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CHM 2045, Fall 2012 Form Code A

Exam 2 (Mitchell, Gower, Williams, Polfer) Name______________________

Instructions: This exam contains 25 questions worth 10 points each. On your Scantron form, enter and bubble your name, UFID, and Form Code (see above). Turn in only your Scantron. You may retain your exam sheet and any other papers. Check bubbling carefully: bubbling errors are non-negotiable. 1. Using the H data given below, which choice is closest to the H for the reaction: N2O3(g) + N2O5(s) 2N2O4(g) NO(g) + NO2(g) N2O3(g), 39.8 kJ/mol NO(g) + NO2(g) + O2(g) N2O5(g), 112.5kJ/mol 2NO2(g) N2O4(g), 57.2kJ/mol 2NO(g) + O2(g) 2NO2(g), 114.2kJ/mol N2O5(s) N2O5(g), +54.1kJ/mol (1) +35.0kJ/mol (2) 22.2 kJ/mol (3) +206.2 kJ/mol (4) +126.6 kJ/mol (5) 241.2 kJ/mol 2. Using valence-bond theory, predict the change, if any, in hybridization of the carbon atom during the reaction: CO2(g) + OH(aq) HCO3(aq) 2 2 (1) sp sp (2) sp sp3 (3) sp sp3 (4) sp sp3d (5) sp3 sp3 (no change) 3. Consider the Lewis structure for the nitric acid molecule, HNO3, and select the false statement. (1) More than one resonance structure is required. (2) The formal charge on nitrogen is +1. (3) In water, the HN bond is broken to form H3O+. (4) The oxidation state of nitrogen is +5. (5) The NO bond order is 4/3. 4. Which of the following transitions in a hydrogen atom would result in the emission of the shortest wavelength photon? (1) n=1 to n=2 (2) n=3 to n=2 (3) n=4 to n=1 (4) n=2 to n=8 (5) n=6 to n=5 5. Which pair is listed in order of increasing basicity? (1) K2O < B2O3 (2) PbO < SiO2 (3) BaO < BeO (4) CO2 < N2O5

(5) B2O3 < Li2O

6. A 455g piece of copper (c = 0.387 J/gK) is heated to 89.5C and placed in an insulated vessel containing 159g of water (c = 4.184 J/gK) at 22.8C. If the heat capacity of the vessel is 10.0J/K, which choice is closest to the final temperature of the system? (1) 46.8C (2) 79.0C (3) 273.8C (4) 36.6C (5) 0.702C 7. Enormous numbers of microwave photons are needed to warm household samples. A bowl of soup containing 363g of water is heated in a microwave oven from 20.0C to 98.0C using radiation with wavelength 122 mm. Assuming that the specific heat capacity of the soup is the same as that of water (4.184 J/gK) and no heat loss to the bowl, which choice is closest to the number of photons absorbed? (1) 7.27x1028 (2) 7.27x1031 (3) 9.13x1028 (4) 7.80x1022 (5) 1.19x105 8. Spectroscopic results for a certain element yielded orbital energy differences as follows: E(level 2 to level 1) = 4.098x1017 J E(level 3 to level 1) = 4.854x1017 J E(level 5 to level 1) = 5.242x1017 J E(level 4 to level 2) = 1.024x1017 J If an electron drops from level 5 to level 4, which choice gives the closest values of the energy and wavelength of the emitted photon? (1) 6.36x1018J, 313 nm (2) 4.22x1017J, 4.71 nm (3) 6.27x1017J, 3.17 nm (4) 4.22x1017J, 471 nm (5) 1.20x1018J, 166 nm 9. Which choice gives, in order, the molecular geometries of PCl4+, PCl5, and PCl6 ? (1) trigonal bipyramidal, trigonal bipyramidal, octahedral (2) tetrahedral, trigonal bipyramidal, octahedral (3) square planar, octahedral, trigonal bipyramidal (4) tetrahedral, octahedral, octahedral (5) square pyramidal, trigonal bipyramidal, octahedral 10. How many sigma () and pi () bonds are in the molecule H2CCHCN? (1) 6 , 2 (2) 6 , zero (3) 4 , 5 (4) 6 , 3 (5) 3 , 3 11. Using the bond energy data given below, which choice is closest to the enthalpy change for the combustion of one mole of acetylene, C2H2, to form carbon dioxide and gaseous water? CH, 456 kJ/mol CC, 962 kJ/mol O=O, 499 kJ/mol C=O, 802 kJ/mol OH, 462 kJ/mol (1) 1759 kJ/mol (2) +653 kJ/mol (3) +594 kJ/mol (4) +1010 kJ/mol (5) 1010 kJ/mol 12. Which choice is a feasible set of orbital quantum numbers (n, l, ml, in order)? (1) 1,0,+1 (2) 2,1,0 (3) 1,1,+1 (4) 2,0,+1 (5) 2,3,+2

Form A 13. Which ground state atom or ion is matched with the correct number of unpaired electrons? (1) Cu+, zero (2) Ca,2 (3) Zn2+,2 (4) Cr,4 (5) Ag+,2 14. Which pair of compounds is listed in order of increasing lattice energy? (1) NaCl < KCl (2) LiF < LiI (3) MgO < CsCl (4) LiF < MgO (5) CaO < BaCl2 15. Which of the following compounds are polar: CBr4, XeF2, SCl4, BrF3, CH3OH (1) XeF2, SCl4, CH3OH only (2) XeF2, SCl4, BrF3, CH3OH only (3) SCl4, BrF3, CH3OH only (4) BrF3, CH3OH only (5) CBr4, XeF2, SCl4, BrF3, CH3OH 16. Which choice gives, in order, the hybridization of carbon in: CH3OH, HCN, CH2O (formaldehyde) (1) sp3,sp,sp3 (2) sp3,sp2,sp2 (3) sp2,sp2,sp2 (4) sp3,sp,sp2 (5) sp3,sp2,sp3 17. Which of the following statements is/are true? I. The 2s orbital in Be is the same size as the 2s orbital in Ne. II. All 3d orbitals are shaped like four-leaf clovers. III. The 3s orbital is more penetrating than the 3d orbital. IV. In Mn, the 4s orbital is higher in energy than 3d. (1) I,III,IV only (2) I,III only (3) III,IV only (4) III only (5) II,III,IV only 18. One part of the Born-Haber cycle for CaF2 is: Ca(g) + 2F(g) Ca2+(g) + 2F(g). Which expression corresponds to the H for this step? (subl =sublimation; EA = electron affinity; IE = ionization energy/enthalpy; latt = lattice; BE = bond dissociation energy/enthalpy) (1) 2IE1,Ca + 2EAF (2) IE1,Ca + IE2,Ca + EAF (3) Hsubl,Ca + IE1,Ca + IE2,Ca + 2EAF (4) IE1,Ca + IE2,Ca + 2BEF2 + 2EAF (5) IE1,Ca + IE2,Ca + 2EAF 19. Which choice has a valid Lewis structure with the indicated formal charge on nitrogen? (1) HNO2,+1 (2) HCN, 1 (3) NO2,1 (4) NO+, zero (5) NH4+, zero 20. When aqueous solutions of barium chloride and sodium carbonate are mixed, a precipitate of barium carbonate forms. Which choice is closest to the H for this reaction? Hf values: Ba2+(aq), -538 kJ/mol Cl(aq),167 kJ/mol Na+(aq), 240. kJ/mol CO32(aq), 676 kJ/mol BaCO3(s), 1219 kJ/mol (1) 5 kJ/mol (2) +5 kJ/mol (3) +809 kJ/mol (4) +402 kJ/mol (5) -1357 kJ/mol 21. Which pair is listed in order of increasing bond dissociation energy? (1) C=O < CO (2) CCl < CBr (3) SiO < CO (4) CO < CS (5) CC < C=C 22. A bomb calorimeter and a coffee-cup calorimeter can both be used to observe heat effects of reactions. Which statement is true about these devices? (1) A coffee-cup calorimeter measures heat transfer by the T of water, but not the bomb calorimeter. (2) For both types, the heat capacity of the calorimeter can usually be ignored. (3) Both types measure the heat transfer at constant pressure, qP. (4) Both types measure the heat transfer at constant volume, qV. (5) A bomb calorimeter is used primarily for combustion reactions. 23. Which set(s) give(s) the atoms/ions in order of increasing ionization energy? I. Al < Si < P < Cl II. Na+ < Mg2+ < Al3+ < Si4+ III. I < Br < Cl < F IV. Be < Mg < Ca < Sr (1) I only (2) I, II, III only (3) I, IV only (4) I, II, IV only (5) III only 24. Which choice gives, in order, the correct shapes for: SO3, IF2, XeO4, SF4 (1) trigonal pyramidal, bent, square planar, tetrahedral (2) trigonal planar, bent, tetrahedral, square planar (3) trigonal planar, linear, square planar, see-saw (4) T-shaped, linear, square planar, tetrahedral (5) trigonal planar, linear, tetrahedral, see-saw 25. Which pair is written in order of increasing bond polarity? (1) HI < HCl (2) CH < CC (3) CN < CBr (4) CH < BH (5) CF < CN

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