Chemistry 1045

Exam 1 Lab Instructor

Fall 2012

Name:ffabnev\a
ID Number:

1. These tests are machine grades; therefore, be sure to use a No. 1 or 2 pencil for marking the answer sheets. Completely blacken the answer circle. If you change an answer, erase the previous mark completely. 2. Write your last name (family name) in the first box of the section marked "NAME". Skip one box and then in the next box write your first name. Example: if a student's name is John L. Doe then his answer sheet would look like this: NAME (LAST FIRST, M.I. D O E J O H N If your whole name does not fit, put as much as will fit. Then blacken the corresponding letters below each space on the answer sheet. 3. Fill in your ID number in the space provided, beginning with 00 followed by your panther ID# in space "A". Column J will remain blank. Then blacken the circles corresponding to the numbers below each space. 4. In the "Grade or Educ" section, indicate the color of the test form you were given: Mark in Grade or Educ. Test Color Stripe Color 1 VI Blue Blue V2 Gold Yellow 2 V3 3 Gray Green 4 V4 Ivory Orange V5 Pink Pink 5 V6 Brown 6 Tan Make sure that you mark in "Grade or Educ" your test color, AND that the color mark above your name on the answer sheet is the same as your test color. It is your responsibility to make sure that colors match. You also need to fill in the test color number in the vertical strip next to the name field.
G R A D E OR E D U C

5. In special Code column P, bubble in your section number, MWF 9:30 AM bubble 1 MWF 11:00 AM bubble 2 MWF 12:30 PM bubble 3 MWF 2:00 PM bubble 5 MW 6:25 PM bubble 6 6. The time limit on this test is about 1 hr 35 min. 2 hours less the administration time. 8. READ THE TEST CAREFULLY. You should find 21 questions on the exam.

CHM 1045

Formula and Constant Sheet EQUATIONS

l f t = 30.48 cm

1km = 0.6214 mi

1 atm = 760 mm Hg
1 m = 39.37 in = 1.094yds 1 mm Hg-= 1 torr

= Av

E = hv

E =b

1
nf

1
n.

1 in = 2.54 cms
1 kg = 2.205 Ibs 1 oz = 28.35 g l l b = 453.59 g

ftl

KE = l/2 mv2
NA 6.022x10 23
-34 h = 6.626*10M Js

= nAH
= 3*10 8 m/s
1*'

RH =1.097xl(T2
Cwa,er=4.184J/gC

E = - 2 . 1 8 x l O ~ 1 8 J ( l / n 2 ) 1 L.atm = 101.325 J
1 cal = 4.184 J

dRT MW = P

_ P2V2

= XSr
Vl,phere

R = 0.0821 L.atm/mol.K
q = C x AT

= f

R = 8.314J/molK lL=1.057qt 1 gallon = 3.785 L

PM RT

Pressure(P) = F/A = m*a/A PV=nRT

AE = q+ w w = - PAY q = AE+ PAY

R
where 0 = 8.85 xlO- 12 C 2 /J.m

IA

Periodic Table

8A
2

1 H
1.01

He
4.00

2A
3 4

3A
5

4A
6

5A
7

6A
8

7A
9 10

Li
6.94

Be
9.01

B
10.81

c
12.01
14

N
14.01

o
16.00
16

F
19.00

Ne
20.18

11

12

13

15 P

17

Na
22.99

Mg
24.31 , 3B
21

Al
26.98 4B
22

Si
28.09

s
32.06
34

18

Cl
35.45

Ar
39.95

30.97

SB
23

B
24

7B
25

SB
26

SB
27

SB
28

IB
29

2B
30 31 32 33 35 36

19

20

K
39.10

Ca
40.08

Sc
44.96

Ti
47.87

V
50.94

Cr
52.00

Mn
54.94

Fe
55.85

Co
58.93

Nl
58.69

Cu
63.55

Zn
65.39
;

Ga
69.72

Ge
72.61

As
74.92

Se
78.96

Br
79.90

Kr
83.80

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

S3 I

54

Rb
85.47

Sr
87.62 j

Y
88.91

Zr
91.22

Nb
92.91

Mo
95.94

Tc
(98)

Ru
101.07

Rh
102.91

Pd
106.42

Ag
107.87

Cd
112.41 '

In
114.82

Sn
118.71

Sb
121.76

Te
127.60

Xe
131.29

126.90

55

56

57

72

73

74

75

76

77

78 Pt

79

80

81

82

83

84

85

86

Cs
132.91

Ba
137.33 \8

La
138.91

Hf
178.49

Ta
180.95

w
183.84
106

Re
186.21

Os
190.23

Ir
192.22

Au
196.97

Hg
200.59

TI
204.38

Pb
207.2

Bi
208.98

Po
(209)

At
(210)

Rn
(222)

195.08

87

89

104

105

107

108

109

Fr
(223)

Ra
(226)

Ac
(227)

Rf
(261)

Db
(262)

(266)

Sg

Bh
(264)

Hs
(269)

Mt
(268)

58

59

60

61

62

63

64

65

66

67

68

69

7 0

71

Ce
140.12

Pr
140.91

Nd
144.24

Pm
(145)

Sm
150.36

Eu
151.96

Gd
157.25

Tb
158.93

Dy
162.50

Ho
164.93

Er
167.26

Tm
168.93

Yb
173.04

Lu
174.97

(atomic mass) In parentheses refers to the atomic mass of the most stable Isotope

90

91

92

93

94

95

96

97

98

99

100

101

102

103

Th
232.04

Pa
231.04

u
238.03

Np
(237)

Pu
(244)

Am
(243)

Cm
(247)

Bk
(247)

Cf
(251)

Es
(252)

Fm
(257)

Md
(258)

No
(259)

Lr
(262)

CHM 1045-All Sections

Exam IB

Fall 2012

^\t 1

Chapters 1 - 3

1. Find the mass of carbon in 1.350 L of acetone (CH^COCH^) given the density of acetone is 0.791 g/mL . i?OL x ( 000ml v
f ^^ .iiiraim "t ' -l.pnlil-l~ ^

( N 669 ^

^ ^^ ^

^^ O^\ fY\ I

1 AO\

/ ( 1 } lOO'Cs^.l^ 2. An unknown element E is found to have two isotopes. The atomic mass of E is 57.15 amu. The mass of the first isotope E - 56 is 56.482 amu, and its natural abundance is 69.19%. Calculate the mass of the second isotope of E?

V. 220.8 g D. 73.59 g E. 1068 g

^ Q?

E. 56:82amu A. B. C. ^. E. Mg,Ca,B Cu,Fe,Co Gd,Tb,Bk, Li,Fr,Rb I,F,C1

6 * 3 0 ' * l * - \ g - G H b | GUI

X^Sg,C/>

3. Which of the following lists contain only transition metals?

4. Which of the following symbols represent isotopes of nitrogen?

;.>
A. ionly B. iionly ,L iii only \~D\i and ii ^E^i and iii

. ?N

Page 1, v5

i. Hg, Pb, and Na are the symbols for mercury, lead, and sodium ii. K, S, and Mn are the symbols for potassium, sulfur, and manganese , and Ti are the symbols for antimony, silver, and tin A. ionly ^.^.ii only Qc. i and ii D. ii and iii E. i and iii 6. What is the name of the following compound Cr(CO3)3

UJ

A. ''Chromium ( III ) carbonate Chromium carbonate C. Chromium ( H ) carbonate D. Chromium ( VI ) carbonate E. Chromium ( EX ) carbonate 7. Sulfurous acid is:

E. HSO3 8. A student in CHM1045L is asked to measure out the area of the classroom and report the answer in m^. Using a measuring tape, the student found that the room is 18.8 by 15.5 ft in area. What should the student report for the area in m^? (1 in. = 2.54 cm)
,2 > *
I <? Q- t t- v ^Oi U K <T-T2 /\ I , . \ ^ O^ '

cr-r-%

9. The radius of a helium atom 3 1 .4 pm. What is the thickness in Gm?

C. 3.14xlO- 17 3.14xl0 4 E..14X10-20 A \. Which of the following statements is/are correct?

X 10

Page 2, v5

10. How many significant figures will the final answer to this calculation have? ( 935.30/2.195)+ 50

/2)i
^2
D. 4 , E. 5

T
Uat/> \ 3

vSa

H3A

11 ^ Which of the following statements is fr-e: i. Lithium and Oxygen will form an ionic bond .uorine and Phosphorus will form an ionic bond . Iodine and Calcium will form a covalent bond . )i only iionly C. iii only D. i and ii E. i,: 12. What is the correct formula for manganese(ni) sulfite? A. Mn3(SC>4)2 B. C^Mn2(S04)3 /D)/ E. 13. Which of the following statements describe a physical change? </j. Condensation of water vapor to form a liquid Sn. Freezing of liquid water into solid water \J iii. Conversion of ammonia to hydrogen and nitrogen gases A. ii only B. i,ii,&iii C. ii & iii ( D.)i and ii E. i and iii 14. The correct name for BrO2~ ig A. Bromate; Percarbonate B. Perbromate; Carbonate C^Hypobromite, Carbonite (upBromite, Carbonate i. Bromite, Hypocarbonite
and

the correct name for CC^- is

Page3,v5

15. Which one of the following samples will have the greatest mass A. B. C. D. E. 6 mol of Neon gas 4 mol of solid silicon 2 mol of Chlorine gas 3 mol of solid potassium 1 mol of Xenon gas

16. The compound dibromobis(ethylenediamine)cobalt(III) chloride has a formula of [Co(C2N2H8)2Br2]Cl< What is the mass percent hydrogen in the compound? A. B. C. D. E. 0.27 % 4.32 % 2.16% 8.63 % 0.54 %

17. When the follwoing equation is balanced properly, the coefficient indicating the number of oxygen molecules being reacted is:

02 (g) > 12 C02 (g) + i

H20 (g)

C \(p

/ (0

'

H > (0

0 50
18. A sample is found to contain 42.613 g of atomic oxygen and 170.665 g of atomic sulfur. According to the Law of Definite Proportions, which of the following would be identified as the same compound as the sample?
A. a compound containing 18.232 g oxygen and 12.179 g sulfur B. a compound containing 22.562 g oxygen and 30.120 g sulfur a compound containing 16.995 g oxygen and 8.514 g sulfur a compound containing 10.448 g oxygen and 41.844 g sulfur compound containing 12.823 g oxygen and 25.684 g sulfur

M9i'W2> <H

A flask can hold 85.66 g of water at 43.00 C. At this temperature the density of water is 0.99107 g/cm^. Calculatelhe mass of methanol that the same container would hold at 20.00 C. The density of methanol is 0.7913 g/mL at 20.00C. B. C. -D. E. g 67.18g 86.43 g 60.87 g 68.39g

o\

Page 4, v5