Christian Ruiz CHEM102 Possible Quiz 6 (Chapters 15 & 16) Questions 1.

In the titration of hydrofluoric acid (HF) with sodium hydroxide (NaOH) the resulting 2.56 millimoles of conjugate base and 16.2 millimoles of acid gave a pH of 2.34. Find the Ka of hydrofluoric acid. a. 7.2 x 10-4 b. 1.4 x 10-3 c. 1.8 x 10-5 d. 6.23 x 10-8 2. Identify the pH of the equivalence point in the titration of 0.1 M NH3 with 0.1 M HCl. a. pH < 7 b. pH = 7 c. pH > 7 3. Which of the following will form a buffer solution when equal amounts are mixed with water? a. HNO3 and NaNO3 b. NaOH and NaCl c. CH3COOH and CH3COONa d. H2SO4 and NH3

4. Which equation represents the Henderson-Hasselbach equation for the pH of a basic buffer? a. pH = pKa + log(

b. pH = 14 - pKb + log(

c. pH = pKb + log(

d. pH = 14 - pKb + log( 5. Which expression represents the Ksp of Ba(IO3)2? a. Ksp = [Ba2+]2[IO3-] b. Ksp = [Ba2+][IO3-]2 c. Ksp = [Ba2+][IO3-] d. Ksp = [Ba2+]2[IO3-]2 6. What is the pH of a solution when 20 mL of 0.1 M H2SO4 is titrated with 10 mL of 0.05 M KOH? a. 2.43 b. 1.48 c. 1.23 d. 8.68

7. How many mL of 0.03 M HCl is needed to titrate 64.5 mL of 0.004 M NaOH? a. 8.6 mL b. 9.3 mL c. 10.4 mL d. 2.3 mL

8. Identify the pH of the equivalence point in the titration of 0.1 M H3PO4 with 0.1 M Ba(OH)2. a. pH < 7 b. pH = 7 c. pH > 7 9. At which point in the titration of a weak acid with a strong base will the pH = pKa of the acid? a. the equivalence point b. 1/3 the equivalence point c. half the equivalence point d. the equivalence point 10. Given that the equilibrium Al(OH)3 (s) Al3+ (aq) + 3OH- (aq) has Ksp = 1.9 x 10-33 and [Al3+] = 9.2 x 10-12, find the [OH-] a. 2.1 x 10-22 b. 5.9 x 10-8 c. 2.4 d. 9.1 x 10-30

11. For the equilibrium reaction shown below, which change will result in a spontaneous forward reaction? 2SO2 (g) + O2 (g) 2SO3 (g) a. Adding SO3 b. Removing O2 c. Adding SO2 d. Adding a catalyst 12. Which of the following is/are false? I. II. III. Entropy increases as a substance changes state from liquid to solid. A nonspontaneous forward reaction requires an input of free energy. Adding a catalyst will disrupt the spontaneity of an equilibrium reaction.

a. I and II b. II and III c. I and III d. I only e. II only 13. Which of the following does not describe a substance at its thermodynamic standard state? a. 1 M concentration b. 10 atm pressure c. 25C d. 1 atm pressure

14. Calculate the standard free energy of formation (Gf) for water in the following reaction at 25C, given that G for the reaction is -14.41 kJ/mol, Gf for C2H4 is 68.1 kJ/mol, and Gf for CH3CH2OH is -174.9 kJ/mol: C2H4 (g)+ H2O (g) CH3CH2OH (g) a. -228.6 kJ/mol b. -390 kJ/mol c. 209.9 kJ/mol d. 51.3 kJ/mol 15. For which process is S positive in the system? a. H2O (g) H2O (s) b. 2H2 (g) + O2 (g) 2H2O (g) c. MgCl2 (s) Mg2+ (aq) + Cl- (aq) d. C4H10 (g) C4H10 (l) 16. What does the sign of a positive G, the standard free energy change, imply? a. The equilibrium concentrations predominate mainly as reactants. b. The equilibrium concentrations predominate mainly as products. c. The equilibrium concentrations are approximately equal regarding the reactants and products. 17. Calculate the standard entropy change for the formation of water, 2H2 (g) + O2 (g) 2H2O (l), given S for H2O is 69.9 J K-1 mol-1, S for H2 is 130.6 J K-1 mol-1, and S for O2 is 205.0 J K-1 mol-1. a. -400.5 J J K-1 mol-1 b. -326.4 J K-1 mol-1 c. -88.9 J K-1 mol-1 d. -325.8 J K-1 mol-1

18. Which phrase(s) do(es) not describe a system at a low temperature? I. II. III. IV. The system is at a low entropy level. The system has a high degree of molecular randomness. The molecules in the system have a low degree of molecular motion. The molecules in the system have a high degree of intermolecular bonding. a. I only b. II only c. III only d. I, III, and IV e. II and IV 19. True or false: Endothermic reactions are always nonspontaneous. a. True b. False 20. According to the second law of thermodynamics: a. The total enthalpy of a system and its surroundings always increases in a spontaneous reaction. b. The total entropy of a system and its surroundings always decreases in a spontaneous reaction. c. The total entropy of a system and its surroundings always increases in a spontaneous reaction. d. The total entropy of a system and its surroundings always increases in a nonspontaneous reaction.