Solutions Code - AC207

SECTION I
1. (b)

400 = c = 20 105 N Ba2+ + SO42 = 1 108 M2/L2

BaSO4

Ksp = s2 = 2. (c) P=

3.

(d) V = 3L T = 300 K P = 0.2 atm PV = RT

= 0.02436 Moles of NH3 = equivalents of NH3

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= 0.02436 Milliequivalents of NH3 = 1000 0.02436 = 24.36 = N 134 4. (b) = 0.18.

400 = c = 20 105 N Ba2+ + SO42 = 1 108 M2/L2

BaSO4

Ksp = s2 =

5.

(a) m= Tf = Kf m = 0.62oC Freezing Point = 0 0.32 = 0.62oC

6.

(c) Rate =

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 Ratio is 1 : 1.25.

7.

(c) CH bond in allylic position is weakest because the allylic free radical is the most stable. Bond between H and sp carbon is stronger than the bond between H and sp3 carbon. > 8 > .

8.

(b) Aqueous ethanol is a protic solvent while the DMSO is aprotic solvent. The attacking nucleophile is solvated in protic solvent and least solvated in aprotic solvent. So, in DMSO, the SN2 substitution takes place at a faster rate with higher yield.

9.

(a) In exothermic reaction, Energy of Product < Energy of reactant SECTION II

1.

C No rearrangement akes place

2. 3. 4.

a b d SECTION III

Paragraph
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1.

(a) The base present in DNA is adenine which is held with thyamine using two hydrogen bonds.

2.

(b) Adenosine is an example of nucleoside, made up of adenine (base) and ribose (sugar moiety).

3.

(c) Guanine is not a pyrimidine base. It is actually a purine base.

Paragraph 1. (d) NF3 is not hydrolysed due to lack of vacant d orbitals in N and F. PF3 & PF5 are not hydrolysed because P F bond is stronger than P O covalent bonds. Hence, NF3, PF3, and PF6 are not hydrolyzed.

2.

(d)

Electron density of N is decreased due to high electronegativity fluorine. 3. (b) The difference in electronegativities of N and F is lowest, hence NF3 is least ionic.
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The electronegativity difference between Bi and Cl is maximum. Hence, BiCl3 is most ionic. SECTION IV 1. a b c d r r p q

2.

a b c d

r q, s p q

3.

a b c d

r p s q

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