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A +BC A B
PB: constant
A+B
C D
A+BC D
C A+B D
% Conversion: fraction of R converted into P % Selectivity of Pi: fraction of Pi/total products % yield Pi = conversion x selectivity
~0
0<<1
b, T
=1
Eapp
Etrue
k = A exp(-E/RT)
-dnA/Adt = Ddc/dx
log k
1/T
Rate = A exp(-E/RT)
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C1
ln A, k E, k
compensation effect
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+ 3 H2
H H
H2 +
H C C H H H
2 CH4
Catalytically-inert elemnet 16
Structure-insensitive rxn: catalytic reaction for which the reaction rate per unit surface area is practically independent of the size or shape of the supported metal crystallites, i.e., independent of the mode of preparation. Also known as a facile reaction. Structure-sensitive rxn: catalytic reaction for which the activity of the catalyst depends on the atomic structure of the catalyst surface, i.e., the rate per unit surface area depends on the size or shape of the supported metal crystallites. Also known as a demanding reaction.
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Langmuir-Hinshelwood Mechanism:
The rate of a heterogeneous reaction is controlled by the reaction of the adsorbed molecules, and that all adsorption and desorption pressure are in equilibrium.
Rideal-Eley mechanism:
----between strongly adsorbed atoms (those chemisorbed) and molecules held to surface only be weak, van der Waals forces (those physically adsorbed).
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