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USA Pinus taeda vs.

Portuguese Eucalyptus globulus

Names
Pinus taeda

Eucalyptus globulus

Common names:

Oldfield pine North Carolina pine Shortleaf pine yellow pine Southern pine Arkansas pine

Common names: Tasmanian Blue Gum Southern Blue Gum Blue gum Eucalyptus Subspecies: Subsp. globulus Subsp. maidenii Subsp. pseudoglobulus Subsp. bicostata

Physical Properties
Pinus taeda

Eucalyptus globulus

Evergreen Softwood Height: 100-115 ft tall Climate: Humid, warm-temperate with long summers and mild winters Annual rainfall 40-60 inches

Evergreen Hardwood Height: 98-180 ft tall Climate: Mild, temperate- high, cool elevations in tropical areas Annual rainfall 35 inches

Bark and Leaves


Pinus taeda

Eucalyptus globulus

Bark: Red-brown to grey brown Scaly Leaves: 6-9 inches long, yellow-green needles Usually three needles per fascicle

Bark: Outer Bark: Grey, brown and greenish or bluish Peels in long strips Grey, shaggy and thick at base Leaves: Juvenile leave 6-15 cm long covered with a blue-grey bloom Mature: Narrow Sickle -shaped Dark shining green

Bark and Leaf Photos


Pinus taeda Eucalyptus globulus

Flowers and Fruit


Pinus taeda

Eucalyptus globulus

Flowers: Male: Long cylindrical Red-yellow Cluster at branch tips Female: Long cylindrical Yellow-purple Cluster at branch tips Fruits: Ovoid- cylindrical 3-6 inches red-brown cones

Flowers: Cream-colored Borne singly in leaf axils Produce honey flavored nector Fruits Gum nuts: Woody 1.5-2.5 cm diameter Seeds are shed through valves on top

Wood Chemical Composition


Pinus taeda

Eucalyptus globulus

Lignin 30% Cellulose 42% Hemicellulose 15.3% 3.8% Xylans Galactoglucomannan 12-14% 4.7% Mannan Extractives 4.4% Ash content 0.4%

Lignin Cellulose Hemicellulose


21.9% 51.3%
27.8% 1.3%

Xylans Glucomannans

Extractives

0.8%

Calorific Value-amount of heat given off upon burning


Pinus taeda

Eucalyptus globulus

Stemwood Bark

4780kcal/kg 5178kcal/kg

Leaves Thick branches Thin branches Bark Seeds

3070 kcal/kg 1871kcal/kg 1821kcal/kg 1412kcal/kg 2763kcal/kg

Fatty Acids
Pinus taeda

Eucalyptus globulus
8.0mg/kg traces traces traces traces

Hexadecanoic acid Octadecanoic acid Eicosanio acid Docosanoic acid Tetracosanoic acid

Hexadecanoic acid 76.1 mg/kg Octadecanoic acid 17.6 mg/kg Eicosanio acid Docosanoic acid 7.39mg/kg 36.6 mg/kg

Tetracosanoic acid 50.4 mg/kg

Sterol Structures
HO
HO

HO

Sitosterol

Campesterol

Cylcoartenol

HO

HO

24- methylene cycloartenol

Citrostadienol

Sterols Percentages
Pinus taeda

Eucalyptus globulus
26.0 mg/kg

Campesterol Sitosterol Cycloartenol

Campesterol Sitosterol Cycloartenol 24-methylene Citrostadienol

8.02 mg/kg 346.7 mg/kg Traces 9.24 mg/kg 24.9 mg/kg

277.0 mg/kg Traces

4-methylene cycloartenol 2.0 mg/kg Citrostadienol 1.0 mg/kg

Present Monolignols
OH
OH

OH

O OH

OH

OH

p-coumaryl alcohol

conif eryl alcohol

sinapyl alcohol

Pinus taeda
H:G 14:86

Eucalyptus globulus
H:G:S 2:36:62

Lignin Functional Groups abundance (/100 C-9 units)


Pinus taeda

Eucalyptus globulus
90-95 20-30 115-120

Methoxy Phenolic Hydroxyl Aliphatic Hydroxyl Benzylic Hydroxyl Carbonyl

Methoxy Phenolic Hydroxyl Aliphatic Hydroxyl Benzylic Hydroxyl Carbonyl

160-164 19 125 54 17-24

20

Lignin Linkages

Pulping Types and Paper


Pinus taeda

Eucalyptus globulus
Bleached sulphate pulping Printing and writing paper Unbleached sulphate pulping Packaging paper Sulphite pulping Tissue and special paper

Asplund pulping Roofing felts Groundwood pulping Fiberboard Kraft pulping High-grade papers

Bleached Kraft Pulping Fibers


Pinus taeda

Eucalyptus globulus

Length Curl Index

2.4 mm 0.095

Length 0.752 mm Curl Index 0.099 Coarseness 8.60 mg/100 m Population 20.0 million fibers/g

Coarseness 24.0 mg/100 m Population 2.58 million fibers/g

Applications
Pinus taeda

Eucalyptus globulus

Wind, sight, and noise barrier on highways Habitat for game and nongame wildlife Soil stabilization and erosion control Timber Pulpwood

Wind, sight and sound barrier on highways Fuel wood Timber Oils extracted from leaves: fragrance, insect repellant, and antibiotics Pulpwood

References
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Pinto, P.; Evtuguin. D.; Neto, C.; Sivestre, A.; Amado, F.; Behavior of Eucalyptus globulus Lignin During Kraft Pulping. II. Analysis by NMR, ESI/MS, and GPC. J. Wood Chem. Technol. (2000) 22(2&3), 109-125. Lisboa, S.; Evtuguin, D.; Neto, P.; Goodfellow, B.; Isolation and structural characterization of polysaccharides dissolved in Eucalyptus globulus kraft black liquors. Carbohydrate Polymers (2005) 60, 77-85. Patt, R.; Kordsachia, O.; Fehr, J.; European hardwoods versus Eucalyptus globulus as a raw material for pulping. Wood Sci. Technol. (2006) 40, 39-48. Pinto, P.; Evtuguin, D.; Neto, P.; Structure of harwood glucuronoxylans: modifications and impact on pulp retention during wood kraft pulping. Xie, Y.; Yasuda, S.; Difference of condensed lignin structures in eucalyptus species. Nordic Pulp and Paper research Journal (2004) 19(1), 18-21. Fonseca, L.; Crespo, R.; Feith, H.; Carvalho, J.; Macedo, A.; Pina, J.; Eucalyptus Forest Information System for the Portuguese Pulp and Paper Industry. Integrated Tool Preceedings (1998) 453-456. Poke, F.; Wright, J.; Raymond, C.; Predicting Extractives and Ligning Contents in Eucalyptus globulus Using Near Infrared Reflectance Analysis. J. Wood Chem. Technol. (2004) 24(1), 55-67. Perez, S.; renedo, C.; Ortiz, A.; Manana, M.; Peredo, D.; Comparison of Energy Potential of the Eucalyptus globulus and the Eucalyptus nitens. ESTI Industriales y Telecommicacion Evtuguin, D.; Neto, C.; Sivla, A.; Domingues, P.; Amado, F.; Robert, D,; Faix, O.; Comprehensive Study on the Chemical Structure of Dioxane Lignin from Plantation Eucalyptus globulus Wood. J. Agric. Food Chem. (2001) 49, 4252-4261. Freire, C.; Silvestre, A.; Neto, C.; Identification of New Hydroxy Fatty Acids and Ferulic Acid Esters in the Wood of Eucalyptus globulus. (2002) 56, 143-149. Nanko, H.; Button, A.; Hillman, D.; Eucalyptus Bleached Kraft The World of Market Pulp 2005, 212-213. Nanko, H.; Button, A.; Hillman, D.; Southern Bleached Softwood Kraft The World of Market Pulp 2005, 180-181. Ralp, J.; Lundquist, K.; Brunow, G.; Lu, F.; kim,, H.; Schatz, S.; Marita, J.; Hatfield, R.; Ralp, S.; Christensen, J.; Boerjan, W.; Ligning: Natural polymers from oxidative soupling 4-hydroxyphenylpropanoids. Phytochemistry Reviews (2004) 3, 29-60. Peng, J.; Lu, F.; Ralph, J.; Isochroman lignin trimers from DFRC-degraded Pinus taeda. Phytochemistry (1999) 50, 659-666. Davin, L.; Lewis, N.; Lignin primary structures and dirigent sites. Current Opinion in Biotechnology (2005) 16, 407415. Chakar, F.; Ragauskas, A.; Review of current and future softwood kraft lignin process chemistry. Industrial Crops and Products (2004) 20, 131-141.

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