CHEMICAL ENGINEERING THERMODYNAMICS

TU-Darmstadt Winter 2009 20!0

Overall Description: A continuation of the first course in thermodynamics. Emphasis on thermodynamic properties of fluids, flow processes, phase and chemical equilibria. Prerequisite Knowledge: College level calculus and differential equations. Application of the First Law of hermodynamics and other basic concepts !enthalpy, internal energy, volumetric wor"#shaft wor" etc$ in closed or open systems %& behavior of pure substances#Equation of 'tate#(enerali)ed Correlations %hase equilibrium of pure substances# the phase rule Entropy and the 'econd Law of hermodynamics#*eversibility Course Objectives: o enhance the "nowledge of pure fluid thermodynamics with the emphasis on application and develop a clear understanding and wor"ing "nowledge of solution thermodynamics and the theories of fluid phase equilibria. A brief introduction will review chemical reaction equilibria, from a process engineering view. Expected Outcomes: After completion of this course the typical student is e+pected to be able to: Evaluate changes in thermodynamic properties !%, &, , ,, -, ' and ($ caused .verview of fugacity and fugacity coefficient of pure species and species in solution %erform various &LE calculations !equilibrium composition of liquid and vapor phases, dew#bubble point and L#& ratio$ using the (amma#%hi formulation and a variety of its simplifications ,se the Aspen%lus process simulator to correctly setup and obtain thermodynamic properties for various systems. .verview of the chemical equilibrium constant for a specific reaction. Time/Place: Recitation !nstructor: Text: Re'erence: (ebPage L/01#02, 3 !4i$ 5:00 6 7:10 o be announced 8r. 8avid 9. 8i+on L:0:#152, ;<7=>:2:=:>=/1>< !w$, di+on?tvt.tu=darmstadt.de !david.di+on?sdsmt.edu$ @orets"y, "Engineering and C#emical T#ermod$namics%& 3iley, /00< 'mith#&an Aess#Abbott, B!ntroduction to C#emical Engineering T#ermod$namicsC, Dth ed., 4c(raw -ill, /002 http:##webpages.sdsmt.edu#Eddi+on# hermoF ,8.html

by mi+ing of various substances without phase change

CHEMICAL ENGINEERING THERMODYNAMICS

TU-Darmstadt Winter 2009 20!0

(rading !'8'4 style of teachingG 'or example onl$$: Item %oints E+ams !1$ >0 Final E+amH !/0$ -omewor"HH 10 %roKect :0 otal :00 H

entative grade scale HHH: %oints earned (rade 70 A 50=57 J D0=D7 C >0=>7 8 L>0 F

he Final will be a /=hour comprehensive e+am. All e+ams will be open te+tboo" and open notes. .f the four e+ams given, only the top three e+am scores will be used in computing the total points and final grade. HH -omewor" turned in late will be subKect to :0M deduction daily. 'ubmitted homewor" must be clean, readable and logically sound. HHH he final grade will be reflective of a studentNs ran" in the class as well as the cumulative points earned. )rading *'or t#is course at T+,Darmstadt-: = 4idterm written e+am 20M = Final written e+am 20M = -omewor" improvement 0.1 pt Topics to .e Covered Chapter 2 = hermodynamic 3eb = 8eparture Functions = *eview Equations of 'tate !Chapter <, briefly$ Chapter > = Equilibrium H %ure Component H 4i+tures Chapter D = Fugacity !chemical potential fugacity equilibrium calculations$ H &apor !overview$, liquid, solids = Fugacity Coefficients !overview$ = Activity Coefficients Chapter 5 = %hase Equilibrium H 8iagrams H &apor 6 Liquid !&LE$ H Liquid 6 Liquid !LLE$ H 'olid 6 Liquid !'LE$ Chapter 7 = *eaction Equilibria !briefly mention tie to fugacity calculations$