XII Chemistry Syllabus for 2012

One Paper Time: 3 Hours 70 mars

!nit "o# Title $ars
Unit I Solid State 4
Unit II Solutions 5
Unit III Electrochemistry 5
Unit IV Chemical Kinetics 5
Unit V Surface Chemistry 4
Unit VI General Principles and Processes of Isolation of Elements 3
Unit VII p -loc! Elements "
Unit VIII d -and f -loc! Elements 5
Unit I# Coordination Compounds 3
Unit # $aloal!anes and $aloarenes 4
Unit #I %lcohols& Phenols and Ethers 4
Unit #II %ldehydes& Ketons and Car'o(ylic %cids )
Unit #III *r+anic Compounds containin+ ,itro+en 4
Unit #IV iomolecules 4
Unit #V Polymers 3
Unit #VI Chemistry in E-eryday .ife 3
Total: 70
!nit I: Soli% State &Perio%s 12'
Classification of solids 'ased on different 'indin+ forces/ molecular& ionic& co-alent and metallic solids&
amorphous and crystalline solids 0elementary idea1& Crystal .attices and unit cells& calculation of
density of unit cell& pac!in+ in solids& -oids& num'er of atoms per unit cell in a cu'ic unit cell& point
defects& electrical and ma+netic properties2
!nit II: Solutions &Perio%s 12'
3ypes of solutions& e(pression of concentration of solutions of solids in li4uids& solu'ility of +ases in
li4uids& solid solutions& colli+ati-e properties - relati-e lo5erin+ of -apour pressure& ele-ation of
'oilin+ point& depression of free6in+ point& osmotic pressure& determination of molecular masses usin+
colli+ati-e properties& a'normal molecular mass2
!nit III: (le)tro)hemistry &Perio%s 1*'
7edo( reactions& conductance in electrolytic solutions& specific and molar conducti-ity& -ariations of
conducti-ity 5ith concentration& Kohlrausch8s .a5& electrolysis and la5 of electrolysis 0elementary
idea1& dry cell -electrolytic cells and Gal-anic cells& lead accumulator& E9: of a cell& standard electrode
potential& ,ernst e4uation and its application to chemical cells& fuel cells2
!nit I+: Chemi)al ,ineti)s &Perio%s 12'
7ate of a reaction 0%-era+e and instantaneous1& factors affectin+ rate of reaction/ concentration&
temperature& catalyst order and molecularity of a reaction& rate la5 and specific rate constant& inte+rated
rate e4uation and half life 0only for 6ero and first order reactions1& collision theory 0elementary idea& no
mathematical treatment12

!nit +: Surfa)e Chemistry &Perio%s -'

%dsorption - physisorption and chemisorption& factors affectin+ adsorption of +ases on solids& colloids
distinction 'et5een true solutions& colloids and suspension; lyophilic & lyopho'ic multimolecular and
macromolecular colloids; properties of colloids; 3yndall effect& ro5nian mo-ement& electrophoresis&
coa+ulation& emulsion - types of emulsions2
!nit +I : .eneral Prin)iples an% Pro)esses of Isolation of (lements &Perio%s -'
Principles and methods of e(traction - concentration& o(idation& reduction - electrolytic method and
refinin+; occurrence and principles of e(traction of aluminium& copper& 6inc and iron2
!nit +II: p /0lo) (lements &Perio%s 1*'
.roup /11 (lements: General introduction& electronic confi+uration& occurrence& o(idation states&
trends in physical and chemical properties; nitro+en preparation properties < uses ; compounds of
nitro+en& preparation and properties of ammonia and nitric acid& o(ides of nitro+en 0Structure only1 ;
Phosphorus - allotropic forms& compounds of phosphorus/ preparation and properties of phosphine&
halides PC3 & PC5 and o(oacids 0elementary idea only12
.roup 12 (lements: General introduction& electronic confi+uration& o(idation states& occurrence&
trends in physical and chemical properties&dio(y+en/ Preparation& Properties and uses& classification of
o(ides& *6one& Sulphure -allotropic forms; compounds of sulphure/ Preparation properties and uses of
sulphur-dio(ide& sulphuric acid/ industrial process of manufacture& properties and uses; o(oacids of
sulphur 0Structures only12
.roup 17 (lements: General introduction& electronic confi+uration& o(idation states& occurrence&
trends in physical and chemical properties; compounds of halo+ens& Preparation properties and uses of
chlorine and hydrochloric acid& interhalo+en compounds& o(oacids of halo+ens 0structures only12
.roup 1- (lements: General introduction& electronic confi+uration& occurrence& trends in physical and
chemical properties& uses2
!nit +III: d an% f 0lo) (lements &Perio%s 1*'
General introduction& electronic confi+uration& occurrence and characteristics of transition metals&
+eneral trends in properties of the first ro5 transition metals - metallic character& ioni6ation enthalpy&
o(idation states& ionic radii& colour& catalytic property& ma+netic properties& interstitial compounds&
alloy formation& preparation and properties of K=Cr=*> and K9n*42
3anthanoi%s / Electronic confi+uration& o(idation states and lanthanoid contraction2
4)tinoi%s / Electronic confi+uration& o(idation states2
!nit IX: Coor%ination Compoun%s &Perio%s 12'
Coordination compounds - Introduction& li+ands& coordination num'er& colour& ma+netic properties and
shapes& IUP%C nomenclature of mononuclear coordination compounds2 ondin+& ?erner8s theory&
V3& and C:3; structure and stereo isomerism& importance of coordination compounds 0in 4ualitati-e
inclusion& e(traction of metals and 'iolo+ical system12
!nit X : Haloalanes an% Haloarenes# &Perio%s 12'
Haloalanes: ,omenclature& nature of C -# 'ond& physical and chemical properties& mechanism of
su'stitution reactions2

Haloarenes: ,ature of C -# 'ond& su'stitution reactions 0@irecti-e influence of halo+en in

monosu'stituted compounds only1
Uses and en-ironmental effects of - trichloromethane& tetrachloromethane& iodoform2
!nit XI: 4l)ohols5 Phenols an% (thers &Perio%s 12'
4l)ohols: ,omenclature& methods of preparation& physical and chemical properties0 of primary
alcohols only1& identification of primary& secondary and tertiary alcohols& mechanism of dehydration&
uses 5ith special reference to methanol and ethanol2
Phenols: ,omenclature& methods of preparation& physical and chemical properties& acidic nature of
phenol& electrophillic su'stitution reactions& uses of phenols2
(thers: ,omenclature& methods of preparation& physical and chemical properties& uses2
!nit XII: 4l%ehy%es5 ,etones an% Carbo6yli) 4)i%s &Perio%s 12'
4l%ehy%es an% ,etones: ,omenclature& nature of car'onyl +roup& methods of preparation& physical
and chemical properties& mechanism of nucleophillic addition& reacti-ity of alpha hydro+en in
aldehydes/ uses2
Carbo6yli) 4)i%s: ,omenclature& acidic nature& methods of preparation& physical and chemical
properties; uses2
!nitXIII: Or7ani) )ompoun%s )ontainin7 "itro7en &Perio%s 10'
4mines: ,omenclature& classification& structure& methods of preparation& physical and chemical
properties& uses& identification of primary& secondary and tertiary amines2
Cyani%es an% Iso)yani%es / 5ill 'e mentioned at rele-ant places in conte(t2
8ia9onium salts: Preparation& chemical reactions and importance in synthetic or+anic chemistry2
!nit XI+: 0iomole)ules &Perio%s 12'
Carbohy%rates / Classification 0aldoses and !etoses1& monosaccahrides 0+lucose and fructose1&
oli+osaccharides 0sucrose& lactose& maltose1& importance2
Proteins /Elementary idea of A - amino acids& peptide 'ond& polypeptides& proteins& structure
of proteins - primary&s econdary& tertiary structure and 4uaternary structures 04ualitati-e idea
only1& denaturation of proteins2
+itamins / Classification and functions2
"u)lei) 4)i%s: @,% and 7,%2
!nit X+: Polymers &Perio%s -'
Classifi)ation / natural and synthetic& methods of polymeri6ation 0addition and condensation1&
copolymeri6ation& some important polymers/ natural and synthetic li!e polythene& nylon polyesters&
'a!elite& ru''er2

!nit X+I: Chemistry in (:ery%ay life &Perio%s -'

Chemi)als in me%i)ines / anal+esics& tran4uili6ers antiseptics& disinfectants& antimicro'ials&
antifertility dru+s& anti'iotics& antacids& antihistamines2
Chemi)als in foo% / preser-ations& artificial s5eetenin+ a+ents2
Cleansin7 a7ents/ soaps and deter+ents& cleansin+ action2
Pra)ti)als
(:aluation S)heme for (6amination $ars
Volumetric %nalysis BC
Salt %nalysis )
Content ased E(periment 4
Class record and -i-a 5
In-esti+atory ProDect 5
Total 30
P;4CTIC43 S<3340!S
4# Surfa)e Chemistry &Perio%s 2'
0a1 Preparation of one lyophilic and one lyopho'ic sol
.yophilic sol - starch& e++ al'umin and +um
.yopho'ic sol - aluminium hydro(ide& ferric hydro(ide& arsenous sulphide2
0'1 Study of the role of emulsifyin+ a+ents in sta'ili6in+ the emulsion of different oils2
0# Chemi)al ,ineti)s &Perio%s *'
0a1 Effect of concentration and temperature on the rate of reaction 'et5een sodium thiosulphate and
hydrochloric acid2
0'1 Study of reaction rates of any one of the follo5in+/
0i1 7eaction of iodide ion 5ith hydro+en pero(ide at room temperature usin+ different concentration of
iodide ions2
0ii1 7eaction 'et5een potassium iodate& 0KI*31 and sodium sulphite/ 0,a=S*31 usin+ starch solution
as indicator 0cloc! reaction12
C# (le)tro)hemistry &Perio%s 2'
Variation of cell potential in EnFEn=GHH Cu=GFCu 5ith chan+e in concentration of electrolytes 0CuS*4 or
EnS*41 at room temperature2
(# Chromato7raphy &Perio%s 2'
i1 Separation of pi+ments from e(tracts of lea-es and flo5ers 'y paper chromato+raphy and
determination of 7f -alues2
ii1 Separation of constituents present in an inor+anic mi(ture containin+ t5o cations only 0constituents
ha-in+ lar+e difference in 7f -alues to 'e pro-ided12
=# Preparation of Inor7ani) Compoun%s
i1 Preparation of dou'le salt of ferrous ammonium sulphate or potash alum2
ii1 Preparation of potassium ferric o(alate2
.# Preparation of Or7ani) Compoun%s &Perio%s *'
Preparation of any t5o of the follo5in+ compounds
i1 %cetanilide
ii1 @i -'en6al acetone

iii1 p-,itroacetanilide
i-1 %niline yello5 or = - ,aphthol aniline dye2
-1 lodoform2
H# Tests for the fun)tional 7roups present in or7ani) )ompoun%s: &Perio%s 2'
Unsaturation& alcoholic& phenolic& aldehydic& !eton& car'o(ylic and amino 0Primary1 +roups2
I# Chara)teristi) tests of )arbohy%rates5 fats an% proteins in pure samples an% their %ete)tion in
7i:en foo% stuffs# &Perio%s *'
># 8etermination of )on)entration? molarity of ,$nO* solution by titratin7 it a7ainst
a stan%ar% solution of: &Perio%s -'
i1 *(alic acid&
ii1 :errous ammonium sulphate
0Students 5ill 'e re4uired to prepare standard solutions 'y 5ei+hin+ themsel-es12
,# @ualitati:e analysis &Perio%s 1*'
@etermination of one cation and one anion in a +i-en salt2
0,ote/ Insolu'le salts e(cluded1
P;O>(CT
Scientific in-esti+ations in-ol-in+ la'oratory testin+ and collectin+ information from other sources2
4 feA su77este% ProBe)ts#
Study of the presence of o(alate ions in +ua-a fruit at different sta+es of ripenin+2
I Study of 4uantity of casein present in different samples of mil!2
I Preparation of soy'ean mil! and its comparison 5ith the natural mil! 5ith respect to curd
formation& effect of temperature& etc2
I Study of the effect of potassium 'isulphate as food preser-ati-e under -arious conditions
0temperature& concentration& time etc21
I Study of di+estion of starch 'y sali-ary amylase and effect of p$ and temperature on it2
BC>
I Comparati-e study of the rate of fermentation of follo5in+ materials/ 5heat flour& +ram
flour& potato Duice& carrot Duice etc2
I E(traction of essential oils present in Saunf 0aniseed1& %D5ain 0carum1& Illaichi 0cardamom12
I Study of common food adulterants in fat& oil& 'utter& su+ar& turmeric po5er& chilli po5der
and pepper2
"ote: 4ny in:esti7atory proBe)t5 Ahi)h in:ol:es about 10 perio%s of Aor5 )an be )hosen Aith the
appro:al of the tea)her#
Recommended Textbooks.
B2 Chemistry Part -I& Pu'lished 'y ,CE73&=CC>
=2 Chemistry Part -II& Pu'lished 'y ,CE73& =CC>