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In this report, we compare and contrast the properties of the two major

material forms used in compression molding of modern Fiber Reinforced Plastic


(FRP) products. Compression molding of FRP in matched metal dies is the
most cost effective method of producing high value composites in production
volumes from thousands to millions of pieces annually. This process has
the best combination of cost, quality and properties of all composite
forming methods. The two major material forms are Liquid Composite
Molding (LCM) and Sheet Molding Compound (SMC). Both forms take
advantage of the benefits of FRP including; corrosion resistance, high strength
to weight ratio, dimensional stability, parts consolidation, dielectric strength,
minimal finishing, high repeatability, low tooling costs, and design flexibility.

The principal difference between LCM and SMC compression molding is


whether or not the fiber reinforcement moves, or flows, as the mold closes to
form the part. LCM uses a variety of preformed fiber reinforcements that
are positively placed in the mold exactly where they need to be in the
final molded part. A measured charge of liquid resin paste is placed on a
portion of the reinforcement and a controlled closure of the press flows
the paste throughout the stationary reinforcement to fill the mold. In contrast,
SMC is a leather-like, pre-manufactured sheet combining fiber reinforcement
and paste that is cut and stacked to cover a portion of the mold. The
controlled closure of the press flows the compound (fiber reinforcement as
well as paste) to fill the mold cavity. In other words, the LCM process flows
the resin through stationary reinforcing fibers to fill the mold cavity and the
SMC process flows both resin and reinforcing fibers to fill the mold cavity.
Table 1 (page 2) summarizes the material and processing properties that
are similar in LCM and SMC.
Table 2 (page 3) summarizes the material and processing properties that
are significantly different in LCM compared to SMC.

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Table 1. Properties that are similar in LCM and SMC
LIQUID COMPOSITE SHEET MOLDING
PROPERTY
MOLDING (LCM) COMPOUND (SMC)
Raw Materials Resin, Reinforcing Fibers, Fillers, Additives
Fiber Content (by weight) 10-75%
Strength (Average tensile and flexural) Varies the same with formulation
Dimensional Control Excellent
Hardness 40 Barcol
Surface Quality
•Orange Peel Class A
•Paintability Very Good
•Bond/IMC Adhesion Excellent
Part Details
•Texture Yes
•Thickness 0.03 inch up to several inches
Process
•Cycle Time Nominal less than 3 minutes but depends on part geometry
•Net Shape Yes
Tooling
•Tool Steel Core and Cavity Yes
•Stops and Heel Plates Yes
•Integral Heating Yes
•Telescopic Shear Edges Yes
•Ejectors Yes

The thermosetting resin gives these a composite with isotropic fiber


materials good stiffness and high orientation, a composite with all its
temperature retention of mechanical fibers aligned in one direction will
The raw materials of LCM and properties. Thus, much of the growth have over three times the strength
SMC are primarily thermosetting in use of SMC and LCM is in metals in the direction of orientation but
resin, fiber reinforcement and replacement. A useful design analogy only one third the strength at 90˚
inorganic fillers such as calcium to metal forming is that LCM is to that direction. From a design
carbonate or clay. They typically more like sheet metal and SMC is standpoint, a common misapplication
account for 95% of the weight of more like a casting. One of the is to assume isotropic laminates in
the composite, the balance being unique features of both SMC and vectorless stress fields. This
release agents, curatives, pigments LCM is low profile technology, simplification is appropriate for
and other functional additives. The which allows the molded part to metals design but leads to both
relative amounts of the ingredients have exactly the same dimensions non-optimized composite designs
can be the same for SMC and LCM as the room temperature steel molds. and to unexpected failures. Composites
resulting in identical physical properties are optimally used in designs that
This amazing property not only
such as density, hardness and orient reinforcement strengths to
yields excellent dimensional control,
flammability. A useful feature of the loads.
it results in large panels as smooth
these composites is the ability to as the best sheet metals. Regardless of the choice between
tailor the properties to specific LCM and SMC, both materials
uses. For example, flammability Fiber content is easily measured
provide extreme design flexibility.
and smoke characteristics can be and indicative of strength and The designer can specify combinations
adjusted to meet strict codes for toughness. Therefore it is commonly
of physical and chemical properties
mass transit interiors; electrical specified. Although usually reported as
as well as part configurations that
resistance can be adjusted from ohms “weight percent”, it is the volume are not possible with any other
(dissipative) to 1012 ohms (insulating); fraction of fiber that provides strength.
material system.
and mechanical stiffness is adjustable The orientation of the fiber is also
from flexible to rigid. critical to strength. As compared to

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Table 2. Properties that are different in LCM and SMC
LIQUID COMPOSITE SHEET MOLDING
PROPERTY
MOLDING (LCM) COMPOUND (SMC)
Strength
•Minimum Value Higher
•Standard Deviation Lower
Local Tailoring Yes Limited
Density Can be Lower Low-side limited by minimum
required filler content.
Toughness (Impact and Hot Strength) Better Good
Surface Quality (Waviness) Better Good
Part Details
•Ribs No Yes
•Bosses Limited Yes
•Molded - in hardware Yes Limited
•Molded - in studs No Yes
•Molded - in cores Yes Limited
•Thickness Limited Yes
Process (Required Molding Pressure) 100-500 psig 700-1,000 psig

Fiber Length. in SMC laminate is more difficult to


The most common fibers are E-glass predict and control. Because the fiber
Fiber Reinforcement. rovings chopped to a length (or flows with the resin, the fibers tend to
LCM laminate fiber content can be blend of lengths) from _” to 4”. orient themselves in the direction of
routinely varied from about 15% to There is a relationship between flow. This phenomenon can be
50% by weight with random fibers fiber length and strength – longer is controlled to some extent by charge
and up to 75% by weight with stronger. For polyester resins the size and location but this practice
oriented fibers. The fiber content strength curve is asymptotic at generally causes performance trade-offs
and orientation throughout the about one inch. Since longer fibers with other laminate properties.
LCM part can vary as required by do not flow as well, most SMC
the application because the fiber fibers are one inch long. LCM Ribs and Bosses.
reinforcement is pre-placed in the fibers are often longer because it Because of the difficulty of
mold and does not move during the improves the integrity and the pre-forming glass fibers to details
molding operation. Standard SMC permeability of the mat. Some such as ribs and bosses, LCM is
will contain between about 10% types of impact performance and limited to generally uniform cross
and 50% fiber by weight with toughness are improved by the section shapes. The pre-combined
special formulations containing up longer fibers. Both SMC and LCM fibers in SMC on the other hand
to 75% fiber by weight. Fiber can incorporate continuous fibers if flow easily to conform to many
content throughout the SMC part is required. Because the fibers do not complex shapes.
very consistent as a result of the flow, LCM can also incorporate
compounding process and the fabrics and non-woven reinforcements. Material Density.
coupled flow of resin and fiber In order to properly flow during the
during molding. For the same reason, Fiber Orientation. molding process, SMC must have at
fiber content throughout the SMC least a given proportion of mineral
The orientation of reinforcing fiber
part cannot be tailored or optimized to in the LCM laminate is determined filler. This restricts the density or
meet application requirements. by its positive placement in the mold specific gravity of SMC on the low
Fiber orientation in SMC is greatly end. LCM does not have such a
cavity. Since the LCM reinforcement
influenced by compound flow as does not move during mold closure, restriction and therefore given identical
the mold closes and is therefore more the fiber orientation is highly tailored part thickness, LCM can produce a
difficult to control. lower density part.
and predictable. The fiber orientation

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Part Weight. averaged and plotted in boxplots same, the variation in flexural
Under the same design stress and frequency histograms as strength is much greater in SMC
conditions, LCM can produce a Figures 1 through 6. than in LCM. In fact, 6 of 14 SMC
lighter weight part compared to SMC. sample areas had average flexural
This is the result of more consistent •Flexural Strength. strength below the lowest performing
strength, higher impact toughness and Figure 1 is a pair of boxplots areas in the LCM part.
the flexibility to design with lower comparing the flexural strength of
density laminates. See Material LCM and SMC samples. Flexural •Tensile Strength.
Density and Mechanical Properties Strength describes the amount of
sections for further discussion. force required to bend and break Figures 2, 5 and 6 show results of
the material when a specific thickness the tensile strength testing on the
Mechanical Properties. test piece is bent. A test piece is LCM and SMC parts. Tensile
supported at both ends, a force is strength describes the amount of
LCM creates composite structures force (tensile stress) required to
that provide higher design strength applied to a small, concentrated
area in the center and the force and break a sample of specific dimensions
allowables than similar laminates when the material is stretched to its
made from SMC. Since 1974, the amount of bending is measured.
Results are reported in pounds per breaking point. The tensile stress at
Molded Fiber Glass Companies
square inch (psi). See ASTM D790 failure is divided by the cross-sectional
(MFG) has periodically compared area of the sample and results are
its modern LCM processes with for specifics.
reported in pounds per square inch
state-of-the-art SMC formulations.
The horizontal line near the center (psi). See ASTM D638 for details.
Recently, MFG completed its latest of each plot shows the sample The tensile strength comparison
test runs on nearly 500 samples mean, or average flexural strength. results are similar to the flexural
taken from truck hoods that were The box areas above and below the strength in that the average tensile
compression molded using the two mean line each represent one strength of the two forms is about
forms. The current samples were quartile or 25% of the data the same but the variation in the
taken from two current model truck samples. The whiskers above and LCM parts is much lower than the
hoods – one a three-piece hood of below the boxed area each represent SMC parts. One particularly
SMC, the other a one-piece hood the remaining quartiles. The figure important result in the tensile
of LCM. The LCM hood had an clearly shows that although the strength test is that the highest
average glass content of about 20% average flexural strength of the two frequency (or mode) of SMC
by weight and the SMC hood was forms is about the same, the LCM strength samples is at the lowest
slightly higher at about 25% glass form produces much less variation end of the scale whereas the mode
content by weight. than the SMC form. A closer look of LCM strength samples is above
shows that as many as 35% of the the average strength.
Similar sample maps were devel- SMC samples have flexural strength
oped for each hood with specimens below the weakest LCM samples. Although the current testing shows
oriented in various important that some areas of SMC can have
directions (longitudinal, cross-car, Figures 3 and 4 are the flexural very high strength compared to
vertical and horizontal). ASTM strength frequency histograms for LCM, it is the low end of the
D638 tensile and D790 flexural the LCM and SMC samples. These variation that causes parts to fail.
strength tests were performed on histograms show that although the In both the design process and end
the samples. Results for samples average strength of both the LCM use, when any area of laminate is
from each area of the hoods were and SMC samples are about the subjected to stress, it is the weaker

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locations that fail, similar to the x Drop Height) and the height LCM paste is very low compared
weak links in a chain. The more where penetration of the dart into with that of SMC and no reinforc-
consistent, controllable and predictable the material occurs. ing fibers are displaced in LCM, as
properties of the resulting laminate they are in SMC. In practice, this
make LCM the process of choice The LCM laminate performs about allows compression molding of
when flexural and tensile strengths 25% better than SMC in the energy larger parts in LCM than in SMC
are important. absorbed in this test. Also, penetration for a given press tonnage and within
occurs in the SMC at the 24 inch the plate size limits of the press.
•Impact Strength. drop height while the LCM required
Figure 7 is a comparison of impact a drop height of 45 inches for
strength, or toughness, of LCM and penetration to start.
SMC laminates as measured using
the Dynatup testing method. This Molding Pressure.
method measures the reactive load The molding pressure for LCM is
produced when a weighted dart is usually a fraction of that required
dropped onto the laminate surface for SMC. Therefore, the press
from a controlled height. The tonnage required is less for LCM
important performance measurements than for SMC for a given part area.
are the energy absorbed (Max Load This is because the viscosity of the

SMC Manufacturing Equipment Robotic Preform Equipment

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Figure 1 Flexural Strength (FS) Comparison Boxplots
Liquid Composite Molding (LCM) and Sheet Molding Compound (SMC) produce laminates
with the same average flexural strength. However, the variation in strength at random orientations
throughout the part is much less in LCM than in SMC. Glass content is 20% by weight
for LCM samples and 25% for SMC samples.

Figure 2 Tensile Strength (TS) Comparison Boxplots


Liquid Composite Molding (LCM) and Sheet Molding Compound (SMC) produce laminates
with the same average tensile strength. However, the variation in strength at random orientations
throughout the part is much less in LCM than in SMC. Glass content is 20% by weight
for LCM samples and 25% for SMC samples

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Figure 3 Liquid Composite Molding (LCM) Flexural Strength (FS) Histogram
Distribution of Flexural Strength test results for samples taken from a truck hood molded
in the Liquid Composite Molding (LCM) form. Variation is low with a minimum sample
flexural strength of about 21,000 psi. Glass content is about 20% by weight.

Figure 4 Sheet Molding Compound (SMC) Flexural Strength (FS) Histogram


Distribution of Flexural Strength test results for samples taken from a truck hood molded
in the Sheet Molding Compound (SMC) form. Variation is higher with a minimum sample flexural
strength down to about 15,000 psi. Glass content is about 25% by weight.

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Figure 5 Liquid Composite Molding (LCM) Tensile Strength (TS) Histogram
Distribution of Tensile Strength test results for samples taken from a truck hood molded
in the Liquid Composite Molding (LCM) form. Variation is low with a minimum sample
tensile strength of about 6000 psi. Glass content is about 20% by weight.

Figure 6 Sheet Molding Compound (SMC) Tensile Strength (TS) Histogram


Distribution of Tensile Strength test results for samples taken from a truck hood molded
in the Sheet Molding Compound (SMC) form. Variation is higher with a minimum
sample tensile strength of about 6000 psi. Glass content is about 25% by weight.

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Figure 7 Impact Strength Comparison of Liquid Composite Molding (LCM) and
Sheet Molding Compound (SMC)
Liquid Composite Molding (LCM) laminate demonstrates higher impact strength than sheet
Molding Compound (SMC) laminate. Dart penetration begins at nearly 50% higher level for
LCM compared to SMC.

The current study compares and high quality products and provides Because of the versatility of FRP/
contrasts the properties of Fiber extreme design flexibility. The designer Composites, the designer is encouraged
Reinforced Plastic (FRP) composites can specify combinations of physical to collaborate with a molder and/or
produced from Liquid Composite and chemical properties as well as part material supplier to optimize
Molding (LCM) and Sheet Molding configurations that are not possible the application.
Compound (SMC). Careful selection with any other material systems.
and application of either form yields

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