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Peraturan Permarkahan CHEMISTRY 4541 Kertas 1,2 dan 3 Mei 2011

BAHAGIAN PENGURUSAN SEKOLAH BERASRAMA PENUH DAN SEKOLAH KECEMERLANGAN KEMENTERIAN PELAJARAN MALAYSIA

PERATURAN PERMARKAHAN PEPERIKSAAN PERTENGAHAN TAHUN 2011 TINGKATAN LIMA

CHEMISTRY MID YEAR 2011 MARKING SCHEME

PAPER 1 PAPER 2 PAPER 3

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SKEMA KERTAS 1 CHEMISTRY 4541/1

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25

A C D D C C A A B D C A B D A C B A B A B B C B B

26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50

B C C C B B D B A B C A D D D B A C B A B B A B B

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3 MARKING SCHEME FOR CHEMISTRY PAPER 2

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1. (a)(i) Haber process (ii) H2 (iii) Temperature : 450 0C Pressure : 200 atm Catalyst : Iron (iv) Sulphuric acid (b)(i) Cl H C=C H H

Mark 1 1 1 1 1 1

1 1 1 9 marks

(ii) PVC does not rust (iii) Produces acidic / toxic gas

2 (a) (i) Diffusion (ii) CuSO4 (iii) Ion (iv) - Copper(II) sulphate is made up of tiny/discrete particles - Particles are in motion // particles move randomly - Particles move through the space in solid agar from high concentration to low concentration (b) (i) 1. Num. of mole = 120 // 0.005 24000 (ii) 1. Num. of oxygen molecules = 120 x 6.0 x 1023

1 1 1 1 1 1 1

1 1 9 Marks

24000 = 3.0 x 1021

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SULIT 3 (a) (i) R / S (ii) 2.4 / 2,4

4 1 1 1

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(b) (i) Q (ii) The atom has 8 valence electron // The atom achieve octet electron arrangement // The atom has electron arrangement 2.8 (c) T(d) S and T have 3 shells filled with electrons (e) (i) 2R + O2 2RO (ii) 1. Num. of mole of R = 4.8 // 0.2 24 2. Mass of RO = 0.2 x [ 24 + 16 ] g // 8.0 g

1 1 1 1+1 1 1 10 marks

4 (a)(i) a chemical formula that shows the simplest ratio of atom of element in a compound (ii) to dry the hydrogen gas / to absorb water vapour (iii) to avoid the oxidation of lead // to avoid the formation of lead oxide (b) (i) Lead Oxygen : (112.18 62.50) g // 49.68 g : (116.02 112.18) g // 3.84 g 1 1 1 1 1 1 1 1

(ii) 49.68 : 3.84 // 0.24 : 0.24 // 1 : 1 207 16 (iii) PbO (c) PbO + H2 Pb + H2O (d) (i) repeat the process of heating, cooling and weighing until the mass of lead is constant (d)(ii) Magnesium is more reactive than hydrogen // Magnesium is placed above hydrogen in reactivity series

1 10 marks

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SULIT 5 (a)(i) Neutralisation (ii) H2SO4 + 2KOH K2SO4 + 2H2O (iii) Pink to colourless (iv) Ma = 1 x 0.1 x 25 2 12.5 = 0.1 moldm-3

5 1 1+1 1

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1 1 1 1 1 1 1 11 marks
Answer Sub Mark Total Mark

(b) 1. 25 cm3 2. Hydrochloric acid is a monoprotic acid // sulphuric acis is a diprotic acid 3. to produce the same concentration of H+ ion // concentration of H+ ion in HCl is half. (c) P : Hydrochloric acid Q : Sulfurik acid

No. 6 (a)
H H C OH H C H H C H H

//

(b)(i) (ii) (c) (i) (ii) (iii) (d) (i)

Propyl ethanoate Sweet pleasant smell Oxidation Orange to green Acidified potassium manganate(VII) solution 1. Functional apparatus 2. Label

1 1 1 1 1 1 1

Porselain chip Glass wool Soaked in propanol Heat wate r

(ii) (e)

1,2 dibromopropane 1. Correct formulae of reactants and products 2. Balance equation 2 C3H7OH + 9 O2 6 CO2 + 8 H2O

1 1 1

TOTAL

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Sub Mark Experiment II Copper electrode become thinner Copper electrode become thicker // Brown solid deposited Copper(II) ion Cu Cu2+ + 2e

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Total Mark

No. 7 (a)

Answer Experiment I Observation at anode Observation at cathode Product at anode Half equation at anode Gas bubbles release Brown solid deposited Oxygen gas 4 OH 2 H2O + O2 + 4e
-

1 +1 1+1

1+1 1+1+1+1 10

(b)(i)

(ii)

1. Positive terminal : Copper Negative terminal : Zinc 2. Electron flow : Zinc to copper through connecting wire 1. Correct formulae of reactants and products 2. Balance equation Positive terminal : Cu2+ Cu + 2e Negative terminal : Zn Zn2+ + 2e Z, Y, X, W 1. Potential difference : 0.6 V 2. Positive terminal : Z 3. Reason : Z is more electropositive than X // Z is place higher than X in electrochemical series. TOTAL

1 1 2

(c)(i) (ii)

1+1 1+1 1 1 1 1

4 1

3 20

8 (a)(i) Both axis are labeled and with unit All points are transferred correctly Uniform scale Shape of the graph is correct (ii) 5.0 cm3 (iii) The number of moles of barium ion = 5.0 x 1.0 // 0.005 mol 1000 The number of moles of sulphate ion = 5.0 x 1.0 // 0.005 mol 1000
1 mole of suphate ion

Mark 1 1 1 1 1 1 1
1

(iv) Ba2+ + SO42- BaSO4 Formula of reactants correct Formula of product correct 4541
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SULIT (b)(i) P : Lead (II) carbonate / PbCO3 Q : Lead(II) oxide / PbO R : Carbon dioxide / CO2 Lead(II)nitrate solution

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(ii)

Test for Pb2+ Pour the solution into a test tube Add potassium iodide solution Yellow precipitate Test for NO3Add dilute sulphuric acid followed by iron(II)sulphate solution Drop/Add slowly concentrated sulphuric acid Brown ring

1 1 1

1 1 1 20 marks

9(a)(i) R Achieve octet electron arrangement // 8 valence electron (ii) 2P + Q2 2PQ Formula of reactants and product correct Balance (b) Electron arrangement for atom of element X : 2.8.1 Electron arrangement for atom of element Y : 2.6 Element X in Group 1 Because one valence electron Period 3 Three shells occupied with electrons (c)(i)In molten state , ions can move freely In solid state , ions are not freely moving// Ions are in a fixed position (ii) Sample answer : Lead (II)bromide Apparatus : Crucible ,battery ,bulb ,connecting wires , tripod stand ,Bunsen burner , carbon electrodes , pipe-clay triangle. Procedure 1. Fill a crucible with solid lead(II)bromide 2. Dip carbon electrodes into lead(II)bromide 3. Switch on / complete the circuit 4.Observe whether the bulb glows** 5. Heat the solid lead(II)bromide until it melts completely 6. Observe whether the bulb glows** ** point 4/6 (1 mark only) 4541
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1 1 1 1 1 1 1 1 1 1

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Observation
State of lead(II)bromide Solid Molten Observation on the bulb The bulb did not glow The bulb glowed brightly.

1 20 marks
No. 10(a)(i) Experiment I = 0.56 cm3s-1 Experiment II = 1.14 cm3s-1 1. Correct formulae of reactants and products 2. Balance equation Zn + 2 HCl ZnCl2 + H2 // Zn + H2SO4 ZnSO4 + H2 1. Rate of reaction in experiment II is higher 2. Concentration of H+ ion in experiment II is higher // sulphuric acid is diprotic acid and hydrochloric acid is monoprotic acid 3. Number of H+ ion perunit volume in experiment II is higher 4. Frequency of collision between zinc and H+ ion in experiment II is higher 5. Frequency of effective collision in experiment II is higher 1. Label and correct unit of both axes 2. Correct curve and label Volume of gas / cm3 1 1 1 2 1 1 1 1 1 1 1 2 1 Answer Sub Mark Total Mark

(ii)

(b)(i)

(ii)

Experiment II

Experiment I

Time / s 3. Curve in experiment II is steeper //Initial rate of reaction in experiment II is higher 4. Concentration of H+ ion in experiment II is higher 5. Maximum volume of gas in both experiment are the same 6. Number of mole of H+ ion in both experiment are the same. 1 1 1 1

6 SULIT

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(c) 1. 2. 3. 4.

9
Arrow upward, energy label and two level Correct position of reactant and product Activation energy without catalyst, Ea Activation energy with catalyst, Ea Energy 1 1 1 1

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Ea Zn + 2HCl Ea

ZnCl2 + H2

(d)

Increase temperature // Use smaller size of zinc TOTAL

1 20

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10

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MARKING SCHEME 4541/3 CHEMISTRY Paper 3 Question Rubric Able to write all the time taken accurately with one decimal places with unit. Answer: 1(a) Temperature 35.0 45.0 55.0 65.0 Time 28.5 s 20.0 s 15.0 s 12.0 s Score

Able to write any 3 readings accurately // All readings correctly but without decimal places. Able to write any 2 readings correctly. No response given / wrong response Question Rubric Able to construct a table to record the data that contain: i. Correct titles ii. Correct readings // ecf from 1(a) iii. Correct unit Sample answer: Temperature (C) Time ( s ) 1 / time ( s 1 ) 28 43.0 0.023 35 28.5 0.035 45 20.0 0.050 55 15.0 65 12.0

2 1 0 Score

1(b )

0.067 0.083

Able to construct a less accurate table that contains: i. Titles ii. Readings iii. Without unit Able to construct a table with at least one title / reading No response or wrong response

2 1 0

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11 Rubric Able to draw the graph correctly

1 / s 1 and axis y : temperature/C time ii. Consistent scale and the graph half of graph paper iii. All the points are transferred correctly iv. Straight line Able to draw the graph incorrectly

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i.

Axis x :

1(c)

2
1 and axis y : temperature// Inverse axes time ii. Consistent scale iii. About 3 points are transferred correctly iv. Straight line Able to state an idea to draw the graph

i.

Axis x :

1 i. Draw the axis x and axis y ii. Straight line No response or wrong response Question Rubric Able to state the relationship between the temperature and the rate of reaction correctly Sample answer: The higher of temperature, the higher of the rate of reaction Able to state the relationship between the temperature and the rate of reaction incorrectly 2 Sample answer: The higher the temperature, the rate of reaction faster. Able to state an idea of relationship between the temperature and the rate of reaction 1 Sample answer: Temperature affects the rate of reaction. No response or wrong response

0 Score

1(d)

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12 Rubric Able to state all the three variables correctly Sample answer: Manipulated variable : Temperature of sodium thiosulphate Responding variable : Rate of reaction Constant variable : Volume and concentration of hydrochloric acid//volume and concentration of sodium thiosulphate Able to state any two variables correctly Able to state any one variables correctly No response or wrong response Score

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1(e)

2 1 0

Question

Rubric Able to give the meaning of the rate of reaction correctly. Sample answer: 1/time for X mark no longer visible // Quantity of sulphur/ precipitate formed compared the time Able to give the meaning of the rate of reaction less accurately. Sample answer: Measure of how quickly a chemical reaction happens//The change/ increase/decrease in the amount of products/reactant per time Able to give an idea of the rate of reaction. Sample answer: Rate of formation of sulphur//time taken to form the sulphur precipitate No response given / wrong response

Score

1(f)

Question

Rubric Able to state all observations correctly. Sample answer: Test tube A B C Observation Brown solid formed// blue solution turns light blue No change // remain unchanged Brown solid formed// blue solution turns light blue

Score

2(a)

Able to state two observations correctly Able to state one observation correctly No response or wrong response

2 1 0

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SULIT Question

13 Rubric Able to state the inference correctly based on observation. Sample answer: Observation Brown solid formed Or Observation Blue solution turns light blue Inference Copper formed. Score

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Inference Concentration/ number of Cu2+ ion decreases // Concentration of copper(II) sulphate /CuSO4 decreases Able to state the inference incorrectly 2(b) Sample answer: Observation Brown solid formed Or Observation Blue solution turns light blue Inference Copper(II) ion/ Cu2+ discharged

Inference Amount of copper(II) ion/ Cu2+ decreases // Cu2+ ion /CuSO4 decreases Able to state an idea of inference Sample answer: Copper (II) sulphate solution changed. No response or wrong response Question Rubric Able to state arrange all metals correctly Sample answer: Magnesium/Mg, Metal X, Copper/Cu Able to state arrange two metals correctly Sample answer: Magnesium/Mg, Metal X // Metal X, Copper/Cu Able to state the idea of metal arrangement in ascending order. Sample answer: Copper/Cu, Metal X, Magnesium/Mg No response given/ wrong response 1 0 Score 3

2(c)

1 0

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Question

Rubric Able to predict the observation correctly Sample answer: No change // Remain unchanged // blue colour does not change Able to predict the observation incorrectly Sample answer: No reaction // No displacement Able to give an idea to predict the observation Sample answer: Silver does not change. No response given/ wrong response

Score 3

2(d)

1 0

Question

Rubric Able to classify all metals correctly Sample answer : Less electropositive Lead / Pb Iron/ Fe Tin/ Sn Able to classify three metals correctly Able to classify any two metals correctly or give opposite answers. Sample answer: More electropositive Less electropositive Lead / Pb Aluminium /Al Iron/ Fe Tin/ Sn No response or wrong response More electropositive Aluminium /Al

Score

2(e)

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Question

Rubric Able to give the problem statement of the experiment correctly Sample answer : Does an acid/glacial ethanoic acid need water to show its acidic properties? // Is water needed for an acid/ glacial ethanoic acid to show its acidic properties? Able to give the problem statement of the experiment incorrectly

Score

3(a) Sample answer : To investigate/study the role of water in showing the properties of an acid. Able to state an idea of problem statement of the experiment Sample answer : Water is needed to show the properties of acid. No response or wrong response Question Rubric Able to state All variables correctly Sample answer : Manipulated variable : Presence of water Responding variable : Acidic properties // Gas produced Constant variable : Acid // glacial ethanoic acid // magnesium r : Volume of acid Able to state any two variables correctly Able to state any one variables correctly No response or wrong response 2

1 0 Score

3(b)

2 1 0

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16 Rubric Able to give the hypothesis correctly Sample answer : Water is needed for an acid to show its acidic properties // Presence of water is essential for an acid to show its acidic properties. Able to give the hypothesis almost correct Score

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3(c)

Sample answer : Ethanoic acid/An acid shows its acidic properties when water is present //The presence of water influence the acidic properties of acid Able to state an idea of the hypothesis Sample answer : The water affect the properties of acid No response or wrong response

1 0 Score

Question

Rubric Able to give the list of the apparatus and materials correctly and completely Sample answer : Apparatus : dry test tube Material : Glacial ethanoic acid, water, magnesium ribbon, wooden splinter Able to give the list of the apparatus and materials correctly but not completely

3(d) Sample answer : Dry test tube Glacial ethanoic acid, water, magnesium ribbon Able to give an idea about the list of the apparatus and substances correctly

1 Sample answer : Test tube and any one substance No response or wrong response

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17 Rubric Able to state all procedures correctly Sample answer : 1. Glacial ethanoic acid is poured into two different dry test tube labeled A and B. 2. Distilled water is added into glacial ethanoic acid in test tube B. 3. A piece of magnesium ribbon is put into test tube A and B. 4. A lighted wooden splinter is placed at the mouth of both test tubes. 5. The observation is recorded. Able to list down steps 1, 2 and 3 Able to list down steps 1 and 3 or 2 and 3 No response or wrong response Score

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3(e)

2 1 0

Question

Rubric Able to exhibit the tabulation of data that includes the following two information correctly 1. Heading for the manipulated variable 2. Heading for the responding variable Sample answer : (Test tube) // Observation (Condition of acid) Test tube A //Glacial ethanoic acid Test tube B //Ethanoic acid solution /in water Able to exhibit the tabulation of data less accurately Tabulation of data has the following elements : 1. Heading for the manipulated variable 2. Heading for the responding variable 3. One condition of acid listed Sample answer : Acid/test tube Glacial ethanoic acid

Score

3(f)

1 Effect//Result

No response or wrong response END OF MARKING SCHEME

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