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CONSEQUENCESOFMULTIPLYINGABALANCEDEQUATION BYACONSTANT IN

CHEMICALEQUILIBRIUM
FOR CAPEUNIT1STUDENTS
(AllcontenthereappliestobothKc andKp; temperaturebeingheldconstant.)
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YOUWILLLEARN
TofindKwhenabalanced equationismultipliedbyanyconstant.

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FACT
Whenabalancedequationis multipliedbyafactor,n,the equilibriumconstantisraisedtothat factor,i.e.itbecomesKn

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EXAMPLE
Thevalueoftheequilibriumconstantfor: N2 +3H2 isK. 2NH3

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EXAMPLE
Thevalueoftheequilibriumconstantfor: N2 +3H2 isK. Whatisthevalueoftheequilibriumconstantfor: 1/2N2 +3/2H2 A.K B.K/2 C.2K NH3 ? D.K2 2NH3

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SOLUTION
ForthereactionN2 +3H2 Kc =K= [NH3]2 [N2]1 [H2]3 2NH3 *Thesuperscript1is includedforclarityonly.

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SOLUTION
ForthereactionN2 +3H2 Kc =K= [NH3]2 [N2]1 [H2]3 2NH3 *Thesuperscript1is includedforclarityonly. NH3

Andforthereaction1/2N2 +3/2H2 Kc = [NH3]1 [N2]1/2 [H2]3/2

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SOLUTION
ForthereactionN2 +3H2 Kc =K= [NH3]2 [N2]1 [H2]3 2NH3 *Thesuperscript1is includedforclarityonly. NH3

Andforthereaction1/2N2 +3/2H2 Kc = [NH3]1 [N2]1/2 [H2]3/2

andyoucanseethat:Kc2 =Kc =K,soKc =K.


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EXTENDINGTHECONCEPT
Ifthecoefficientsofthechemicalequationare: 1. Doubled,thevalueofKissquared.

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EXTENDINGTHECONCEPT
Ifthecoefficientsofthechemicalequationare: 1. Doubled,thevalueofKissquared. 2. Halved,thevalueofKisreplacedbyitssquareroot.

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EXTENDINGTHECONCEPT
Ifthecoefficientsofthechemicalequationare: 1. Doubled,thevalueofKissquared. 2. Halved,thevalueofKisreplacedbyitssquareroot. 3. Multipliedbyn,thevalueofKisraisedtothenthpower.

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END
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