Académique Documents
Professionnel Documents
Culture Documents
C 6 H 12 O 6
2 C H 3C H 2 O H + 2 C O 2
Y east enzym es
Alkane Alkanol
+ -
[H 3 O ][R O ] -1
K a = K [H 2 O ] = m ol L , and pK a = -log K a
[R O H ]
Alcohols are acidic compared to alkanes and haloalkanes because
the electronegative oxygen atom is able to stabilize the negative
charge of the alkoxide ion.
To drive the alcohol/alkoxide equilibrium towards the conjugate
base, a base stronger than alkoxide must be used to remove the
proton:
Reaction with
formaldehyde
produces a
primary
alcohol.
Aldehydes other than formaldehyde form secondary alcohols.