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Dr. Akepati S. Reddy Deptt. Analytical Services TCIRD, Thapar Technology Campus Patiala P!"#A$% & '() **(
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Based on the manner of bringing the gas phase in contact with the liquid phase categorized as
Gas phase contacting scrubbers use gas stream energy iquid phase contacting scrubbers use liquid stream energy Wet film scrubbers use energy of both liquid and gas streams !ombination liquid phase and gas phase scrubbers use energy of both liquid and gas streams "echanically aided scrubbers mechanically dri#en rotors are used for the contact
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"edium energy scrubbers pressure drop &*1&' +igh energy scrubbers pressure drop (1&' #enturi and condensation scrubbers
But many scrubbers operate o#er a wider range pressure drop
Depending on the use categorized as ,crubbers primarily used for collecting particles ,crubbers primarily used for gaseous pollutants remo#al Dry scrubbers are categorized as Dry sorbent in-ectors .D,/0 ,pray dryer absorbers .,D10 also 2nown as semi*dry scrubbers or spray dryers
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,enturi Scrubbers
1 gas phase contact scrubber used to collect both particles and gaseous pollutants +as $ sections4 con#erging5 throat and di#erging section 67haust stream is forced to mo#e through throat at e7tremely high #elocity .$8*128 m9sec:0
iquid is introduced into the throat either at the throat or at the entrance of the con#erging section
1t the throat the liquid is sheared from walls and atomized into #ery small droplets Gas e7iting the di#erging section is forced to slow down for remo#ing the liquid droplets 6ntrainment separator .cyclonic or mesh pad or blade separator0 is used for the remo#al of entrained liquid droplets
!yclonic separator when used is connected to the #enturi usually by a flooded elbow
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Converging section
Diverging section
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,enturi Scrubbers
<on*wetted .dry throat0 approach #enturi
liquid is introduced at the throat in case of high temperature e7haust ca2ing of throat can occur appropriate for cool moist e7haust
=enturi with round throat can not handle larger flows .( >>888 m$9hr0 * =enturi with long5 narrow5 rectangular throat can be used
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,enturi Scrubbers
@or handling #ariable gas flows ad-ustable throat #enturis .with #arying throat areas0 are used
=enturi with a plunger or ad-ustable disc mo#ing up and down the throat .decreasing and increasing annular opening of the throat0 Aectangular throat #enturis with mo#able plates that decrease or increase throat area
=enturi rod or rod dec2 scrubber a number of pipes parallel to each other in the e7haust flow path create a series of rectangular throat openings
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,enturi Scrubbers
+ighest particle collection efficiency .B8*BBC0 among scrubbers
Dperated at pressure drops of & to 188 inches .gas #elocity in the throat is $8 to 128 m9,0
/ncreasing pressure drop across increases efficiency
,enturi Scrubbers
Wear or abrasion of the scrubber shell is the primary maintenance problem with #enturis
ining the throat with silicon carbide or using replaceable liner can minimize the problem
1 pre*cleaner through remo#ing larger particles can also reduce abrasion problem
@looded elbow at the bottom of the scrubber can reduce abrasion downstream to the throat
-.ector ,enturi
1ctually a spray tower capable of mo#ing e7haust without the aid of any blower or fan
Ereferred in e7plosi#e or e7tremely corrosi#e en#ironment
+igh pressure .1&*128 psig0 and high rate .?*1$ 9m$0 liquid spray .with a lone nozzle0 into throat creates #acuum5 suc2s e7haust from the side duct and mo#es through the #enturi 6ntrainment separator is usually used 6ffecti#e in remo#ing particles of (1) size but gas absorption efficiencies are #ery low @or e7tremely high collection efficiencies multiple stages of e-ector #enturis are used Eressure drop across is 1:$ to 1$ cm water 1brasion can be problem in nozzles and throat
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/ri+ice Scrubbers
"edium energy .& to 2& cm water pressure drop across0 de#ices used for particals remo#al .and also gases0 67haust stream is forced through a pool of liquid at high #elocity .1&:2 m9,0 creating liquid droplets
arger particles are remo#ed by impingement on scrubber liquid surface * smaller particles by impacting liquid droplets
Baffles9air foils are pro#ided for the turbulent mi7ing of liquid droplets with the e7haust Baffles placed in the path of cleaned e7haust stream ser#e as impingement surfaces for entrainment remo#al
,ludge accumulated in the scrubber needs liquid circulation through a sludge remo#al facility
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/ri+ice Scrubbers
Designed to operate with a specific liquid le#el for a gi#en gas #elocity
Gas #elocities should not fluctuate beyond 18*1&C of design #alues ow gas flows or reduced liquid le#els reduce atomization and particle collection efficiencies
Designed for ma7imum e7haust flow rate and ma2eup air is introduced when flows become less
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/ri+ice Scrubbers
"aintaining water le#el at desired le#el .in the face of sludge separation and remo#al0 is an important and difficult maintenance problem Elugging and scale buildup are not problems
Aeacti#e scrubbing .gaseous pollutants chemically react with liquid0 can still produce scales and plug the internals
!ollection efficiencies are moderate and used for the remo#al of (1 ) particles iquid gas ratio is
1:$ to &:$ 9m$ for particles remo#al 8:8? to 8:? 9m$ for gases
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Plate To0ers
6ffecti#e in remo#ing gaseous pollutants
Earticulates can also be simultaneously remo#ed !an pro#e good for flue gas desulphurization
Dne or more plates are mounted horizontally inside a #ertical column 67haust enters at the bottom and flows upwards passing through the plates iquid enters at top and tra#els across each plate to a down comer and from their to ne7t plate below and ultimately to the tower bottom
iquid to gas ratio followed is 8:? to 2:8 9m$
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Fhese are medium energy scrubbers .2:& to 28 cm pressure drop per plate0
Plate To0ers
Elates are sie#e5 impingement5 bubble cap and #al#e types
,ie#e plates4 +a#e 1>88*B8889m2 openings of 8:$2*2:& cm size and form 18*188) size droplets /mpingement plates4 plate openings ha#e impaction targets abo#e to increase the gas*liquid contact Bubble cap plates4 around each hole a riser is pro#ided o#er the riser a cap with se#eral slots is pro#ided =al#e plates4 ha#e liftable caps abo#e the openings and plates attached to legs limit the capsG #ertical mo#ement
,maller openings can increase the particle collection efficiency but can get plugged !ost wise sie#e plates are cheapest5 impingement plates come ne7t5 and bubble cap plates are the costliest
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Plate To0ers
Gas remo#al efficiencies of ( B>C can be easily achie#ed and for increasing efficiencies following can be done
/ncreasing number of plates Hsing higher liquid to gas ratios /ncreasing pressure drop across the plates
Plate To0ers
,usceptible to plugging and9or scale build*up problems
high solid content in scrubber liquor can be a cause can not be used for e7haust with dust or stic2y materials access to plates for cleaning is important water sprays underside the lower most plate can a#oid wet*dry interface and scaling low p+ wash can dissol#e and remo#e scales
+igher liquid in-ection rates and higher e7haust gas #elocities can cause flooding of plates this in turn increase pressure drop but decreases gas*liquid mi7ing Foo low gas #elocities cause weeping .liquid dripping through holes0 and decrease the gas*liquid contact Eoor scrubbing liquor distribution can be a problem
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Spray To0ers
ow energy .pressure drop is 1:$ to ?:; cm water0 ine7pensi#e de#ices Hsed as pre*scrubbers for remo#ing
larger particles .of size (18*2&)0 highly soluble gases .with &8*>8C efficiency * plate towers and pac2ed towers are superior for gas absorption remo#al0 chemical reagent addition to the liquid .I"nD3 for odor remo#al0 can also increase the efficiency
Spray To0ers
!ounter*current5 co*current and cross*current configurations are used !ross*current configurations .horizontal spray scrubbers0 can ha#e more than one spray sections
@or better results the liquid can flow counter*current and cleanest liquid can be sprayed in the last section
!ounter*current configurations can ha#e multile#el liquid spray nozzles @or similar collection efficiencies co*current configuration is smaller than a counter*current configuration
67haust relati#e #elocity is higher in the counter*current configuration
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Spray To0ers
67haust enters the bottom and mo#es upwards in counter* current flow configuration 67haust gas #elocity is within 8:$ to 1:2m9sec: to pre#ent liquid carry o#er iquid at pressure is 18*388 psig is sprayed through nozzles downwards into the spray tower Eroduces droplets of size &88 to 1888) .#enturis produce 18 to &8) size droplets0
in-ection of liquid at $88 to 3&8 psig pressure creates fog li2e droplets
Spray To0ers
Decreasing liquid droplet size and increasing liquid to gas ratio can increase the absorption remo#al iquid droplets after falling short distance tend to agglomerate into bigger drops or hit walls and comedown affecting efficiency
!ompletely open design ha#e least scale buildup and plugging problems <ozzle plugging or eroding can occur specially with recycled liquid
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Eressure drop is 2:& to ?:& cm water iquid to gas ratio is 8:1$ 9m$ iquid inlet pressure is %1& psig "aintenance problems are the least solids buildup on baffles can occur
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ess efficient in remo#ing gaseous pollutants and not chosen for gaseous pollutant remo#al
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,traightening #anes are pro#ided at the top of the chamber !an also act as entrainment separators
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iquid to gas ratio employed is 8:$ to 1:$ 9m$ iquid inlet pressure is 2>8 to 2>88 2Ea
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!heaper but weight is more than that of plate tower Eac2ing material supported o#er trays is sprayed with liquid to form liquid film coat 67haust is passed through pac2ing for contact with liquid and absorption remo#al of gaseous pollutants
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+igher gas #elocity through pac2ing ensures good mi7ing but can cause flooding of pac2ing /ncreasing liquid in-ection increases absorption efficiency but can cause flooding
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Eerforated tubes4
!an be buried within the pac2ing allows the pac2ing abo#e the perforated tube to act as entrainment separator 1#oids liquid blowing against the side walls of the tower Fubes .and perforations0 can clog and 2nowing it is difficult
,pray nozzles4
<ozzle clogging and erosion can be a problem Hse of fewer relati#ely large nozzles can a#oid the clogging !an be easily inspected Eressure drop is the highest among the three
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Fower internals are not easily accessible and cleaning requires shutting the system and remo#ing5 cleaning and reinstalling the pac2ing
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ower gas flow rates can result in gas channeling iquid to gas ratio employed is 8:1$ to 2:8 9m$ and liquid inlet pressure is &*1& psig Eressure drop is 1:? to & cm water per foot or 2 to >:& cm of water per meter of installed pac2ing and & to 22 cm of water across the pac2ed tower
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Ereferred when high collection efficiency of particulates and gaseous pollutants is required Ero#ides effecti#e absorption li2e pac2ed and plate towers but without plugging problems Because of high gas #elocities these are much more compact than pac2er towers and plate towers but these are not as energy efficient as the latter 3?
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"aintenance problems
Elugging and scale buildup can occur specially at the scrubber inlet and on the pac2ing support grid <ozzle maintenance is of concern in lime or limestone scrubbing systems Deterioration of spheres of pac2ing can occur from high temperature and constant rubbing against each other
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/ncreasing liquid*to*gas ratio5 increasing the depth of pac2ing and increasing the number of pac2ing stages enhance adsorption
Aemo#al efficiencies are BBC for gases @or ,D2 remo#al from flue gases > 9m$ ratio is used
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Earticulate matter control de#ice to remo#e the reaction products5 e7cess sorbent and other ,E" of the e7haust
@abric filters or 6lectrostatic precipitators are used
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6fficiency is &8C for ,D2 and B8C for +!l in simple systems can be increased by
!ooling and9or humidifying the flue gas Aecycling portion of the collected particulate matter .has unreacted sorbent0 Dperating at higher stoichiometric ratios of sorbent /ntroducing an e7pansion9reaction chamber can increase residence time and efficiency
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1tomizer ,pray dryer chamber .absorption tower9reaction chamber0 Earticulate control de#ice Earticulate recycle system .optional0
67haust is introduced into absorbing tower .reaction or drying chamber0 for contacting with finely atomized al2aline slurry
Fhen passed through a fabric filter or an electrostatic precipitator for the particulates remo#al !ollected solids can be recycled and used in slurry ma2ing
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1mount of water to be used depends on incoming flue gas temperature and moisture content 1l2aline slurry loading rate depends on acid gas le#el in the e7haust and remo#al efficiency desired Hse of 1:& to 2:& times stoichiometric ratio can achie#e ?&* ;$ >8C ,D2 remo#al or B&C +!l remo#al
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ength to diameter ratio for chambers with rotary atomizers is 8:>41 droplets should not deposit on walls
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Draining and flushing of lines and storage tan2s during e7tended downtimes is also helpful ow quality lime and9or water can result in scaling5 plugging ;> and reduce acid gas remo#al efficiencies