9/EC, Equipment and protective systems


intended for use in potentially explosive atmospheres;
• ATEX 137 workplace directive 99/92/EC, Minimum requirements for
improving the safety and health protection of workers potentially at risk
from explosive atmospheres.

Manufacturers Standards

Significant reference needs to be made to manufacturers equipment standards


during the execution of a renewable hydrogen installation. As with many evolving
technologies, the first groups of consumers are often those that have to
complete the last phase of product testing. Experience on a range of installations
has given the experience that equipment supplied may often be at variance from
the manufacturers published specification; and this can lead to challenges when
integrating systems.

Guidance from Professional Associations

BCGA British Compressed Gas Association, Codes of Practice provide guidance on


best practise for the use of compressed gases in the UK. Whilst the regulations
pertaining to hydrogen in its gaseous state are the most relevant to current UK
Renewable Hydrogen installations, legislation pertaining to liquid and
cryogenically stored hydrogen may become relevant as hydrogen installations
evolve and more advanced storage technologies are used.

The BCGA provide guidance on the use of industrial compressed gases, which
provide

• Code of Practice CP8 Safe Storage of gaseous hydrogen in seamless


cylinders and similar containers

• Code of Practice CP25 Revalidation of bulk liquid oxygen, nitrogen,


argon and hydrogen cryogenic storage tanks.

• Code of Practice CP33 The bulk storage of gaseous hydrogen at user


premises 2005.

In addition to the UK professional associations, there are also some international


organisations who produce publications relating to safety and best practise that
are of note.

In addition, the IGC provide the following guidance notes:

• 6/93 Code of Practice: Safety in storage, handling and distribution of


liquid hydrogen.

• 15/96 Gaseous Hydrogen Stations

Whilst the U.S. Compressed Gas Association provide the following guidance
notes;

• G-5 Hydrogen

• G5-4 Standard for Hydrogen Piping at Consumer Locations

• G5-5 Hydrogen vent systems

Furthermore, the U.S. National Fire Protection Association provide the following
guidance:

• 50A Gaseous hydrogen systems at consumer sites

• 50B Liquefied hydrogen systems at consumer sites

Planning Process
We can assume that if you are looking at producing a hydrogen installation, you
already have a client who is receptive to innovative building technologies. Due to
the level of the technology development, this is really a pre-requisite for a
renewable hydrogen installation. There are challenges with educating those
involved with the planning process about the risks and benefits associated with
hydrogen and experience from real-world installations shows that there is a clear
need for knowledge transfer between members of the planning community to
transfer information about successful installations in one locality to those
responsible for decision making in others.

Notes on Hydrogen Integration for Architects & Service Engineers

• Fuel cells in the sub-100kw range typically occupy the same space as a
19” rack, commonly used for housing I.T. equipment; this is for their
application and deployment in data centre applications. By way of
illustration, 10kW “HyPM” modules fit in a standard 19” rack, with a 10kW
module occupying a 5U space in the rack. Power conditioning equipment
may also occupy a rack-mount installation, sharing common space.

• High temperature systems up to 200kW are approximately the size of a


20” container once all the auxiliary devices, safety systems and
conditioning electronics are included.

• Many of the requirements of existing plant rooms are still applicable for
the larger systems, but consideration should be given to the properties of
the fuel gas used – e.g. H2 is very buoyant compared to air.

• As a minimum many fuel cells require clearance at the front and the rear
for easy maintenance, this is manufacturer dependent.

• Consideration will need to be given to the siting of:

o Electrical cables flowing to and from the fuel cell.

o Hydrogen supply pipework supplying power to the fuel cell.

o An exhaust pipe which will be large diameter and take a similar


form to a gas boiler flue.

o A waste water drain for the exhaust water from the fuel cell.

• Consideration should be given to how to treat the water from the fuel cell.
The water is of exceptionally high, pure quality. Some local authorities are
happy for this water to go to soakaway rather than enter the drainage
system. A green building project may repurpose this water, by using it as
part of a greywater recycling system. Waste water from the exhaust of a
fuel cell system is pure demineralised, and de-ionised H20. in its self it is
not considered healthy to drink too much such pure water as it is thought
to remove nutrients from the body. If mixed with other drinking water this
effect would in theory be removed. A common trick I have seen is for the
manufacturers of fuel cells to mix the exhaust water with Whisky to add
the necessary minerals and charged particles!

• The output flow of water is dependent on the size of the fuel cell stack, in
the example of a 5kW plug power unit as used in the PURE project, the
output water flow was 2L/h at 5kW (full power) although the stack power
will be a little higher than this to accommodate BOP loading.

• Careful consideration should be given to siting the exhaust vent for fuel
cell installations. It should be ensured that this vent does not create an
“ATEX zone”. All potential sources of ignition should be isolated from the
area where the exhaust emerges. Whilst highly manufacturer specific,
some fuel cells vent directly, others vent indirectly.

• Dry hydrogen flowing through metal pipes has the potential to build up
static charge. All metal pipework needs to be equipotentially bonded to
prevent the build up of charge. This should be done in accordance with the
17th Edition Wiring Regulation.

• It should be noted that the output power from a fuel cell is direct current
and may be regulated or unregulated. This D.C. can either be used directly
with appliances and devices designed for D.C. operation, or an inverter
can be used to convert the D.C. to 230v 50Hz mains supply.

• Many fuel cells are of a “box within a box” design, which means any
hydrogen leaks can be contained. Equipment that is not of this design may
lead to a hydrogen leak turning the room into an ATEX zone. Additional
ventilation at high level should be provided to allow hydrogen to ventilate
freely to the atmosphere, and the architectural detailing should be such as
to permit hydrogen to rise to the highest point of the room for ventilation.

Figure 4

Allowing hydrogen to ventilate naturally provides for passive safety


Conclusions

The adoption of renewable hydrogen installations in the built environment is


likely to look increasingly inevitable in a world which is rapidly moving towards
the adoption of low carbon building technologies.

Current installations are by ‘early adopters’ and ‘innovators’ who are willing to
tolerate the steep learning curve associated with hydrogen technology at its
present state of development. This learning curve is partly offset by available
grant funding for developing innovative projects.

Buildings that are considered very good candidates for FC technology are data
centres, this is due to the existence or planned installation of some form of UPS
system to ensure data throughput is not lost in the event of any power outage.

On the larger scale manufacturers of high temperature fuel cells such as MTU
install them into large public or municipal buildings such as hospitals, concert
venues office blocks etc, to provide heat and power from a natural gas source.
The emissions are much lower in Co2 and Nox etc than a combustion engine or
gas turbine using the same fuel stock, and the electrical efficiency is much
higher.

Installations will become more cost-effective as codes of best practise, regulation


from the industry and standard configurations are developed. There is a need for
knowledge sharing within the building, planning and safety communities to
ensure that best practise about the practical aspects of hydrogen
implementation is effectively disseminated.
References:

Butera, F., (2008) Towards the Renewable Built Environment, In: Droge, P., Urban
Energy Transition: From Fossil Fuels to Renewable Power, Elsevier Science

Garrity, L., (2004) Public Perception and Economic Preferences towards the use of
H2FC buses in Perth, Hydrogen and Fuel cell futures Conference 12th-15th
September 2004,

Gazey, R., Salman, S.K., & Aklil-D’Halluin, D.D. (2006) A field application
experience of integrating hydrogen technology with wind power in a remote
island location, Journal of Power Sources, 157 (2) pp. 841-847

Gammon, R., Roy, A., Barton, J., & Little, M., (2006) Hydrogen and Renewables
Integration (HARI), Report to the International Energy Agency HIA Task 18, CREST
(Centre for Renewable Energy Systems Technology), Loughborough University,
UK

Harper G.D.J., (2006) "The Merton Rule" In: Hall, K.D ed., (2006) "Green Building
Bible - Volume 1.: Essential Information to Help You Make Your Home and
Buildings Less Harmful to the Environment, the Community and Your Family" 3rd
Ed. Llandysul, Wales: Green Building Press pp.56-59 ISBN:978-1898130062

Harper, G.D.J., (2008) Hydrogen integration at West Beacon Farm, Green Building
Magazine p.64-65

Harper, G.D.J., (2008) Working towards a hydrogen future: an interview with Allan
Jones, p.66-68

Harper, G.D.J., (2008) Hydrogen homes for Scotland, p.69

Pitts, A., (2008) Future-proof construction – Future building and systems design
for energy and fuel flexibility, Energy Policy, 36 pp.4539-4543

Sovacool, B.K., & Hirsh, R.F., (2008) Island wind-hydrogen energy: A significant
potential US resource, Renewable Energy, 33, 8, pp.1928-1935

Van Ruijven, B., Van Vuuren, D.P., De Vries, B., (2007) The potential role of
hydrogen in energy systems with and without climate policy, International
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