2.

Section A consists of THREE stilldured questions, one from each Module. Section B consists of THREE 'xll'nded response questions, one from each Module. For Section A, write your answel'I<ill the spaces provided in this booklet. For Section B, write your answers in III- answer booklet provided.

3.

Copyright 2010 Caribbl'lIll Examinations Council All rights reserved.

(b)

Intermolecular forces ofattraction influencl.' III ph kill prop 'I,ties orsubstances, such as, their melting points, boiling points, and Illuh lit II POIIlI lInd non-polar solvents. Consider the structure of the following Nuh follow.
tllIl

o
II

H
I

II
I

II
II II

Ii

H3C-C-CH3

HC-C-('
3 I I

I I I I C-C-C-H I I I I

H (B)

Oil

I-propullill
onlll" (II rein"

II Ii H H (C') butane

(i)

Plac~ substances A, Band C in order point first).

hoiling point (lowest boiling

(ii)

Identify the intermolecular attra<.:liVl'fill'l'

in (b) (i) above.

(hund

ill

!\!\CII of the substances

(iii)

Describe the origin of TW( I Ill' the intermolecular attractive fore (b)(ii).

'N 11t1l11~tl III

(c)

Complete Table 1 by indicating wllttlt 'I' EACH of the substances, potassium bromide, acetone and solid iodine are solubl 'Ill insoluble in the two solvents, water (polar solvent) and toluene (non-polar solvent).

Substance

Water (Polar)

Toluene (Non-polar)

Potassium bromide

Acetone

Soluble

Solid iodine

Describe, solubility

IIsing FI Y I,
rrodu ,( III

l' f

('11(

l'lIl ill I sleps, an ex Iwrltl) \111 wll kh )11)) al room kl11lwrlltlll .

t'lll1

be Llsed to determine

the

(b)

The solubility

product,
dl1l ('.

K,p' at 25C

for cuklllln

Ilthon It

u 03) was found to be

5.0

10 mol2
<)

(c)

Calculate the solubility ofcalciul11lllrhonate (!<.p (i) pure water

5.0 x 10-9 moP dm--6at 2

"e) in

[3 marks] (d) What is responsible for the differen~' between the solubilities in (c) (i) and (c) (ii) above?

[1 mark] Total 15 marks

(b)

A student was provid 'd with three test tubtN. A red hot wirl.: (l:xcl.:(,;ding JOO 0c) was qllidd observations Wl.:rc 1'l:(;()I'(kd in Table 2.

JlA< '1ll'Olltlltnillg
pllll"d

one hydrogen halide. Illln cuch test tube in turn. The

Test Thbe I II III

Ilydrogcn Halide Ilydrogcl1 chloride Ilydrogl.:n bromide Ilydrogen iodide

S
(

(iii)

Using the rl.:levant information provid d in the observations recorded in Table _.

ill III

dutu booklet,

explain the trend

(c)

Concentrated sulphuric acid was car f\.lIly added to test tubes containing sodium chlorid and sodium bromide respectively.

(d)

The products of the reaction in (c) (i) above were passed into water and the resultant solution treated with AgNOiaq) followed by aqueous ammonia.

MODULE

FlINDAMENTALS IN ('IU.I\1!,TI~ ' State TH R EE filctOI H whit'll

1I fleet

the fi rst

10111 III hill

11'1

01 Ih

I m nts.

13 marks]

(i) (ii) (iii) (iv) (v) (c) Explain

Cu

02
Mn2' Fell Ca how ionization energy data provitk
I

IIIH

Inl II

II "ml tl

lib 'hells.

[3 marks]
(d) Study Figure I which shows the logarithm III III energies of an elcmcnt and answer the qUQ I Oil
1111
\

I II II

1I 'ccssive

ionisation

hh II II !low,

;;.,
b1l
I.
Q)

C
Q)

c .$2 ...
c<l

'" 'i::
.$2 .
b1l

...
<:>

6 7 8 9 10 II 11 l:l 14 15 16 17 18 19 Number ofthr IUIIIHIIIIIIII

1111 clement

Figure I. I '0J!:IO of ionisation ell('I'I~I{'N of

(i)

Write the electronic configullItiol1 of the element represented in Figurl; I. II murk

(iii)

Write a balanced

equation tn Illustrate the first ionisation of the element.

12 ma.ksl

MOI)l)LJ~ 2
KINETICS AND l';QUILIBRIA
10

Copy and complete Table. equilibrium systems.

show the type of equilibrium for the selected

System Number I 2

Equilibrium

System

Type of Equilibrium

Saturated solution or a salt at room temperature The vertical balalll'ing of a ruler on a flat surface Heating of limestolle at 800C

(ii)

State TWO characteristics Table 3.

(If

the equilibrium

represented

by System I in
L2marks]

Substances A,-B, X and Y form an quilibrium mixture represented by the equation below.

(ii)

What deduction can be made when the equilibrium constant is much greater than I? [1 mark]

(c)

When sol id bislllut Ii (III) chloride, BiCl i ulld d III produced. Thl.:s '\lI11pnullds form an cqullilll hllllllil
j

1111'1, II

hit prt;cipitate BiOCI is

pl'
~1l1I.:d by

1111 1

the equation

(i)

Explain wll tile wllile precipitate. UI()( 'I, tli IIPI III
Hel to the qllllihrilll11 mixture.

tilt

Ih IIddilion ofaqueous
12 mnrksl

(ii)

Explain wllot would he observed if' cquilibrilllll I\\I:-.t\ll\:.

II lllf/1C

olllfn 01 WlIl I

Wll,

lidded to the

13 mllrksl
(I"

(d)

Phosphorus(V) ell IllI'i(!l', 1'( 'I,. decomposl.:s represented by Ill, (1'101\(111

iiI

IIIHllortllflun quilibrium

mixture

One equilibrium of 0.20 mol dm

Inixturc III this temperutul' 'ontnin tlnd (J.() I() mol dm-J rcsp cli 1.
fI('

PCI~ und PCIJ at concentrations

Given Kc at 250 mixture.

0.19 mol dm

1,

cllh:lIIUI' III

'oncentration

ofCl2 in the [3 marks]

(i)

State the general trend in IIlomic radii in moving from left to right II On) Period 3 (from sodium to al' \Ill). 11 murk

(b)

Each element in Period 3 exhibits metallic or giant molecular.

\III

of three structures: simple molecular, gillut

(c)

Study Figure 2 which shows the vlIl'llItionin melting points across the elements in Period 3 and answer the question thai follows.

With reference to structure and bonJing, account for the variation in melting points shown in the figure. [3 marks]

Sketch tl sitwlUI

dillHllllll

to Figurt'

#c

II '11 ill Cl (I') III illustrate the variation

in

th' clcclrkul
With r'("fell' (d) (i) ab()Vt', Describe lh '

CllllUUl'tivity

of the

t'l'llH III

hi I'

lid .L

[2 marks]
in

10 'tl"Uclure, exrlll

11III

huwn on your sketch

13 marks]
I CUrllllll

which ocellI.

hI

II 1111I1'11

11111

gas.

i heuted in dry chlorine 11 mark]