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ISOTHERM PWR
Flameless Pressurized Oxy-combustion Energy - with emissions close to zero Based on Trial Plant
Capacities.
Process 80,000 tonnes of waste per annum or 220 tonnes per day based on 24 hour production. (Please note that the plant may be further developed to increase capacity) Dispose of difficult materials 1) 2) 3) 4) 5) Tyres Asbestos Polythene bags Rubber Plastic
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ISOTHERM PWR
Innovative Technology In cooperation with ENEA (Italian Gov.Agency for Alternative Power Technologies)
International Patent Applications N.
WO2004/094904 WO2005/108867 WO2008/080561 WO2009/071230 WO2009/071238 WO2009/071239 Application, filing in Italy 28/07/2009
Description
METHOD AND PLANT FOR THE TREATMENT OF MATERIALS IN PARTICULAR WASTE MATERIALS AND REFUSE HIGH-EFFICIENCY COMBUSTORS WITH RECUDED ENVIRONMENTAL IMPACT AND PROCESSES FOR POWER GENERATION DERIVABLE THE REFROM PROCESS FOR THE PURIFICATION OF COMBUSTION FUMES COMBUSTION PROCESS COMBUSTION PROCESS COMBUSTION PROCESS BOILER
5 MWth Demonstration Unit is in operation since 2004 at ANSALDO Combustion Research Centre 15 MWth waste-to-energy Industrial Unit onstream at Jurong (Singapore) since 2008
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Flameless combustion
MILD, flameless, FLOX,volume comb. volume expanded - controllable
Cool Zone
High UniformTemperature
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Pressurized Reactor
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Molten slag quenched in a water bath Vitreous, Granular Zero Residual Carbon Impervious to heavy metals migration Fully inert
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vs
To maintain old fashion combustor and to match emergencies with a pletora of fumes post-treatment operation
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ISOTHERM PWR
Flameless Pressurized Oxy-combustion 5 MWth Pilot Unit - Aerial View
120 ft X 60 ft
Blower
Small Compact Simple (few unit operation) Fully automated Easy to operate
Boiler
Fumes Neutralization
Reactor
Feeding set
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Industrial Development Projects In Cooperation with Industry Leaders To Materialize NEW Competitive Commercial Solutions In each Application Segment
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1 WASTE TO ENERGY
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WASTE TO ENERGY
Wastes caloric value * kJ/kg 37,509 Oxygen consumption (kg/hr) 5,240 Steam production (t/hr) t/hr 19,810 400C - 40 bar Power consumption kW 1,800
* Minimum caloric value LHV 6,300 kJ/kg (1,500 kCal/kg)
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WASTE TO ENERGY
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WASTE TO ENERGY
GAS LIQUID GRANULAR SOLID As heavily contaminated as Cl, PCBs, Heavy Metals
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WASTE TO ENERGY
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High Temperature Noxious gas Pressurized Oxy-Combustion Complete Oxidation No smoke plume at gas stack TOC (TOTAL
AIR EMISSIONS ISOTHERM performance Environment Unique Text, L.152/2006 (Italian legislation by EU directives) 30 mg/Nm3 30 mg/Nm3 250 mg/Nm3 400 mg/Nm3 200 mg/Nm3
CO NO2 SO2
O2
NiO
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up to 6 hours
up to 6 hours
N/A
N/A
N/A
* Including energy for cryogenic Oxygen and CO2 compression * * Including ASU separation unit and CO2 compression up to 60 barg Ref. 1: MIT J. Hong et al. - Analysis of oxy-fuel combustion power cycle utilizing a pressurized coal Combustor Energy 34 (2009) 13321340 Ref. 2: DOE, NETL Pulverized Coal Oxy Combustion Power Plant - (2007) Ref.3: DOE, NETL Futuregen Project : IGCC 150 MWe demonstration unit CAPEX 1.6 B$ Ref. 4 Coal price-equalized equivalent yield
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Pulverization
Combustor
radiant
Boiler
Fabric Filter
DESOx
DENOx
Heavy ashes
Rankin Cycle
Fly ashes
Sludge
45%
55%
Fumes Post-treatment accounts already 55% of Capex and of operational complexity
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Combustor
radiant
Boiler
Fabric Filter
DESOx
DENOx
MEA
MEA (to incineration)
Heavy ashes
Rankin Cycle
Fly ashes
Sludge
45%
55%
+35%
Further addition to FUMES POST-TREATMENT from 55 to 65% of CAPEX from 44% down to 33% overall yield much longer train / complexity
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ASU
Pulverization
Combustor
radiant
Boiler
Fabric Filter
DESOx
DENOx
Heavy ashes
Rankin Cycle
Fly ashes
Sludge
Longer train in Post-treatment Question mark on CO2 Title > possible cryo-fractioning
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COMPETITOR APPROACH
to retain traditional combustion flame technology to add more post-treatment (& pretreatment) operations, to comply with new emergencies
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ASU
Combustor
Boiler
DESOx
CO2 Compression
Vitrified slag
Rankin Cycle
Sludge
Condensed water
< 75% CAPEX vs COMPETITOR 36% overall yield SIMPLE FLEXIBLE FUEL VELOX (10% to 100%) EASY TO RUN Block diagram visual assessment sometimes fools competitive analysis
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ZERO EMISSION COAL FIRED POWER Energy from Coal Airborn Emission
NO FLUE GAS !!! NO STACK !!! EFFLUENTS ARE READY FOR SUBSOIL INJECTION AND STORAGE !!!
Chemical analysis of the effluents CO NOx SOx TOC HCl PAH Dust (total) PM 2.5 Dioxin, Furans Heavy metals SOOT CO2 v (in flue gas)
Isotherm PWR < 1 mg/m3 < 100 mg/m3 < 30 mg/m3 < 0.05 mg/m3 < 0.1 mg/m3 < 0.0001 mg/m3 < 1 mg/m3 < 10 g/m3 < 0.0001 mg/m3 < 0.1 mg/m3 Zero > 93
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Energy from Coal - The Demo Unit Projection of the Mass balance for a 320 MW coal power generation Unit
Coal flow rate 130,000 kg/hr Oxygen consumption 267,000 kg/hr Net Energy production 2,560,000 MWh/y Vitrified slag flow rate up to 28,000 kg/hr
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Energy from Coal 2015 TARGET: 320 MWe COAL FIRED ZEP DEMO
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Process Core
Flexible Fuel Capability (i.e. broad spectrum of low ranking fuels) Reduced fuel pre-treatment (grinding only) capital and operating cost Global efficiency, CO2 capture included, at least comparable with more popular ZEP technology candidates Lower Capex (<75% vs competitor) core unit compactness for retrofit No ashes residues No air inlet (no CO2 dilution)
a a a a a a a a
Energy Cycle
Simplified coal logistic (water slurry) 80 times less volume, 10 times less heat turnaround losses 100% heat recovered at high energy value (605 C, 240 bar, USC steam) High combustor rangeability (from 10 to 100%) High boiler rangeability (10 to 100%) Promptness in fulfilling rapidly varying power load demand; Ease for further yield improvement (turbo expander) Ease for synergism with advanced (ceramic membrane) Oxygen separation process
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4 OIL HEAVIES
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CONTACT POINTS
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