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The impact of corrosion on the oil industry has been viewed in terms of its effect on both capital and operational expenditures (CAPEX and OPEX) and health, safety, and the environment (HSE) this overview covers corrosion and metallurgy issues related to drilling, production, transportation, and refinery activities. Corrosion-related failures constitute over 25% of failures experienced in the oil and gas industry.
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29784-The Impact of Corrosion on Oil and Gas Industry
The impact of corrosion on the oil industry has been viewed in terms of its effect on both capital and operational expenditures (CAPEX and OPEX) and health, safety, and the environment (HSE) this overview covers corrosion and metallurgy issues related to drilling, production, transportation, and refinery activities. Corrosion-related failures constitute over 25% of failures experienced in the oil and gas industry.
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The impact of corrosion on the oil industry has been viewed in terms of its effect on both capital and operational expenditures (CAPEX and OPEX) and health, safety, and the environment (HSE) this overview covers corrosion and metallurgy issues related to drilling, production, transportation, and refinery activities. Corrosion-related failures constitute over 25% of failures experienced in the oil and gas industry.
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Attribution Non-Commercial (BY-NC)
Formats disponibles
Téléchargez comme PDF, TXT ou lisez en ligne sur Scribd
Oil and Gas Industry M.B. Kermani, SPE, and Don Harrop, BP Intl. Summary The impact of corrosion on the oil industry has been viewed in terms of its effect on both capital and operational expenditures (CAPEX and OPEX) and health, safety, and the environment (HSE). To fight against the high cost and the impact of corrosion within the oil in- dustry, an overview of topical research and engineering activities is presented. This covers corrosion and metallurgy issues related to drilling, production, transportation, and refinery activities. Introduction The wide-ranging environmental conditions prevailing in the oil and gas industry necessitates appropriate and cost-effective materi- als choice and corrosion-control measures. Corrosion-related failures constitute over 25% of failures experi- enced in the oil and gas industry. More than half of these failures are associated with sweet- (CO 2 ) and sour- (H 2 S) producing fluids. An analysis of failures during the 1980s in a limited industry-wide sur- vey 1 is summarized in Tables 1 and 2. Corrosion can impose a significant cost penalty on the choice of material at the design stage, and its possible occurrence also has se- rious safety and environmental implications. Furthermore, as pro- duction conditions tend to become more corrosive, they require a more stringent corrosion management strategy. Cost of Corrosion The economic impact of corrosion can be viewed in terms of both CAPEX and OPEX and HSE. Quantifying the cost of corrosion in these categories is not an easy task. Nevertheless, a recent in-house survey on the cost of corrosion to the BP Group presents a fairly comprehensive examination of such costs, and, in general terms, provides a valuable insight into the relative breakdown of likely cor- rosion costs affecting operators within the industry. It is widely recognized that corrosion costs typically represent in any 1 year roughly 3% of gross domestic product (GDP) for developed countries. If this is translated directly onto a companys balance sheet as a percentage of turnover, then it represents a major cost in any 1 year. There are four main ways in which corrosion costs can be incurred: 1. Design expenditure or CAPEX. Costs incurred at the project stage, representing additional capital outlay on preventing, minimiz- ing, or controlling corrosion, compared to the expenditure that would have been required if corrosion did not exist. For example, capital ex- penditure because of corrosion on North Sea projects undertaken by BP in the 1980s averaged about 8% of total project CAPEX. 2. Operating expenditure or OPEX. Day-to-day costs associated with corrosion control and repair and including planned/unplanned maintenance costs as a result of corrosion damage. For example, in 1988, between 25% and 33% of maintenance costs of BPs oilfields in the U.K. Continental Shelf were corrosion-related. 3. Replacement expenditure. Costs incurred in replacing/repair- ing major pieces of corroded plant and equipment where replace- ment/repair would be classified as capital expenditure. For exam- ple, the cost of replacing the Forties main oil line riser because of internal corrosion was U.S. $11.5 million in 1987. 4. Lost revenue. Costs associated with lost production, spoilage/ contamination of products, or the costs of deferred cash flow caused by delays in production caused by corrosion-related problems. Copyright 1996 Society of Petroleum Engineers Original SPE manuscript received for review March 23, 1995. Revised manuscript received Jan. 2, 1996. Paper peer approved Jan. 24, 1996. Paper (SPE 29784) first presented at the 1995 SPE Middle East Oil Show held in Bahrain, March 1114. It is also common to categorize corrosion costs in terms of avoid- able and unavoidable. Savings under avoidable costs may be re- alized by better use of existing or currently available technology to- gether with greater corrosion awareness and education with whole life-cost analysis. By contrast, there are other types of unavoidable costs that currently have to be incurred because of the realities of the world in which we live. Reduction of costs that are currently unavoidable or even poten- tially avoidable will depend on advances in technology, and thus present challenges for research and development (R&D). BPs experience suggests that avoidable costs appear to arise from the combination of a lack of readily available information (about the cost consequences of corrosion failures), variable quality of information dissemination, and, in some instances, a tendency to minimize initial capital outlay. The Impact of Corrosion on HSE While cost is an important consequence of poor corrosion control and awareness, of equal importance is the potential impact of corrosion on HSE. If unchecked or poorly controlled, corrosion can seriously affect plant and equipment integrity as well as its serviceability. This raises the risk of leaks and discharges of often flammable fluids and gases that present a potentially serious health and safety hazard. Also, such releases may well have unacceptable environmental properties and consequences inherent to the fluids themselves and/or associated with the production chemicals added to aid processing and transport (e.g., scale inhibitors, demulsifiers, and corrosion inhibitors). The last 15 years has seen a heightened awareness of and sensitiv- ity to the environmental impact of the use and subsequent discharge of industrial chemicals. In the case of the oil and gas exploration and production (E&P) industry, the application of production chemicals is now essential to the successful operation of most fields; however, this increases the risk of their subsequent entry into the surrounding environment. The situation has now changed significantly as gov- ernmental bodies have become better informed 2 and are conse- quently invoking ever tighter controls, together with a far more green public consciousness. While the situation awaits a resolu- tion, it is nevertheless clear that tighter legislation will emerge and its appropriateness more regularly challenged. There is a balance to be struck between toxicity vs. biodegradation vs. bioaccumulation in defining the overall environmental acceptabil- ity of a product for a given application. This is being addressed through the Chemical Hazard Assessment and Risk Management (CHARM) scheme, 3 which is an Oslo/Paris Commission-driven ini- tiative. Acceptance of the environmental risk evaluation model is still being debated, but until clear criteria are in place, it leaves the E&P industry, and the chemical supply companies in particular, unclear as to upon what product acceptance and development should be based. HSE concerns also apply to coatings where there is a drive to re- duce their volatile organic compounds (VOC) content and a move to high solids or more water-based paint system. There have also been concerns raised about the use of zinc anodes for offshore use given the toxicity of zinc. Corrosion in Drilling Operations In recent years, the premature, and sometimes catastrophic, failure of drillstring components has become an increasingly important consider- ation in drilling-engineering design and research. Many cases of critical component failure have been experienced in applications where fail- ures had not been encountered previously. In addition, increasingly complex designs and more stringent demands have been sought on the load-carrying components of drillstring. These failures occur more fre- SPE Production & Facilities, August 1996 187 TABLE 1ANALYSIS OF SELECTED NUMBER OF FAILURES IN PETROLEUM RELATED INDUSTRIES Type of failure Frequency (%) Corrosion (all types) 33 Fatigue 18 Mechanical damage/overload 14 Brittle fracture 9 Fabrication defects (excluding welding defects) 9 Welding Defects 7 Others 10 TABLE 2CAUSE OF CORROSION-RELATED FAILURE IN PETROLEUM-RELATED INDUSTRIES Type of failure Total failure (%) CO 2 related 28 H 2 S related 18 Preferential weld 18 Pitting 12 Erosion corrosion 9 Galvanic 6 Crevice 3 Impingement 3 Stress corrosion 3 quently in directional wells, and contractors are seldom aware of the problem until a washout or a twist-off occurs. 1,4,5 The failures impose cost penalties in the form of lost rig time, damaged tubular goods, un- planned workovers, and abandoned or side-tracked wells. Drillstring failures result predominantly from cracks initiated at the last engaged thread of made-up tool joints, 4 shown in Fig. 1. Typically, most of these failures are caused by a corrosion fatigue process. Cyclic tension, torsion, and bending are present and, more importantly, the presence of drilling fluids and downhole vibration assist in the formation and growth of corrosion fatigue cracks lead- ing to failures. Even though corrosion fatigue has been recognized as the cause of these failures for some time, it is only in more recent years that serious problems arising from these failures have been frequently encountered and have led to systematic studies. 1,4-6 Whatever the cracking mechanism, it appears that the sequence of tool-joint failure can be divided into two stages: crack formation and crack propagation. The sequence of crack formation and propa- gation are illustrated in Fig. 2. Initiation is caused by the susceptibil- ity of tool-joint steel to hydrogen embrittlement in the presence of drilling fluids; propagation is caused by an appreciably lower fa- tigue strength of tool-joint steel in the presence of drilling fluid. 4 Both stages of cracking are dependent on mechanical, physical, and environmental factors. Great efforts and extensive studies on the subject have led to the development of preventive and predictive measures aimed at minimizing the incident of failure. 1,4-6 Lack of sensitivity of current inspection techniques is responsible for losing sight of these cracksrecent development of alternative inspection techniques would lead to better detection of these cracks, hence reducing the incidence of failure. 1,5,7 The combination of better inspection techniques and knowledge of crack propagation rates leads to better definition of the necessary inspection frequency to achieve failure-free operation. Production Facilities Production TubingSour-Service Conditions. The appropriate choice of materials for well completions in sour fields is an important factor in the economic success of oil and gas activities. The choice is governed by mechanical properties, resistance to both corrosion dam- age and sulfide-stress cracking (SSC), availability, and cost. Resistance to SSC is often the principal factor affecting the choice of materials for H 2 S-containing environments because the occur- rence of SSC can result in a catastrophic and potentially hazardous Fig. 1Critical locations for fatigue of drillstring threaded con- nections. failure associated with a hydrogen embrittlement mechanism. This is becoming increasingly important as wells are drilled deeper and downhole conditions tend to become more corrosive with higher levels of hydrogen sulfide. This often necessitates the selection of highly alloyed, highly priced materials. Therefore, it is important to identify the mechanism of cracking and a method of assessing can- didate materials so that the most cost-effective choice can be made. For SSC to occur, a combination of tensile stress and an environ- ment containing hydrogen sulfide is required. Hydrogen sulfide has a dual role in such cases; first, it results in a lowering of the pH of the environment, and second, it catalyzes the penetration of atomic hydrogen into the material. 8 Therefore, it is apparent that both solu- tion chemistry and mechanical factors are the governing parameters in the performance of materials in sour-service conditions. The for- mer is a prerequisite for the availability of hydrogen at the metal sur- face, and the latter enhances hydrogen diffusion. In deference to the foregoing, it is apparent that factors that pro- mote hydrogen embrittlement would in turn affect the SSC behavior of materials. These include factors that affect hydrogen availability, entry, and its transport within the metal lattice. Thus, the solution chemistry, particularly pH, can govern the performance of materials in sour environments. Solution acidity in the presence of sulfide ions (sour environments) both facilitates the hydrogen evolution reaction, making it the dominant cathodic reaction, and enhances the amount of hydrogen absorbed within the lattice, thus increasing the degree of susceptibility to SSC. Fig. 2Sequence of cracking in drillstring tool joints. 188 SPE Production & Facilities, August 1996 Fig. 3Limits of sour service for downhole tubular steels. Bearing in mind the limitations of NACE MR0175 9 to address solution chemistry, new limits of sour service have been developed for a range of carbon and low-alloy steels as well as corrosion resis- tant alloys: the development of plots correlating solution pH with H 2 S partial pressure in a domain-type relationship 8 as shown in Fig. 3. Based on these domains, it is possible to identify the appropriate environmental conditions relevant to the service limits of steels most frequently used for completion tubing. This approach has led to the selection of the most suitable and cost-effective materials for sour-service applications. 10 Marine Structures. Offshore fixed-production platforms are constructed from low-strength marine structural steels. These struc- tures are subject to cathodic protection (often together with a surface coating) to prevent their general corrosion. The ability to predict corrosion fatigue behavior of marine structural steels is of prime im- portance in life prediction and reliability assessment of offshore structures. The fatigue performance of these C-Mn steels when stressed in saline solutions has been the object of intensive studies in recent years. 11-13 These data have demonstrated that the presence of saline environments increases the fatigue crack growth rates Fig. 4Fatigue crack growth rate of BS 4360 Grade 50D structur- al steel in aerated 3.5% NaCl solution (minimum load/maximum load ratio, R+0). (FCGR) over the values measured in air by a factor of 2/4, but the degree of enhancement is dependent on both the stress intensity range and the cathodic protection level, as shown in Fig. 4. The influence of cathodic potential is explained on the basis of the build-up of hydrogen at the crack tip. It can be speculated that the two competing processes in this situation are hydrogen build-up or its availability at the crack tip and the effective crack-tip strain rate in developing freshly created metal. Hydrogen entering the metal lattice at the crack tip by means of freshly created surfaces builds up to a concentration sufficient to induce brittle cleavage fracture over a distance ahead of the crack tip, the extent of which is determined by the effective strain rate at the crack tip. 12 The acceleration in crack propagation rate results in a decrease in the predicted life of tubular joints, 12,13 as shown in Fig. 5. Transportation Facilities An aqueous phase is inevitably coproduced with oil and/or gas at some point in the life of a field. The inherent corrosivity of this aqueous phase is then heavily dependent on the level of CO 2 and H 2 S acidic gases, which are also coproduced. The presence of H 2 S, CO 2 , and brine in crude oil not only give rise to increased corrosion risk/rates, but also, under certain circumstances, can lead to envi- ronmental fracture assisted by enhanced uptake of hydrogen atoms into the steel. Apart from the possibility of SSC in oil and gas transportation pipelines, absorption of hydrogen generated by corrosion of carbon steels in wet H 2 S-containing environments can have other adverse effects on the properties of steels. One adverse effect that has been observed in pipeline steels is the development of blisters and/or cracks along the rolling direction of the steel. These are associated with inclusions and segregations. The terms hydrogen-induced cracking (HIC), hydrogen-pressure cracking, and hydrogen-in- duced stepwise cracking (SWC) are used to describe cracking of this type in pipeline steels. Another phenomenon is that of stress-ori- ented hydrogen-induced cracking (SOHIC), which is facilitated in the presence of hoop stress. The only satisfactory solution is the specification of steel grades resistant to such cracking mechanisms. CO 2 CorrosionSweet Service Conditions. CO 2 is usually pres- ent in produced fluids, and although it does not in itself cause the cat- astrophic failure mode of cracking associated with H 2 S, its presence in contact with an aqueous phase can nevertheless result in very high corrosion rates where the mode of attack is often highly localized (Mesa corrosion). In fact, CO 2 corrosion, or sweet corrosion, is by far the most prevalent form of attack encountered in oil and gas pro- duction and transportation. The problem of CO 2 corrosion has long been recognized and has prompted extensive studies. 14 CO 2 dissolves in water to give carbonic acid, a weak acid compared to mineral acids as it does not fully dissociate: CO 2 )H 2 OH + )HCO 3 H 2 CO 3 Fig. 5Corresponding stressnumber of cycles to failure (S/N) curves. SPE Production & Facilities, August 1996 189 TABLE 3RULE OF THUMB; CO 2 CORROSION OF CARBON AND LOW-ALLOY STEELS Conditions Corrosivity P CO2 t7 psi (0.5 bar) Corrosion Unlikely 7 psi (0.5 bar)tP CO2 t30 psi (2 bar) Possible Corrosion P CO2 u30 psi (2 bar) Corrosion While there is some debate about the mechanism of CO 2 corro- sion in terms of which dissolved species are involved in the corro- sion reaction, it is evident that the resulting corrosion rate is depen- dent on the partial pressure of CO 2 gas and temperature. This in turn will determine solution pH and the concentration of dissolved spe- cies for a given temperature. A very simple rule of thumb approach often cited in the indus- try in defining the risk of CO 2 corrosion of carbon and low-alloy steels is given in Table 3. This is based on field experience, princi- pally in the U.S. However, more specific questions on service life, risk analysis, cor- rosion allowance, and inhibited corrosion rates require the ability to conduct a quantitative assessment, i.e., the ability to predict corrosion rates for a given set of conditions. Consequently, the relationship be- tween corrosion rate and CO 2 partial pressure has formed the basis of a number of predictive models/equations for carbon steels. Among these relationships, the most widely recognized and used is the ap- proach of de Waard. 15 The current form of the basic equation is log(V r )+6.23*1119/(t)273))0.0013t)0.41log(pCO 2 ) *0.34 pH act . There are appropriate correction factors for gas fugacity, corro- sion scales/surface films, i.e., Fe 3 0 4 and/or FeCO 3 , the influence of flow (mass-transfer effects) and steel composition. Correlation with field experience suggests that the de Waard approach generally pre- dicts the worst-case corrosion rate. A more pragmatic approach that places direct emphasis on knowledge of the water chemistry is that of Crolet, 14 which defines severity in terms of low, medium, or high risk. This approach takes into consideration not only predicted potential corrosion rate, but also in-situ pH, Ca 2+ /HCO 3
ratio, concentration of dissolved or-
ganic acids (notably acetic acid), velocity and, most importantly, correlation with field experience (based on downhole corrosion rate data). The risk assessment is run on a spreadsheet (CORMED). It must be remembered, however, that these models/equations are not strictly valid in the presence of H 2 S because of formation of protective sulfide films that may nevertheless be susceptible to localized breakdown under long-term exposure. Fig. 6 sets out a process for determining CO 2 corrosion risk/rate. In achieving this, a key element is the interaction be- tween the corrosion engineer and the petroleum engineer to ensure that the service conditions are correctly defined and relevant. Flow and Erosion. The effect of flow on CO 2 corrosion generally re- mains a grey area in the predictive process. However, it is not only flow velocity that needs to be determined, the flow regime is of equal importance, which for multi- or mixed-phase fluids will determine whether water wetting of the steel surface will occur. Clearly, if con- Fig. 6The procedure in defining CO 2 corrosion risk. tinuous hydrocarbon wetting is occurring, then the corrosion risk will be extremely low. Key factors here are oil/water ratio and emulsion tendency/stability. For many crude oils, the presence of a water cutuapproximately 35% will lead to water becoming the continuous phase for a fully mixed oil/water system such that corrosion then be- comes a continuous potential risk. Similarly, if the gas/oil ratio (GOR) isu5,000, then continuous water wetting can be expected. The flow parameter currently favored for determining the effect of velocity on corrosion rate and scale and inhibitor film formation/ stability is liquid shear stress at the pipe wall. Although there is lim- ited reported data on upper limits regarding shear stress, a figure of l00 Pa for C-steel above which disruption to surface films becomes a concern is considered by some as appropriate. However, it must be recognized that for specific situations it may be necessary to con- duct laboratory tests under simulated flow conditions. Laboratory testing becomes particularly critical where erosion caused by the presence of particulates is a concern. There are no in- dustry guidelines that adequately cover this situation. The common- ly cited API RP-14E 16 recommended practice strictly refers to pure gas-in-liquid induced erosion (i.e., no particulates present) and ap- plies the basic formula V e +C/(m)
. The relationship is essentially empirical as is the value of the constant, C, used for a given material; this is more often than not based on indi- vidual operator experience. For example, BP currently uses 135 for C-steel, 200 for 13% Cr steel, and 235 for Duplex stainless steels, ac- cepting that these are still conservative figures. Use of API RP-14E is nevertheless routinely used to size pipe or set velocity limits. Where sand and particulates are present, the most commonly cited equations for predicting purely erosion rates are that of Salama and Venkatesh. 16 h+1.8610 5 (WV 2 )/(Pd 2 ), or h+9.310 4 (WV 2 )/(Pd 2 ). The first equation contains a large degree of conservatism and adds on two standard deviations. The second equation has a constant based on additional work referred to by Salma and Venkatesh 16 and leads to a less conservative prediction. However, for many situations, the mechanism is one of erosion- corrosion where there are still no satisfactory equations to predict rates of metal loss. Here, it is expected that there will be synergy af- fecting the rate of attack of carbon and low-alloy steels, but little or none for corrosion-resistant alloys that rapidly repassivate. Refinery Several natural constituents present in oil can cause corrosion of refin- ery equipment. These constituents include sulphur compounds, salt water, inorganic and organic chlorides, organic and inorganic acids, and nitrogen that forms cyanides. Extensive research has led to recommen- dations in the appropriate use of alloys and corrosion control methods for these applications. . Refinery facilities in contact with H 2 at high tem- peratures and pressures may suffer from hydrogen damage. Because atomic hydrogen diffuses readily in the steel, cracking may result from the formation of CH 4 at high pressures in internal voids in the metal. This results in internal fissuring at grain boundaries plus decarburiza- tion with loss of strength, which may lead to equipment failure. In this respect, the use of chromium and molybdenum steels has been shown to improve the resistance to hydrogen damage. Steel development has offered improved strength properties, and the vanadium-modified steels also have much enhanced resistance to hydrogen damage. Also, improved and sensitive monitoring of damage has led to more accurate analysis of the safe remaining life of components. 17 Discussion and Summary To achieve a safe and environmentally acceptable operation while reducing the high cost of corrosion requires a systematic and re- sponsive corrosion management strategy to be put in place. The life- cycle of corrosion management strategy must embrace inception, design, development, and implementation/operation with a whole life commitment to responsive monitoring and inspection. Success- ful implementation of corrosion management strategy will also de- 190 SPE Production & Facilities, August 1996 pend on close communication between the corrosion engineer, pro- duction chemist, inspection personnel, and petroleum or plant engineershence, corrosion management is not a function that should be managed separately from all other operations/activities. In the search for new sources of oil and gas, operational activities have moved to harsher environments in deeper high-pressure/high- temperature wells and deep waters. This is bringing increased chal- lenges to the economy of project development and subsequent op- eration wherein materials integrity and prediction of long term performance are key issues. In drilling operation, premature fatigue failures of drillstring components have become an increasingly important consideration in drilling engineering design and research. Predictive and preven- tive measures to reduce the likelihood of failure are key factors to successful drilling operations. In production activities, deep water exploitation is essential in the search for the new sources of hydrocarbon. This introduces a major challenge in materials engineering that requires sophisticated structural designs together with high-integrity medium strength structural steels. Transportation of wet crude oil and natural gas, and particularly multiphase fluids, has posed considerable attention in recent years, especially for the development of marginal fields. A cost-effective and appropriate corrosion strategy with respect to the selection and utilization of corrosion inhibitors, corrosion monitoring, and in- spection techniques is vital for economic viability. The selection of materials for sweet and sour duty highlights the need to give relevant consideration to solution chemistryparticu- larly the in-situ pH, for design in sour-service environments, and flow regime for design in sweet-service conditionstogether with the partial pressures of the CO 2 and H 2 S gases. Finally, with the growing environmental awareness and imposed international legislation, corrosion issues within refineries are be- coming increasingly prominent, requiring focused and intensive re- search and engineering activities. Nomenclature C+ empirical constant, ft/sec(lbm/ft 3 ) 0.5 d+ pipe diameter, L, in. h+ erosion rate, mil/year m+ gas/liquid mixture density at operating pressure and temperature, m/L 3 , lbm/ft 3 pCO 2 + partial pressure of CO 2 , m/Lt 2 , bar pH act + actual pH in the presence of dissolved salts P+ material hardness, m/Lt 2 , psi t+ temperature, T, C V+ mixed velocity, L/t, ft/sec V e + limiting fluid velocity above which erosion may occur, L/t, ft/sec V r + corrosion rate, L/t, mm/yr W+ solids production rate, L 3 /t, bbl/month Acknowledgment We thank BP Exploration for permission to publish this paper. References 1. Kermani, M.B.: Hydrogen Cracking and Its Mitigation in the Petro- leum Industry, Proc., 1994 Conference on Hydrogen Transport and Cracking in Metals, A. Turnbull (ed.) Inst. of Materials, London, 18. 2. Report of the Paris Commission (PARCOM) on the Use and Discharge of Production and Exploration Chemicals in the North Sea Oil Industry, Paris Commission, London, 1987. 3. Schobben, P.M. et al.: CHARM: An Environment Risk Evaluation Model for Offshore E&P Chemicals, Phase 1 Report, TNO Laborato- ries for Applied Marine Research, Den Helder (Netherlands) and Aqua- team A/S (Norway) 1994. 4. Kermani, M.B.: Drill String Threaded Connections: Failure Analyses and Case Studies, Proc., 1989 Intl. Conference on Fatigue of Large Threaded Connections, W.D. Dover (ed.) Engineering Materials Advi- sory Services Ltd., London, 3556. 5. Dale, B.A.: An Experimental Investigation of Fatigue Crack Growth in Tubulars, SPEDE (Dec. 1988) 356; Trans., AIME, 285. 6. Gonzalez-Rodriguez, J.G. and Procter, R.P.M.: Environmental Cracking of AISI 4145 Steel in Drilling Muds, Advances in Corrosion and Protec- tion, R.P.M. Procter (ed.) Pergamon Press, Oxford (1993) 515520. 7. Topp, D.: The Use of Manual and Automated ACFM Technique for Sub- sea and Topside Crack Detection and Sizing, presented at the 1994 Off- shore South East Asia Conference and Exhibition, Singapore, Dec. 612. 8. Kermani, M.B. et al.: Experimental Limits of Sour Service for Tubular Steels, paper No. 21 presented at the 1991 NACE Annual Conference, Cincinnati, OH, March 1115. 9. NACE Standard MR0175-94, Sulphide Stress Cracking Resistant Me- tallic Materials for Oilfield Equipment, Natl. Assoc. of Corrosion En- gineers, Houston, 1994. 10. Kermani, M.B., Martin, J.W., and Waite, D.F.: Hydrogen Sulphide Cracking of Downhole Tubulars, Proc., SPE Annual Technical Con- ference and Exhibition, Bahrain (1991) 237246. 11. Procter, R.P.M.: Cathodic Protection Theory and PracticeThe Pres- ent Status, Coventry, Paper No. 18, Inst. of Corrosion Science and Technology, London, 1982. 12. Kermani, M.B. and Abbassian, F.: Corrosion Fatigue of Marine Struc- tural Steels in Saline Environments, Proc., 12th Intl. Corrosion Con- gress, Houston (1993) 16711691. 13. Dover, W.D. and Dharmavasan, S.: Fatigue Fracture Analysis of T and Y Joints, Proc., 14th Annual Offshore Technology Conference, Hous- ton (1992) 315319. 14. Crolet, J.L.: Which CO 2 Corrosion, Hence Which Prediction? Pre- dicting CO 2 Corrosion in the Oil and Gas Industry, M.B. Kermani and L.M. Smith (eds.), European Federation of Corrosion Series, Inst. of Materials, London (1994) 129. 15. de Waard C., Lotz U., and Dugstad A.: Influence of Liquid Velocity on CO 2 Corrosion: A Semi-Empirical Model, paper No. 128 presented at the 1995 NACE Annual Conference CORROSION 95, Orlando, FL, March 2631. 16. Salama, M.M. and Venkatesh, E.S.: Evaluation of API RP 14E Erosional Velocity Limitations for Offshore Gas Wells, paper OTC 4485 presented at the 1983 Annual Offshore Technology Conference, May 25. 17. Liaw, P.K., Saxena, A., and Schefer, J.: Predicting the Life of High Temperature Structural Components in Power Plants, J. of Metals (Feb. 1992) 4348. SI Metric Conversion Factors bar 1.0* E)05+Pa bbl 1.589 873 E*01+m 3 ft 3.048* E*01+m F (F*32)/1.8 +C in. 2.54* E)00+cm mil 2.54* E*05+m psi 6.894 757 E)00+kPa *Conversion factor is exact. SPEPF Bijan Kermani has been involved in a number of areas associated with oilfield corrosion and metallurgy since joining BP Intl. in 1985, particularly materials selection and corrosion control in exploration, production, transportation, and refinery facilities. He has held several key posts in BP, including Corrosion and Met allurgy TeamLeader at BPResearch, andis currently aSenior Ma terials Consultant at BPGroupResearchandEngineeringCentre. He worked as a Research Fellowat SINTEF Centre in Norway and then joinedtheacademicstaff of Tehran U. In 1982, he startedhis previous position as a member of the academic staff at the U. of Manchester, subsequent to which he joined BP Intl. He is a lead ing authority on oilfield corrosion and materials and has several key publications on his field of expertise related to environment sensitive cracking, materials selection, and corrosion control strategy. Bijan obtainedhis PhDin corrosionfromU. of Leeds. Don Harrop has an MS degree in chemistry from the U. of London. Af ter graduation, he spent 2 years working on corrosion of rein forced concrete before joining BP in 1977. Since then, he has worked on many research and engineering aspects of corrosion and materials related to oil and gas production/transportation and downstream refining and petrochemicals. Particular inter ests lieincorrosionpredictionandinhibition, corrosionmonitoring, materials for sour service, and electrochemical aspects of corro sion. He is currently a principal engineer at BP's Research & Engi neering center providing global consultancy to the BP Group. Kermani Harrop