EXPERIMENT :

AIM : To preparation of glyptal resin. APPARATUS : R.B. flask, water condenser, conical flask, test tube. REQUIREMENTS : Phthalic anhydride, glycerol, R.B. flask, beaker, water condenser. PROCESS : 1. In 25 !l R.B. flask, take 15 g! of phthalic anhydride and 11 !l glycerol. 2. "ttach a water condenser to the neck of flask, reflu# the content of flask on stand bath at 1$ %1& c for 15 !in. $. "fter this period transfer the brown yellow resin in to a pre'iously weighted test tube. (. note down the weighty of glyptal resin for!ed glyptal is resin soluble in acetone. OBSERVATION : 1. weight of the glass capsule ) 2. weight of poly!er * glass capsule ) $. weight of poly!er ) CHEMICALS : 1. 2. $. (. burette + conical flask + indicator + colour change +

CALCULATIONS : "cid 'alue of poly!er ) !olecular weight of ,-. / nor!ality of ,-. / b.r. 0eight of the sa!ple

RESULT : 0eight of glyptal resin for!ed )

EXPERIMENT :
AIM : To deter!ine the acid 'alue of gi'en poly!er sa!ple 1 glyptal resin2 APPARATUS : conical flask, glass capsule, burette, pipette, water bath.

REQUIREMENT : "cetone, . 5 3 ,-. solution, poly!er sa!ple, indicator. PROCESS : 1. 2. $. (. 5. 4. &. 5. 6. weight actually about 1 g! of poly!er sa!ple in pre'iously weighted glass. transfer the capsule with poly!er in a clean conical flask. add &5 !l acetone. war! the solution of flask in water bath till co!plete dissolution of poly!er sa!ple. cool the flask at roo! te!perature add 2%$ drops of phenolphthalein indicator. titrate the content of flask as possible as respecti'ely against slandered .5 3 ,-. solution until the pink colour appear. repeat procedure till constant reading obtained. tabulate the obser'ation.

CHEMICALS : 1. weight of phthalic anhydride ) 2. 'olu!e of glycerol ) REACTION :

CALCULATION : 1. weight of the e!pty test tube ) 2. weight of poly!er with test tube ) $. weight of poly!er ) RESULT : "cid 'alue of the gi'en poly!er sa!ple 1glyptal resin2 )

EXPERIMENT :
AIM : to prepare phenol for!aldehyde resin fro! phenol 1resol2 APPARATUSE : R.B. flask, water condenser, conical flask, test tube. REQUIREMENTS : phenol, for!aline, 3.$ solution. PROCESS : 1. take a !i#ture of 1 g! of phenol and 2 !l of for!aline and 1 !l of 3.$ solution in a clean dry round botto! flask.

2. attach a water condenser to the neck of the flask, reflu# the content of the flask drectly. $. first heat slowly then strongly for $ !in. (. after the period of !i#ture a7uires red colour and beco!es 'iscous on heating 5. a ti!e will reach when the bubble will escape with difficulty fro! the surface of the solution at this ti!e stop the heating pour i!!ediately the content of flask in the weighted. 4. deter!ine the rate of resin for!ed. CHEMICALS : 1. weight of phenol ) 2. 'olu!e of for!aline ) $. 'olu!e of 3.$ solution ) REACTION :

CALCULATION : 1. weight of the test tube ) 2. weight of the resol with test tube ) $. weight of the resol ) RESULT : The weight of phenol for!aldehyde )

EXPERIMENT :
AIM : to prepare phenol for!aldehyde resin fro! phenol 1no'alac2 APPARATUSE : R.B. flask, water condenser, conical flask, test tube. REQUIREMENTS : phenol, for!alin, o#alic acid. PROCESS : 1. take a !i#ture of 1 g! of phenol and 2 !l of for!aline and .&5 g! of o#alic acid in a clean dry R.B. flask 2. attach a water condenser to the neck to the flask, reflu# the content of the flask directly on wire gauge. $. first heat slowly and then strongly for $ !in. (. after this period the !i#ture ac7uires red colour and it beca!es 'iscous on heating. 5. a ti!e will reach when the bubble will escape with difficulty fro! the surface of the solution.

4. at that ti!e stop heating and pour i!!ediately the content of flask in to pre'ious weighted test tube. &. deter!ine the weight of resin for!ed. CHEMICALS : 1. weight of the phenol ) 2. 'olu!e of for!aline ) $. weight of o#alic acid ) REACTION :

CALCULATION : 1. weight of the e!pty test tube ) 2. weight of the poly!er with test tube ) $. weight of poly!er ) RESULT : 0eight of phenol for!aldehyde resin for!ed )

89P8RI:83T + "I: + to prepare urea for!aldehyde resin fro! urea. "PP"R"T;<8 + R.B. flask, water condenser, conical flask. R8=;IR83:83T< + urea, for!aldehyde 1for!aline2, 13 3a-., 3.$, indicator. PR->8<< + 1. in a clean 25 !l R.B. flask take 15 !l of for!aline 1( ? .>.-2 solution. 2. ad@ust the P. of for!aline to &%&.5 by 1 3 3a-. solution and B.A... uni'ersal indicator. $. now add & g! of urea and 1 !l of li7uor 3.$. (. reflu# the content of the flask until first bubble of e#other!ic reaction appaears. 5. if necessary take away the oil it gently under reflu# for one hr. 4. fro! the start of e#other!ic reaction care should be taken to see that the content of the flask are against whilst the solution reflu# cooling it to roo! te!perature. &. deter!ine the weight of resin obtained. >.8:I>"B< + 1. 2. 'olu!e of for!aline ) weight of urea )

$. (. 5.

'olu!e of li7uor 3.$ ) 'olu!e of uni'ersal indictor ) 'olu!e of 3a-. )

R8">TI-3 +

>"B>;B"TI-3 + 1. weight of the e!pty test tube ) 2. weight of poly!er with test tube ) $. weight of poly!er ) R8<;BT + "!ount of urea for!aldehyde resin for!ed )

1. 89P8RI:83T + "I: + to prepare !ela!ine for!aldehyde fro! !ela!ine. "PP"R"T;<8 + R.B. flask, water condenser. R8=;IR:83T< + !ela!ine, for!aline, 1 3 3a-., li7uor 3.$, uni'ersal indicator. PR->8<< + 1. 2. $. (. 5. 4. &. 5. in a clean 25 !l R.B. flask take 15 !l for!aline solution. ad@ust the P. to &%&.5 by 1 3 3a-. C BA. uni'ersal indicator. add 1 g! !ela!ine and 1 !l of li7uor a!!onia. reflu# the content of flask unit first bubble of slightly e#other!ic reaction appears. boil it gently under reflu# for an hr. swirl the flask regularly. stop heating reaction between reaction !ass beco!es 'iscous. transfer it to pre'iously weighted test tube.

>.8:I>"B< + 1. 2. $. (. weight of !ela!ine ) weight of for!aline ) indicator ) BA. uni'ersal indicator 'olu!e of li7uor 3.$ )

R8">TI-3 +

>"B>;B"TI-3 + 1. weight of the e!pty test tube ) 2. weight of poly!er with test tube ) $. weight of poly!er ) R8<;BT + 0eight of !ela!ine for!aldehyde for!ed )

89P8RI:83T + "I: + To prepare pri!ary cellulose acetate fro! cellulose. "PP"R"T;<8 + beaker, glass rod, conical flask. R8=;IR83:83T< + >ellulose sa!ple, acetylating !i#ture 1&5 !l glacial acetic acid * 5 !l acetic anhydride * ( drops of concentared .2<-(2 PR->8<< + 1. take 5 g!s. -f cotton in 25 !l conical flask. 2. to it adds acetylating !i#ture and !i#ed it thoroughly. $. then close the conical with water glass with and heat t on water bath for either one hr. or until the cotton dissol'es co!pletely. (. now re!o'e the conical fro! te!perature and add around 2 !l of cold water to it. 5. the ppt of cellulose acetate co!es out. 4. filter it, dry it and weight it. >.8:I>"B< + 1. weight of cotton ) 2. acetylating !i#ture R8">TI-3 +

R8<;BT + 0eight of cellulose acetate collected ) 89P8RI:83T + "I: + to prepare polystyrene fro! styrene. "PP"R"T;<8 + R.B. flask, water condenser R8=;IR83:83T< + inhibitor free styrene, benDo#yl pero#ide. PR->8<< + 1. take 1 !l inhibitor free styrene in test tube. 2. add to it .15 g! benDoyl pero#ide and !aintain te!perature to 4 for $ !in. $. then raise te!perature for 45 c (. afterward rise te!perature to &5 c for $ !in. 5. finally heat to 6 c till !ass beco!es highly 'iscous. 4. transfer it to pre'iously weightedtest tube. >.8:I>"B< + 1. 'olu!e of styrene ) 2. density of styrene ) R8">TI-3 + cC keep it

>"B>;B"TI-3 + 1. weight of test tube ) 2. weight of test tube * poly!er ) $. weight of poly!er ) R8<;BT +

0eight of polystyrene for!ed )