Acid Blue 25

************* MATERIAL SAFETY DATA SHEET *************
I. PRODUCT IDENTIFICATION TRADE NAME--------- ACID BLUE 7 CHEMICAL NAME-----CHEMICAL FAMILY---COLOR INDEX #-----C. A. S. #--------LAST REVISION DATE. N/A ACID DYES ACID BLUE 7 N/A 4/29/2009
II. HAZARDOUS COMPONENTS COMPONENT PERCENT ----- None III. PHYSICAL DATA BOILING POINT--N/A VAPOR PRESSURE--N/A VAPOR DENSITY---N/A VOLATILITY----- N/A FREEZE POINT--- N/A MELTING POINT---N/A IV. FIRE AND EXPLOSION DATA FLASH POINT N/A FILAMMABLE LIMITS. N/A IN CASE OF FIRE-----DRY CHEMICAL, CO2, WATER SPRAY OR REGULAR FOAM. MOVE CONTAINERS FROM FIRE AREA IF YOU CAN DO IT WITHOUT RISK. APPLY COOLING WATER TO SIDES OF CONTAINERS THAT ARE EXPOSED TO FLAMES UNTIL WELL AFTER FIRE IS OUT. SOLUB. IN WATER--SOLUBLE IN WATER ODOR--- NONE APPEARANCE--DARK POWDER SPECIFIC GRAV-- N/A EVAP. RATE--- N/A pH OF PRODUCTN/A
MATERIAL SAFETY DATA SHEET (CONTINUED) ************************** IV. FIRE AND EXPLOSION DATA (CONTINUED) FIRE-FIGHTING PROCEDURES----USE SELF-CONTAINED BREATHING APPARATUS TO PROTECT AGAINST POTENTIALLY TOXIC AND IRRITATING FUMES. FIRE AND EXPLOSION HAZARDS-----IN CASE OF FIRE OR EXPLOSION, KEEP UNNECESSARY PEOPLE AWAY. ISOLTAE HAZARD AREA AND DENY ENTRY. STAY UPWIND, OUT OF LOW AREAS, AND VENTILATE CLOSED SPACES BEFORE ENTERING.
V. REACTIVITY DATA STABILITY------- Stable. CONDITIONS TO AVOID----- NONE KNOWN. INCOMPATIBILITY. STRONG OXIDIZING AGENTS. HAZARDOUS DECOMPOSITION PRODUCTS---------BURNING WILL PRODUCE OXIDES OF CARBON, NITROGEN, AND OTHER POTENATIALLY TOXIC FUMES. HAZARDOUS POLYMERIZATION----- Will not Occur. CONDITIONS TO AVOID---NONE KNOWN.
VI. HEALTH HAZARD DATA THRESHOLD LIMIT VALUE-----NOT ESTABLISHED. MAY CAUSE EYE & SKIN IRRITATION. DUST MAY IRRITATE THE RESPIRATORY TRACT. HAZARD WARNINGS-----D. 0. T. NON-REGULATED SUBSTANCE. THIS PRODUCT IN ITS PRESENT STATE POSES NO THREAT TO HUMAN HEALTH OR THE ENVIRONMENT.
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MATERIAL SAFETY DATA SHEET (CONTINUED) ************************** VII. EMERGENCY AND FIRST AID PROCEDURES PROCEDURES: EYES: FLUSH EYES WITH WATER FOR AT LEAST 15 MINUTES. SKIN: WASH WITH MILD SOAP AND WATER. IF IRRITATION OCCURS GET MEDICAL ATTENTION. IF CLOTHING IS CONTAMINATED, RE- MOVE AND WASH BEFORE REUSE. INHALATION: REMOVE TO FRESH AIR. GET MEDICAL ATTENTION. INGESTION: IF CONSCIOUS, GIVE PLENTY OF WATER TO DRINK. GET MEDICAL ATTENTION. IF UNCONSCIOUS, DO NOT GIVE ANYTHING TO DRINK. GET IMMEDIATE MEDICAL ATTENTION.
VIII. SPECIAL PROTECTION INFORMATION RESPIRATORY. NIOSH APPROVED DUST RESPIRATOR WHEN NEEDED.
SKIN-------IMPERVIOUS GLOVES AND APPROPRIATE EQUIPMENT TO PREVENT PROBABILITY OF PERSONAL CONTACT.
EYES----SIDE-SHIELD SAFETY GLASSES.
VENTILATION----Local Exhaust. OTHER PROTECTION--- DELUGE SAFETY SHOWER AND EYE WASH STATION SHOULD BE LOCATEI NEAR WORK AREA.
MATERIAL SAFETY DATA SHEET (CONTINUED) ************************** IX. SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN:::: DO NOT TOUCH OR WALK THROUGH SPILLED MATERIAL: STOP LEAK IF YOU CAN DO IT WITHOUR RISK. TAKE UP WITH SAND OR OTHER NON-COMBUSTIBLE ABSORBENT MATERIALS AND PLACE INTO CONTAINERS FOR LATER DISPOSAL. SCRUB SPILL AREA WITH DETERGENT, FLUSH WITH COPIOUS AMOUNT OF WATER.
WASTE DISPOSAL METHOD----BURY OR INCINERATE ACCORDING TO FEDERAL, STATE AND LOCAL REGULATIONS.
CONTAINER REUSE METHOD----CONTAINERS SHOULD NOT BE REUSED WITHOUT PROFESSIONAL CLEANING AND RECONDITIONING.
X. PRECAUTION MEASURES 29 CFR 1910.1200 AND STATE RIGHT TO KNOW LAWS MAY DESIGNATE THIS PRODUCT AS A NUISANCE DUST. PLEASE REFER TO SECTION XII OF MATERIAL SAFETY DATA SHEET FOR HANDLING INSTRUCTIONS.
XI. TRANSPORTATION INFORMATION DOT HAZARD CLASS---- NON-HAZARDOUS PROPER SHIPPING NAME----NON-HAZARDOUS MATERIAL
DOT IDENTIFICATION # .. COMMODITY CLASS---- INK MATERIAL
XII. REGULATORY INFORMATION
S. A. R. A.--- NOT REPORTABLE T.S.C.A---- IN COMPLIANCE 0. S. H. A. HAZARD CLASSIFICATION: ACUTE:NO CHRONIC: NO FLAMMABLE: NO REACTIVE: NO OXIDIZER: NO HEALTH H.M.I.S. CLASSIFICATION: N.F.P.A CODES: 1 1 FLAMMABILITY 1 1 REACTIVITY 1 1 PERSONAL PROT. F N
MATERIAL SAFETY DATA SHEET (END) **************************
XIII. STATES RIGHT TO KNOW LAWS HAZARDOUS MATERIALS ** NONE*** INGREDIENTS STATE INFORMATION * * N O N E * * ***NON-HAZARDOUS MATERIALS * STATE INFORMATION:::: INGREDIENTS :::PROPRIETARY ACID DYES ::: MA. N.J, PA, CA GLAUBERS SALT 7767-86-68 MA, N.J, PA, CA XIV. OTHER INFORMATION
ALL INFORMATION AND DATA APPEARING ON THIS M. S. D. S. ARE BELIEVED TO BE RELIABLE & ACCURATE. HOWEVER, IT IS THE USER'S RESPONSIBILITY TO DETERMINE THE SAFETY, TOXICITY, AND SUITABILITY FOR HIS OWN USE OF THE PRODUCT DESCRIBED. SINCE THE ACTUAL USE BY OTHERS IS BEYOND OUR CONTROL, NO GUARANTEE, EXPRESSED OR IMPLIED, IS MADE BY KEYCOLOUR INC,, INCORPORATED.USER ASSUMES ALL RISK AND RESPONSIBILITY.
MATERIAL SAFETY DATA SHEET

-----------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION I: CHEMICAL PRODUCT AND COMPANY IDENTIFICATION -----------------------------------------------------------------------------------------------------------------------------------------------------------------TRADE NAME: AMENYL YELLOW RG CHEMICAL FAMILY: ACID YELLOW 19
EMERGENCY PHONE NUMBER:
CHEMTREC 800-424-9300
DATE PREPARED: DECEMBER 2009 ---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION II: COMPOSITION/INFORMATION ON HAZARDOUS INGREDIENTS ---------------------------------------------------------------------------------------------------------------------------------------------------------------CHEMICAL NAME CAS NUMBER %BY WT. TLV/PEL AZO DYE 12220-64-3 NOT ESTABLISHED --------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION III: HAZARDS IDENTIFICATION ---------------------------------------------------------------------------------------------------------------------------------------------------------------EMERGENCY OVERVIEW: MAY CAUSE SKIN, EYE AND RESPIRATORY IRRITATION. EFFECTS OF OVEREXPOSURE: EYE CONTACT: NONE IRRITATING. SKIN CONTACT: NONE IRRITATING. INHALATION: MAY BE IRRITATING. INGESTION: NOT KNOWN. CHRONIC EXPOSURE: NOT KNOWN. CARCINOGENICITY: NOT LISTED AS AN IARC, NTP OR OSHA CARCINOGEN. MEDICAL CONDITIONS AGGREVATED BY EXPOSURE: NOT KNOWN PRIMARY ROUTES OF ENTRY: SKIN CONTACT, EYE CONTACT AND INHALATION. ---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION IV: FIRST AID MEASURES ---------------------------------------------------------------------------------------------------------------------------------------------------------------EYE CONTACT: IMMEDIATELY FLUSH EYE WITH FLOWING WATER FOR AT LEAST 15 MINUTES, HOLDING EYELIDS APART TO IRRIGATE THOROUGHLY. GET MEDICAL ATTENTION. SKIN CONTACT: WASH THOROUGHLY WITH SOAP AND WATER. GET MEDICAL ATTENTION IF IRRITATION DEVELOPS. REMOVE AND LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. INHALATION: REMOVE TO FRESH AIR. IF BREATHING IS DIFFICULT, GIVE OXYGEN. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. GET MEDICAL ATTENTION. INGESTION: DILUTE WITH WATER AND INDUCE VOMITING. GET MEDICAL ATTENTION. NEVER GIVE FLUIDS OR INDUCE VOMITING IF PATIENT IS UNCONSCIOUS OR HAS CONVULSIONS. ---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION V: FIRE FIGHTING MEASURES ---------------------------------------------------------------------------------------------------------------------------------------------------------------FLASH POINT: NOT DETERMINED. LOWER EXPLOSIVE LIMIT: NOT APPLICABLE. UPPER EXPLOSIVE LIMIT: NOT APPLICABLE THERMAL DECOMPOSITION: 180C AUTOIGNITION TEMPERATURE: 360C EXTINGUISHING MEDIA: WATER, DRY CHEMICAL, CARBON DIOXIDE, AND FOAM. 1 MSDS 02-0002
SPECIAL FIRE FIGHTING PROCEDURES: FIREFIGHTERS SHOULD BE EQUIPPED WITH SELF CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING. UNUSUAL HAZARDS: DUST AMY BE EXPLOSIVE IF MIXED WITH AIR IN CRITICAL PROPORTIONS AND IN THE PRESENCE OF SOURCE OF IGNITION. ---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION VI: ACCIDENTAL RELEASE MEASURES ---------------------------------------------------------------------------------------------------------------------------------------------------------------STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: WEAR APPROPRIATE SAFETY EQUIPMENT. CONTAIN AND CLEAN UP SPILL IMMEDIATELY. PREVENT FROM ENTERING FLOOR DRAINS. SWEEP POWDERS CAREFULLY MINIMIZING DUSTING. SHOVEL ALL SPILL MATERIALS INTO DISPOSAL DRUMS AND FOLLOW DISPOSAL INSTRUCTIONS. SCRUB SPILL AREA WITH DETERGENT AND FLUSH WITH COPIOUS AMOUNTS OF WATER. ---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION VII: HANDLING AND STORAGE ---------------------------------------------------------------------------------------------------------------------------------------------------------------HANDLING: IN ACCORDANCE WITH GOOD INDUSTRIAL PRACTICES, HANDLE WITH CARE AND AVOID PERSONAL CONTACT. CONTAINERS SHOULD BE TRIPLE RINSED ACCORDING TO FEDERAL REGULATIONS AND/OR GOOD WASTE MANAGEMENT PRCATICES. FOR INDUSTRIAL USE ONLY. STORAGE: KEEP CONTAINERS CLOSED WHEN NOT IN USE. ---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION VIII: EXPOSURE CONTROL/PERSONAL PROTECTION ---------------------------------------------------------------------------------------------------------------------------------------------------------------ENGINEERING CONTROLS: LOCAL EXHAUST TO MINIMIZE EXPOSURE. RESPIRATORY PROTECTION: IF EXPOSURE TO DUST IS LIKELY, A NIOSH APPROVED DUST RESPIRATOR IS RECOMMENDED. EXPOSURE LIMITS: NOT ESTABLISHED. EYE PROTECTION: WEAR SAFETY GLASSES WITH SIDE SHIELDS OR SAFETY GOGGLES. SKIN PROTECTION: WEAR RUBBER GLOVES. OTHER PROTECTIVE MEASURES: WEAR APRON, COVERALLS, BOOTS AND LONG SLEEVE SHIRT TO PREVENT SKIN CONTACT. HYGIENIC PRACTICES: EYEWASH FOUNTAINS SHOULD BE EASILY ACCESSIBLE. SHOWER AFTER HANDLING THIS PRODUCT. WORK CLOTHES SHOULD BE WASHED BEFORE REUSE. BEFORE EATING, DRINKING, OR SMOKING, WASH HANDS AND FACE WITH SOAP AND WATER. ---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION IX: PHYSICAL AND CHEMICAL PROPERTIES ---------------------------------------------------------------------------------------------------------------------------------------------------------------APPEARANCE: YELLOW POWDER ODOR: NONE SOLUBILITY IN WATER: SOLUBLE BOILING POINT: NOT APPLICABLE. MELTING POINT: 100C. PH: 7.5-9.0 -------------------------------------------------------------------------------------------------------------------------------------SECTION X: STABILITY AND REACTIVITY ---------------------------------------------------------------------------------------------------------------------------------------------------------------STABILITY: STABLE. CONDITIONS TO AVOID: NONE KNOWN. HAZARDOUS POLYMERIZATION: WILL NOT OCCUR. INCOMPATIBLE MATERIALS: NONE KNOWN. 2 MSDS 02-0002
HAZARDOUS DECOMPOSITION PRODUCTS: BURNING WILL PRODUCE OXIDES OF CARBON, NITROGEN AND SULFUR. ---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION XI: TOXICOLOGICAL PROPERTIES ---------------------------------------------------------------------------------------------------------------------------------------------------------------RAT, ORAL LD50: >5000 MG/KG RABBIT, SKIN: NON IRRITANT RABBIT, EYES: NON IRRITANT. ADDITIONAL TOXICITY DATA: SKIN SENSITIZATION: NONE KNOWN ---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION XII: ECOLOGICAL INFORMATION ---------------------------------------------------------------------------------------------------------------------------------------------------------------BACTERIAL TOXICITY (IC50): BST>300 MG/L 3 HOURS FISH TOXICITY (LC0): >1000 MG/L 48 HOURS (LC50): >500 MG/L TROUT ---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION XIII: DISPOSAL CONSIDERATIONS ---------------------------------------------------------------------------------------------------------------------------------------------------------------WASTE DISPOSAL METHOD: THIS PRODUCT IS NOT TO BE CONSIDERED A HAZARDOUS WASTE UNDER RCRA (40 CFR 261).DISPOSAL MUST BE IN ACCORDANCE WITH APPLICABLE GOVERNMENTAL REGULATIONS. CONTAINER DISPOSAL INFORMATION: CONTAINERS SHOULD BE TRIPLE RINSED ACCORDING TO FEDERAL REGULATIONS AND/OR GOOD WASTE MANAGEMENT PRACTICE. ---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION XIV: TRANSPORTATION INFORMATION ---------------------------------------------------------------------------------------------------------------------------------------------------------------DOT PROPER SHIPPING NAME: NOT REGULATED. DOT TECHNICAL NAME: NOT APPLICABLE. DOT HAZARD CLASS: NOT APPLICABLE. HAZARD SUBCLASS: NOT APPLICABLE. DOT UN/NA NUMBER: NOT APPLICABLE. PACKING GROUP: NOT APPLICABLE. RESP. GUIDE PAGE: NOT APPLICABLE. DOT REPORTABLE QUANTITY: NOT APPLICABLE. DOT LABELS: NOT APPLICABLE. ---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION XV: REGULATORY INFORMATION ---------------------------------------------------------------------------------------------------------------------------------------------------------------SARA TITLE III SECTION 302: THIS PRODUCT DOES NOT CONTAIN ANY CHEMICALS REGULATED UNDER SECTION 302 AS EXTREMELY HAZARDOUS. SARA TITLE III SECTION 304 (CERCLA): THIS PRODUCT DOES NOT CONTAIN ANY CHEMICALS REGULATED UNDER SECTION 304 AS A HAZARDOUS SUBSTANCE FOR EMERGENCY RELEASE NOTIFICATION. SARA TITLE III SECTION 312 HAZARD RATING: ACUTE: NO CHRONIC: NO FLAMMABILITY: NO REACTIVITY: NO PRESSURE: NO SARA TITLE III SECTION 313: THIS PRODUCT IS NOT REPORTABLE FOR SARA 313. TSCA: THIS PRODUCT IS REGISTERED UNDER THE REGULATIONS OF THE TOXIC SUBSTANCES CONTROL ACT (TSCA). STATE RIGHT TO KNOW INFORMATION INGREDIENT ACID YELLOW 19 3 CAS NUMBER 12220-64-3 MSDS 02-0002
---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION XVI: OTHER INFORMATION ---------------------------------------------------------------------------------------------------------------------------------------------------------------HMIS RATING: HEALTH - 1 FIRE - 1 REACTIVITY - 0 PERSONAL PROTECTION - E NFPA RATING: HEALTH - 1 FIRE - 1 REACTIVITY - 0 - DISCLAIMER: KEYCOLOUR INC. BELIEVES ALL THE INFORMATION AND DATA GIVEN IS ACCURATE AS OF THE DATE OF PREPARATION AND IS OFFERED IN GOOD FAITH. THIS INFORMATION IS GIVEN WITHOUT WARRANTY OR REPRESENTATION SOLELY FOR YOUR CONSIDERATION, INVESTIGATION, AND VERIFICATION. SINCE CONDITIONS OF USE ARE BEYOND OUR CONTROL, KEYCOLOUR INC. EXPRESSLY DISCLAIMS ALL LIABILITY FOR THE USE OR HANDLING OF THIS PRODUCT. ------------------------------------------------------------------------------------------------------------------------------------------
MSDS 02-0002
MATERIAL SAFETY DATA SHEET KEYCOLOUR INC.

-----------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION I: CHEMICAL PRODUCT AND COMPANY IDENTIFICATION -----------------------------------------------------------------------------------------------------------------------------------------------------------------TRADE NAME: AMENYL BLUE SW CRUDE CHEMICAL FAMILY: ACID BLUE 25
CHEMTREC 800-424-9300
DATE PREPARED: DECEMBER 2009 ---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION II: COMPOSITION/INFORMATION ON HAZARDOUS INGREDIENTS CHEMICAL NAME CAS NUMBER % BY WT. TLV/PEL ANTHRAQUINONE 6408-78-2 80% NOT ESTABLISHED --------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION III: HAZARDS IDENTIFICATION ---------------------------------------------------------------------------------------------------------------------------------------------------------------EMERGENCY OVERVIEW: MAY CAUSE SKIN, EYE AND RESPIRATORY IRRITATION. EFFECTS OF OVEREXPOSURE: EYE CONTACT: MAY BE IRRITATING. SKIN CONTACT: MAY BE IRRITATING. INHALATION: MAY BE IRRITATING. INGESTION: NOT KNOWN. CHRONIC EXPOSURE: NOT KNOWN. CARCINOGENICITY: NOT LISTED AS AN IARC, NTP OR OSHA CARCINOGEN. MEDICAL CONDITIONS AGGREVATED BY EXPOSURE: NOT KNOWN PRIMARY ROUTES OF ENTRY: SKIN CONTACT, EYE CONTACT AND INHALATION. ---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION IV: FIRST AID MEASURES ---------------------------------------------------------------------------------------------------------------------------------------------------------------EYE CONTACT: IMMEDIATELY FLUSH EYE WITH FLOWING WATER FOR AT LEAST 15 MINUTES, HOLDING EYELIDS APART TO IRRIGATE THOROUGHLY. GET MEDICAL ATTENTION. SKIN CONTACT: WASH THOROUGHLY WITH SOAP AND WATER. GET MEDICAL ATTENTION IF IRRITATION DEVELOPS. REMOVE AND LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. INHALATION: REMOVE TO FRESH AIR. IF BREATHING IS DIFFICULT, GIVE OXYGEN. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. GET MEDICAL ATTENTION. INGESTION: DILUTE WITH WATER AND INDUCE VOMITING. GET MEDICAL ATTENTION. NEVER GIVE FLUIDS OR INDUCE VOMITING IF PATIENT IS UNCONSCIOUS OR HAS CONVULSIONS. ---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION V: FIRE FIGHTING MEASURES ---------------------------------------------------------------------------------------------------------------------------------------------------------------FLASH POINT: NOT DETERMINED. LOWER EXPLOSIVE LIMIT: NOT APPLICABLE. UPPER EXPLOSIVE LIMIT: NOT APPLICABLE AUTOIGNITION TEMPERATURE: NOT DETERMINED. EXTINGUISHING MEDIA: WATER, DRY CHEMICAL, CARBON DIOXIDE, AND FOAM.
MSDS 02-0002
SPECIAL FIRE FIGHTING PROCEDURES: FIREFIGHTERS SHOULD BE EQUIPPED WITH SELF CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING. UNUSUAL HAZARDS: DUST MAY BE EXPLOSIVE IF MIXED WITH AIR IN CRITICAL PROPORTIONS AND IN THE PRESENCE OF SOURCE OF IGNITION. ---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION VI: ACCIDENTAL RELEASE MEASURES ---------------------------------------------------------------------------------------------------------------------------------------------------------------STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: WEAR APPROPRIATE SAFETY EQUIPMENT. CONTAIN AND CLEAN UP SPILL IMMEDIATELY. PREVENT FROM ENTERING FLOOR DRAINS. SWEEP POWDERS CAREFULLY MINIMIZING DUSTING. SHOVEL ALL SPILL MATERIALS INTO DISPOSAL DRUMS AND FOLLOW DISPOSAL INSTRUCTIONS. SCRUB SPILL AREA WITH DETERGENT AND FLUSH WITH COPIOUS AMOUNTS OF WATER. ---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION VII: HANDLING AND STORAGE ---------------------------------------------------------------------------------------------------------------------------------------------------------------HANDLING: IN ACCORDANCE WITH GOOD INDUSTRIAL PRACTICES, HANDLE WITH CARE AND AVOID PERSONAL CONTACT. CONTAINERS SHOULD BE TRIPLE RINSED ACCORDING TO FEDERAL REGULATIONS AND/OR GOOD WASTE MANAGEMENT PRCATICES. FOR INDUSTRIAL USE ONLY. STORAGE: KEEP CONTAINERS CLOSED WHEN NOT IN USE. ---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION VIII: EXPOSURE CONTROL/PERSONAL PROTECTION ---------------------------------------------------------------------------------------------------------------------------------------------------------------ENGINEERING CONTROLS: LOCAL EXHAUST TO MINIMIZE EXPOSURE. RESPIRATORY PROTECTION: IF EXPOSURE TO DUST IS LIKELY, A NIOSH APPROVED DUST RESPIRATOR IS RECOMMENDED. EXPOSURE LIMITS: NOT ESTABLISHED. EYE PROTECTION: WEAR SAFETY GLASSES WITH SIDE SHIELDS OR SAFETY GOGGLES. SKIN PROTECTION: WEAR RUBBER GLOVES. OTHER PROTECTIVE MEASURES: WEAR APRON, COVERALLS, BOOTS AND LONG SLEEVE SHIRT TO PREVENT SKIN CONTACT. HYGIENIC PRACTICES: EYEWASH FOUNTAINS SHOULD BE EASILY ACCESSIBLE. SHOWER AFTER HANDLING THIS PRODUCT. WORK CLOTHES SHOULD BE WASHED BEFORE REUSE. BEFORE EATING, DRINKING, OR SMOKING, WASH HANDS AND FACE WITH SOAP AND WATER. ---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION IX: PHYSICAL AND CHEMICAL PROPERTIES ---------------------------------------------------------------------------------------------------------------------------------------------------------------APPEARANCE: BLUE POWDER ODOR: SLIGHT ODOR SOLUBILITY IN WATER: SOLUBLE BOILING POINT: NOT APPLICABLE. MELTING POINT: NOT ESTABLISHED. -------------------------------------------------------------------------------------------------------------------------------------SECTION X: STABILITY AND REACTIVITY ---------------------------------------------------------------------------------------------------------------------------------------------------------------STABILITY: STABLE. CONDITIONS TO AVOID: NONE KNOWN. HAZARDOUS POLYMERIZATION: WILL NOT OCCUR. INCOMPATIBLE MATERIALS: NONE KNOWN.
MSDS 02-0002
HAZARDOUS DECOMPOSITION PRODUCTS: BURNING WILL PRODUCE OXIDES OF CARBON, NITROGEN AND SULFUR. ---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION XI: TOXICOLOGICAL PROPERTIES ---------------------------------------------------------------------------------------------------------------------------------------------------------------RAT, ORAL LD50: NOT ESTABLISHED RABBIT, SKIN: NOT ESTABLISHED RABBIT, EYES: NOT ESTABLISHED, PROBABLY IRITATING. ADDITIONAL TOXICITY DATA: NOT KNOWN. ---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION XII: ECOLOGICAL INFORMATION ---------------------------------------------------------------------------------------------------------------------------------------------------------------NO INFORMATION IS CURRENTLY AVAILABLE. ---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION XIII: DISPOSAL CONSIDERATIONS ---------------------------------------------------------------------------------------------------------------------------------------------------------------WASTE DISPOSAL METHOD: THIS PRODUCT IS NOT TO BE CONSIDERED A HAZARDOUS WASTE UNDER RCRA (40 CFR 261).DISPOSAL MUST BE IN ACCORDANCE WITH APPLICABLE GOVERNMENTAL REGULATIONS. CONTAINER DISPOSAL INFORMATION: CONTAINERS SHOULD BE TRIPLE RINSED ACCORDING TO FEDERAL REGULATIONS AND/OR GOOD WASTE MANAGEMENT PRACTICE. ---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION XIV: TRANSPORTATION INFORMATION ---------------------------------------------------------------------------------------------------------------------------------------------------------------DOT PROPER SHIPPING NAME: NOT REGULATED. DOT TECHNICAL NAME: NOT APPLICABLE. DOT HAZARD CLASS: NOT APPLICABLE. HAZARD SUBCLASS: NOT APPLICABLE. DOT UN/NA NUMBER: NOT APPLICABLE. PACKING GROUP: NOT APPLICABLE. RESP. GUIDE PAGE: NOT APPLICABLE. DOT REPORTABLE QUANTITY: NOT APPLICABLE. DOT LABELS: NOT APPLICABLE. ---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION XV: REGULATORY INFORMATION ---------------------------------------------------------------------------------------------------------------------------------------------------------------SARA TITLE III SECTION 302: THIS PRODUCT DOES NOT CONTAIN ANY CHEMICALS REGULATED UNDER SECTION 302 AS EXTREMELY HAZARDOUS. SARA TITLE III SECTION 304 (CERCLA): THIS PRODUCT DOES NOT CONTAIN ANY CHEMICALS REGULATED UNDER SECTION 304 AS A HAZARDOUS SUBSTANCE FOR EMERGENCY RELEASE NOTIFICATION. SARA TITLE III SECTION 312 HAZARD RATING: ACUTE: YES CHRONIC: NO FLAMMABILITY: NO REACTIVITY: NO PRESSURE: NO SARA TITLE III SECTION 313: THIS PRODUCT IS NOT REPORTABLE FOR SARA 313. TSCA: THIS PRODUCT IS REGISTERED UNDER THE REGULATIONS OF THE TOXIC SUBSTANCES CONTROL ACT (TSCA). STATE RIGHT TO KNOW INFORMATION INGREDIENT ACID BLUE 25 CAS NUMBER 6408-78-2
MSDS 02-0002
---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION XVI: OTHER INFORMATION ---------------------------------------------------------------------------------------------------------------------------------------------------------------HMIS RATING: HEALTH - 2 FIRE - 1 REACTIVITY - 0 PERSONAL PROTECTION - E NFPA RATING: HEALTH - 1 FIRE - 1 REACTIVITY 0
------------------------------------------------------------------------------------------------------------------------------------------DISCLAIMER: KEYCOLOUR INC. BELIEVES ALL THE INFORMATION AND DATA GIVEN IS ACCURATE AS OF THE DATE OF PREPARATION AND IS OFFERED IN GOOD FAITH. THIS INFORMATION IS GIVEN WITHOUT WARRANTY OR REPRESENTATION SOLELY FOR YOUR CONSIDERATION, INVESTIGATION, AND VERIFICATION. SINCE CONDITIONS OF USE ARE BEYOND OUR CONTROL, KEYCOLOUR INC. EXPRESSLY DISCLAIMS ALL LIABILITY FOR THE USE OR HANDLING OF THIS PRODUCT.
MSDS 02-0002
24 Hour Emergency Phones In U.S. Call CHEMTEL 1-800-255-3924 Outside U.S. call CHEMTEL Collect at; 1-813-248-0585
HMIS RATINGS:
HEALTH:
SECTION 1: PRODUCT IDENTIFICATION

Product I.D.: Product Name: Product Description: C.I. Name: C.I. Number: Chemical Family: CAS Number: Effective Date: K410 ALIZARINE BRILLANT GREEN 175% Acid Green Colorant Powder Acid Green 25 61570 Anthraquinone dye 4403-90-1 July 17, 2009
SECTION 2: HAZARD IDENTIFICATION AND EMERGENCY OVERVIEW

Emergency Overview: Unprotected contact may cause eye, respiratory, skin irritation Eye Contact: Depending on duration and personal sensitivity, unprotected contact may cause mild irritation, discomfort, redness, watering, itching or other effects. Heavy contact or for prolonged period may increase effects. Follow ALL supervisor and Personal Protection instructions in Section 8 of this SDS. Skin Contact: Depending on degree of unprotected contact with product and individual sensitivity, may cause mild irritation to skin, redness, rash, itching, and other effects. Constant/repeated long-term contact with some powdered products may cause abrasion of skin or increase other effects. Some liquid components may be absorbed through unprotected skin causing or adding to effects. Inhalation: Depending on duration of unprotected inhalation of product, vapors, mists, aerosols or dusts may cause mild irritation of the nose, throat, lungs and mucous membranes. Effects may include shortness of breath, cough, nausea, headache or other effects. Prolonged or heavy exposure, or heating of liquid material may increase severity of symptoms. Ingestion: Depending on amount swallowed, product can cause mild irritation of mouth, throat, esophagus, stomach, and gastrointestinal tract. Effects may include upset stomach, abdominal discomfort, nausea, vomiting, gastrointestinal disturbances, dizziness, diarrhea, or other effects. Aspiration into lungs during vomiting is an emergency and may cause lung injury and life-threatening conditions. Medical Conditions Aggravated by Exposure:
SAFETY DATA SHEET (continued)

K410 ALIZARINE BRILLANT GREEN 175%
Page 2 of 7
Improper protection allowing contact with vapors, mists, aerosols, liquids, splashes or dusts of product by inhalation, eye contact, or skin contact may aggravate pre-existing conditions or diseases of the respiratory system, skin, or eyes. Individuals with above-noted conditions or known or suspected chemical sensitivities or allergies should avoid working with chemicals. Skin Sensitization: Not known to cause skin sensitization. With careful handling and when good chemical hygiene procedures are followed, harmful effects are not expected. As a precaution against unforeseen or unexpected sensitivity or possible allergic reactions, follow ALL Personal Protection instructions in Section 8 of this SDS. Respiratory Sensitization: Not known to cause respiratory sensitization. With careful handling and good chemical hygiene procedures being followed, no harmful effects are expected . As a precaution against unforeseen or unexpected sensitivity or possible allergic reactions, follow ALL Personal Protection instructions in Section 8 of this SDS. All PPE must be cleaned and maintained after each shift. All exposures should be avoided. Individuals known to be, or suspected to be sensitive to chemical exposure should not work with chemicals. Special Warnings: None for this material Unusual Health Hazards: None for this material Supplemental Hazard Information: No additional information is currently available Notes to Physician: Treat Symptomatically based on Section 2 Hazard Warnings and Section 3 ingredients unless indicated otherwise Cancer Information: *** Not known to contain carcinogens ***
SECTION 3: OSHA HAZARDOUS INGREDIENTS

Component Acid Green 25 CAS Number 4403-90-1 Wt % 100.00% OSHA - PEL 15mg/m3 TWA Total dust 5mg/m3 Respirable ACGIH - TLV 10mg/m3 TWA Total dust 3mg/m3 Respirable Recommended PEL Not applicable
1.00 Important Notice: 1 . Unprotected contact with ingredients listed in Section 3 may be hazardous based on OSHA 29 CFR 1910.1200 & related appendices. Components not listed are 0 trade secrets, non-hazardous, or not reportable. This SDS is not intended to offer full disclosure, but all component information is available to medical or emergency personnel. All hazards are based on contact exposure. Effects may be unpredictable and may vary from person to person due to individual reactions. Reducing or 0
eliminating contact can reduce or eliminate risk. Use protective equipment and clothing in Section 8 to minimize or eliminate contact. Users are responsible for hazard determination and communication. Unless indicated otherwise, non-carcinogenic components are indicated within a 1-10% range, and investigated or potential carcinogens within a 0.1-1% range. HMIS ratings are based on data interpretation, and vary from company to company. They are intended only for quick, general identification of the degree of potential hazards. Hazards range from 0 (Minimal) up to 4 (Severe). Consult the National Paint & Coatings Association HMIS Manual for detailed information on ratings. To handle material safely, consider all information in this SDS.
1.00
SECTION 4: FIRST AID INSTRUCTIONS

Eye Contact: Immediately rinse with flowing water for at least 15 minutes while holding eyelids open. Get immediate medical attention, as a precaution. Have a copy of this Safety Data Sheet available. Skin Contact: Immediately remove contaminated clothing. Wash affected area with soap and rinse with plenty of water. Get medical attention, as a precaution. Have a copy of this Safety Data Sheet available.

K410 ALIZARINE BRILLANT GREEN 175% Inhalation:
Page 3 of 7
Immediately move person to fresh air. If breathing is difficult give oxygen, call 911, calm the individual. If not breathing, call 911, give artificial respiration (CPR) until medical help arrives. Have this Safety Data Sheet available. Ingestion: Do not induce vomiting unless directed to do so by a doctor or by other emergency medical personnel. Forced vomiting of certain chemicals may cause aspiration and lung damage. Have this Safety Data Sheet available.
SECTION 5: FIRE FIGHTING INSTRUCTIONS

Unusual hazards: None expected Other Hazards: None known Types of Extinguishers: CO2, dry chemical, foam, water fog or spray depending on type of fire Fire Fighting Directions: Wear self-contained breathing equipment and fire-proof clothing. Use water spray to cool fire exposed containers if they cannot be safely moved.
SECTION 6: ACCIDENTAL SPILL OR RELEASE INSTRUCTIONS

Special Precautions: None known. Follow general precautions shown below. Reporting: Check the applicable RQs in Section 15 Static Discharges: IMPORTANT - FOR DYES CONTAINING FLAMMABLE SOLVENTS (Check section 3 for ingredients, section 5 or 9 for flash point, section 14 for transport classification). IF FLAMMABLE, GUARD AGAINST FIRE AND EXPLOSION: Take precautionary measures against static discharges when cleaning up leaks or spills of combustibles, flammables and powders. Containers should be properly grounded with metal straps, cables or other appropriate means to relieve static electricity buildup or generation. IMPORTANT: When using, mixing, filling, or otherwise dispensing any types of solvents, do not allow buildup of flammable or combustible vapors or vapor-air mixtures in confined spaces, storage tanks, or any other areas or enclosures. Totes, drums, pails, and all other containers should be completely sealed when not in use. Flammable vapors can travel a distance to ignition sources and cause fire or explosion. Take every precaution and monitor all safety factors and systems, including maintaining more-than-adequate air-exchange ventilation. Environmental Protection: Immediately dike liquid spills with inert absorbent material (sand, "Oil Dry" or other commercially available spill absorbent) to contain and soak up liquid. Prevent material from entering floor drains, sewers, or any bodies of water. For powder spills, use sweeping compound, sawdust, or other appropriate material to contain dust. If possible, recover any uncontaminated materials to re-use. Protective equipment and clothing: Wear all proper personal protective equipment and clothing to care for spill situation. See section 8 of this Safety Data Sheet. Clean up: After containing liquid spill by diking and soaking up with inert absorbent material, place in labeled container to be sealed for proper and regulated disposal. Only the slightest residue should remain. Try to save uncontaminated material for reuse whenever possible. For powders, use sweeping compound to minimize dust and pick up as much product as possible. Do not allow liquids to seep into drains, sewers, lakes, rivers, etc. Check Sections 1 and 2 for dye description or type. Solvent dye residue may be cleaned by scrubbing with detergent, depending on type. Do not add water to water-soluble dyes. Dye is concentrated. This will increase amount of color to remove. All cleaning or scrubbing liquids used should be absorbed and placed in labeled containers for correct disposal. Absorbent material containing solvents may release combustible or flammable vapors and should be handled accordingly, properly labeled and disposed. Check Sections 2, 5, 13 & 15 for applicable instructions and regulations.

Page 4 of 7
SECTION 7: HANDLING AND STORAGE

Warnings and Precautions: No special precautions anticipated. Wear all PPE in section 8 as a precaution, and avoid physical contact with material. Personal Protection: Wear ALL proper personal protective equipment as outlined in section 8 of this SDS. Handling, Storage & Temperature Conditions: Keep containers tightly sealed in cool & dry area, out of direct sunlight. IMPORTANT: FOR PRODUCTS LISTING FLAMMABLE/COMBUSTIBLE SOLVENTS or LOW FLASH POINTS - GUARD AGAINST FIRE AND EXPLOSION: Store away from fire hazards and ignition sources, high heat, open flames, welding, hot plates, steam pipes, radiators, etc. Maintain good ventilation. Guard against static discharges. Ground all containers before mixing or filling. Use non-sparking tools to open, close or otherwise work with containers. Limit indoor storage to approved areas with automatic sprinklers. Vapors expected to be released when material is heated during process operations. STATIC CHARGES: Take precautionary measures against static discharges when mixing, cleaning, filling or otherwise dispensing combustible or flammable liquids. Containers should be properly grounded with metal straps, cables or other appropriate means to relieve static electricity build-up or generation. VAPORS: IMPORTANT: DO NOT ALLOW buildup of flammable or combustible vapors or vapor-air mixtures in confined spaces, storage tanks, or any other areas or enclosures. Totes, drums and all other containers should be completely sealed when not in use. Vapors can travel a distance to ignition sources and cause fire or explosion. Take every precaution and monitor all safety factors and systems, including maintaining more-than-adequate air-exchange ventilation. POWDERS: General precautions: Although unlikely in most instances, GUARD AGAINST DUST EXPLOSION HAZARD. Eliminate or keep dust to a minimum. Under the right conditions, high dust concentrations of certain particle sizes mixed with air in a critical ratio in the presence of an ignition source can theoretically cause a dust explosion. Be sure to PROPERLY ground containers when filling, mixing or otherwise dispensing powders. KEEP WORK AREA CLEAN AND DUST-FREE. Follow all Section 8 recommendations for Exposure Controls and Personal Protection. WATER-BASED PRODUCTS: DO NOT ALLOW TO FREEZE.
SECTION 8: EXPOSURE CONTROLS AND PERSONAL PROTECTION

Note: Selecting protective equipment & clothing: When choosing personal protective equipment and clothing, consider each worker's environment, all chemicals being handled, temperature, ventilation, and all other conditions. Determination of the level of protection needed for the eyes, skin and respiratory system under working conditions is the responsibility of the product end-user or shift supervisor. SDS Sections 2, 3, 8 and 11 should be consulted. Eye protection: As a precaution, wear indirectly vented, splash-proof chemical safety goggles. When handling liquids, wear splash-proof goggles under a clear face-shield. Face shield is not to be used without these goggles. The type or extent of protection needed should be determined by the product end-user or shift supervisor. Skin Protection: Always wear impervious, chemical-resistant synthetic or rubber gloves. Check with manufacturer for best glove for the material being handled. Wear good quality long sleeved work shirt, coveralls, and a rubber or plastic apron. Wash hands after handling and before eating, drinking or using restroom. Shower after each shift. Clean contaminated but reusable protective equipment and clothing before reusing and wearing again. Discard contaminated disposable gloves and clothing. The type or extent of protection needed should be determined by the product end-user or shift supervisor. Respiratory Protection: Depending on type of material handled and processing conditions, the appropriate NIOSH approved air-purifying organic vapor/mist respirator or dust respirator (with proper pre-filters if required) should be worn as a precaution when any inhalation contact with product is possible. A properly selected, disposable NIOSH approved air-purifying mask may be acceptable (Check with the mask manufacturer). After each shift or when equipment becomes contaminated, clean the respirator and replace filters in compliance with 29 CFR 1910.134. Discard disposables as often as required. The type or extent of protection needed should be determined by the product end-user, shift supervisor or other appropriate on-site manager. Eye Washes and Other Protection:

Page 5 of 7
Eye wash stations and drench showers should be located within 100 feet or 10-second walk of the work area per ANSI standard Z358.1-1990. Ventilation: Local exhaust or other appropriate ventilation should be used to maintain exposure limits below specified amounts recommended by OSHA, NIOSH, or ACGIH and to draw spray, aerosol, vapors, or dusts away from workers and prevent routine inhalation. At least 10 air changes per hour are recommended for good room ventilation. IMPORTANT - GUARD AGAINST FIRE AND EXPLOSION: When using, mixing, filling, or otherwise dispensing any types of solvents, do not allow buildup of flammable or combustible vapors or vapor-air mixtures in confined spaces, storage tanks, or any other areas or enclosures. Totes, drums and all other containers should be completely sealed when not in use. Vapors can travel a distance to ignition sources and cause fire or explosion. Take every precaution and monitor all safety factors and systems, including maintaining more-than-adequate air-exchange ventilation. Airborne Exposure Limits: Not referenced in literature
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

Flash Point: pH: % Total VOC: % Total Solids / Non-Volatiles: Appearance: Density: Odor: Freezing/Melting Point: Lbs. per gallon: Specific Gravity: Solubility: Other Properties: Other Components: Decomposition Temperature: Not applicable Not established 0.00 100.00 Greenish powder Not established None Not established Not established Not established Soluble. Test in particular applications. No further data Not established ~ 100 C
All Data shown above are typical values, not specifications.
SECTION 10: STABILITY AND REACTIVITY

Stability: Product is expected to be stable under normal, ambient (controlled) conditions concerning heat, moisture, pressure, fire and ignition hazards, and ventilation. Contact with incompatible or reactive materials may cause hazardous reactions in some products if indicated. Check information below. Hazardous Polymerization: Product will not undergo polymerization. Conditions to Avoid: Keep containers well sealed, avoid contact with incompatible materials, humidity or high heat Incompatible Materials: Oxidizing & reducing agents may destroy color. Hazardous Decomposition Products: In fire: Oxides of carbon, nitrogen sulfur, chlorine, sodium Possible Hazard Reactions: None known
SECTION 11: TOXICOLOGICAL INFORMATION

Component
Acid Green 25
Eye Effect
Mild irritant (Rabbit)
Skin Effect
Mild irritant (Rabbit)
Skin Sens
No Data
Resp Sens
No Data
Oral LD50
> 10,000 mg/kg
Inh LC50
No Data
Mutagen
No Data
Other Tox Data

No Data
Other Info
No Data

Page 6 of 7
SECTION 12: ECOLOGICAL DATA

Other Test Data
Component
AOX
Aquatic Tox
BOD
Biodeg.
COD
Ecotoxicity
Sewage
Other Info
*** No Data ***
SECTION 13: DISPOSAL AND ENVIRONMENTAL CONSIDERATION
Reuse of materials: Reclaim all uncontaminated material to reuse, recycle or otherwise rework whenever possible. Contain - Do not release: Do not release into sewers, water systems, ground systems or ecosystems without proper authorization. Disposal Methods: Incinerate, treat, or bury (landfill), after sampling and testing, at facility approved by applicable federal, state, and local authorities. Empty Containers: Empty containers may contain residue and/or vapors and should not be reused unless professionally cleaned and reconditioned. Crush if not cleaned, to prevent reuse. Applicable Regulations: Special Instructions: See Section 15 if regulated See Section 15 if regulated
SECTION 14: SHIPPING AND TRANSPORTATION INFORMATION

DOT Regulations (Ground): NOT REGULATED IATA Regulations (Air): NOT REGULATED IMDG / IMO Regulations (Water): NOT REGULATED
SECTION 15: REGULATORY INFORMATION

FEDERAL AND STATE LISTS
Component Acid Green 25 CAS Number 4403-90-1 Weight % 100.00% Regulatory List No listings known to be applicable.
SARA 311/312 Hazard Categories: Immediate/Acute Health Hazard: Chronic/Delayed Hazard: Fire Hazard: Sudden Release of Pressure Hazard: Reactivity Hazard: YES NO NO NO NO

Page 7 of 7
GLOBAL CHEMICAL REGISTRATION LISTINGS: AICS (Australia): DSL (Canada): ECL (Korea): EINECS (Europe): ENCS (Japan): IECSC (China): NZIoC (New Zealand): PICCS (Phillippines): TSCA (US): Components listed Components listed Components listed Components listed Components listed Components listed Components listed Components listed Components listed
EU Reach: Keystone has taken all relative steps to ensure REACH-Compliance. Please contact us with any REACH-Related questions. OTHER LISTINGS: Other national or regional registrations not yet determined.
SECTION 16: OTHER INFORMATION

Reason for Revision: Reviewed: Disclaimer: The information and recommendations contained herein are based upon data believed to be correct. However, no guarantee or warranty of any kind, expressed or implied, is made with respect to the information contained herein. This Safety Data Sheet was prepared to comply with the OSHA Hazard Communication Standard 29 CFR 1910.1200, and supersedes any previous information. Previously dated sheets are invalid and inapplicable. END OF SDS Format revisions 071709

--------------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION I: CHEMICAL PRODUCT AND COMPANY IDENTIFICATION --------------------------------------------------------------------------------------------------------------------------------------------------------------------TRADE NAME: AMENYL BLUE 2GA CRUDE CHEMICAL FAMILY: ANTHRAQUINONE C.I.#: ACID BLUE 40 CAS#: 6424-85-7
CHEMTREC 800-424-9300
DATE PREPARED: NOVEMBER 2009 ---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION II: COMPOSITION/INFORMATION ON HAZARDOUS INGREDIENTS ---------------------------------------------------------------------------------------------------------------------------------------------------------------CHEMICAL NAME CAS NUMBER %BY WT. TLV/PEL ACID BLUE 40 6424-85-7 NONE AS PER 29CFR PART 1910.1200. NONE UNDER TITLE III OF SARA. --------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION III: HAZARDS IDENTIFICATION ---------------------------------------------------------------------------------------------------------------------------------------------------------------EMERGENCY OVERVIEW: MAY CAUSE SKIN, EYE AND RESPIRATORY IRRITATION. EFFECTS OF OVEREXPOSURE: EYE CONTACT: MAY BE IRRITATING. SKIN CONTACT: MAY BE IRRITATING. INHALATION: MAY BE IRRITATING. INGESTION: NOT KNOWN. CHRONIC EXPOSURE: NOT KNOWN. CARCINOGENICITY: NOT LISTED AS AN IARC, NTP OR OSHA CARCINOGEN. MEDICAL CONDITIONS AGGREVATED BY EXPOSURE: NOT KNOWN PRIMARY ROUTES OF ENTRY: SKIN CONTACT, EYE CONTACT AND INHALATION. ---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION IV: FIRST AID MEASURES ---------------------------------------------------------------------------------------------------------------------------------------------------------------EYE CONTACT: IMMEDIATELY FLUSH EYE WITH FLOWING WATER FOR AT LEAST 15 MINUTES, HOLDING EYELIDS APART TO IRRIGATE THOROUGHLY. GET MEDICAL ATTENTION. SKIN CONTACT: WASH THOROUGHLY WITH SOAP AND WATER. GET MEDICAL ATTENTION IF IRRITATION DEVELOPS. REMOVE AND LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. INHALATION: REMOVE TO FRESH AIR. IF BREATHING IS DIFFICULT, GIVE OXYGEN. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. GET MEDICAL ATTENTION. INGESTION: DILUTE WITH WATER AND INDUCE VOMITING. GET MEDICAL ATTENTION. NEVER GIVE FLUIDS OR INDUCE VOMITING IF PATIENT IS UNCONSCIOUS OR HAS CONVULSIONS. ---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION V: FIRE FIGHTING MEASURES ---------------------------------------------------------------------------------------------------------------------------------------------------------------FLASH POINT: NOT DETERMINED. 1 MSDS 02-0002
LOWER EXPLOSIVE LIMIT: NOT APPLICABLE. UPPER EXPLOSIVE LIMIT: NOT APPLICABLE AUTOIGNITION TEMPERATURE: NOT DETERMINED. EXTINGUISHING MEDIA: WATER, DRY CHEMICAL, CARBON DIOXIDE, AND FOAM. SPECIAL FIRE FIGHTING PROCEDURES: FIREFIGHTERS SHOULD BE EQUIPPED WITH SELF CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING. UNUSUAL HAZARDS: DUST MAY BE EXPLOSIVE IF MIXED WITH AIR IN CRITICAL PROPORTIONS AND IN THE PRESENCE OF SOURCE OF IGNITION. ---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION VI: ACCIDENTAL RELEASE MEASURES ---------------------------------------------------------------------------------------------------------------------------------------------------------------STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: WEAR APPROPRIATE SAFETY EQUIPMENT. CONTAIN AND CLEAN UP SPILL IMMEDIATELY. PREVENT FROM ENTERING FLOOR DRAINS. SWEEP POWDERS CAREFULLY MINIMIZING DUSTING. SHOVEL ALL SPILL MATERIALS INTO DISPOSAL DRUMS AND FOLLOW DISPOSAL INSTRUCTIONS. SCRUB SPILL AREA WITH DETERGENT AND FLUSH WITH COPIOUS AMOUNTS OF WATER. ---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION VII: HANDLING AND STORAGE ---------------------------------------------------------------------------------------------------------------------------------------------------------------HANDLING: IN ACCORDANCE WITH GOOD INDUSTRIAL PRACTICES, HANDLE WITH CARE AND AVOID PERSONAL CONTACT. CONTAINERS SHOULD BE TRIPLE RINSED ACCORDING TO FEDERAL REGULATIONS AND/OR GOOD WASTE MANAGEMENT PRCATICES. FOR INDUSTRIAL USE ONLY. STORAGE: KEEP CONTAINERS CLOSED WHEN NOT IN USE. ---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION VIII: EXPOSURE CONTROL/PERSONAL PROTECTION ---------------------------------------------------------------------------------------------------------------------------------------------------------------ENGINEERING CONTROLS: LOCAL EXHAUST TO MINIMIZE EXPOSURE. RESPIRATORY PROTECTION: IF EXPOSURE TO DUST IS LIKELY, A NIOSH APPROVED DUST RESPIRATOR IS RECOMMENDED. EXPOSURE LIMITS: NOT ESTABLISHED. EYE PROTECTION: WEAR SAFETY GLASSES WITH SIDE SHIELDS OR SAFETY GOGGLES. SKIN PROTECTION: WEAR RUBBER GLOVES. OTHER PROTECTIVE MEASURES: WEAR APRON, COVERALLS, BOOTS AND LONG SLEEVE SHIRT TO PREVENT SKIN CONTACT. HYGIENIC PRACTICES: EYEWASH FOUNTAINS SHOULD BE EASILY ACCESSIBLE. SHOWER AFTER HANDLING THIS PRODUCT. WORK CLOTHES SHOULD BE WASHED BEFORE REUSE. BEFORE EATING, DRINKING, OR SMOKING, WASH HANDS AND FACE WITH SOAP AND WATER. ---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION IX: PHYSICAL AND CHEMICAL PROPERTIES ---------------------------------------------------------------------------------------------------------------------------------------------------------------APPEARANCE: BLUE POWDER ODOR: SLIGHT ODOR SOLUBILITY IN WATER: SOLUBLE BOILING POINT: NOT APPLICABLE. MELTING POINT: NOT ESTABLISHED. -------------------------------------------------------------------------------------------------------------------------------------SECTION X: STABILITY AND REACTIVITY ---------------------------------------------------------------------------------------------------------------------------------------------------------------STABILITY: STABLE. CONDITIONS TO AVOID: NONE KNOWN. 2 MSDS 02-0002
HAZARDOUS POLYMERIZATION: WILL NOT OCCUR. INCOMPATIBLE MATERIALS: NONE KNOWN. HAZARDOUS DECOMPOSITION PRODUCTS: BURNING WILL PRODUCE OXIDES OF CARBON, NITROGEN AND SULFUR. ---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION XI: TOXICOLOGICAL PROPERTIES ---------------------------------------------------------------------------------------------------------------------------------------------------------------RAT, ORAL LD50: GREATER THAN 5000 MG/KG RABBIT, SKIN: MILDLY IRRITATING RABBIT, EYES: MODERATELY IRRITATING. ADDITIONAL TOXICITY DATA: NOT KNOWN. ---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION XII: ECOLOGICAL INFORMATION ---------------------------------------------------------------------------------------------------------------------------------------------------------------NO INFORMATION IS CURRENTLY AVAILABLE. ---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION XIII: DISPOSAL CONSIDERATIONS ---------------------------------------------------------------------------------------------------------------------------------------------------------------WASTE DISPOSAL METHOD: THIS PRODUCT IS NOT TO BE CONSIDERED A HAZARDOUS WASTE UNDER RCRA (40 CFR 261).DISPOSAL MUST BE IN ACCORDANCE WITH APPLICABLE GOVERNMENTAL REGULATIONS. CONTAINER DISPOSAL INFORMATION: CONTAINERS SHOULD BE TRIPLE RINSED ACCORDING TO FEDERAL REGULATIONS AND/OR GOOD WASTE MANAGEMENT PRACTICE. ---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION XIV: TRANSPORTATION INFORMATION ---------------------------------------------------------------------------------------------------------------------------------------------------------------DOT PROPER SHIPPING NAME: NOT REGULATED. DOT TECHNICAL NAME: NOT APPLICABLE. DOT HAZARD CLASS: NOT APPLICABLE. HAZARD SUBCLASS: NOT APPLICABLE. DOT UN/NA NUMBER: NOT APPLICABLE. PACKING GROUP: NOT APPLICABLE. RESP. GUIDE PAGE: NOT APPLICABLE. DOT REPORTABLE QUANTITY: NOT APPLICABLE. DOT LABELS: NOT APPLICABLE. ---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION XV: REGULATORY INFORMATION ---------------------------------------------------------------------------------------------------------------------------------------------------------------SARA TITLE III SECTION 302: THIS PRODUCT DOES NOT CONTAIN ANY CHEMICALS REGULATED UNDER SECTION 302 AS EXTREMELY HAZARDOUS. SARA TITLE III SECTION 304 (CERCLA): THIS PRODUCT DOES NOT CONTAIN ANY CHEMICALS REGULATED UNDER SECTION 304 AS A HAZARDOUS SUBSTANCE FOR EMERGENCY RELEASE NOTIFICATION. SARA TITLE III SECTION 312 HAZARD RATING: ACUTE: NO CHRONIC: NO FLAMMABILITY: NO REACTIVITY: NO PRESSURE: NO SARA TITLE III SECTION 313: THIS PRODUCT IS NOT REPORTABLE FOR SARA 313. TSCA: THIS PRODUCT IS REGISTERED UNDER THE REGULATIONS OF THE TOXIC SUBSTANCES CONTROL ACT (TSCA).
MSDS 02-0002
STATE RIGHT TO KNOW INFORMATION INGREDIENT ACID BLUE 40
CAS NUMBER 6424-85-7
---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION XVI: OTHER INFORMATION ---------------------------------------------------------------------------------------------------------------------------------------------------------------HMIS RATING: HEALTH - 1 FIRE - 1 REACTIVITY - 0 PERSONAL PROTECTION - F NFPA RATING: HEALTH - 1 FIRE - 1 REACTIVITY 0
MSDS 02-0002
MATERIAL SAFETY DATA SHEET --------------------------------------------------------------------------------------------------------------------------------------SECTION I: CHEMICAL PRODUCT AND COMPANY IDENTIFICATION --------------------------------------------------------------------------------------------------------------------------------------TRADE NAME: AMECID RHODAMINE B 400% CHEMICAL FAMILY: XANTHENE
CHEMTREC 800-424-9300
DATE PREPARED: JULY 2009 --------------------------------------------------------------------------------------------------------------------------------------SECTION II: COMPOSITION/INFORMATION ON HAZARDOUS INGREDIENTS --------------------------------------------------------------------------------------------------------------------------------------CHEMICAL NAME ACID RED 52 CAS NUMBER 3520-42-1 %BY WT. TLV/PEL NOT ESTABLISHED
--------------------------------------------------------------------------------------------------------------------------------------SECTION III: HAZARDS IDENTIFICATION --------------------------------------------------------------------------------------------------------------------------------------EMERGENCY OVERVIEW: MAY CAUSE SKIN, EYE AND RESPIRATORY IRRITATION. EFFECTS OF OVEREXPOSURE: EYE CONTACT: MAY BE IRRITATING. SKIN CONTACT: MAY BE IRRITATING. INHALATION: MAY BE IRRITATING. INGESTION: NOT KNOWN. CHRONIC EXPOSURE: NOT KNOWN. CARCINOGENICITY: NOT LISTED AS AN IARC, NTP OR OSHA CARCINOGEN. MEDICAL CONDITIONS AGGREVATED BY EXPOSURE: NOT KNOWN PRIMARY ROUTES OF ENTRY: SKIN CONTACT, EYE CONTACT AND INHALATION. --------------------------------------------------------------------------------------------------------------------------------------SECTION IV: FIRST AID MEASURES --------------------------------------------------------------------------------------------------------------------------------------EYE CONTACT: IMMEDIATELY FLUSH EYE WITH FLOWING WATER FOR AT LEAST 15 MINUTES, HOLDING EYELIDS APART TO IRRIGATE THOROUGHLY. GET MEDICAL ATTENTION. SKIN CONTACT: WASH THOROUGHLY WITH SOAP AND WATER. GET MEDICAL ATTENTION IF IRRITATION DEVELOPS. REMOVE AND LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. INHALATION: REMOVE TO FRESH AIR. IF BREATHING IS DIFFICULT, GIVE OXYGEN. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. GET MEDICAL ATTENTION. INGESTION: DILUTE WITH WATER AND INDUCE VOMITING. GET MEDICAL ATTENTION. NEVER GIVE FLUIDS OR INDUCE VOMITING IF PATIENT IS UNCONSCIOUS OR HAS CONVULSIONS. --------------------------------------------------------------------------------------------------------------------------------------1 MSDS 02-0002
SECTION V: FIRE FIGHTING MEASURES --------------------------------------------------------------------------------------------------------------------------------------FLASH POINT: NOT DETERMINED. LOWER EXPLOSIVE LIMIT: NOT APPLICABLE. UPPER EXPLOSIVE LIMIT: NOT APPLICABLE AUTOIGNITION TEMPERATURE: NOT DETERMINED. EXTINGUISHING MEDIA: WATER, DRY CHEMICAL, CARBON DIOXIDE, AND FOAM. SPECIAL FIRE FIGHTING PROCEDURES: FIREFIGHTERS SHOULD BE EQUIPPED WITH SELF CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING. UNUSUAL HAZARDS: DUST MAY BE EXPLOSIVE IF MIXED WITH AIR IN CRITICAL PROPORTIONS AND IN THE PRESENCE OF SOURCE OF IGNITION. --------------------------------------------------------------------------------------------------------------------------------------SECTION VI: ACCIDENTAL RELEASE MEASURES --------------------------------------------------------------------------------------------------------------------------------------STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: WEAR APPROPRIATE SAFETY EQUIPMENT. CONTAIN AND CLEAN UP SPILL IMMEDIATELY. PREVENT FROM ENTERING FLOOR DRAINS. SWEEP POWDERS CAREFULLY MINIMIZING DUSTING. SHOVEL ALL SPILL MATERIALS INTO DISPOSAL DRUMS AND FOLLOW DISPOSAL INSTRUCTIONS. SCRUB SPILL AREA WITH DETERGENT AND FLUSH WITH COPIOUS AMOUNTS OF WATER. --------------------------------------------------------------------------------------------------------------------------------------SECTION VII: HANDLING AND STORAGE --------------------------------------------------------------------------------------------------------------------------------------HANDLING: IN ACCORDANCE WITH GOOD INDUSTRIAL PRACTICES, HANDLE WITH CARE AND AVOID PERSONAL CONTACT. CONTAINERS SHOULD BE TRIPLE RINSED ACCORDING TO FEDERAL REGULATIONS AND/OR GOOD WASTE MANAGEMENT PRCATICES. FOR INDUSTRIAL USE ONLY. STORAGE: KEEP CONTAINERS CLOSED WHEN NOT IN USE. --------------------------------------------------------------------------------------------------------------------------------------SECTION VIII: EXPOSURE CONTROL/PERSONAL PROTECTION --------------------------------------------------------------------------------------------------------------------------------------ENGINEERING CONTROLS: LOCAL EXHAUST TO MINIMIZE EXPOSURE. RESPIRATORY PROTECTION: IF EXPOSURE TO DUST IS LIKELY, A NIOSH APPROVED DUST RESPIRATOR IS RECOMMENDED. EXPOSURE LIMITS: NOT ESTABLISHED. EYE PROTECTION: WEAR SAFETY GLASSES WITH SIDE SHIELDS OR SAFETY GOGGLES. SKIN PROTECTION: WEAR RUBBER GLOVES. OTHER PROTECTIVE MEASURES: WEAR APRON, COVERALLS, BOOTS AND LONG SLEEVE SHIRT TO PREVENT SKIN CONTACT. HYGIENIC PRACTICES: EYEWASH FOUNTAINS SHOULD BE EASILY ACCESSIBLE. SHOWER AFTER HANDLING THIS PRODUCT. WORK CLOTHES SHOULD BE WASHED BEFORE REUSE. BEFORE EATING, DRINKING, OR SMOKING, WASH HANDS AND FACE WITH SOAP AND WATER. --------------------------------------------------------------------------------------------------------------------------------------SECTION IX: PHYSICAL AND CHEMICAL PROPERTIES --------------------------------------------------------------------------------------------------------------------------------------APPEARANCE: RED POWDER ODOR: NO ODOR SOLUBILITY IN WATER: SOLUBLE BOILING POINT: NOT APPLICABLE.
2 MSDS 02-0002
MELTING POINT: NOT ESTABLISHED. pH: 6.5-8.0 @ 1G/L WATER -------------------------------------------------------------------------------------------------------------------------------------SECTION X: STABILITY AND REACTIVITY --------------------------------------------------------------------------------------------------------------------------------------STABILITY: STABLE. CONDITIONS TO AVOID: NONE KNOWN. HAZARDOUS POLYMERIZATION: WILL NOT OCCUR. INCOMPATIBLE MATERIALS: NONE KNOWN. HAZARDOUS DECOMPOSITION PRODUCTS: BURNING WILL PRODUCE OXIDES OF CARBON, NITROGEN AND SULFUR. --------------------------------------------------------------------------------------------------------------------------------------SECTION XI: TOXICOLOGICAL PROPERTIES --------------------------------------------------------------------------------------------------------------------------------------RAT, ORAL LD50: >5000 MG/KG RABBIT, SKIN: NOT IRRITATING RABBIT, EYES: NOT IRRITATING ADDITIONAL TOXICITY DATA: NONE KNOWN. --------------------------------------------------------------------------------------------------------------------------------------SECTION XII: ECOLOGICAL INFORMATION --------------------------------------------------------------------------------------------------------------------------------------NO INFORMATION IS CURRENTLY AVAILABLE. --------------------------------------------------------------------------------------------------------------------------------------SECTION XIII: DISPOSAL CONSIDERATIONS --------------------------------------------------------------------------------------------------------------------------------------WASTE DISPOSAL METHOD: THIS PRODUCT IS NOT TO BE CONSIDERED A HAZARDOUS WASTE UNDER RCRA (40 CFR 261).DISPOSAL MUST BE IN ACCORDANCE WITH APPLICABLE GOVERNMENTAL REGULATIONS. CONTAINER DISPOSAL INFORMATION: CONTAINERS SHOULD BE TRIPLE RINSED ACCORDING TO FEDERAL REGULATIONS AND/OR GOOD WASTE MANAGEMENT PRACTICE. --------------------------------------------------------------------------------------------------------------------------------------SECTION XIV: TRANSPORTATION INFORMATION --------------------------------------------------------------------------------------------------------------------------------------DOT PROPER SHIPPING NAME: NOT REGULATED. DOT TECHNICAL NAME: NOT APPLICABLE. DOT HAZARD CLASS: NOT APPLICABLE. HAZARD SUBCLASS: NOT APPLICABLE. DOT UN/NA NUMBER: NOT APPLICABLE. PACKING GROUP: NOT APPLICABLE. RESP. GUIDE PAGE: NOT APPLICABLE. DOT REPORTABLE QUANTITY: NOT APPLICABLE. DOT LABELS: NOT APPLICABLE. --------------------------------------------------------------------------------------------------------------------------------------SECTION XV: REGULATORY INFORMATION --------------------------------------------------------------------------------------------------------------------------------------3 MSDS 02-0002
SARA TITLE III SECTION 302: THIS PRODUCT DOES NOT CONTAIN ANY CHEMICALS REGULATED UNDER SECTION 302 AS EXTREMELY HAZARDOUS. SARA TITLE III SECTION 304 (CERCLA): THIS PRODUCT DOES NOT CONTAIN ANY CHEMICALS REGULATED UNDER SECTION 304 AS A HAZARDOUS SUBSTANCE FOR EMERGENCY RELEASE NOTIFICATION. SARA TITLE III SECTION 312 HAZARD RATING: ACUTE:NO CHRONIC: YES FLAMMABILITY: NO REACTIVITY: NO PRESSURE: NO SARA TITLE III SECTION 313: THIS PRODUCT IS NOT REPORTABLE FOR SARA 313. TSCA: THIS PRODUCT IS REGISTERED UNDER THE REGULATIONS OF THE TOXIC SUBSTANCES CONTROL ACT (TSCA).
STATE RIGHT TO KNOW INFORMATION
INGREDIENT XANTHENE DYE
CAS NUMBER 3520-42-1
---------------------------------------------------------------------------------------------------------------------------------SECTION XVI: OTHER INFORMATION --------------------------------------------------------------------------------------------------------------------------------------HMIS RATING: HEALTH - 1 FIRE - 1 REACTIVITY - 0 PERSONAL PROTECTION - B NFPA RATING: HEALTH - 1 FIRE - 1 REACTIVITY - 0 -----------------------------------------------------------------------------------------------------------------------------------------DISCLAIMER: KEYCOLOUR INC. BELIEVES ALL THE INFORMATION AND DATA GIVEN IS ACCURATE AS OF THE DATE OF PREPARATION AND IS OFFERED IN GOOD FAITH. THIS INFORMATION IS GIVEN WITHOUT WARRANTY OR REPRESENTATION SOLELY FOR YOUR CONSIDERATION, INVESTIGATION, AND VERIFICATION. SINCE CONDITIONS OF USE ARE BEYOND OUR CONTROL, KEYCOLOUR INC. EXPRESSLY DISCLAIMS ALL LIABILITY FOR THE USE OR HANDLING OF THIS PRODUCT. +
MSDS 02-0002
MSDS 02-0002

-----------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION I: CHEMICAL PRODUCT AND COMPANY IDENTIFICATION -----------------------------------------------------------------------------------------------------------------------------------------------------------------TRADE NAME: AMECID VIOLET NRR CHEMICAL FAMILY: ANTHRAQUINONE DYE
CHEMTREC 800-424-9300
DATE PREPARED: FEBRUARY 22, 2009 ---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION II: COMPOSITION/INFORMATION ON HAZARDOUS INGREDIENTS ---------------------------------------------------------------------------------------------------------------------------------------------------------------CHEMICAL NAME CAS NUMBER %BY WT. TLV/PEL ACID VIOLET 76 63589-10-6 60-80% NOT ESTABLISHED --------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION III: HAZARDS IDENTIFICATION ---------------------------------------------------------------------------------------------------------------------------------------------------------------EMERGENCY OVERVIEW: MAY CAUSE SKIN, EYE AND RESPIRATORY IRRITATION. EFFECTS OF OVEREXPOSURE: EYE CONTACT: MAY BE IRRITATING. SKIN CONTACT: MAY BE IRRITATING. INHALATION: MAY BE IRRITATING. INGESTION: HARMFUL IF SWALLOWED. MAY CAUSE IRRITATION OF GASTROINTESTINAL TRACT. CHRONIC EXPOSURE: NOT KNOWN. CARCINOGENICITY: NOT LISTED AS AN IARC, NTP OR OSHA CARCINOGEN. MEDICAL CONDITIONS AGGREVATED BY EXPOSURE: NOT KNOWN PRIMARY ROUTES OF ENTRY: SKIN CONTACT, EYE CONTACT AND INHALATION. ---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION IV: FIRST AID MEASURES ---------------------------------------------------------------------------------------------------------------------------------------------------------------EYE CONTACT: IMMEDIATELY FLUSH EYE WITH FLOWING WATER FOR AT LEAST 15 MINUTES, HOLDING EYELIDS APART TO IRRIGATE THOROUGHLY. GET MEDICAL ATTENTION. SKIN CONTACT: WASH THOROUGHLY WITH SOAP AND WATER. GET MEDICAL ATTENTION IF IRRITATION DEVELOPS. REMOVE AND LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. INHALATION: REMOVE TO FRESH AIR. IF BREATHING IS DIFFICULT, GIVE OXYGEN. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. GET MEDICAL ATTENTION. INGESTION: DILUTE WITH WATER AND INDUCE VOMITING. GET MEDICAL ATTENTION. NEVER GIVE FLUIDS OR INDUCE VOMITING IF PATIENT IS UNCONSCIOUS OR HAS CONVULSIONS. ----------------------------------------------------------------------------------------------------------------------------------------------------------------
SECTION V: FIRE FIGHTING MEASURES ---------------------------------------------------------------------------------------------------------------------------------------------------------------FLASH POINT: NOT DETERMINED. LOWER EXPLOSIVE LIMIT: NOT APPLICABLE. UPPER EXPLOSIVE LIMIT: NOT APPLICABLE AUTOIGNITION TEMPERATURE: NOT DETERMINED. EXTINGUISHING MEDIA: WATER, DRY CHEMICAL, CARBON DIOXIDE, AND FOAM. SPECIAL FIRE FIGHTING PROCEDURES: FIREFIGHTERS SHOULD BE EQUIPPED WITH SELF CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING. UNUSUAL HAZARDS: DUST MAY BE EXPLOSIVE IF MIXED WITH AIR IN CRITICAL PROPORTIONS AND IN THE PRESENCE OF SOURCE OF IGNITION. ---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION VI: ACCIDENTAL RELEASE MEASURES ---------------------------------------------------------------------------------------------------------------------------------------------------------------STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: WEAR APPROPRIATE SAFETY EQUIPMENT. CONTAIN AND CLEAN UP SPILL IMMEDIATELY. PREVENT FROM ENTERING FLOOR DRAINS. SWEEP POWDERS CAREFULLY MINIMIZING DUSTING. SHOVEL ALL SPILL MATERIALS INTO DISPOSAL DRUMS AND FOLLOW DISPOSAL INSTRUCTIONS. SCRUB SPILL AREA WITH DETERGENT AND FLUSH WITH COPIOUS AMOUNTS OF WATER. ---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION VII: HANDLING AND STORAGE ---------------------------------------------------------------------------------------------------------------------------------------------------------------HANDLING: IN ACCORDANCE WITH GOOD INDUSTRIAL PRACTICES, HANDLE WITH CARE AND AVOID PERSONAL CONTACT. CONTAINERS SHOULD BE TRIPLE RINSED ACCORDING TO FEDERAL REGULATIONS AND/OR GOOD WASTE MANAGEMENT PRCATICES. FOR INDUSTRIAL USE ONLY. STORAGE: KEEP CONTAINERS CLOSED WHEN NOT IN USE. ---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION VIII: EXPOSURE CONTROL/PERSONAL PROTECTION ---------------------------------------------------------------------------------------------------------------------------------------------------------------ENGINEERING CONTROLS: LOCAL EXHAUST TO MINIMIZE EXPOSURE. RESPIRATORY PROTECTION: IF EXPOSURE TO DUST IS LIKELY, A NIOSH APPROVED DUST RESPIRATOR IS RECOMMENDED. EXPOSURE LIMITS: NOT ESTABLISHED. EYE PROTECTION: WEAR SAFETY GLASSES WITH SIDE SHIELDS OR SAFETY GOGGLES. SKIN PROTECTION: WEAR RUBBER GLOVES. OTHER PROTECTIVE MEASURES: WEAR APRON, COVERALLS, BOOTS AND LONG SLEEVE SHIRT TO PREVENT SKIN CONTACT. HYGIENIC PRACTICES: EYEWASH FOUNTAINS SHOULD BE EASILY ACCESSIBLE. SHOWER AFTER HANDLING THIS PRODUCT. WORK CLOTHES SHOULD BE WASHED BEFORE REUSE. BEFORE EATING, DRINKING, OR SMOKING, WASH HANDS AND FACE WITH SOAP AND WATER. ---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION IX: PHYSICAL AND CHEMICAL PROPERTIES ---------------------------------------------------------------------------------------------------------------------------------------------------------------APPEARANCE: DARK VIOLET POWDER ODOR: NONE SOLUBILITY IN WATER: 10 G/L @20C.
BOILING POINT: NOT APPLICABLE. MELTING POINT: NOT ESTABLISHED. -------------------------------------------------------------------------------------------------------------------------------------SECTION X: STABILITY AND REACTIVITY ---------------------------------------------------------------------------------------------------------------------------------------------------------------STABILITY: STABLE. CONDITIONS TO AVOID: NONE KNOWN. HAZARDOUS POLYMERIZATION: WILL NOT OCCUR. INCOMPATIBLE MATERIALS: OXIDIZING AND REDUCING AGENTS. HAZARDOUS DECOMPOSITION PRODUCTS: BURNING WILL PRODUCE OXIDES OF CARBON, NITROGEN AND SULFUR. ---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION XI: TOXICOLOGICAL PROPERTIES ---------------------------------------------------------------------------------------------------------------------------------------------------------------RAT, ORAL LD50: NOT DETERMINED. RABBIT, SKIN: MAY BE IRRITATING RABBIT, EYES: PROBABLY IRRITATING ADDITIONAL TOXICITY DATA: NOT KNOWN. ---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION XII: ECOLOGICAL INFORMATION ---------------------------------------------------------------------------------------------------------------------------------------------------------------NO INFORMATION IS CURRENTLY AVAILABLE. ---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION XIII: DISPOSAL CONSIDERATIONS ---------------------------------------------------------------------------------------------------------------------------------------------------------------WASTE DISPOSAL METHOD: THIS PRODUCT IS NOT TO BE CONSIDERED A HAZARDOUS WASTE UNDER RCRA (40 CFR 261).DISPOSAL MUST BE IN ACCORDANCE WITH APPLICABLE GOVERNMENTAL REGULATIONS. CONTAINER DISPOSAL INFORMATION: CONTAINERS SHOULD BE TRIPLE RINSED ACCORDING TO FEDERAL REGULATIONS AND/OR GOOD WASTE MANAGEMENT PRACTICE. ---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION XIV: TRANSPORTATION INFORMATION ---------------------------------------------------------------------------------------------------------------------------------------------------------------DOT PROPER SHIPPING NAME: NOT REGULATED. DOT TECHNICAL NAME: NOT APPLICABLE. DOT HAZARD CLASS: NOT APPLICABLE. HAZARD SUBCLASS: NOT APPLICABLE. DOT UN/NA NUMBER: NOT APPLICABLE. PACKING GROUP: NOT APPLICABLE. RESP. GUIDE PAGE: NOT APPLICABLE. DOT REPORTABLE QUANTITY: NOT APPLICABLE. DOT LABELS: NOT APPLICABLE. ---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION XV: REGULATORY INFORMATION ---------------------------------------------------------------------------------------------------------------------------------------------------------------SARA TITLE III SECTION 302: THIS PRODUCT DOES NOT CONTAIN ANY CHEMICALS REGULATED UNDER SECTION 302 AS EXTREMELY HAZARDOUS. SARA TITLE III SECTION 304 (CERCLA): THIS PRODUCT DOES NOT CONTAIN ANY CHEMICALS REGULATED UNDER SECTION 304 AS A HAZARDOUS SUBSTANCE FOR EMERGENCY RELEASE NOTIFICATION.
SARA TITLE III SECTION 312 HAZARD RATING: ACUTE: NO CHRONIC: NO FLAMMABILITY: NO REACTIVITY: NO PRESSURE: NO SARA TITLE III SECTION 313: THIS PRODUCT IS NOT REPORTABLE FOR SARA 313. TSCA: THIS PRODUCT IS REGISTERED UNDER THE REGULATIONS OF THE TOXIC SUBSTANCES CONTROL ACT (TSCA). STATE RIGHT TO KNOW INFORMATION INGREDIENT CAS NUMBER ACID VIOLET 76 63589-10-6 ---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION XVI: OTHER INFORMATION ---------------------------------------------------------------------------------------------------------------------------------------------------------------HMIS RATING: HEALTH - 1 FIRE - 1 REACTIVITY - 0 PERSONAL PROTECTION - E NFPA RATING: HEALTH - 1 FIRE - 1 REACTIVITY 0
For 24 hours emergency Chemtrec :: 800-424-9300

I. PRODUCT IDENTIFICATION TRADE NAME--------- TURQUOISE 86 CHEMICAL NAME------ N/A CHEMICAL FAMILY----PHTHALOCYANINE dYE C. A. S. #--------- 1330-38-7 LAST REVISION DATE. 10/29/09 II. HAZARDOUS COMPONENTS Metaphosphoric acid hexasodium Salt Content:2 % Remarks This product is not regulated under the OSHA hazard communication standard, 29CFR1910.1200. or SARA Title III Sect. 312 III. PHYSICAL DATA BOILING POINT--N/A VAPOR PRESSURE--N/A VAPOR DENSITY---N/A VOLATILITY----- N/A FREEZE POINT--- N/A MELTING POINT---N/A IV. FIRE AND EXPLOSION DATA FLASH POINT N/A FILAMMABLE LIMITS. N/A IN CASE OF FIRE-----DRY CHEMICAL, CO2, WATER SPRAY OR REGULAR FOAM. MOVE CONTAINERS FROM FIRE AREA IF YOU CAN DO IT WITHOUT RISK. APPLY COOLING WATER TO SIDES OF CONTAINERS THAT ARE EXPOSED TO FLAMES UNTIL WELL AFTER FIRE IS OUT.
Phthalocyanine dye
SOLUB. IN WATER--SOLUBLE IN WATER ODOR--- NONE APPEARANCE--DARK POWDER SPECIFIC GRAV-- N/A EVAP. RATE--- N/A pH OF PRODUCTN/A
VENTILATION----Local Exhaust. OTHER PROTECTION--- DELUGE SAFETY SHOWER AND EYE WASH STATION SHOULD BE LOCATEI NEAR WORK AREA. Ecological information: Physico-chemical eliminability : approx. 75 % Method : Iron sulphate precipitation Fish toxicity : LC50 > 100 mg/l (72 h, Leuciscus idus) Method : Range Finding Test Bacteria toxicity : 1,000 mg/l No inhibitory effects, Test method: Growth inhibition test modified according to G. Bringmann, Gesundheitsingenieur 94, 366-369 (1973) Chemical oxygen demand (COD) : 700 mg/g Remarks: Test results of an analogous product. Product does not add to the AOX-value of the sewage. (DIN EN 1485) This product contains approx. 3,6 % complex bonded copper. The product does not release nitrogen which can contribute to eutrophication. The product contains 0,6 % phophorus as phosphate.
S. A. R. A.--- REPORTABLE
Sara 313 This product contains the following component that is subject to the reporting requirements under 40 CFR 372. contains: Copper-Phthalocyanine-Complex Content: > 50 % Dyestuff Copper Content: 3.6 % CAS number : 7440-50-8 Sara 312 Immediate (acute) health hazard No Delayed (chronic) health hazard No Fire hazard No Sudden Release of Pressure No Reactivity No Other regulations
No labelling is required in accordance with the EEC directives. T.S.C.A---- IN COMPLIANCE
0. S. H. A. HAZARD CLASSIFICATION: ACUTE:NO CHRONIC: NO FLAMMABLE: NO REACTIVE: NO OXIDIZER: NO HEALTH H.M.I.S. CLASSIFICATION: N.F.P.A CODES: 1 1 FLAMMABILITY 1 1 REACTIVITY 1 1 PERSONAL PROT. F N
XIII. STATES RIGHT TO KNOW LAWS HAZARDOUS MATERIALS ** NONE*** INGREDIENTS STATE INFORMATION * * N O N E * * XIV. OTHER INFORMATION
ALL INFORMATION AND DATA APPEARING ON THIS M. S. D. S. ARE BELIEVED TO BE RELIABLE & ACCURATE. HOWEVER, IT IS THE USER'S RESPONSIBILITY TO DETERMINE THE SAFETY, TOXICITY, AND SUITABILITY FOR HIS OWN USE OF THE PRODUCT DESCRIBED. SINCE THE ACTUAL USE BY OTHERS IS BEYOND OUR CONTROL, NO GUARANTEE, EXPRESSED OR IMPLIED, IS MADE BY KEYCOLOUR INCORPORATED. USER ASSUMES ALL RISK AND RESPONSIBILITY.
TRADE NAME: KEYACID VIOLET CRUDE PRODUCT ID: K701 EMERGENCY PHONE: Call CHEMTEL 800.255.3924 ________________________________________________________________________________ ____ M A T E R I A L S A F E T Y D A T A S H E E T
________________________________________________________________________________ ____ N O T E: DO NOT DETACH THIS GUIDANCE COVER SHEET FROM THE REST OF THIS DOCUMENT. This page indicates the Keycolour Trade Name and Product ID. This identifying information must be referenced when ordering products or making inquiries. ________________________________________________________________________________ ____ A) YOUR CERTIFICATION OF COMPLIANCE UNDER FEDERAL AND STATE REGULATIONS IMPORTANT NOTE: THIS DOCUMENT IS YOUR OFFICIAL CERTIFICATION OF COMPLIANCE as stated in each applicable section. It is compiled in accordance with OSHA's Hazard Communication standard (29 CFR 1910.1200), and other federal and state regulations. NOTE: NO ADDITIONAL COMPANY CERTIFICATION OF COMPLIANCE IS REQUIRED WHEN COMPLIANCE IS INDICATED IN THE APPROPRIATE SECTION OF THIS DOCUMENT. To avoid use of outdated information, please completely destroy ALL previously dated MSDS' that are on file. ________________________________________________________________________________ ____ B) ABOUT THE FORMAT OF THIS MATERIAL SAFETY DATA SHEET New and updated MSDS' are presented in the ANSI Z400.1 Sixteen-section format. All available information is included in systematic updates. ________________________________________________________________________________ ____ C) ABOUT THE PURPOSE AND AVAILABILITY OF THIS DOCUMENT Under the federal to Know OSHA Hazard Communication Standard and some State Right
laws, employers using this product in their operation must make this MSDS available to all employees handling this product in any manner. The MSDS must be readily available for review by all persons concerned. This MSDS is designed to effectively communicate Health and Physical Hazards to the material handler and all other responsible persons concerned with Health and Environmental protection and regulatory compliance. Distributors receiving this MSDS are obligated to readily provide a copy to their customers, affiliates, and agents. ________________________________________________________________________________ ____ D) THE PRODUCT USER RESPONSIBILITY NOTICE This type of document cannot cover all possible unique situations. It is the product user's responsibility to provide a safe workplace, and to pass on all Health, Safety and Environmental information to all employees and customers that may handle this product. Under 29 CFR 1910.1200, all product users and handlers must be informed of U.S. OSHA requirements, and the need to be familiar with them. ________________________________________________________________________________ ____ <<<<<<<<<< MATERIAL SAFETY DATA SHEET >>>>>>>>>> -----------------------------------------------------------------------------EFFECTIVE DATE: 11-01-09 04-29-06 NONE SUPERSEDES: PRODUCT CODE: K701
------------------------------------------------------------------------------SECTION 1 CHEMICAL IDENTIFICATION SYNONYM : ACID VIOLET 90(CHROMIUM COMPLEXED DYE) CAS NUMBER : 61916-41-4 CHEMICAL FAMILY: AZO METAL COMPLEX DYE ------------------------------------------------------------------------------SECTION 2 COMPOSITION INFORMATION ON HAZARDOUS INGREDIENTS COMPONENT NAME ACID VIOLET 90 (CHROMIUM COMPLEX DYE)* CHROMIUM* CAS NUMBER 61916-41-4 7440-47-3 PEL NE .5 MG/M3 TLV NE .5 MG/M3 % 85 <3
(AS CR)
(AS CR)
*READ SECTIONS 3 AND 11 FOR ANY ADDITIONAL HEALTH & SAFETY INFORMATION ------------------------------------------------------------------------------SECTION 3 HAZARD IDENTIFICATION AND EMERGENCY OVERVIEW HMIS RATINGS HEALTH FLAMMABILITY REACTIVITY PROTECTION 1 1 0 F
EMERGENCY OVERVIEW: POSSIBLE EXPOSURES: EYES, SKIN, BREATHING DUSTS, ACCIDENTAL SWALLOWING POSSIBLE HEALTH EFFECTS: EYE CONTACT: CAN CAUSE MODERATE IRRITATION 1 SKIN CONTACT: BASED ON ANIMAL TOXICITY DATA, THIS PRODUCT IS NOT EXPECTED TO IRRITATE, HOWEVER, PROLONGED CONTACT CAN POSSIBLY CAUSE IRRITATION 1 BREATHING DUST: NE 1 SWALLOWING: NE 1 SENSITIZATION: NK TARGET ORGANS: EYES, POSSIBLY SKIN CANCER INFORMATION: PRODUCT AND COMPONENTS NOT KNOWN TO US TO BE CARCINOGENS NTP: NK IARC: NK OSHA: NR 1 PRECAUTIONS: TO HELP PROTECT YOURSELF FROM EITHER EXPECTED OR UNFORSEEN IRRITATION OR ALLERGIC REACTIONS, WORKERS SHOULD WEAR ALL PROPERLY SELECTED PROTECTIVE EQUIPMENT AND CLOTHING AS INSTRUCTED IN SECTION 8 OF THIS MSDS. WASH HANDS AND FACE AFTER HANDLING AND BEFORE EATING, DRINKING, SMOKING OR USING RESTROOM FACILITIES. AFTER EACH SHIFT, CLEAN ALL PROTECTIVE EQUIPMENT, WASH ALL WORK CLOTHES, AND SHOWER. SEE SECTION 11, TOXICOLOGY INFORMATION UNUSUAL HAZARDS: IF MIXED WITH AIR IN SUFFICIENT AMOUNTS & PROPORTIONS, ORGANIC DUSTS CAN FORM FLAMMABLE OR EXPLOSIVE DUST/AIR MIXTURES. AS PRECAUTIONS, KEEP AREAS CLEAN AND AVOID DUST BUILD-UP. HAVE PLENTY OF GOOD VENTILATION. AVOID CREATING VERY DUSTY CONDITIONS. WHEN MIXING, POURING OR PROCESSING BULK AMOUNTS OF POWDERS, GROUND ALL CONTAINERS AND AVOID STATIC CHARGES, SPARKS, SMOKING, OPEN FLAMES, OR OTHER POSSIBLE CAUSES OF FIRE OR EXPLOSION. ------------------------------------------------------------------------------SECTION 4 FIRST AID MEASURES EYE CONTACT: IMMEDIATELY RINSE WITH PLENTY OF CLEAN FLOWING WATER FOR 15 TO 20 MINUTES, HOLDING EYELIDS OPEN TO RINSE COMPLETELY. CALL A DOCTOR,
AND GET MEDICAL ATTENTION IMMEDIATELY, AS A PRECAUTION. SKIN CONTACT: REMOVE AFFECTED CLOTHING. WASH AFFECTED SKIN AREA WITH PLENTY OF SOAP AND WATER. RINSE WITH PLENTY OF WATER. WASH ALL WORK CLOTHES BEFORE WEARING AGAIN. IF ANY REDNESS, SWELLING, ITCHING, OR PAIN OF THE SKIN STARTS, SEE A DOCTOR IMMEDIATELY. BREATHING PRODUCT DUST: MOVE PERSON TO FRESH AIR. IF PERSON IS HAVING DIFFICULTY BREATHING, GIVE OXYGEN. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. GET EMERGENCY MEDICAL HELP IMMEDIATELY. CALL 911 IF AVAILABLE IN YOUR AREA, OR OTHER MEDICAL EMERGENCY NUMBER. SWALLOWING OF PRODUCT: IF PERSON IS CONSCIOUS, GIVE WATER OR MILK TO DILUTE STOMACH CONTENTS. NEVER GIVE ANY FLUIDS OR FORCE VOMITING IF THE PERSON IS UNCONSCIOUS, OR IS HAVING CONVULSIONS, OR HAS NO GAG REFLEX. CONTACT A DOCTOR IMMEDIATELY TO GET MEDICAL HELP, CALL 911, OR OTHER MEDICAL EMERGENCY SERVICES AVAILABLE IN YOUR AREA. ------------------------------------------------------------------------------SECTION 5 FIRE FIGHTING MEASURES FLASH POINT : NA TYPES OF EXTINGUISHERS : CO2, DRY CHEMICAL, FOAM, WATER SPRAY FIREFIGHTING DIRECTIONS: WEAR SELF-CONTAINED BREATHING APPARATUS TO PROTECT AGAINST POSSIBLY TOXIC FUMES. WEAR FULL FIRE-PROTECTIVE CLOTHING. UNUSUAL HAZARDS : NONE KNOWN ------------------------------------------------------------------------------SECTION 6 ACCIDENTAL SPILL OR RELEASE MEASURES INSTRUCTIONS FOR SPILLS AND RELEASES: WEAR A NIOSH APPROVED DUST RESPIRATOR, WITH ALL PROTECTIVE CLOTHING AND EQUIPMENT AS DIRECTED IN SECTION 8. CONTAIN AND CLEAN UP SPILL IMMEDIATELY. SWEEP POWDERS CAREFULLY, USING AN ABSORBENT (SWEEPING COMPOUND) TO KEEP DOWN THE DUST IN THE AREA. SCOOP MATERIAL & ABSORBENT INTO DISPOSAL DRUM, AND SEAL. RCRA STATUS: SEE REGULATORY INFORMATION, SECTION 15. ENVIRONMENTAL PROTECTION: PREVENT FROM ENTERING FLOOR DRAINS OR SEWERS. DO NOT RELEASE TO SEWER WITHOUT ALL PROPER GOVERNMENT AUTHORITIES PERMISSION. CHECK SECTION 13, "DISPOSAL CONSIDERATIONS/ENVIRONMENTAL PROTECTION PROCEDURES" FOR ANY ADITIONAL INFORMATION. ------------------------------------------------------------------------------SECTION 7 HANDLING AND STORAGE PROTECT PRODUCT FROM MOISTURE, STORE IN COOL, DRY PLACE UNDER LOW RELATIVE HUMIDITY, AWAY FROM EXCESSIVE HEAT. STORE IN ORIGINAL OR SIMILAR WATERPROOF CONTAINERS. RESEAL CONTAINERS TIGHTLY AFTER EACH USE.
------------------------------------------------------------------------------SECTION 8 EXPOSURE CONTROLS AND PERSONAL PROTECTION NOTE: WHEN SELECTING PERSONAL PROTECTIVE EQUIPMENT AND CLOTHING, FOLLOW ALL MANUFACTURER SPECIFICATIONS AND RECOMMENDATIONS THAT APPLY TO YOUR SPECIFIC OPERATIONS AND PROCESSING CONDITIONS. TAKE INTO CONSIDERATION ALL CONDITIONS AND ALL CHEMICALS TO BE HANDLED OR PROCESSED EYE PROTECTION: WEAR SPLASH-PROOF CHEMICAL SAFETY GOGGLES. CONTACT LENSES SHOULD NOT BE WORN WHEN WORKING WITH CHEMICALS. SKIN PROTECTION: WEAR CHEMICALLY RESISTANT RUBBER GLOVES, SELECTED WITH YOUR SPECIFIC PROCESSING CONDITIONS AND CHEMICALS TO BE HANDLED IN MIND. WEAR COVERALLS AND BOOTS TO MINIMIZE SKIN CONTACT. AS PRECAUTIONS, WASH HANDS & FACE WITH MILD SOAP & WATER BEFORE EATING, DRINKING, SMOKING, OR USING RESTROOM. AFTER EACH SHIFT, CLEAN ALL PROTECTIVE EQUIPMENT, WASH WORK CLOTHES AND SHOWER. LUNG, THROAT & NASAL PROTECTION: WEAR NIOSH APPROVED DUST RESPIRATOR FOR YOUR PARTICULAR OPERATION AND MATERIALS BEING HANDLED. OTHER PROTECTION: EYE WASH FOUNTAINS & DRENCH SHOWERS SHOULD BE LOCATED WITHIN 100 FEET OR A 10 SECOND WALK OF THE WORK AREA PER ANSI Z358.1-1990 VENTILATION: LOCAL EXHAUST IS RECOMMENDED. ------------------------------------------------------------------------------SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES DESCRIPTION MELTING POINT WATER SOLUBILITY PH BULK DENSITY : : : : : BLUISH PINK POWDER; NO ODOR DECOMPOSES BEFORE MELTING 30 G/L 5.6 @ 1% SOLUTION NE
------------------------------------------------------------------------------SECTION 10 STABILITY AND REACTIVITY STABILITY : STABLE CONDITIONS TO AVOID : NK HAZARDOUS POLYMERIZATION: NOT APPLICABLE INCOMPATIBLE MATERIALS : AVOID STRONG OXIDIZING & STRONG REDUCING MATERIALS HAZARDOUS DECOMPOSITION PRODUCTS: BURNING CAN PRODUCE CO, CO2, OXIDES OF NITROGEN AND SULFUR, AND OTHER POTENTIALLY TOXIC FUMES. ------------------------------------------------------------------------------SECTION 11 TOXICOLOGY INFORMATION FOR C.I. ACID VIOLET 90: ORAL LD50 (RAT): > 5000 MG/KG DERMAL LD50 (RAT): NE INHALATION LC50 (RAT): NE EYE EFFECTS (RABBIT): MODERATE IRRITANT 1
SKIN EFFECTS (RABBIT): NE 1 BREATHING EFFECTS: NE 1 CHECK SECTION 3 FOR ANY OTHER OBSERVATIONS, EXPECTATIONS OR COMMENTS 1) AS PRECAUTIONS TO HELP MINIMIZE CONTACT, WEAR ALL PROTECTIVE EQUIPMENT & CLOTHING AS INSTRUCTED IN THE EXPOSURE CONTROLS AND PERSONAL PROTECTION SECTION OF THIS MSDS. SEE SECTION SECTION 8. GENERAL PRECAUTIONS: ALWAYS PRACTICE GOOD INDUSTRIAL HYGIENE, HANDLE WITH CARE, AVOID PERSONAL CONTACT. DO NOT GET INTO EYES OR ON SKIN, DO NOT BREATHE DUST OF PRODUCT, DO NOT SWALLOW. WASH HANDS WITH SOAP AND WATER, AND RINSE WELL AFTER HANDLING PRODUCT. SHOWER AFTER EACH SHIFT. WASH ALL WORK CLOTHING AND COMPLETELY CLEAN ALL PROTECTIVE EQUIPMENT AFTER EACH SHIFT. READ SECTIONS 3 AND 8. MUTAGENICITY: NK ADDITIONAL INFORMATION: CHECK SECTION 3 MEDICAL CONDITIONS MADE WORSE BY EXPOSURE: PERSONS WITH BREATHING AND LUNG PROBLEMS CAN BE AFFECTED BY BREATHING IN ANY TYPE OF DUSTY MATERIAL. PERSONS WITH ASTHMA, ALLERGIES, OR OTHER BREATHING-RELATED PROBLEMS SHOULD STAY AWAY FROM, NOT HANDLE, AND NOT BE EXPOSED TO ANY DUSTY PRODUCTS OR DUSTY CONDITIONS AS A PRECAUTIONARY MEASURE. ------------------------------------------------------------------------------SECTION 12 ECOLOGICAL DATA BOD 5: NE COD: NE FISH TOXICITY: NE SEED TOXICITY: NE CWA TOXIC POLLUTANTS: NK BIOLOGICAL ELIMINATION: NE ------------------------------------------------------------------------------SECTION 13 DISPOSAL CONSIDERATIONS/ENVIRONMENTAL PROTECTION PROCEDURES DISPOSAL METHODS: IT IS RECOMMENDED THAT YOU SELECT AN ALTERNATIVE BELOW ACCORDING TO THE FOLLOWING ORDER OF PREFERENCE, DEPENDING ON ENVIRONMENTAL IMPACT: 1) RECYCLE OR REWORK MATERIAL IF AT ALL POSSIBLE 2) INCINERATE MATERIAL AT AN APPROVED FACILITY 3) TREAT AT AN ACCEPTABLE WASTE TREATMENT FACILITY, OR MUNICIPAL WASTE TREATMENT PLANT AFTER PROPER TESTING & APPROVAL OF WASTE SAMPLES IF DISPOSED OF IN IT'S ORIGINAL UNUSED FORM, THIS MATERIAL SHOULD BE TREATED, AND DISPOSED OF AT AN APPROVED SITE OR FACILITY, IN COMPLIANCE WITH ALL APPLICABLE FEDERAL, STATE & LOCAL ENVIRONMENTAL REGULATIONS. YOU MUST CONTACT THE PROPER GOVERNMENT AGENCIES FOR ADDITIONAL DIRECTIONS.
ALL WASTE MATERIAL & WASTE WATER SHOULD BE DISPOSED OF CORRECTLY, UNDER ALL FEDERAL, STATE , CITY & COUNTY LAWS. RCRA STATUS: SEE SECTION 15, REGULATORY INFORMATION DO NOT RELEASE ANY CHEMICALS, DYES OR DYE SOLUTIONS INTO ANY WATERWAYS OR SYSTEMS WITHOUT PROPER GOVERNMENT TESTING AND AUTHORIZATION. CONTAINER REUSE: AN "EMPTY" CONTAINER CAN CONTAIN PRODUCT RESIDUE, AND SHOULD NOT BE REUSED. IF NOT PROFESSIONALLY CLEANED & RECONDITIONED, CRUSHING OR OTHER MEANS IS RECOMMENDED TO PREVENT UNAUTHORIZED REUSE ------------------------------------------------------------------------------SECTION 14 TRANSPORT INFORMATION DOT STATUS: NR -----------------------------------------------------------------------------SECTION 15 REGULATORY INFORMATION AICS (Australia): Listed CAA: PRODUCT IS NOT MANUFACTURED WITH, NOR DOES IT CONTAIN CLASS I OR CLASS II OZONE DEPLETING CHEMICALS. CAL. PROP. 65: CONTAINS THE FOLLOWING CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER OR REPRODUCTIVE TOXICITY: NO QUANTITATIVE DATA IS CURRENTLY AVAILABLE. CERCLA: CONTAINS CHROMIUM COMPOUND. FOR REPORTABLE QUANTITY SEE 40 CFR 302.4 CONEG-TYPICAL METALS PRESENT IN PPM: CADMIUM NE CHROMIUM NE LEAD NE MERCURY NE DSL (Canada): Listed ECL (Korea): Not listed EINECS: Listed ENCS (Japan): Listed FDA STATUS: NL OTHER TYPICAL DATA IN PPM: ANTIMONY NE ARSENIC NE BARIUM NE COBALT NE COPPER NE MANGANESE NE SELENIUM NE SILVER NE ZINC NE RCRA: COMPOUND PER SE HAZARDOUS WASTE UNDER RCRA EP TOXICITY D007 (CHROMIUM) SARA 311/312: IMMEDIATE/ACUTE HEALTH HAZARD : DELAYED/CHRONIC HEALTH HAZARD : FIRE HAZARD : SUDDEN RELEASE OF PRESSURE HAZARD: REACTIVITY HAZARD : (40 CFR 261.24) YES YES NO NO NO
SARA 313: C.I. ACID VIOLET 90 (CHROMIUM COMPLEX DYE), 85% CHROMIUM, 7440-47-3, <3% TSCA: LISTED USDA: NL WHMIS: NC ------------------------------------------------------------------------------SECTION 16 OTHER INFORMATION V-003714-02171999-LKB ACRONYM LIST NA NC ND NE NH NK NL NR = = = = = = = = NOT APPLICABLE TO THIS MATERIAL NOT CERTAIN, UNDETERMINED NO DATA IS CURRENTLY AVAILABLE NOT ESTABLISHED, NO TESTING IS PLANNED NOT HAZARDOUS UNDER CITED REGULATIONS NONE KNOWN NOT LISTED OR APPROVED UNDER THESE REGULATIONS NOT REGULATED OR REPORTABLE
NIOSH = NATIONAL INSTITUTE FOR OCCUPATIONAL SAFETY AND HEALTH THE INFORMATION AND RECOMMENDATIONS CONTAINED HEREIN ARE BASED UPON DATA BELIEVED TO BE CORRECT. HOWEVER, NO GUARANTEE OR WARRANTY OF ANY KIND EXPRESSED OR IMPLIED, IS MADE WITH RESPECT TO THE INFORMATION CONTAINED HEREIN. THIS MATERIAL SAFETY DATA SHEET WAS PREPARED TO COMPLY WITH THE OSHA HAZARD COMMUNICATION STANDARD 29 CFR 1910.1200, AND SUPERSEDES ANY PREVIOUS INFORMATION. PREVIOUSLY DATED SHEETS ARE INVALID & UNAPPLICABLE.
CHEMTREC (24HOUR) 800-424-9300

-----------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION I: CHEMICAL PRODUCT AND COMPANY IDENTIFICATION -----------------------------------------------------------------------------------------------------------------------------------------------------------------TRADE NAME: AMECID WOOL BLUE R CHEMICAL FAMILY: AZO
CHEMTREC 800-424-9300
DATE PREPARED: SEPTEMBER 2009 ---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION II: COMPOSITION/INFORMATION ON HAZARDOUS INGREDIENTS ---------------------------------------------------------------------------------------------------------------------------------------------------------------CHEMICAL NAME CAS NUMBER %BY WT. TLV/PEL ACID BLUE 92 03861-73-2 65-80% NOT ESTABLISHED --------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION III: HAZARDS IDENTIFICATION ---------------------------------------------------------------------------------------------------------------------------------------------------------------EMERGENCY OVERVIEW: MAY CAUSE SKIN, EYE AND RESPIRATORY IRRITATION. EFFECTS OF OVEREXPOSURE: EYE CONTACT: MAY BE IRRITATING. SKIN CONTACT: MAY BE IRRITATING. INHALATION: MAY BE IRRITATING. INGESTION: NOT KNOWN. CHRONIC EXPOSURE: NOT KNOWN. CARCINOGENICITY: NOT LISTED AS AN IARC, NTP OR OSHA CARCINOGEN. MEDICAL CONDITIONS AGGREVATED BY EXPOSURE: NOT KNOWN PRIMARY ROUTES OF ENTRY: SKIN CONTACT, EYE CONTACT AND INHALATION. ---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION IV: FIRST AID MEASURES ---------------------------------------------------------------------------------------------------------------------------------------------------------------EYE CONTACT: IMMEDIATELY FLUSH EYE WITH FLOWING WATER FOR AT LEAST 15 MINUTES, HOLDING EYELIDS APART TO IRRIGATE THOROUGHLY. GET MEDICAL ATTENTION. SKIN CONTACT: WASH THOROUGHLY WITH SOAP AND WATER. GET MEDICAL ATTENTION IF IRRITATION DEVELOPS. REMOVE AND LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. INHALATION: REMOVE TO FRESH AIR. IF BREATHING IS DIFFICULT, GIVE OXYGEN. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. GET MEDICAL ATTENTION. INGESTION: DILUTE WITH WATER AND INDUCE VOMITING. GET MEDICAL ATTENTION. NEVER GIVE FLUIDS OR INDUCE VOMITING IF PATIENT IS UNCONSCIOUS OR HAS CONVULSIONS. ---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION V: FIRE FIGHTING MEASURES ---------------------------------------------------------------------------------------------------------------------------------------------------------------FLASH POINT: NOT DETERMINED. LOWER EXPLOSIVE LIMIT: NOT APPLICABLE. UPPER EXPLOSIVE LIMIT: NOT APPLICABLE AUTOIGNITION TEMPERATURE: NOT DETERMINED. 1 MSDS 02-0002
EXTINGUISHING MEDIA: WATER, DRY CHEMICAL, CARBON DIOXIDE, AND FOAM. SPECIAL FIRE FIGHTING PROCEDURES: FIREFIGHTERS SHOULD BE EQUIPPED WITH SELF CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING. UNUSUAL HAZARDS: DUST AMY BE EXPLOSIVE IF MIXED WITH AIR IN CRITICAL PROPORTIONS AND IN THE PRESENCE OF SOURCE OF IGNITION. ---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION VI: ACCIDENTAL RELEASE MEASURES ---------------------------------------------------------------------------------------------------------------------------------------------------------------STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: WEAR APPROPRIATE SAFETY EQUIPMENT. CONTAIN AND CLEAN UP SPILL IMMEDIATELY. PREVENT FROM ENTERING FLOOR DRAINS. SWEEP POWDERS CAREFULLY MINIMIZING DUSTING. SHOVEL ALL SPILL MATERIALS INTO DISPOSAL DRUMS AND FOLLOW DISPOSAL INSTRUCTIONS. SCRUB SPILL AREA WITH DETERGENT AND FLUSH WITH COPIOUS AMOUNTS OF WATER. ---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION VII: HANDLING AND STORAGE ---------------------------------------------------------------------------------------------------------------------------------------------------------------HANDLING: IN ACCORDANCE WITH GOOD INDUSTRIAL PRACTICES, HANDLE WITH CARE AND AVOID PERSONAL CONTACT. CONTAINERS SHOULD BE TRIPLE RINSED ACCORDING TO FEDERAL REGULATIONS AND/OR GOOD WASTE MANAGEMENT PRCATICES. FOR INDUSTRIAL USE ONLY. STORAGE: KEEP CONTAINERS CLOSED WHEN NOT IN USE. ---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION VIII: EXPOSURE CONTROL/PERSONAL PROTECTION ---------------------------------------------------------------------------------------------------------------------------------------------------------------ENGINEERING CONTROLS: LOCAL EXHAUST TO MINIMIZE EXPOSURE. RESPIRATORY PROTECTION: IF EXPOSURE TO DUST IS LIKELY, A NIOSH APPROVED DUST RESPIRATOR IS RECOMMENDED. EXPOSURE LIMITS: NOT ESTABLISHED. EYE PROTECTION: WEAR SAFETY GLASSES WITH SIDE SHIELDS OR SAFETY GOGGLES. SKIN PROTECTION: WEAR RUBBER GLOVES. OTHER PROTECTIVE MEASURES: WEAR APRON, COVERALLS, BOOTS AND LONG SLEEVE SHIRT TO PREVENT SKIN CONTACT. HYGIENIC PRACTICES: EYEWASH FOUNTAINS SHOULD BE EASILY ACCESSIBLE. SHOWER AFTER HANDLING THIS PRODUCT. WORK CLOTHES SHOULD BE WASHED BEFORE REUSE. BEFORE EATING, DRINKING, OR SMOKING, WASH HANDS AND FACE WITH SOAP AND WATER. ---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION IX: PHYSICAL AND CHEMICAL PROPERTIES ---------------------------------------------------------------------------------------------------------------------------------------------------------------APPEARANCE: DARK BLUE POWDER ODOR: NONE SOLUBILITY IN WATER: SOLUBLE PH: 3.0-5.5 BOILING POINT: NOT APPLICABLE. MELTING POINT: NOT ESTABLISHED. -------------------------------------------------------------------------------------------------------------------------------------SECTION X: STABILITY AND REACTIVITY ---------------------------------------------------------------------------------------------------------------------------------------------------------------STABILITY: STABLE. CONDITIONS TO AVOID: NONE KNOWN. HAZARDOUS POLYMERIZATION: WILL NOT OCCUR. 2 MSDS 02-0002
INCOMPATIBLE MATERIALS: NONE KNOWN. HAZARDOUS DECOMPOSITION PRODUCTS: BURNING WILL PRODUCE OXIDES OF CARBON, NITROGEN AND SULFUR. ---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION XI: TOXICOLOGICAL PROPERTIES ---------------------------------------------------------------------------------------------------------------------------------------------------------------RAT, ORAL LD50: NOT ESTABLISHED RABBIT, SKIN: NOT ESTABLISHED RABBIT, EYES: MAY BE IRRITATING ADDITIONAL TOXICITY DATA: NOT KNOWN. ---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION XII: ECOLOGICAL INFORMATION ---------------------------------------------------------------------------------------------------------------------------------------------------------------NO INFORMATION IS CURRENTLY AVAILABLE. ---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION XIII: DISPOSAL CONSIDERATIONS ---------------------------------------------------------------------------------------------------------------------------------------------------------------WASTE DISPOSAL METHOD: THIS PRODUCT IS NOT TO BE CONSIDERED A HAZARDOUS WASTE UNDER RCRA (40 CFR 261).DISPOSAL MUST BE IN ACCORDANCE WITH APPLICABLE GOVERNMENTAL REGULATIONS. CONTAINER DISPOSAL INFORMATION: CONTAINERS SHOULD BE TRIPLE RINSED ACCORDING TO FEDERAL REGULATIONS AND/OR GOOD WASTE MANAGEMENT PRACTICE. ---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION XIV: TRANSPORTATION INFORMATION ---------------------------------------------------------------------------------------------------------------------------------------------------------------DOT PROPER SHIPPING NAME: NOT REGULATED. DOT TECHNICAL NAME: NOT APPLICABLE. DOT HAZARD CLASS: NOT APPLICABLE. HAZARD SUBCLASS: NOT APPLICABLE. DOT UN/NA NUMBER: NOT APPLICABLE. PACKING GROUP: NOT APPLICABLE. RESP. GUIDE PAGE: NOT APPLICABLE. DOT REPORTABLE QUANTITY: NOT APPLICABLE. DOT LABELS: NOT APPLICABLE. ---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION XV: REGULATORY INFORMATION ---------------------------------------------------------------------------------------------------------------------------------------------------------------SARA TITLE III SECTION 302: THIS PRODUCT DOES NOT CONTAIN ANY CHEMICALS REGULATED UNDER SECTION 302 AS EXTREMELY HAZARDOUS. SARA TITLE III SECTION 304 (CERCLA): THIS PRODUCT DOES NOT CONTAIN ANY CHEMICALS REGULATED UNDER SECTION 304 AS A HAZARDOUS SUBSTANCE FOR EMERGENCY RELEASE NOTIFICATION. SARA TITLE III SECTION 312 HAZARD RATING: ACUTE: YES CHRONIC: NO FLAMMABILITY: NO REACTIVITY: NO PRESSURE: NO SARA TITLE III SECTION 313: THIS PRODUCT IS NOT REPORTABLE FOR SARA 313. TSCA: THIS PRODUCT IS REGISTERED UNDER THE REGULATIONS OF THE TOXIC SUBSTANCES CONTROL ACT (TSCA). STATE RIGHT TO KNOW INFORMATION INGREDIENT ACID BLUE 92 3 CAS NUMBER 03861-73-2 MSDS 02-0002
---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION XVI: OTHER INFORMATION ---------------------------------------------------------------------------------------------------------------------------------------------------------------HMIS RATING: HEALTH -1 FIRE - 1 REACTIVITY - 0 PERSONAL PROTECTION - E NFPA RATING: HEALTH - 1 FIRE - 1 REACTIVITY 0
MSDS 02-0002
Within U.S. Call CHEMTEL 1-800-255-3924 Outside U.S. Call Collect: CHEMTEL 1-813-248-0585
HMIS RATINGS:
HEALTH:
FIRE: 1
REACTIVITY: 0
PERSONAL PROTECTION:

Product I.D.: Product Name: Product Description: C.I. Name: C.I. Number: Chemical Family: CAS Number: Effective Date: K219 ACID BLUE 113 Powdered Acid Blue 113 Acid Blue 113 26360 Azo dyes 3351-05-1 September 14, 2009

Recommended PEL Not applicable
Component Acid Blue 113
CAS Number 3351-05-1
Wt % 90 - 100%
OSHA - PEL 15 mg/m3 TWA Total dust 5 mg/m3 Respirable
ACGIH - TLV 10 mg/m3 TWA Total dust 3 mg/m3 Respirable
Emergency Overview: Mild to moderate eye irritant Eye Contact: Depending on product form and the degree and length of unprotected exposure, vapors, mists, splashes, or dusts of product or components can cause one or more of the following health effects: MILD TO MODERATE IRRITATION, discomfort, redness, watering and itching to unprotected eyes. Other effects as follows, by component, ONLY apply when component is listed in Section 2: Acid Yellow 80103651: Over-exposure risks damage to eyes. Iron Oxide: Long-term exposure can stain eyes causing "rust rings". Skin Contact:
MATERIAL SAFETY DATA SHEET (continued)

K219 ACID BLUE 113 NOT KNOWN OR EXPECTED to present a significant hazard to skin. However, as a precaution against unforeseen, unexpected irritation, hypersensitivity or allergic reactions, follow ALL supervisor instructions, and Section 8 instructions for use of Personal Protective Equipment. Inhalation: The hazards and health effects from UNPROTECTED INHALATION of vapors, mists or aerosols of this product HAVE NOT BEEN DETERMINED. As a precaution against the possibility of effects to existing medical conditions, unknown irritation, hypersensitivity, allergic reactions, or other unforeseen health effects, be sure to follow ALL supervisor instructions, AND Section 8 MSDS instructions for use of Personal Protective Equipment and clothing when working with this product. Ingestion: NOT EXPECTED to be a hazard with proper handling and good chemical hygiene procedures being followed. Wear appropriate, chemically impervious gloves to avoid accidental transferring and swallowing of chemical residue. This chemical may be a greater health hazard if swallowed deliberately, or in a large amount. In such cases, some effects may parallel those of inhalation or skin absorption. Medical Conditions Aggravated by Exposure: Unprotected or improperly protected exposures to (breathing) any vapors, mists, aerosols, or dusts of this product or its components MAY AGGRAVATE one or more of the following pre-existing medical conditions: Respiratory (breathing related) problems (asthma, allergies, etc.), skin conditions, or disorders. kidney disorders, liver disorders. Avoid ALL exposures. Individuals with any of the above-noted conditions, or with any known or suspected chemical sensitivities or allergies should avoid working with or being exposed to any chemicals. Skin Sensitization: NOT KNOWN to cause skin sensitization or allergic reactions. Harmful effects are not expected. Respiratory Sensitization: The possibility of respiratory sensitization caused by inhalation exposure to product dusts, vapors, mists or aerosols HAS NOT BEEN DETERMINED. As a precaution against unknown effects on existing respiratory conditions, hypersensitivity, allergic reactions, or other unforeseen health effects, be sure to read, understand and follow all supervisor instructions, AND instructions for wearing Personal Protective Equipment and clothing in Section 8 of this MSDS. Avoid unprotected inhalation of product in any form. Supplemental Hazard Information: No additional information available Notes to Physician: No notes available Cancer Information: *** Not known to contain carcinogens ***
Page 2 of 7

Eye Contact: Immediately rinse with plenty of water for at least 15 minutes. Get immediate medical attention, as a precaution. Skin Contact: Immediately remove contaminated clothing. Wash affected area with soap and rinse with plenty of water. Get medical attention, as a precaution. Inhalation: Move person to fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration, and get emergency medical help immediately. Have this Material Safety Data Sheet available.

K219 ACID BLUE 113 Ingestion: Do not induce vomiting unless directed to do so by emergency medical personnel. Have this Material Safety Data Sheet available.
Page 3 of 7

Flash Point: Not applicable Unusual hazards: None expected Other Hazards: None known Types of Extinguishers: CO2, dry chemical, foam, water fog or spray depending on type of fire Fire Fighting Directions: Wear self-contained breathing equipment and fire-proof clothing. Use water spray to cool fire exposed containers if they cannot be safely moved.

Special Precautions: None known. Follow general precautions shown below. Static Discharges: Take precautionary measures against static discharges when mixing, filling or otherwise dispensing any powders, combustibles, or flammable liquids. Containers should be properly grounded with metal straps, cables or other appropriate means to relieve static electricity build-up. Environmental Protection: Immediately dike liquid spills with inert absorbent material (sand, "Oil Dry" or other commercially available spill absorbent) to contain and soak up liquid. Prevent material from entering floor drains, sewers, or any bodies of water. For powder spills, use sweeping compound, sawdust, or other appropriate material to contain dust. If possible, recover any uncontaminated materials to re-use. Protective equipment and clothing: Wear all proper personal protective equipment and clothing to care for spill situation. See section 8 of this MSDS. Clean up: After containing spill by diking and soaking up with inert absorbent material, place in labeled container to be sealed for proper and regulated disposal. Save uncontaminated material for reuse whenever possible. Do not allow any liquid to seep into drains, sewers, lakes, rivers, etc.

Warnings and Precautions: No special precautions anticipated. Wear all PPE in section 8 as a precaution, and avoid physical contact with material. Personal Protection: Wear ALL proper personal protective equipment as outlined in section 8 of this MSDS. Storage & Temperature Conditions: Keep conditions cool, dry, out of direct sunlight, away from high heat, with at least minimal ventilation. Protect from freezing.

Note: Selecting protective equipment & clothing: When choosing personal protective equipment and clothing, consider each worker environment, all chemicals being handled, temperature and all other conditions.

K219 ACID BLUE 113 Eye protection: Always wear indirectly vented, splash-proof chemical safety goggles under a clear face-shield. Face shield is not to be used without these goggles. Skin Protection: Always wear most impervious gloves such as nitrile or other proper chemical-resistant gloves for the job, along with proper coveralls, rubber or plastic apron, etc. Wash hands before eating, drinking or using restroom. Shower after each shift. Clean contaminated protective equipment and clothing before reusing. Respiratory Protection: Depending on materials handled, ALWAYS wear an appropriate NIOSH approved organic vapor/mist respirator, or dust respirator, with all proper filters as required whenever exposure to vapors or dusts is expected. After each shift or when equipment becomes contaminated, clean respirator in compliance with 29 CFR 1910.134. Eye Washes and Other Protection: Eye wash stations and drench showers should be located within 100 feet or 10-second walk of the work area per ANSI standard Z358.1-1990. Ventilation: Local exhaust should be used to maintain exposure limits below specified amounts recommended by OSHA, NIOSH, or ACGIH and to draw spray, aerosol, vapors, or dusts away from workers and prevent routine inhalation. At least 10 air changes per hour are recommended for good room ventilation. Airborne Exposure Limits: Not referenced in literature
Page 4 of 7

pH: % Water Content: % Total NonVolatiles: % Total Solids: % Total VOC: Boiling Point: Color: Bulk Density (Solid): Form: Odor: Specific Gravity (Liquid): Vapor Pressure: Water Solubility: Solvent Solubility: 7.5 - 9.0 @ 1 g/l H20 0 100% 100% 0 Not applicable Blue Not established Powder None Not applicable 0 100 g/l @ 30 C (86 F) Not applicable
The quantity of VOC's reported here is calculated based on the U.S. EPA definition. State or local definitions may differ. To request additional Regulatory Compliance Data, call 312-666-2015.

Stability: Product is stable under normal, ambient (controlled) conditions concerning heat, moisture, pressure, ventilation and exposure to incompatible or reactive materials.

K219 ACID BLUE 113 Hazardous Polymerization: Product will not undergo polymerization. Conditions to Avoid: Moisture in storage, high dust condition & static charges, incompatibles. Incompatible Materials: Strong oxidizing agents, strong acids, strong bases Hazardous Decomposition Products: In fire: Oxides of carbon, nitrogen & sulfur
Page 5 of 7

Oral LD50 (Rat): Eye Effects (Rabbit): Skin Effects (Rabbit): Mutagenicity: Inhalation LC50 (Rat): Skin Sensitization (Guinea Pig): Respiratory Sensitization: Additional Toxicity Data: > 5000 mg/kg Irritant Non-irritant No data currently available No data currently available No data currently available No data currently available No data currently available

BOD: COD: Aquatic Toxicity: Biodegradability: Persistence: Ecotoxicity: Other Data: No data currently available No data currently available No data currently available No data currently available No data currently available No data currently available No additional data is available

K219 ACID BLUE 113
Page 6 of 7

DOT Regulations (Ground): NOT REGULATED IATA Regulations (Air): NOT REGULATED

Component Acid Blue 113 CAS Number 3351-05-1 Weight % 90 -100% Regulatory List No references
Regulatory List Reference: 1- CONEG 3-SARA 304/CERCLA Hazardous Substance 2-RCRA Hazardous Waste 4-SARA 311/312 Hazard Categories: Immediate/Acute Health Hazard: Delayed/Chronic Health Hazard: Fire Hazard: Sudden Release of Pressure Hazard: Reactivity Hazard: 6-Clean Water Act 8-SOCMI Chemical 10-PSM Highly Hazardous Chemical 12-WHMIS (Canada) 14-NIOSH Recommendations 16-Marine Pollutants
5-SARA 313 Toxic Release Chemical 7-Clean Air Act 9-Ozone Depleting Chemical 11-FDA Status 13-USDA Status 15-Other Regulatory Information 17-State Lists CA-California Proposition 65 DE-Delaware Air Quality Management List FL-Florida Toxic Substances List MA-Massachusetts Hazardous Substance List MI-Michigan Critical Materials Register MN-Minnesota Hazardous Substances List NJ-RTK-New Jersey RTK Hazardous Substance List NJ-TCPA-New Jersey TCPA Extremely Hazardous Substance List NY-New York List of Hazardous Substances PA-Pennsylvania Hazardous Substance List WA-Washington Permissible Exposure Limits for Air Contaminates
SARA 311/312 Hazard Categories: Immediate / Acute Health Hazard: Chronic / Delayed Hazard: Fire Hazard: Sudden Release of Pressure Hazard: Reactivity Hazard: NATIONAL CHEMICAL INVENTORIES: AICS (Australia): Not yet determined Yes No No No No

K219 ACID BLUE 113 ASIA-PAC (Asia-Pacific): DSL (Canada): ECL (Korea): EINECS (Europe): ENCS (Japan): IECSC (China): PICCS (Phillipines): TSCA (US): OTHER: Supplemental Regulatory Information: For additional International, Federal or State regulatory compliance information not shown: Call 312-666-2015. Not yet determined Not yet determined Not yet determined Not yet determined Not yet determined Not yet determined Not yet determined Components Listed
Page 7 of 7

Reason for Revision: None at this time
Disclaimer: The information and recommendations contained herein are based upon data believed to be correct. However, no guarantee or warranty of any kind, expressed or implied, is made with respect to the information contained herein. This Material Safety Data Sheet was prepared to comply with the OSHA Hazard Communication Standard 29 CFR 1910.1200, and supersedes any previous information. Previously dated sheets are invalid and inapplicable. END OF MSDS

-----------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION I: CHEMICAL PRODUCT AND COMPANY IDENTIFICATION -----------------------------------------------------------------------------------------------------------------------------------------------------------------TRADE NAME: AMENYL BRILLIANT RED B CHEMICAL FAMILY: MONOAZO
CHEMTREC 800-424-9300
DATE PREPARED: FEBRUARY 2010 ---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION II: COMPOSITION/INFORMATION ON HAZARDOUS INGREDIENTS ---------------------------------------------------------------------------------------------------------------------------------------------------------------CHEMICAL NAME CAS NUMBER %BY WT. TLV/PEL ACID RED 131 70210-37-6 NOT ESTABLISHED --------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION III: HAZARDS IDENTIFICATION ---------------------------------------------------------------------------------------------------------------------------------------------------------------EMERGENCY OVERVIEW: MAY CAUSE SKIN, EYE AND RESPIRATORY IRRITATION. EFFECTS OF OVEREXPOSURE: EYE CONTACT: IRRITATING. SKIN CONTACT: MAY BE IRRITATING. INHALATION: MAY BE IRRITATING. INGESTION: NOT KNOWN. CHRONIC EXPOSURE: NOT KNOWN. CARCINOGENICITY: NOT LISTED AS AN IARC, NTP OR OSHA CARCINOGEN. MEDICAL CONDITIONS AGGREVATED BY EXPOSURE: NOT KNOWN PRIMARY ROUTES OF ENTRY: SKIN CONTACT, EYE CONTACT AND INHALATION. ---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION IV: FIRST AID MEASURES ---------------------------------------------------------------------------------------------------------------------------------------------------------------EYE CONTACT: IMMEDIATELY FLUSH EYE WITH FLOWING WATER FOR AT LEAST 15 MINUTES, HOLDING EYELIDS APART TO IRRIGATE THOROUGHLY. GET MEDICAL ATTENTION. SKIN CONTACT: WASH THOROUGHLY WITH SOAP AND WATER. GET MEDICAL ATTENTION IF IRRITATION DEVELOPS. REMOVE AND LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. INHALATION: REMOVE TO FRESH AIR. IF BREATHING IS DIFFICULT, GIVE OXYGEN. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. GET MEDICAL ATTENTION. INGESTION: DILUTE WITH WATER AND INDUCE VOMITING. GET MEDICAL ATTENTION. NEVER GIVE FLUIDS OR INDUCE VOMITING IF PATIENT IS UNCONSCIOUS OR HAS CONVULSIONS. ---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION V: FIRE FIGHTING MEASURES ---------------------------------------------------------------------------------------------------------------------------------------------------------------FLASH POINT: NOT DETERMINED. LOWER EXPLOSIVE LIMIT: NOT APPLICABLE. UPPER EXPLOSIVE LIMIT: NOT APPLICABLE AUTOIGNITION TEMPERATURE: NOT DETERMINED. EXTINGUISHING MEDIA: WATER, DRY CHEMICAL, CARBON DIOXIDE, AND FOAM. 1 MSDS 02-0002
SPECIAL FIRE FIGHTING PROCEDURES: FIREFIGHTERS SHOULD BE EQUIPPED WITH SELF CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING. UNUSUAL HAZARDS: DUST AMY BE EXPLOSIVE IF MIXED WITH AIR IN CRITICAL PROPORTIONS AND IN THE PRESENCE OF SOURCE OF IGNITION. ---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION VI: ACCIDENTAL RELEASE MEASURES ---------------------------------------------------------------------------------------------------------------------------------------------------------------STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: WEAR APPROPRIATE SAFETY EQUIPMENT. CONTAIN AND CLEAN UP SPILL IMMEDIATELY. PREVENT FROM ENTERING FLOOR DRAINS. SWEEP POWDERS CAREFULLY MINIMIZING DUSTING. SHOVEL ALL SPILL MATERIALS INTO DISPOSAL DRUMS AND FOLLOW DISPOSAL INSTRUCTIONS. SCRUB SPILL AREA WITH DETERGENT AND FLUSH WITH COPIOUS AMOUNTS OF WATER. ---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION VII: HANDLING AND STORAGE ---------------------------------------------------------------------------------------------------------------------------------------------------------------HANDLING: IN ACCORDANCE WITH GOOD INDUSTRIAL PRACTICES, HANDLE WITH CARE AND AVOID PERSONAL CONTACT. CONTAINERS SHOULD BE TRIPLE RINSED ACCORDING TO FEDERAL REGULATIONS AND/OR GOOD WASTE MANAGEMENT PRCATICES. FOR INDUSTRIAL USE ONLY. STORAGE: KEEP CONTAINERS CLOSED WHEN NOT IN USE. ---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION VIII: EXPOSURE CONTROL/PERSONAL PROTECTION ---------------------------------------------------------------------------------------------------------------------------------------------------------------ENGINEERING CONTROLS: LOCAL EXHAUST TO MINIMIZE EXPOSURE. RESPIRATORY PROTECTION: IF EXPOSURE TO DUST IS LIKELY, A NIOSH APPROVED DUST RESPIRATOR IS RECOMMENDED. EXPOSURE LIMITS: NOT ESTABLISHED. EYE PROTECTION: WEAR SAFETY GLASSES WITH SIDE SHIELDS OR SAFETY GOGGLES. SKIN PROTECTION: WEAR RUBBER GLOVES. OTHER PROTECTIVE MEASURES: WEAR APRON, COVERALLS, BOOTS AND LONG SLEEVE SHIRT TO PREVENT SKIN CONTACT. HYGIENIC PRACTICES: EYEWASH FOUNTAINS SHOULD BE EASILY ACCESSIBLE. SHOWER AFTER HANDLING THIS PRODUCT. WORK CLOTHES SHOULD BE WASHED BEFORE REUSE. BEFORE EATING, DRINKING, OR SMOKING, WASH HANDS AND FACE WITH SOAP AND WATER. ---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION IX: PHYSICAL AND CHEMICAL PROPERTIES ---------------------------------------------------------------------------------------------------------------------------------------------------------------APPEARANCE: POWDER ODOR: NONE SOLUBILITY IN WATER: SOLUBLE BOILING POINT: NOT APPLICABLE. MELTING POINT: NOT ESTABLISHED. -------------------------------------------------------------------------------------------------------------------------------------SECTION X: STABILITY AND REACTIVITY ---------------------------------------------------------------------------------------------------------------------------------------------------------------STABILITY: STABLE. CONDITIONS TO AVOID: NONE KNOWN. HAZARDOUS POLYMERIZATION: WILL NOT OCCUR. INCOMPATIBLE MATERIALS: NONE KNOWN.
MSDS 02-0002
HAZARDOUS DECOMPOSITION PRODUCTS: BURNING WILL PRODUCE OXIDES OF CARBON, NITROGEN AND SULFUR. ---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION XI: TOXICOLOGICAL PROPERTIES ---------------------------------------------------------------------------------------------------------------------------------------------------------------RAT, ORAL LD50: NOT ESTABLISHED RABBIT, SKIN: NOT ESTABLISHED RABBIT, EYES: NOT ESTABLISHED, PROBABLY IRRITATING. ADDITIONAL TOXICITY DATA: NOT KNOWN. ---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION XII: ECOLOGICAL INFORMATION ---------------------------------------------------------------------------------------------------------------------------------------------------------------NO INFORMATION IS CURRENTLY AVAILABLE. ---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION XIII: DISPOSAL CONSIDERATIONS ---------------------------------------------------------------------------------------------------------------------------------------------------------------WASTE DISPOSAL METHOD: THIS PRODUCT IS NOT TO BE CONSIDERED A HAZARDOUS WASTE UNDER RCRA (40 CFR 261).DISPOSAL MUST BE IN ACCORDANCE WITH APPLICABLE GOVERNMENTAL REGULATIONS. CONTAINER DISPOSAL INFORMATION: CONTAINERS SHOULD BE TRIPLE RINSED ACCORDING TO FEDERAL REGULATIONS AND/OR GOOD WASTE MANAGEMENT PRACTICE. ---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION XIV: TRANSPORTATION INFORMATION ---------------------------------------------------------------------------------------------------------------------------------------------------------------DOT PROPER SHIPPING NAME: NOT REGULATED. DOT TECHNICAL NAME: NOT APPLICABLE. DOT HAZARD CLASS: NOT APPLICABLE. HAZARD SUBCLASS: NOT APPLICABLE. DOT UN/NA NUMBER: NOT APPLICABLE. PACKING GROUP: NOT APPLICABLE. RESP. GUIDE PAGE: NOT APPLICABLE. DOT REPORTABLE QUANTITY: NOT APPLICABLE. DOT LABELS: NOT APPLICABLE. ---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION XV: REGULATORY INFORMATION ---------------------------------------------------------------------------------------------------------------------------------------------------------------SARA TITLE III SECTION 302: THIS PRODUCT DOES NOT CONTAIN ANY CHEMICALS REGULATED UNDER SECTION 302 AS EXTREMELY HAZARDOUS. SARA TITLE III SECTION 304 (CERCLA): THIS PRODUCT DOES NOT CONTAIN ANY CHEMICALS REGULATED UNDER SECTION 304 AS A HAZARDOUS SUBSTANCE FOR EMERGENCY RELEASE NOTIFICATION. SARA TITLE III SECTION 312 HAZARD RATING: ACUTE: YES CHRONIC: NO FLAMMABILITY: NO REACTIVITY: NO PRESSURE: NO SARA TITLE III SECTION 313: THIS PRODUCT IS NOT REPORTABLE FOR SARA 313. TSCA: THIS PRODUCT IS REGISTERED UNDER THE REGULATIONS OF THE TOXIC SUBSTANCES CONTROL ACT (TSCA). STATE RIGHT TO KNOW INFORMATION INGREDIENT ACID RED 131 CAS NUMBER 70210-37-6
MSDS 02-0002
---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION XVI: OTHER INFORMATION ---------------------------------------------------------------------------------------------------------------------------------------------------------------HMIS RATING: HEALTH - 1 FIRE - 1 REACTIVITY - 0 PERSONAL PROTECTION - F NFPA RATING: HEALTH - 1 FIRE - 1 REACTIVITY - 0 DISCLAIMER: KEYCOLOUR INC. BELIEVES ALL THE INFORMATION AND DATA GIVEN IS ACCURATE AS OF THE DATE OF PREPARATION AND IS OFFERED IN GOOD FAITH. THIS INFORMATION IS GIVEN WITHOUT WARRANTY OR REPRESENTATION SOLELY FOR YOUR CONSIDERATION, INVESTIGATION, AND VERIFICATION. SINCE CONDITIONS OF USE ARE BEYOND OUR CONTROL, KEYCOLOUR INC. EXPRESSLY DISCLAIMS ALL LIABILITY FOR THE USE OR HANDLING OF THIS PRODUCT.
MSDS 02-0002

--------------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION I: CHEMICAL PRODUCT AND COMPANY IDENTIFICATION --------------------------------------------------------------------------------------------------------------------------------------------------------------------TRADE NAME: AMENYL YELLOW BGT CHEMICAL FAMILY: AZO DYE
CHEMTREC 800-424-9300
DATE PREPARED: NOVEMBER 2009 ---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION II: COMPOSITION/INFORMATION ON HAZARDOUS INGREDIENTS ---------------------------------------------------------------------------------------------------------------------------------------------------------------CHEMICAL NAME CAS NUMBER %BY WT. TLV/PEL ACID YELLOW 135 12235-21-1 NOT ESTABLISHED DEXTRIN 9004-53-9 3%+ SODIUM CHLORIDE 7647-14-5 3%+ --------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION III: HAZARDS IDENTIFICATION ---------------------------------------------------------------------------------------------------------------------------------------------------------------EMERGENCY OVERVIEW: MAY CAUSE SKIN, EYE AND RESPIRATORY IRRITATION. EFFECTS OF OVEREXPOSURE: EYE CONTACT: MAY BE IRRITATING. SKIN CONTACT: MAY BE IRRITATING. INHALATION: MAY BE IRRITATING. INGESTION: NOT KNOWN. CHRONIC EXPOSURE: NOT KNOWN. CARCINOGENICITY: NOT LISTED AS AN IARC, NTP OR OSHA CARCINOGEN. MEDICAL CONDITIONS AGGREVATED BY EXPOSURE: NOT KNOWN PRIMARY ROUTES OF ENTRY: SKIN CONTACT, EYE CONTACT AND INHALATION. ---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION IV: FIRST AID MEASURES ---------------------------------------------------------------------------------------------------------------------------------------------------------------EYE CONTACT: IMMEDIATELY FLUSH EYE WITH FLOWING WATER FOR AT LEAST 15 MINUTES, HOLDING EYELIDS APART TO IRRIGATE THOROUGHLY. GET MEDICAL ATTENTION. SKIN CONTACT: WASH THOROUGHLY WITH SOAP AND WATER. GET MEDICAL ATTENTION IF IRRITATION DEVELOPS. REMOVE AND LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. INHALATION: REMOVE TO FRESH AIR. IF BREATHING IS DIFFICULT, GIVE OXYGEN. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. GET MEDICAL ATTENTION. INGESTION: DILUTE WITH WATER AND INDUCE VOMITING. GET MEDICAL ATTENTION. NEVER GIVE FLUIDS OR INDUCE VOMITING IF PATIENT IS UNCONSCIOUS OR HAS CONVULSIONS. ---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION V: FIRE FIGHTING MEASURES ---------------------------------------------------------------------------------------------------------------------------------------------------------------FLASH POINT: NOT DETERMINED. LOWER EXPLOSIVE LIMIT: NOT APPLICABLE. UPPER EXPLOSIVE LIMIT: NOT APPLICABLE AUTOIGNITION TEMPERATURE: NOT DETERMINED. 1 MSDS 02-0002
EXTINGUISHING MEDIA: WATER, DRY CHEMICAL, CARBON DIOXIDE, AND FOAM. SPECIAL FIRE FIGHTING PROCEDURES: FIREFIGHTERS SHOULD BE EQUIPPED WITH SELF CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING. UNUSUAL HAZARDS: DUST AMY BE EXPLOSIVE IF MIXED WITH AIR IN CRITICAL PROPORTIONS AND IN THE PRESENCE OF SOURCE OF IGNITION. ---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION VI: ACCIDENTAL RELEASE MEASURES ---------------------------------------------------------------------------------------------------------------------------------------------------------------STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: WEAR APPROPRIATE SAFETY EQUIPMENT. CONTAIN AND CLEAN UP SPILL IMMEDIATELY. PREVENT FROM ENTERING FLOOR DRAINS. SWEEP POWDERS CAREFULLY MINIMIZING DUSTING. SHOVEL ALL SPILL MATERIALS INTO DISPOSAL DRUMS AND FOLLOW DISPOSAL INSTRUCTIONS. SCRUB SPILL AREA WITH DETERGENT AND FLUSH WITH COPIOUS AMOUNTS OF WATER. ---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION VII: HANDLING AND STORAGE ---------------------------------------------------------------------------------------------------------------------------------------------------------------HANDLING: IN ACCORDANCE WITH GOOD INDUSTRIAL PRACTICES, HANDLE WITH CARE AND AVOID PERSONAL CONTACT. CONTAINERS SHOULD BE TRIPLE RINSED ACCORDING TO FEDERAL REGULATIONS AND/OR GOOD WASTE MANAGEMENT PRCATICES. FOR INDUSTRIAL USE ONLY. STORAGE: KEEP CONTAINERS CLOSED WHEN NOT IN USE. ---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION VIII: EXPOSURE CONTROL/PERSONAL PROTECTION ---------------------------------------------------------------------------------------------------------------------------------------------------------------ENGINEERING CONTROLS: LOCAL EXHAUST TO MINIMIZE EXPOSURE. RESPIRATORY PROTECTION: IF EXPOSURE TO DUST IS LIKELY, A NIOSH APPROVED DUST RESPIRATOR IS RECOMMENDED. EXPOSURE LIMITS: NOT ESTABLISHED. EYE PROTECTION: WEAR SAFETY GLASSES WITH SIDE SHIELDS OR SAFETY GOGGLES. SKIN PROTECTION: WEAR RUBBER GLOVES. OTHER PROTECTIVE MEASURES: WEAR APRON, COVERALLS, BOOTS AND LONG SLEEVE SHIRT TO PREVENT SKIN CONTACT. HYGIENIC PRACTICES: EYEWASH FOUNTAINS SHOULD BE EASILY ACCESSIBLE. SHOWER AFTER HANDLING THIS PRODUCT. WORK CLOTHES SHOULD BE WASHED BEFORE REUSE. BEFORE EATING, DRINKING, OR SMOKING, WASH HANDS AND FACE WITH SOAP AND WATER. ---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION IX: PHYSICAL AND CHEMICAL PROPERTIES ---------------------------------------------------------------------------------------------------------------------------------------------------------------APPEARANCE: YELLOW POWDER ODOR: NONE SOLUBILITY IN WATER: SOLUBLE BOILING POINT: NOT APPLICABLE. MELTING POINT: NOT ESTABLISHED. EVAPORATION RATE: IS SLOWER THAN BUTYL ACETATE SPECIFIC GRAVITY: 0.51 pH @5.0%: 7 - 8 -------------------------------------------------------------------------------------------------------------------------------------SECTION X: STABILITY AND REACTIVITY ---------------------------------------------------------------------------------------------------------------------------------------------------------------STABILITY: STABLE. CONDITIONS TO AVOID: NONE KNOWN. 2 MSDS 02-0002
HAZARDOUS POLYMERIZATION: WILL NOT OCCUR. INCOMPATIBLE MATERIALS: NONE KNOWN. HAZARDOUS DECOMPOSITION PRODUCTS: BURNING WILL PRODUCE OXIDES OF CARBON, NITROGEN AND SULFUR. ---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION XI: TOXICOLOGICAL PROPERTIES ---------------------------------------------------------------------------------------------------------------------------------------------------------------RAT, ORAL LD50: 3000 MG/KG LC50: 200 PPM RABBIT, SKIN: IRRITATING RABBIT, EYES: IRRITATING ADDITIONAL TOXICITY DATA: NOT KNOWN. ---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION XII: ECOLOGICAL INFORMATION ---------------------------------------------------------------------------------------------------------------------------------------------------------------NO INFORMATION IS CURRENTLY AVAILABLE. ---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION XIII: DISPOSAL CONSIDERATIONS ---------------------------------------------------------------------------------------------------------------------------------------------------------------WASTE DISPOSAL METHOD: THIS PRODUCT IS NOT TO BE CONSIDERED A HAZARDOUS WASTE UNDER RCRA (40 CFR 261).DISPOSAL MUST BE IN ACCORDANCE WITH APPLICABLE GOVERNMENTAL REGULATIONS. CONTAINER DISPOSAL INFORMATION: CONTAINERS SHOULD BE TRIPLE RINSED ACCORDING TO FEDERAL REGULATIONS AND/OR GOOD WASTE MANAGEMENT PRACTICE. ---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION XIV: TRANSPORTATION INFORMATION ---------------------------------------------------------------------------------------------------------------------------------------------------------------DOT PROPER SHIPPING NAME: NOT REGULATED. DOT TECHNICAL NAME: NOT APPLICABLE. DOT HAZARD CLASS: NOT APPLICABLE. HAZARD SUBCLASS: NOT APPLICABLE. DOT UN/NA NUMBER: NOT APPLICABLE. PACKING GROUP: NOT APPLICABLE. RESP. GUIDE PAGE: NOT APPLICABLE. DOT REPORTABLE QUANTITY: NOT APPLICABLE. DOT LABELS: NOT APPLICABLE. ---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION XV: REGULATORY INFORMATION ---------------------------------------------------------------------------------------------------------------------------------------------------------------SARA TITLE III SECTION 302: THIS PRODUCT DOES NOT CONTAIN ANY CHEMICALS REGULATED UNDER SECTION 302 AS EXTREMELY HAZARDOUS. SARA TITLE III SECTION 304 (CERCLA): THIS PRODUCT DOES NOT CONTAIN ANY CHEMICALS REGULATED UNDER SECTION 304 AS A HAZARDOUS SUBSTANCE FOR EMERGENCY RELEASE NOTIFICATION. SARA TITLE III SECTION 312 HAZARD RATING: ACUTE: NO CHRONIC: NO FLAMMABILITY: NO REACTIVITY: NO PRESSURE: NO SARA TITLE III SECTION 313: THIS PRODUCT IS NOT REPORTABLE FOR SARA 313. TSCA: THIS PRODUCT IS REGISTERED UNDER THE REGULATIONS OF THE TOXIC SUBSTANCES CONTROL ACT (TSCA). 3 MSDS 02-0002
STATE RIGHT TO KNOW INFORMATION INGREDIENT ACID YELLOW 135 DEXTRIN SODIUM CHLORIDE
CAS NUMBER 12235-21-1 9004-53-9 7647-14-5
SECTION XVI: OTHER INFORMATION ---------------------------------------------------------------------------------------------------------------------------------------------------------------HMIS RATING: HEALTH - 2 FIRE - 1 REACTIVITY - 0 PERSONAL PROTECTION - F NFPA RATING: HEALTH - 1 FIRE - 1 REACTIVITY 0
DISCLAIMER: KEYCOLOUR INC. BELIEVES ALL THE INFORMATION AND DATA GIVEN IS ACCURATE AS OF THE DATE OF PREPARATION AND IS OFFERED IN GOOD FAITH. THIS INFORMATION IS GIVEN WITHOUT WARRANTY OR REPRESENTATION SOLELY FOR YOUR CONSIDERATION, INVESTIGATION, AND VERIFICATION. SINCE CONDITIONS OF USE ARE BEYOND OUR CONTROL, KEYCOLOUR INC. EXPRESSLY DISCLAIMS ALL LIABILITY FOR THE USE OR HANDLING OF THIS PRODUCT. -------------------------------------------------------------------------------------------------------------------------------------------
MSDS 02-0002
HMIS RATINGS:
HEALTH:
FIRE: 1
REACTIVITY: 0

Product I.D.: Product Name: Product Description: Chemical Family: Effective Date: K502 ACID orange 144 218% Acid Orange Colorant Powder Metallized azo dye July 15, 2009

Emergency Overview: Depending on duration and individual sensitivity, unprotected contact may cause mild eye, respiratory, skin irritation. May cause allergic skin reactions in some sensitive individuals. May cause allergic respiratory reaction or sensitization in some individuals. Eye Contact: Depending on duration and personal sensitivity, unprotected contact may cause mild irritation, discomfort, redness, watering, itching or other effects. Heavy contact or for prolonged period may increase effects. Follow ALL supervisor and Personal Protection instructions in Section 8 of this SDS. Skin Contact: Depending on amount and length of direct, unprotected contact, vapors, mists, splashes, aerosols, or dusts of product may cause varying dgrees of irritation, possible ALLERGIC REACTIONS in some individuals, redness, rash, itching, burning feeling, drying, cracking, pain, swelling, or other effects in some sensitive individuals. Prolonged or repeated contact may cause inflammation, or other effects in some persons. Inhalation: Depending on duration of unprotected inhalation of product, vapors, mists, aerosols or dusts may cause mild irritation of the nose, throat, lungs and mucous membranes, shortness of breath, sneezing, cough, runny nose, nausea, headache and other effects. Prolonged or heavy exposure, or heating of liquid material may increase severity of symptoms. Ingestion: Depending on amount swallowed, product can cause mild irritation of mouth, throat, esophagus, stomach, and gastrointestinal tract, upset stomach, abdominal discomfort, nausea, vomiting, gastrointestinal disturbances, dizziness, diarrhea, and other effects. Aspiration into lungs during vomiting is an emergency and may cause lung injury and life-threatening conditions. Higher dose may increase irritation and severity of symptoms. Medical Conditions Aggravated by Exposure:

K502 ACID orange 144 218%
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Improper protection allowing contact with vapors, mists, aerosols, splashes or dusts of product by inhalation, eye contact, skin contact or swallowing may aggravate one or more of the following pre-existing medical conditions: Respiratory problems (asthma, allergies, etc.), skin conditions, eye conditions. Ingestion may have potential to aggravate kidney or liver disorders. Heavy or long-term contact may increase effects. Avoid ALL exposures. Individuals with any of the above-noted conditions should avoid working with chemicals. Skin Sensitization: Not known to cause skin sensitization. With careful handling and when good chemical hygiene procedures are followed, harmful effects are not expected. As a precaution against unforeseen or unexpected sensitivity or possible allergic reactions, follow ALL Personal Protection instructions in Section 8 of this SDS. Respiratory Sensitization: Improper protection from inhalation of product dust, mist, vapor, etc. MAY CAUSE RESPIRATORY SENSITIZATION OR ALLERGIC REACTIONS in some individuals. Persons known to have or suspected of having chemical sensitivity or allergic reactions should avoid contact. Symptoms may include: Itching watery eyes, swelling of eyelids. sneezing, itchy, runny nose., cough, shortness of breath, asthma-like symptoms such as tight chest, difficult breathing. It may take repeated or prolonged exposure for symptoms to appear. Reactions may be unpredictable and life-threatening for some individuals. IF SYMPTOMS APPEAR, IMMEDIATELY remove person from contact area, GET MEDICAL HELP and follow Section 4 instructions. Special Warnings: None for this material Unusual Health Hazards: None for this material Supplemental Hazard Information No additional information is currently available Notes to Physician Treat Symptomatically based on Section 2 Hazard Warnings and Section 3 ingredients unless indicated otherwise Cancer Information:
Chemical Name Cr+3 (Complexed within dye molecule) CAS # 7440-47-3 WT % 1.20% IARC Group 3 Unclassifiable on human carcinogenicity NTP NONE OSHA NONE NIOSH NONE ACGIH NONE

Component Cr+3 (Complexed within dye molecule) Confidential Acid Orange dye CAS Number 7440-47-3 Undisclosed Wt % 1.20% 98.80% OSHA - PEL 0.5 mg/m3 TWA Not established ACGIH - TLV 0.5 mg/m3 TWA Not established Recommended PEL Not applicable Not applicable
2.00 Important Notice: 2 . Unprotected contact with ingredients listed in Section 3 may be hazardous based on OSHA 29 CFR 1910.1200 & related appendices. Components not listed are trade 0 secrets, non-hazardous, or not reportable. This SDS is not intended to offer full disclosure, but all component information is available to medical or emergency personnel. All hazards are based on contact exposure. Effects may be unpredictable and may vary from person to person due to individual reactions. Reducing or 0
eliminating contact can reduce or eliminate risk. Use protective equipment and clothing in Section 8 to minimize or eliminate contact. Users are responsible for hazard determination and communication. Unless indicated otherwise, non-carcinogenic components are indicated within a 1-10% range, and investigated or potential carcinogens within a 0.1-1% range. HMIS ratings are based on data interpretation, and vary from company to company. They are intended only for quick, general identification of the degree of potential hazards. Hazards range from 0 (Minimal) up to 4 (Severe). Consult the National Paint & Coatings Association HMIS Manual for detailed information on ratings. To handle material safely, consider all information in this SDS.
2.00

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Eye Contact: Immediately rinse with flowing water for at least 15 minutes while holding eyelids open. Get immediate medical attention, as a precaution. Skin Contact: Immediately remove contaminated clothing. Wash affected area with soap and rinse with plenty of water. Get medical attention, as a precaution. Inhalation: Immediately move person to fresh air. If breathing is difficult give oxygen, call 911, calm the individual. If not breathing, call 911, give artificial respiration (CPR) until medical help arrives. Have this Material Safety Data Sheet available. Ingestion: Do not induce vomiting unless directed to do so by a doctor or by other emergency medical personnel. Forced vomiting of certain chemicals may cause aspiration and lung damage. Have this Material Safety Data Sheet available.

Unusual hazards: None expected Other Hazards: None known Types of Extinguishers: CO2, dry chemical, foam, water fog or spray depending on type of fire Fire Fighting Directions: Wear self-contained breathing equipment and fire-proof clothing. Use water spray to cool fire exposed containers if they cannot be safely moved.

Special Precautions: None known. Follow general precautions shown below. Static Discharges: IMPORTANT - GUARD AGAINST FIRE AND EXPLOSION: Take precautionary measures against static discharges when cleaning up leaks or spills of powders, combustibles, or flammable liquids. Containers should be properly grounded with metal straps, cables or other appropriate means to relieve static electricity build-up or generation. IMPORTANT: When using, mixing, filling, or otherwise dispensing any types of solvents, do not allow buildup of flammable or combustible vapors or vapor-air mixtures in confined spaces, storage tanks, or any other areas or enclosures. Totes, drums and all other containers should be completely sealed when not in use. Vapors can travel a distance to ignition sources and cause fire or explosion. Take every precaution and monitor all safety factors and systems, including maintaining more-than-adequate air-exchange ventilation. Environmental Protection: Immediately dike liquid spills with inert absorbent material (sand, "Oil Dry" or other commercially available spill absorbent) to contain and soak up liquid. Prevent material from entering floor drains, sewers, or any bodies of water. For powder spills, use sweeping compound, sawdust, or other appropriate material to contain dust. If possible, recover any uncontaminated materials to re-use. Protective equipment and clothing: Wear all proper personal protective equipment and clothing to care for spill situation. See section 8 of this MSDS. Clean up:

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After containing liquid spill by diking and soaking up with inert absorbent material, place in labeled container to be sealed for proper and regulated disposal. Only the slightest residue should remain. Try to save uncontaminated material for reuse whenever possible. For powders, use sweeping compound to minimize dust and pick up as much product as possible. Do not allow liquids to seep into drains, sewers, lakes, rivers, etc. Check Sections 1 and 2 for dye description or type. Solvent dye residue may be cleaned by scrubbing with detergent, depending on type. Do not add water to water-soluble dyes. Dye is concentrated. This will increase amount of color to remove. All cleaning or scrubbing liquids used should be absorbed and placed in labeled containers for correct disposal. Absorbent material containing solvents may release combustible or flammable vapors and should be handled accordingly, properly labeled and disposed. Check Sections 2, 5, 13 & 15 for applicable instructions and regulations.

Warnings and Precautions: No special precautions anticipated. Wear all PPE in section 8 as a precaution, and avoid physical contact with material. Personal Protection: Wear ALL proper personal protective equipment as outlined in section 8 of this SDS. Handling, Storage & Temperature Conditions: Keep containers tightly sealed in cool & dry area, out of direct sunlight. IMPORTANT: FOR PRODUCTS LISTING FLAMMABLE/COMBUSTIBLE SOLVENTS or LOW FLASH POINTS - GUARD AGAINST FIRE AND EXPLOSION: Store away from fire hazards and ignition sources, high heat, open flames, welding, hot plates, steam pipes, radiators, etc. Maintain good ventilation. Guard against static discharges. Ground all containers before mixing or filling. Use non-sparking tools to open, close or otherwise work with containers. Limit indoor storage to approved areas with automatic sprinklers. Vapors expected to be released when material is heated during process operations. STATIC CHARGES: Take precautionary measures against static discharges when mixing, cleaning, filling or otherwise dispensing combustible or flammable liquids. Containers should be properly grounded with metal straps, cables or other appropriate means to relieve static electricity build-up or generation. VAPORS: IMPORTANT: DO NOT ALLOW buildup of flammable or combustible vapors or vapor-air mixtures in confined spaces, storage tanks, or any other areas or enclosures. Totes, drums and all other containers should be completely sealed when not in use. Vapors can travel a distance to ignition sources and cause fire or explosion. Take every precaution and monitor all safety factors and systems, including maintaining more-than-adequate air-exchange ventilation. POWDERS: General precautions: Although unlikely in most instances, GUARD AGAINST DUST EXPLOSION HAZARD. Eliminate or keep dust to a minimum. Under the right conditions, high dust concentrations of certain particle sizes mixed with air in a critical ratio in the presence of an ignition source can theoretically cause a dust explosion. Be sure to PROPERLY ground containers when filling, mixing or otherwise dispensing powders. KEEP WORK AREA CLEAN AND DUST-FREE. Follow all Section 8 recommendations for Exposure Controls and Personal Protection. WATER-BASED PRODUCTS: DO NOT ALLOW TO FREEZE.

Note: Selecting protective equipment & clothing: When choosing personal protective equipment and clothing, consider each worker's environment, all chemicals being handled, temperature, ventilation, and all other conditions. Determination of the level of protection needed for the eyes, skin and respiratory system under working conditions is the responsibility of the product end-user or shift supervisor. SDS Sections 2, 3, 8 and 11 should be consulted. Eye protection: As a precaution, wear indirectly vented, splash-proof chemical safety goggles. When handling liquids, wear splash-proof goggles under a clear face-shield. Face shield is not to be used without these goggles. The type or extent of protection needed should be determined by the product end-user or shift supervisor. Skin Protection:

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Always wear impervious, chemical-resistant synthetic or rubber gloves. Check with manufacturer for best glove for the material being handled. Wear good quality long sleeved work shirt, coveralls, and a rubber or plastic apron. Wash hands after handling and before eating, drinking or using restroom. Shower after each shift. Clean contaminated but reusable protective equipment and clothing before reusing and wearing again. Discard contaminated disposable gloves and clothing. The type or extent of protection needed should be determined by the product end-user or shift supervisor. Respiratory Protection: Depending on type of material handled and processing conditions, it is recommended that an appropriate NIOSH approved organic vapor/mist respirator, or dust respirator (with proper filters as required) be worn when exposure to product is expected. After each shift or when equipment becomes contaminated, clean respirator and replace filters in compliance with 29 CFR 1910.134. The type or extent of protection needed should be determined by the product end-user or shift supervisor. Eye Washes and Other Protection: Eye wash stations and drench showers should be located within 100 feet or 10-second walk of the work area per ANSI standard Z358.1-1990. Ventilation: Local exhaust or other appropriate ventilation should be used to maintain exposure limits below specified amounts recommended by OSHA, NIOSH, or ACGIH and to draw spray, aerosol, vapors, or dusts away from workers and prevent routine inhalation. At least 10 air changes per hour are recommended for good room ventilation. IMPORTANT - GUARD AGAINST FIRE AND EXPLOSION: When using, mixing, filling, or otherwise dispensing any types of solvents, do not allow buildup of flammable or combustible vapors or vapor-air mixtures in confined spaces, storage tanks, or any other areas or enclosures. Totes, drums and all other containers should be completely sealed when not in use. Vapors can travel a distance to ignition sources and cause fire or explosion. Take every precaution and monitor all safety factors and systems, including maintaining more-than-adequate air-exchange ventilation. Airborne Exposure Limits:
Chemical Name Cr+3 (Complexed within dye molecule) CAS # 7440-47-3 WT % 1.20% NIOSH - REL 0.5 mg/m3 TWA NIOSH - IDLH Not established OTHER OEL'S Not established

Flash Point: pH: % Total VOC: % Total Solids / Non-Volatiles: Color: Density: Form: Odor: Freezing/Melting Point: Specific Gravity: Water Solubility: Solvent Solubility: Other Properties: Other Components: Decomposition Temperature: Not established ~ 5.0 0 100 Brown Not established Powder None Not established Not established Soluble. Test in specific applications and systems. Not applicable No further data Not established Not Established

K502 ACID orange 144 218% Stability:
Page 6 of 8
Product is expected to be stable under normal, ambient (controlled) conditions concerning heat, moisture, pressure, fire and ignition hazards, and ventilation. Contact with incompatible or reactive materials may cause hazardous reactions in some products if indicated. Check information below. Hazardous Polymerization: Product will not undergo polymerization. Conditions to Avoid: None Known Incompatible Materials: None Known Hazardous Decomposition Products: In fire: Oxides of carbon, nitrogen, sulfur Possible Hazard Reactions: None known

Component
Confidential Acid Orange dye
Eye Effect
May be irritating
Skin Effect
May be irritating
Skin Sens
No Data
Resp Sens
No Data
Oral LD50
(Rat): > 2000 mg/kg
Inh LC50
No Data
Mutagen
No Data
Other Tox Data

No Data
Other Info
May be respiratory irritant

Other Tox Data
Component
Eye Effect
Skin Effect
Skin Sens
Resp Sens
Oral LD50
Inh LC50
Mutagen
Other Info
*** No Data ***

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DOT Regulations (Ground): NOT REGULATED IATA Regulations (Air): NOT REGULATED IMDG / IMO Regulations (Water): NOT REGULATED

Component Cr+3 (Complexed within dye molecule) Confidential Acid Orange dye CAS Number 7440-47-3 Undisclosed Weight % 1.20% 98.80% Regulatory List 2: 5000, 8, 11: D007, 13: 0.1%, 15: DE MA MN NJ Chromium III compound (Actual Cr+3 @ <1.2%).: SARA 313: 0.1%, CERCLA Hazardous substance: RQ=5000 lbs, RCRA: D007, State lists: DE, ID, IL, MA, MI, MN, NY,
Regulatory List Reference: NOTE: When no components are shown in space above this note, no federal or state reporting requirements apply to this product. When components are listed above, list numbers shown below indicate applicable regulations.* List numbers 1-Accidental Release Substance 2-CERCLA 304 Hazardous Substance (RQ) 3-Reserved 4-Clean Air Act-Sec. 111 Volatile Organic Compounds (VOC) 5-Clean Air Act-Sec. 112 Haz. Air Pollutant (HAP, HAP Code) 6-Clean Air Act-Ozone Depleting Chemical (ODC) 7-Clean Water Act-RQ 8-Clean Water Act-Priority Pollutant (PP) RQ 9-Marine Pollutant (MP) 10-PSM Highly Hazardous Chemical 11-RCRA Hazardous Waste (RCRA Code) 12-SARA 302 Extremely Hazardous Substance (EHS) (RQ) 13-SARA 313 Toxic Release Inventory (TRI) (TR Conc., TR Threshold) 14-SOCMI Chemical (CAA) 15-State Lists CA-California Proposition 65, DE-Delaware, ID-Idaho, ME-Maine, MA-Massachusetts, MI-Michigan, MN-Minnesota, NJ-RTK New Jersey Hazardous Substance List, NJ-TCPA New Jersey Extremely Hazardous Substance List, NY-New York, PA-Pennsylvania, WA-Washington, WV-West Virginia, WI-Wisconsin 16-Supplemental regulatory information (SRI) * Numbers shown immediately after a List Number indicate additional specific information. Examples: 2: 5000 (2 = CERCLA, 5000 = RQ), 11: D007 (11 = RCRA, D007 = Chromium) Revised 011808 wln (Current list not applicable to previous Safety Data Sheets)

K502 ACID orange 144 218% SARA 311/312 Hazard Categories: Immediate/Acute Health Hazard: Chronic/Delayed Hazard: Fire Hazard: Sudden Release of Pressure Hazard: Reactivity Hazard: GLOBAL CHEMICAL REGISTRATION LISTINGS AICS (Australia): ASIA-PAC (Asia Pacific): DSL (Canada): ECL (Korea): EINECS (Europe): ENCS (Japan): IECSC (China): PICCS (Phillippines): TSCA (US): Status not determined Status not determined Status not determined Status not determined Status not determined Status not determined Status not determined Status not determined Components listed YES YES NO NO NO
Page 8 of 8
OTHER: No additional information applies, or no supplemental information is available at this time.

Reason for Revision: Reviewed: Disclaimer: The information and recommendations contained herein are based upon data believed to be correct. However, no guarantee or warranty of any kind, expressed or implied, is made with respect to the information contained herein. This Material Safety Data Sheet was prepared to comply with the OSHA Hazard Communication Standard 29 CFR 1910.1200, and supersedes any previous information. Previously dated sheets are invalid and inapplicable. END OF MSDS New format. General review and update. 071509 wln

I. PRODUCT IDENTIFICATION TRADE NAME--------- ACID BLACK 194 CHEMICAL NAME-----CHEMICAL FAMILY---COLOR INDEX #-----C. A. S. #--------LAST REVISION DATE. N/A ACID DYE ACID BLACK 194 57693-14-8 10/29/09
II. HAZARDOUS COMPONENTS Azo Chromium Complex Dyestuff Content: >= 95 - <= 98 % Remarks Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. III. PHYSICAL DATA BOILING POINT--N/A VAPOR PRESSURE--N/A VAPOR DENSITY---N/A VOLATILITY----- N/A FREEZE POINT--- N/A MELTING POINT---N/A IV. FIRE AND EXPLOSION DATA FLASH POINT N/A FILAMMABLE LIMITS. N/A IN CASE OF FIRE-----DRY CHEMICAL, CO2, WATER SPRAY OR REGULAR FOAM. MOVE CONTAINERS FROM FIRE AREA IF YOU CAN DO IT WITHOUT RISK. APPLY COOLING WATER TO SIDES OF CONTAINERS THAT ARE EXPOSED TO FLAMES UNTIL WELL AFTER FIRE IS OUT. SOLUB. IN WATER--SOLUBLE IN WATER ODOR--- NONE APPEARANCE--DARK POWDER SPECIFIC GRAV-- N/A EVAP. RATE--- N/A pH OF PRODUCTN/A
MATERIAL SAFETY DATA SHEET (CONTINUED) ************************** VII. EMERGENCY AND FIRST AID PROCEDURES PROCEDURES: EYES: FLUSH EYES WITH WATER FOR AT LEAST 15 MINUTES. SKIN: WASH WITH MILD SOAP AND WATER. IF IRRITATION OCCURS GET MEDICAL ATTENTION. IF CLOTHING IS CONTAMINATED, RE- MOVE AND WASH BEFORE REUSE. INHALATION: REMOVE TO FRESH AIR. GET MEDICAL ATTENTION. INGESTION: IF CONSCIOUS, GIVE PLENTY OF WATER TO DRINK. GET MEDICAL ATTENTION. IF UNCONSCIOUS, DO NOT GIVE ANYTHING TO DRINK. GET IMMEDIATE MEDICAL ATTENTION. VIII. SPECIAL PROTECTION INFORMATION RESPIRATORY. NIOSH APPROVED DUST RESPIRATOR WHEN NEEDED. SKIN-------IMPERVIOUS GLOVES AND APPROPRIATE EQUIPMENT TO PREVENT PROBABILITY OF PERSONAL CONTACT. EYES----SIDE-SHIELD SAFETY GLASSES. VENTILATION----Local Exhaust. OTHER PROTECTION--- DELUGE SAFETY SHOWER AND EYE WASH STATION SHOULD BE LOCATEI NEAR WORK AREA.
IX. Ecological information Biodegradability : > 70 % (Colour decrease) Readily eliminable from water Method : Batch method Analysis method:, Photometry Biodegradability : If regulations are followed when introducing effluent into biological waste water treatment plants, no adverse effect on the degradation activity of activated sludge is to be expected. Fish toxicity : LC50 1 - 10 mg/l (96 h, Brachydanio rerio) Method : Range Finding Test Bacteria toxicity : EC50 > 1,000 mg/l (0.5 h, Pseudomonas putida) Method : OECD 209 Chemical oxygen demand (COD) : 960 mg/g Remarks: Test results of a similarly composed product Product does not add to the AOX-value of the sewage. (DIN EN 1485) This product contains approx. 3,0 % complex bonded chromium. The product does not release nitrogen which can contribute to eutrophication. The product does not contain phosphates or organophosphorus compounds.
MATERIAL SAFETY DATA SHEET (CONTINUED) ************************** X. SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN:::: DO NOT TOUCH OR WALK THROUGH SPILLED MATERIAL: STOP LEAK IF YOU CAN DO IT WITHOUR RISK. TAKE UP WITH SAND OR OTHER NON-COMBUSTIBLE ABSORBENT MATERIALS AND PLACE INTO CONTAINERS FOR LATER DISPOSAL. SCRUB SPILL AREA WITH DETERGENT, FLUSH WITH COPIOUS AMOUNT OF WATER.
XI. PRECAUTION MEASURES 29 CFR 1910.1200 AND STATE RIGHT TO KNOW LAWS MAY DESIGNATE THIS PRODUCT AS A NUISANCE DUST. PLEASE REFER TO SECTION XII OF MATERIAL SAFETY DATA SHEET FOR HANDLING INSTRUCTIONS.
XII. TRANSPORTATION INFORMATION
D.O.T. Information CFR Tech. name: IMDG IATA_C IATA_P
UNNR: 3077 Environmentally hazardous Class: 9 PG:III AZO CHROMIUM COMPLEX DYESTUFF UNNR: 3077 Environmentally hazardous Class: 9 PG:III EmS:F-A , S-F UNNR: 3077 Environmentally hazardous Class: 9 PG:III UNNR: 3077 Environmentally hazardous Class: 9 PG:III
substance, solid, n.o.s. substance, solid, n.o.s. substance, solid, n.o.s. substance, solid, n.o.s.
XIII. REGULATORY INFORMATION
Sara 313 This product contains the following component that is subject to the reporting requirements under 40 CFR 372. contains: Chromium compound Content: 98 % Chromium Content: 3 % CAS number : 7440-47-3 Sara 312 Immediate (acute) health hazard No Delayed (chronic) health hazard No Fire hazard No Sudden Release of Pressure No Reactivity No Other regulations Labelling in accordance with the EEC directives: Hazard symbols: N Dangerous for the environment R51/53 : Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S61 : Avoid release to the environment. Refer to special instructions/Safety data sheets.
S. A. R. A.--- REPORTABLE
T.S.C.A---- IN COMPLIANCE 0. S. H. A. HAZARD CLASSIFICATION: ACUTE:NO CHRONIC: NO FLAMMABLE: NO REACTIVE: NO OXIDIZER: NO HEALTH H.M.I.S. CLASSIFICATION: N.F.P.A CODES: 1 1 FLAMMABILITY 1 1 REACTIVITY 1 1 PERSONAL PROT. F N
XIV. STATES RIGHT TO KNOW LAWS HAZARDOUS MATERIALS ** NONE*** INGREDIENTS STATE INFORMATION * * N O N E * * ***NON-HAZARDOUS MATERIALS * STATE INFORMATION:::: INGREDIENTS :::PROPRIETARY ACID DYES ::: MA. N.J, PA, CA GLAUBERS SALT 7767-86-68 MA, N.J, PA, CA XV. OTHER INFORMATION
ALL INFORMATION AND DATA APPEARING ON THIS M. S. D. S. ARE BELIEVED TO BE RELIABLE & ACCURATE. HOWEVER, IT IS THE USER'S RESPONSIBILITY TO DETERMINE THE SAFETY, TOXICITY, AND SUITABILITY FOR HIS OWN USE OF THE PRODUCT DESCRIBED. SINCE THE ACTUAL USE BY OTHERS IS BEYOND OUR CONTROL, NO GUARANTEE, EXPRESSED OR IMPLIED, IS MADE BY KEYCOLOUR, INCORPORATED. USER ASSUMES ALL RISK AND RESPONSIBILITY.

-----------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION I: CHEMICAL PRODUCT AND COMPANY IDENTIFICATION -----------------------------------------------------------------------------------------------------------------------------------------------------------------TRADE NAME: AMENYL YELLOW A4R 280% CHEMICAL FAMILY: AZO
CHEMTREC 800-424-9300
DATE PREPARED: FEBRUARY 2010 ---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION II: COMPOSITION/INFORMATION ON HAZARDOUS INGREDIENTS ---------------------------------------------------------------------------------------------------------------------------------------------------------------CHEMICAL NAME CAS NUMBER %BY WT. TLV/PEL ACID YELLOW 199 70865-20-2 NOT ESTABLISHED GLAUBERS SALT 7647-14-5 --------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION III: HAZARDS IDENTIFICATION ---------------------------------------------------------------------------------------------------------------------------------------------------------------EMERGENCY OVERVIEW: MAY CAUSE SKIN, EYE AND RESPIRATORY IRRITATION. EFFECTS OF OVEREXPOSURE: EYE CONTACT: MAY BE IRRITATING. SKIN CONTACT: MAY BE IRRITATING. INHALATION: MAY BE IRRITATING. INGESTION: NOT KNOWN. CHRONIC EXPOSURE: NOT KNOWN. CARCINOGENICITY: NOT LISTED AS AN IARC, NTP OR OSHA CARCINOGEN. MEDICAL CONDITIONS AGGREVATED BY EXPOSURE: NOT KNOWN PRIMARY ROUTES OF ENTRY: SKIN CONTACT, EYE CONTACT AND INHALATION. ---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION IV: FIRST AID MEASURES ---------------------------------------------------------------------------------------------------------------------------------------------------------------EYE CONTACT: IMMEDIATELY FLUSH EYE WITH FLOWING WATER FOR AT LEAST 15 MINUTES, HOLDING EYELIDS APART TO IRRIGATE THOROUGHLY. GET MEDICAL ATTENTION. SKIN CONTACT: WASH THOROUGHLY WITH SOAP AND WATER. GET MEDICAL ATTENTION IF IRRITATION DEVELOPS. REMOVE AND LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. INHALATION: REMOVE TO FRESH AIR. IF BREATHING IS DIFFICULT, GIVE OXYGEN. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. GET MEDICAL ATTENTION. INGESTION: DILUTE WITH WATER. GET MEDICAL ATTENTION. NEVER GIVE FLUIDS OR INDUCE VOMITING IF PATIENT IS UNCONSCIOUS OR HAS CONVULSIONS. ---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION V: FIRE FIGHTING MEASURES ---------------------------------------------------------------------------------------------------------------------------------------------------------------FLASH POINT: NOT DETERMINED. LOWER EXPLOSIVE LIMIT: NOT APPLICABLE. UPPER EXPLOSIVE LIMIT: NOT APPLICABLE AUTOIGNITION TEMPERATURE: NOT DETERMINED. EXTINGUISHING MEDIA: WATER, DRY CHEMICAL, CARBON DIOXIDE, AND FOAM. 1 MSDS 02-0002
SPECIAL FIRE FIGHTING PROCEDURES: FIREFIGHTERS SHOULD BE EQUIPPED WITH SELF CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING. UNUSUAL HAZARDS: DUST MAY BE EXPLOSIVE IF MIXED WITH AIR IN CRITICAL PROPORTIONS AND IN THE PRESENCE OF SOURCE OF IGNITION. ---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION VI: ACCIDENTAL RELEASE MEASURES ---------------------------------------------------------------------------------------------------------------------------------------------------------------STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: WEAR APPROPRIATE SAFETY EQUIPMENT. CONTAIN AND CLEAN UP SPILL IMMEDIATELY. PREVENT FROM ENTERING FLOOR DRAINS. SWEEP POWDERS CAREFULLY MINIMIZING DUSTING. SHOVEL ALL SPILL MATERIALS INTO DISPOSAL DRUMS AND FOLLOW DISPOSAL INSTRUCTIONS. SCRUB SPILL AREA WITH DETERGENT AND FLUSH WITH COPIOUS AMOUNTS OF WATER. ---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION VII: HANDLING AND STORAGE ---------------------------------------------------------------------------------------------------------------------------------------------------------------HANDLING: IN ACCORDANCE WITH GOOD INDUSTRIAL PRACTICES, HANDLE WITH CARE AND AVOID PERSONAL CONTACT. CONTAINERS SHOULD BE TRIPLE RINSED ACCORDING TO FEDERAL REGULATIONS AND/OR GOOD WASTE MANAGEMENT PRCATICES. FOR INDUSTRIAL USE ONLY. STORAGE: KEEP CONTAINERS CLOSED WHEN NOT IN USE. ---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION VIII: EXPOSURE CONTROL/PERSONAL PROTECTION ---------------------------------------------------------------------------------------------------------------------------------------------------------------ENGINEERING CONTROLS: LOCAL EXHAUST TO MINIMIZE EXPOSURE. RESPIRATORY PROTECTION: IF EXPOSURE TO DUST IS LIKELY, A NIOSH APPROVED DUST RESPIRATOR IS RECOMMENDED. EXPOSURE LIMITS: NOT ESTABLISHED. EYE PROTECTION: WEAR SAFETY GLASSES WITH SIDE SHIELDS OR SAFETY GOGGLES. SKIN PROTECTION: WEAR RUBBER GLOVES. OTHER PROTECTIVE MEASURES: WEAR APRON, COVERALLS, BOOTS AND LONG SLEEVE SHIRT TO PREVENT SKIN CONTACT. HYGIENIC PRACTICES: EYEWASH FOUNTAINS SHOULD BE EASILY ACCESSIBLE. SHOWER AFTER HANDLING THIS PRODUCT. WORK CLOTHES SHOULD BE WASHED BEFORE REUSE. BEFORE EATING, DRINKING, OR SMOKING, WASH HANDS AND FACE WITH SOAP AND WATER. ---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION IX: PHYSICAL AND CHEMICAL PROPERTIES ---------------------------------------------------------------------------------------------------------------------------------------------------------------APPEARANCE: DARK POWDER ODOR: NONE SOLUBILITY IN WATER: SOLUBLE BOILING POINT: NOT APPLICABLE. MELTING POINT: NOT ESTABLISHED. -------------------------------------------------------------------------------------------------------------------------------------SECTION X: STABILITY AND REACTIVITY ---------------------------------------------------------------------------------------------------------------------------------------------------------------STABILITY: STABLE. CONDITIONS TO AVOID: STRONG OXIDIZING AGENTS. HAZARDOUS POLYMERIZATION: WILL NOT OCCUR. INCOMPATIBLE MATERIALS: NONE KNOWN.
MSDS 02-0002
HAZARDOUS DECOMPOSITION PRODUCTS: BURNING WILL PRODUCE OXIDES OF CARBON, NITROGEN AND SULFUR. ---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION XI: TOXICOLOGICAL PROPERTIES ---------------------------------------------------------------------------------------------------------------------------------------------------------------RAT, ORAL LD50: NOT ESTABLISHED RABBIT, SKIN: NOT ESTABLISHED RABBIT, EYES: NOT ESTABLISHED, PROBABLY IRRITATING. ADDITIONAL TOXICITY DATA: NOT KNOWN. ---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION XII: ECOLOGICAL INFORMATION ---------------------------------------------------------------------------------------------------------------------------------------------------------------NO SIGNIFICATN HARMFUL ENVIRONMENTAL EFFECTS ARE SHOWN. ---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION XIII: DISPOSAL CONSIDERATIONS ---------------------------------------------------------------------------------------------------------------------------------------------------------------WASTE DISPOSAL METHOD: THIS PRODUCT IS NOT TO BE CONSIDERED A HAZARDOUS WASTE UNDER RCRA (40 CFR 261).DISPOSAL MUST BE IN ACCORDANCE WITH APPLICABLE GOVERNMENTAL REGULATIONS. CONTAINER DISPOSAL INFORMATION: CONTAINERS SHOULD BE TRIPLE RINSED ACCORDING TO FEDERAL REGULATIONS AND/OR GOOD WASTE MANAGEMENT PRACTICE. ---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION XIV: TRANSPORTATION INFORMATION ---------------------------------------------------------------------------------------------------------------------------------------------------------------DOT PROPER SHIPPING NAME: NOT REGULATED. DOT TECHNICAL NAME: NOT APPLICABLE. DOT HAZARD CLASS: NOT APPLICABLE. HAZARD SUBCLASS: NOT APPLICABLE. DOT UN/NA NUMBER: NOT APPLICABLE. PACKING GROUP: NOT APPLICABLE. RESP. GUIDE PAGE: NOT APPLICABLE. DOT REPORTABLE QUANTITY: NOT APPLICABLE. DOT LABELS: NOT APPLICABLE. ---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION XV: REGULATORY INFORMATION ---------------------------------------------------------------------------------------------------------------------------------------------------------------SARA TITLE III SECTION 302: THIS PRODUCT DOES NOT CONTAIN ANY CHEMICALS REGULATED UNDER SECTION 302 AS EXTREMELY HAZARDOUS. SARA TITLE III SECTION 304 (CERCLA): THIS PRODUCT DOES NOT CONTAIN ANY CHEMICALS REGULATED UNDER SECTION 304 AS A HAZARDOUS SUBSTANCE FOR EMERGENCY RELEASE NOTIFICATION. SARA TITLE III SECTION 312 HAZARD RATING: ACUTE: YES CHRONIC: NO FLAMMABILITY: NO REACTIVITY: NO PRESSURE: NO SARA TITLE III SECTION 313: THIS PRODUCT IS NOT REPORTABLE FOR SARA 313. TSCA: THIS PRODUCT IS REGISTERED UNDER THE REGULATIONS OF THE TOXIC SUBSTANCES CONTROL ACT (TSCA). STATE RIGHT TO KNOW INFORMATION INGREDIENT ACID YELLOW 199 GLAUBERS SALT CAS NUMBER 70865-20-2 7647-14-5 STATES MA, NJ, PA, CA MA, NJ, PA, CA
MSDS 02-0002
---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION XVI: OTHER INFORMATION ---------------------------------------------------------------------------------------------------------------------------------------------------------------HMIS RATING: HEALTH - 1 FIRE - 1 REACTIVITY - 1 PERSONAL PROTECTION - F NFPA RATING: HEALTH - 1 FIRE - 1 REACTIVITY 1 PERSONAL PROTECTION - N
MSDS 02-0002

--------------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION I: CHEMICAL PRODUCT AND COMPANY IDENTIFICATION --------------------------------------------------------------------------------------------------------------------------------------------------------------------TRADE NAME: AMECID FLUORESCENT YELLOW AF CHEMICAL FAMILY: COUMARIN
973-471-3200
DATE PREPARED: OCTOBER 28, 2005 ---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION II: COMPOSITION/INFORMATION ON HAZARDOUS INGREDIENTS ---------------------------------------------------------------------------------------------------------------------------------------------------------------CHEMICAL NAME CAS NUMBER %BY WT. TLV/PEL ACID YELLOW 250 NOT ESTABLISHED --------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION III: HAZARDS IDENTIFICATION ---------------------------------------------------------------------------------------------------------------------------------------------------------------EMERGENCY OVERVIEW: MAY CAUSE SKIN, EYE AND RESPIRATORY IRRITATION. EFFECTS OF OVEREXPOSURE: EYE CONTACT: MAY BE IRRITATING. SKIN CONTACT: MAY BE IRRITATING. INHALATION: MAY BE IRRITATING. INGESTION: NOT KNOWN. CHRONIC EXPOSURE: NOT KNOWN. CARCINOGENICITY: NOT LISTED AS AN IARC, NTP OR OSHA CARCINOGEN. MEDICAL CONDITIONS AGGREVATED BY EXPOSURE: NOT KNOWN PRIMARY ROUTES OF ENTRY: SKIN CONTACT, EYE CONTACT AND INHALATION. ---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION IV: FIRST AID MEASURES ---------------------------------------------------------------------------------------------------------------------------------------------------------------EYE CONTACT: IMMEDIATELY FLUSH EYE WITH FLOWING WATER FOR AT LEAST 15 MINUTES, HOLDING EYELIDS APART TO IRRIGATE THOROUGHLY. GET MEDICAL ATTENTION. SKIN CONTACT: WASH THOROUGHLY WITH SOAP AND WATER. GET MEDICAL ATTENTION IF IRRITATION DEVELOPS. REMOVE AND LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. INHALATION: REMOVE TO FRESH AIR. IF BREATHING IS DIFFICULT, GIVE OXYGEN. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. GET MEDICAL ATTENTION. INGESTION: DILUTE WITH WATER AND INDUCE VOMITING. GET MEDICAL ATTENTION. NEVER GIVE FLUIDS OR INDUCE VOMITING IF PATIENT IS UNCONSCIOUS OR HAS CONVULSIONS. ---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION V: FIRE FIGHTING MEASURES ---------------------------------------------------------------------------------------------------------------------------------------------------------------FLASH POINT: NOT DETERMINED. LOWER EXPLOSIVE LIMIT: NOT APPLICABLE. UPPER EXPLOSIVE LIMIT: NOT APPLICABLE AUTOIGNITION TEMPERATURE: NOT DETERMINED. EXTINGUISHING MEDIA: WATER, DRY CHEMICAL, CARBON DIOXIDE, AND FOAM. 1 MSDS 02-0002
SPECIAL FIRE FIGHTING PROCEDURES: FIREFIGHTERS SHOULD BE EQUIPPED WITH SELF CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING. UNUSUAL HAZARDS: DUST AMY BE EXPLOSIVE IF MIXED WITH AIR IN CRITICAL PROPORTIONS AND IN THE PRESENCE OF SOURCE OF IGNITION. ---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION VI: ACCIDENTAL RELEASE MEASURES ---------------------------------------------------------------------------------------------------------------------------------------------------------------STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: WEAR APPROPRIATE SAFETY EQUIPMENT. CONTAIN AND CLEAN UP SPILL IMMEDIATELY. PREVENT FROM ENTERING FLOOR DRAINS. SWEEP POWDERS CAREFULLY MINIMIZING DUSTING. SHOVEL ALL SPILL MATERIALS INTO DISPOSAL DRUMS AND FOLLOW DISPOSAL INSTRUCTIONS. SCRUB SPILL AREA WITH DETERGENT AND FLUSH WITH COPIOUS AMOUNTS OF WATER. ---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION VII: HANDLING AND STORAGE ---------------------------------------------------------------------------------------------------------------------------------------------------------------HANDLING: IN ACCORDANCE WITH GOOD INDUSTRIAL PRACTICES, HANDLE WITH CARE AND AVOID PERSONAL CONTACT. CONTAINERS SHOULD BE TRIPLE RINSED ACCORDING TO FEDERAL REGULATIONS AND/OR GOOD WASTE MANAGEMENT PRCATICES. FOR INDUSTRIAL USE ONLY. STORAGE: KEEP CONTAINERS CLOSED WHEN NOT IN USE. ---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION VIII: EXPOSURE CONTROL/PERSONAL PROTECTION ---------------------------------------------------------------------------------------------------------------------------------------------------------------ENGINEERING CONTROLS: LOCAL EXHAUST TO MINIMIZE EXPOSURE. RESPIRATORY PROTECTION: IF EXPOSURE TO DUST IS LIKELY, A NIOSH APPROVED DUST RESPIRATOR IS RECOMMENDED. EXPOSURE LIMITS: NOT ESTABLISHED. EYE PROTECTION: WEAR SAFETY GLASSES WITH SIDE SHIELDS OR SAFETY GOGGLES. SKIN PROTECTION: WEAR RUBBER GLOVES. OTHER PROTECTIVE MEASURES: WEAR APRON, COVERALLS, BOOTS AND LONG SLEEVE SHIRT TO PREVENT SKIN CONTACT. HYGIENIC PRACTICES: EYEWASH FOUNTAINS SHOULD BE EASILY ACCESSIBLE. SHOWER AFTER HANDLING THIS PRODUCT. WORK CLOTHES SHOULD BE WASHED BEFORE REUSE. BEFORE EATING, DRINKING, OR SMOKING, WASH HANDS AND FACE WITH SOAP AND WATER. ---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION IX: PHYSICAL AND CHEMICAL PROPERTIES ---------------------------------------------------------------------------------------------------------------------------------------------------------------APPEARANCE: YELLOW POWDER ODOR: NO ODOR SOLUBILITY IN WATER: SOLUBLE BOILING POINT: NOT APPLICABLE. MELTING POINT: NOT ESTABLISHED. -------------------------------------------------------------------------------------------------------------------------------------SECTION X: STABILITY AND REACTIVITY ---------------------------------------------------------------------------------------------------------------------------------------------------------------STABILITY: STABLE. CONDITIONS TO AVOID: NONE KNOWN. HAZARDOUS POLYMERIZATION: WILL NOT OCCUR. INCOMPATIBLE MATERIALS: NONE KNOWN. 2 MSDS 02-0002
HAZARDOUS DECOMPOSITION PRODUCTS: BURNING WILL PRODUCE OXIDES OF CARBON, NITROGEN AND SULFUR. ---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION XI: TOXICOLOGICAL PROPERTIES ---------------------------------------------------------------------------------------------------------------------------------------------------------------RAT, ORAL LD50: >5000 MG/KG RABBIT, SKIN: NOT ESTABLISHED RABBIT, EYES: IRRITATING ADDITIONAL TOXICITY DATA: NOT KNOWN. ---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION XII: ECOLOGICAL INFORMATION ---------------------------------------------------------------------------------------------------------------------------------------------------------------NO INFORMATION IS CURRENTLY AVAILABLE. ---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION XIII: DISPOSAL CONSIDERATIONS ---------------------------------------------------------------------------------------------------------------------------------------------------------------WASTE DISPOSAL METHOD: THIS PRODUCT IS NOT TO BE CONSIDERED A HAZARDOUS WASTE UNDER RCRA (40 CFR 261).DISPOSAL MUST BE IN ACCORDANCE WITH APPLICABLE GOVERNMENTAL REGULATIONS. CONTAINER DISPOSAL INFORMATION: CONTAINERS SHOULD BE TRIPLE RINSED ACCORDING TO FEDERAL REGULATIONS AND/OR GOOD WASTE MANAGEMENT PRACTICE. ---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION XIV: TRANSPORTATION INFORMATION ---------------------------------------------------------------------------------------------------------------------------------------------------------------DOT PROPER SHIPPING NAME: NOT REGULATED. DOT TECHNICAL NAME: NOT APPLICABLE. DOT HAZARD CLASS: NOT APPLICABLE. HAZARD SUBCLASS: NOT APPLICABLE. DOT UN/NA NUMBER: NOT APPLICABLE. PACKING GROUP: NOT APPLICABLE. RESP. GUIDE PAGE: NOT APPLICABLE. DOT REPORTABLE QUANTITY: NOT APPLICABLE. DOT LABELS: NOT APPLICABLE. ---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION XV: REGULATORY INFORMATION ---------------------------------------------------------------------------------------------------------------------------------------------------------------SARA TITLE III SECTION 302: THIS PRODUCT DOES NOT CONTAIN ANY CHEMICALS REGULATED UNDER SECTION 302 AS EXTREMELY HAZARDOUS. SARA TITLE III SECTION 304 (CERCLA): THIS PRODUCT DOES NOT CONTAIN ANY CHEMICALS REGULATED UNDER SECTION 304 AS A HAZARDOUS SUBSTANCE FOR EMERGENCY RELEASE NOTIFICATION. SARA TITLE III SECTION 312 HAZARD RATING: ACUTE: YES CHRONIC: NO FLAMMABILITY: NO REACTIVITY: NO PRESSURE: NO SARA TITLE III SECTION 313: THIS PRODUCT IS NOT REPORTABLE FOR SARA 313. TSCA: THIS PRODUCT IS REGISTERED UNDER THE REGULATIONS OF THE TOXIC SUBSTANCES CONTROL ACT (TSCA). STATE RIGHT TO KNOW INFORMATION INGREDIENT PROPRIETARY CAS NUMBER
MSDS 02-0002
SECTION XVI: OTHER INFORMATION ---------------------------------------------------------------------------------------------------------------------------------------------------------------HMIS RATING: HEALTH - 1 FIRE - 1 REACTIVITY - 0 PERSONAL PROTECTION H, n NFPA RATING: HEALTH - 1 FIRE - 1 REACTIVITY 0 DISCLAIMER: KEYCOLOUR INC. BELIEVES ALL THE INFORMATION AND DATA GIVEN IS ACCURATE AS OF THE DATE OF PREPARATION AND IS OFFERED IN GOOD FAITH. THIS INFORMATION IS GIVEN WITHOUT WARRANTY OR REPRESENTATION SOLELY FOR YOUR CONSIDERATION, INVESTIGATION, AND VERIFICATION. SINCE CONDITIONS OF USE ARE BEYOND OUR CONTROL, KEYCOLOUR INC. EXPRESSLY DISCLAIMS ALL LIABILITY FOR THE USE OR HANDLING OF THIS PRODUCT.
MSDS 02-0002
TRADE NAME: ACID BLUE 260 CRUDE PRODUCT ID: K260 PREPARED FOR: EMERGENCY PHONE: Call CHEMTEL 800-255-3924 ________________________________________________________________________________ ____ M A T E R I A L S A F E T Y D A T A S H E E T
________________________________________________________________________________ ____ N O T E: DO NOT DETACH THIS GUIDANCE COVER SHEET FROM THE REST OF THIS DOCUMENT. This page indicates the Keycolour Trade Name and Product ID. This identifying information must be referenced when ordering products or making inquiries. ________________________________________________________________________________ ____ A) YOUR CERTIFICATION OF COMPLIANCE UNDER FEDERAL AND STATE REGULATIONS IMPORTANT NOTE: THIS DOCUMENT IS YOUR OFFICIAL CERTIFICATION OF COMPLIANCE as stated in each applicable section. It is compiled in accordance with OSHA's Hazard Communication standard (29 CFR 1910.1200), and other federal and state regulations. NOTE: NO ADDITIONAL COMPANY CERTIFICATION OF COMPLIANCE IS REQUIRED WHEN COMPLIANCE IS INDICATED IN THE APPROPRIATE SECTION OF THIS DOCUMENT. To avoid use of outdated information, please completely destroy ALL previously dated MSDS' that are on file. ________________________________________________________________________________ ____ B) ABOUT THE FORMAT OF THIS MATERIAL SAFETY DATA SHEET New and updated MSDS' are presented in the ANSI Z400.1 Sixteen-section format. All available information is included in systematic updates. ________________________________________________________________________________ ____ C) ABOUT THE PURPOSE AND AVAILABILITY OF THIS DOCUMENT Under the federal OSHA Hazard Communication Standard and some State Right to Know laws, employers using this product in their operation must make this MSDS available
to all employees handling this product in any manner. The MSDS readily available for review by all persons concerned.
must be
This MSDS is designed to effectively communicate Health and Physical Hazards to the material handler and all other responsible persons concerned with Health and Environmental protection and regulatory compliance. Distributors receiving this MSDS are obligated to readily provide a copy to their customers, affiliates, and agents. ________________________________________________________________________________ ____ D) THE PRODUCT USER RESPONSIBILITY NOTICE This type of document cannot cover all possible unique situations. It is the product user's responsibility to provide a safe workplace, and to pass on all Health, Safety and Environmental information to all employees and customers that may handle this product. Under 29 CFR 1910.1200, all product users and handlers must be informed of U.S. OSHA requirements, and the need to be familiar with them. ________________________________________________________________________________ ____ <<<<<<<<<< MATERIAL SAFETY DATA SHEET >>>>>>>>>> ------------------------------------------------------------------------------PREPARATION DATE PRODUCT ID 09-25-09 K260
------------------------------------------------------------------------------SECTION 1 CHEMICAL IDENTIFICATION C.I. NAME CAS NUMBER CHEMICAL FAMILY PHYSICAL FORM : : : : PROPRIETARY PROPRIETARY ANTHRAQUINONE DYE POWDER
------------------------------------------------------------------------------SECTION 2 HAZARDOUS INGREDIENTS NK ------------------------------------------------------------------------------SECTION 3 HAZARD IDENTIFICATION AND EMERGENCY OVERVIEW HMIS RATINGS
HEALTH FLAMMABILITY REACTIVITY PROTECTION
0 1 0 F, N
EMERGENCY OVERVIEW: POSSIBLE EXPOSURES: EYES, SKIN, BREATHING DUSTS, ACCIDENTAL SWALLOWING POSSIBLE HEALTH EFFECTS: EYE CONTACT: NOT EXPECTED TO IRRITATE 1 SKIN CONTACT: NOT EXPECTED TO IRRITATE 1 BREATHING DUST: NE. TAKE PRECAUTIONS. 1 SWALLOWING: NE. WASH HANDS AFTER HANDLING & BEFORE EATING & DRINKING. 1 SENSITIZATION: NK TARGET ORGANS: NE CANCER INFORMATION: PRODUCT AND COMPONENTS NOT KNOWN TO US TO BE CARCINOGENS NTP: NK IARC: NK OSHA: NR 1 PRECAUTIONS: TO HELP PROTECT AGAINST EXPECTED, OR UNFORSEEN IRRITATIONS OR REACTIONS, WEAR ALL PROPERLY SELECTED PROTECTIVE EQUIPMENT AND CLOTHING AS INSTRUCTED IN SECTION 8 OF THIS MATERIAL SAFETY DATA SHEET. WORKERS SHOULD WASH THEIR HANDS AND FACE AFTER HANDLING AND BEFORE EATING, DRINKING, SMOKING OR USING RESTROOM FACILITIES. AFTER EACH SHIFT, CLEAN ALL PROTECTIVE EQUIPMENT, WASH ALL WORK CLOTHES, AND SHOWER. CHECK SECTION 11 FOR TOXICOLOGY INFORMATION. UNUSUAL HAZARDS: IF MIXED WITH AIR IN SUFFICIENT AMOUNTS & PROPORTIONS, ORGANIC DUSTS CAN FORM FLAMMABLE OR EXPLOSIVE DUST/AIR MIXTURES. AS PRECAUTIONS, KEEP AREAS CLEAN AND AVOID DUST BUILD-UP. HAVE PLENTY OF GOOD VENTILATION. AVOID CREATING VERY DUSTY CONDITIONS. WHEN MIXING, POURING OR PROCESSING BULK AMOUNTS OF POWDERS, GROUND ALL CONTAINERS AND AVOID STATIC CHARGES, SPARKS, SMOKING, OPEN FLAMES, OR OTHER POSSIBLE CAUSES OF FIRE OR EXPLOSION. ------------------------------------------------------------------------------SECTION 4 FIRST AID INSTRUCTIONS EYE CONTACT: IMMEDIATELY RINSE WITH PLENTY OF CLEAN FLOWING WATER FOR AT LEAST 20 MINUTES, HOLDING EYELIDS OPEN TO RINSE COMPLETELY. CALL A DOCTOR, AND GET MEDICAL QUICKLY, AS A PRECAUTION. SKIN CONTACT: REMOVE AFFECTED CLOTHING. WASH AFFECTED SKIN AREA WITH PLENTY OF SOAP AND WATER. RINSE WITH PLENTY OF WATER. WASH ALL WORK CLOTHES BEFORE WEARING AGAIN. IF ANY REDNESS, SWELLING, ITCHING, OR PAIN OF THE SKIN STARTS, SEE A DOCTOR QUICKLY AS A PRECAUTION. BREATHING PRODUCT DUST: MOVE PERSON TO FRESH AIR. IF PERSON IS HAVING DIFFICULTY BREATHING, GIVE OXYGEN. IF NOT BREATHING, GIVE ARTIFICIAL
RESPIRATION. GET EMERGENCY MEDICAL HELP FAST. CALL 911 IF AVAILABLE IN YOUR AREA. IF NOT AVAILABLE CALL ANOTHER MEDICAL EMERGENCY NUMBER. SWALLOWING OF PRODUCT: IF CONSCIOUS, GIVE PLENTY OF WATER TO DRINK AND GET MEDICAL HELP FAST. IF UNCONSCIOUS, DO NOT GIVE ANYTHING TO DRINK TO DRINK. CALL A DOCTOR AND GET EMERGENCY MEDICAL HELP FAST. ------------------------------------------------------------------------------SECTION 5 FIRE FIGHTING INSTRUCTIONS PHYSICAL HAZARDS : FLASH POINT : TYPES OF EXTINGUISHERS : FIREFIGHTING DIRECTIONS: AGAINST POSSIBLY TOXIC NK NA CO2, FOAM, DRY CHEMICAL, WATER SPRAY WEAR SELF-CONTAINED BREATHING APPARATUS TO PROTECT FUMES. WEAR FULL FIRE-PROTECTIVE CLOTHING.
------------------------------------------------------------------------------SECTION 6 ACCIDENTAL SPILL OR RELEASE INSTRUCTIONS WEAR A NIOSH APPROVED DUST RESPIRATOR, ALONG WITH ALL PROTECTIVE CLOTHING AN EQUIPMENT AS DIRECTED IN SECTION 8. CONTAIN AND CLEAN UP SPILL IMMEDIATELY. SWEEP POWDERS CAREFULLY, USING AN ABSORBENT (SUCH AS SWEEPING COMPOUND) TO KEEP DOWN THE DUST IN THE AREA. SCOOP MATERIAL & ABSORBENT INTO DISPOSAL DRUM, AND SEAL. RCRA STATUS: SEE REGULATORY INFORMATION, SECTION 15. ENVIRONMENTAL PROTECTION: PREVENT FROM ENTERING FLOOR DRAINS OR SEWERS. DO NOT RELEASE TO SEWER OR TO ANY BODIES OF WATER OR STREAMS WITHOUT HAVING PROPER GOVERNMENT APPROVAL AT ALL LEVELS, SEE SECTION 13, DISPOSAL CONSIDERATIONS/ENVIRONMENTAL PROTECTION PROCEDURES FOR ANY ADITIONAL INFORMATION. ------------------------------------------------------------------------------SECTION 7 HANDLING AND STORAGE PROTECT PRODUCT FROM MOISTURE, STORE IN COOL, DRY PLACE UNDER LOW RELATIVE HUMIDITY, AWAY FROM EXCESSIVE HEAT. STORE IN ORIGINAL OR EQUIVALENT WATERPROOF CONTAINERS. RESEAL CONTAINERS TIGHTLY AFTER EACH USE. SHELF LIFE: INDEFINITE WHEN STORED CAREFULLY AS INSTRUCTED ABOVE. ------------------------------------------------------------------------------SECTION 8 EXPOSURE CONTROLS AND PERSONAL PROTECTION NOTE: WHEN SELECTING PERSONAL PROTECTIVE EQUIPMENT AND CLOTHING, FOLLOW ALL MANUFACTURER SPECIFICATIONS AND RECOMMENDATIONS THAT APPLY TO YOUR SPECIFIC OPERATIONS AND PROCESSING CONDITIONS. TAKE INTO CONSIDERATION ALL CONDITIONS AND ALL CHEMICALS TO BE HANDLED OR PROCESSED EYE PROTECTION: WEAR SPLASH-PROOF CHEMICAL SAFETY GOGGLES. CONTACT LENSES
SHOULD NOT BE WORN WHEN WORKING WITH CHEMICALS. SKIN PROTECTION: WEAR CHEMICALLY RESISTANT RUBBER GLOVES, SELECTED WITH YOUR SPECIFIC PROCESSING CONDITIONS AND CHEMICALS TO BE HANDLED IN MIND WEAR COVERALLS AND BOOTS TO MINIMIZE SKIN CONTACT. AS PRECAUTIONS, WASH HANDS & FACE WITH MILD SOAP & WATER BEFORE EATING, DRINKING, SMOKING, OR USING RESTROOM. AFTER EACH SHIFT, CLEAN ALL PROTECTIVE EQUIPMENT, WASH WORK CLOTHES, AND SHOWER. LUNG, THROAT & NASAL PROTECTION: WEAR NIOSH APPROVED DUST RESPIRATOR FOR YOUR PARTICULAR OPERATION AND MATERIALS BEING HANDLED. OTHER PROTECTION: EYE WASH FOUNTAINS & DRENCH SHOWERS SHOULD BE LOCATED WITHIN 100 FEET OR A 10 SECOND WALK OF THE WORK AREA PER ANSI Z358.1-1990 VENTILATION: LOCAL EXHAUST IS RECOMMENDED, MECHANICAL EXHAUST ACCEPTABLE ------------------------------------------------------------------------------SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES DESCRIPTION : DECOMPOSITION TEMP: PH : WATER SOLUBILITY : BULK DENSITY : BLUE POWDER; NO ODOR NE 9.0 - 10.0 @ 1 G/L WATER 10 G/L @ 30 C NE
------------------------------------------------------------------------------SECTION 10 STABILITY AND REACTIVITY STABILITY : STABLE CONDITIONS TO AVOID : NK HAZARDOUS POLYMERIZATION: WILL NOT OCCUR INCOMPTABILE MATERIALS : NK HAZARDOUS DECOMPOSITION PRODUCTS: BURNING CAN PRODUCE OXIDES OF CARBON, NITROGEN OR SULFUR ------------------------------------------------------------------------------SECTION 11 TOXICOLOGY INFORMATION ORAL LD50 (RAT): > 5000 MG/KG DERMAL LD50 (RAT): NE INHALATION LC50 (RAT): NE EYE EFFECTS (RABBIT): NOT AN IRRITANT 1 SKIN EFFECTS (RABBIT): NOT AN IRRITANT 1 BREATHING EFFECTS: NE. TAKE PRECAUTIONS. 1) NOTE: ALTHOUGH THIS PRODUCT IS NOT AN IRRITANT BASED ON ANIMAL STUDIES, INDIVIDUALS CAN STILL BECOME SENSITIVE TO, OR REACT TO ANY CHEMICALS IN ANY OF THEIR WORK AREAS. AS PRECAUTIONS, BE SURE TO WEAR ALL PROTECTIVE EQUIPMENT AND CLOTHING AS EXPLAINED IN SECTION 8 OF THIS MSDS. GENERAL PRECAUTIONS: ALWAYS PRACTICE GOOD INDUSTRIAL HYGIENE, HANDLE WITH CARE, AVOID PERSONAL CONTACT. DO NOT GET INTO EYES OR ON SKIN, DO NOT
BREATHE DUST OF PRODUCT, DO NOT SWALLOW. WASH HANDS WITH SOAP AND WATER, AND RINSE WELL AFTER HANDLING PRODUCT. SHOWER AFTER EACH SHIFT. WASH ALL WORK CLOTHING AND COMPLETELY CLEAN ALL PROTECTIVE EQUIPMENT AFTER EACH SHIFT. SEE SECTION 2. MUTAGENICITY: NK MORE INFORMATION: SEE SECTION 3, HAZARD IDENTIFICATION & EMERGENCY OVERVIEW MEDICAL CONDITIONS WORSENED BY EXPOSURE: PERSONS WITH BREATHING AND LUNG PROBLEMS CAN BE AFFECTED BY BREATHING IN ANY TYPE OF DUSTY MATERIAL. PERSONS WITH ASTHMA, ALLERGIES, OR OTHER BREATHING-RELATED PROBLEMS SHOULD STAY AWAY FROM, NOT HANDLE, AND NOT BE EXPOSED TO ANY DUSTY PRODUCTS OR DUSTY CONDITIONS AS A PRECAUTIONARY MEASURE. ------------------------------------------------------------------------------SECTION 12 ECOLOGICAL DATA BOD 5: 15.0 MG/G COD: 1280.0 MG/G FISH TOXICITY: LC50 = 6 MG/L (TROUT) 48 HR EFFECT ON WASTE TREATMENT BACTERIA: > 300 MG/L ACTIVATED SLUDGE RESPIRATION INHIBITION TEST: NE CWA TOXIC POLLUTANTS: NK ADDITIONAL ENVIRONMENTAL DATA: NE ------------------------------------------------------------------------------SECTION 13 DISPOSAL CONSIDERATIONS/ENVIRONMENTAL PROTECTION PROCEDURES DISPOSAL METHODS: IT IS RECOMMENDED THAT YOU SELECT AN ALTERNATIVE BELOW ACCORDING TO THE FOLLOWING ORDER OF PREFERENCE, DEPENDING ON ENVIRONMENTAL IMPACT: 1) RECYCLE OR REWORK MATERIAL IF AT ALL POSSIBLE 2) INCINERATE MATERIAL AT AN APPROVED FACILITY 3) TREAT AT AN ACCEPTABLE WASTE TREATMENT FACILITY, OR MUNICIPAL WASTE TREATMENT PLANT AFTER PROPER TESTING & APPROVAL WASTE SAMPLES. IF DISPOSED OF IN IT'S ORIGINAL UNUSED FORM, THIS MATERIAL SHOULD BE TREATED, AND DISPOSED OF AT AN APPROVED SITE OR FACILITY, IN COMPLIANCE WITH ALL APPLICABLE FEDERAL, STATE & LOCAL ENVIRONMENTAL REGULATIONS. YOU MUST CONTACT THE PROPER GOVERNMENT AGENCIES FOR ADDITIONAL DIRECTIONS. ALL WASTE MATERIAL & WASTE WATER SHOULD BE DISPOSED OF CORRECTLY, UNDER ALL FEDERAL, STATE , CITY & COUNTY LAWS. RCRA STATUS: CHECK SECTION 15, REGULATORY INFORMATION DO NOT RELEASE ANY CHEMICALS, DYE, OR DYE SOLUTION INTO ANY WATERWAYS OR SEWER SYSTEMS WITHOUT PROPER GOVERNMENT PERMISSION AT ALL LEVELS. CONTAINER REUSE: AN "EMPTY" CONTAINER CAN CONTAIN PRODUCT RESIDUE, AND SHOULD NOT BE REUSED. IF NOT PROFESSIONALLY CLEANED & RECONDITIONED, CRUSHING OR OTHER MEANS IS RECOMMENDED TO PREVENT UNAUTHORIZED REUSE
------------------------------------------------------------------------------SECTION 14 SHIPPING/TRANSPORT INFORMATION DOT STATUS (HIGHWAY & RAIL): NR IATA STATUS (AIR): NR -----------------------------------------------------------------------------SECTION 15 REGULATORY INFORMATION AICS (AUSTRALIA): NC CAL. PROP. 65: TO THE BEST OF OUR PRESENT KNOWLEDGE BASED ON THE INFORMATION AVAILABLE AT THE TIME OF THIS ENTRY, WE ARE NOT AWARE OF ANY CHEMICALS PRESENT IN THIS PRODUCT THAT ARE KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER OR REPRODUCTIVE TOXICITY. CERCLA: NH CLEAN AIR ACT: TITLE III-HAP'S: NK TITLE V-VOC'S: NK TITLE VI-ODC'S: NOT MANUFACTURED WITH NOR CONTAINING CLASS I OR II ODC'S CONEG-TYPICAL METALS PRESENT IN PPM: CADMIUM NE CHROMIUM NE LEAD NE MERCURY NE DSL (CANADA): NC ECL (KOREA): NC EINECS (EUROPE): NC ENCS (JAPAN): NC FDA STATUS: NL OTHER TYPICAL DATA IN PPM: NK RCRA: NOT HAZARDOUS IN IT'S PURCHASED FORM. HOWEVER, UNDER RCRA, IT IS THE PRODUCT USER'S RESPONSIBILITY TO DETERMINE AT TIME OF DISPOSAL IF ANY MATERIAL CONTAINING THE PRODUCT OR DERIVED FROM THE PRODUCT IS A HAZARDOUS WASTE. SARA 311/312: IMMEDIATE/ACUTE HEALTH HAZARD : NO DELAYED/CHRONIC HEALTH HAZARD : NO FIRE HAZARD : NO SUDDEN RELEASE OF PRESSURE HAZARD: NO REACTIVITY HAZARD : NO SARA 313: NR TSCA: COMPONENTS LISTED USDA: NL WHMIS: NC ------------------------------------------------------------------------------SECTION 16 OTHER INFORMATION ACRONYM LIST NA = NOT APPLICABLE TO THIS MATERIAL NC = NOT CERTAIN, UNDETERMINED ND = NO DATA IS CURRENTLY AVAILABLE
NE NH NK NL NR
= = = = =
NOT ESTABLISHED, NO TESTING IS PLANNED NOT HAZARDOUS UNDER CITED REGULATIONS NONE KNOWN, NO INFORMATION FOUND IN DATA SEARCHS NOT LISTED OR APPROVED UNDER THESE REGULATIONS NOT REGULATED OR REPORTABLE
NIOSH = NATIONAL INSTITUTE FOR OCCUPATIONAL SAFETY AND HEALTH THE INFORMATION AND RECOMMENDATIONS CONTAINED HEREIN ARE BASED UPON DATA BELIEVED TO BE CORRECT. HOWEVER, NO GUARANTEE OR WARRANTY OF ANY KIND EXPRESSED OR IMPLIED, IS MADE WITH RESPECT TO THE INFORMATION CONTAINED HEREIN. THIS MATERIAL SAFETY DATA SHEET WAS PREPARED TO COMPLY WITH THE OSHA HAZARD COMMUNICATION STANDARD 29 CFR 1910.1200, AND SUPERSEDES ANY PREVIOUS INFORMATION. PREVIOUSLY DATED SHEETS ARE INVALID & UNAPPLICABLE.

-----------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION I: CHEMICAL PRODUCT AND COMPANY IDENTIFICATION -----------------------------------------------------------------------------------------------------------------------------------------------------------------TRADE NAME: ACID RED 266 200% CHEMICAL FAMILY: Acid Red 266
CHEMTREC 800-424-9300
DATE PREPARED: DECEMBER 2009 ---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION II: COMPOSITION/INFORMATION ON HAZARDOUS INGREDIENTS ---------------------------------------------------------------------------------------------------------------------------------------------------------------CHEMICAL NAME CAS NUMBER %BY WT. TLV/PEL AZO DYE 57741-47-6 NOT ESTABLISHED --------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION III: HAZARDS IDENTIFICATION ---------------------------------------------------------------------------------------------------------------------------------------------------------------EMERGENCY OVERVIEW: MAY CAUSE SKIN, EYE AND RESPIRATORY IRRITATION. EFFECTS OF OVEREXPOSURE: EYE CONTACT: IRRITATING. SKIN CONTACT: MAY BE IRRITATING. INHALATION: MAY BE IRRITATING. INGESTION: NOT KNOWN. CHRONIC EXPOSURE: NOT KNOWN. CARCINOGENICITY: NOT LISTED AS AN IARC, NTP OR OSHA CARCINOGEN. MEDICAL CONDITIONS AGGREVATED BY EXPOSURE: NOT KNOWN PRIMARY ROUTES OF ENTRY: SKIN CONTACT, EYE CONTACT AND INHALATION. ---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION IV: FIRST AID MEASURES ---------------------------------------------------------------------------------------------------------------------------------------------------------------EYE CONTACT: IMMEDIATELY FLUSH EYE WITH FLOWING WATER FOR AT LEAST 15 MINUTES, HOLDING EYELIDS APART TO IRRIGATE THOROUGHLY. GET MEDICAL ATTENTION. SKIN CONTACT: WASH THOROUGHLY WITH SOAP AND WATER. GET MEDICAL ATTENTION IF IRRITATION DEVELOPS. REMOVE AND LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. INHALATION: REMOVE TO FRESH AIR. IF BREATHING IS DIFFICULT, GIVE OXYGEN. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. GET MEDICAL ATTENTION. INGESTION: DILUTE WITH WATER AND INDUCE VOMITING. GET MEDICAL ATTENTION. NEVER GIVE FLUIDS OR INDUCE VOMITING IF PATIENT IS UNCONSCIOUS OR HAS CONVULSIONS. ---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION V: FIRE FIGHTING MEASURES ---------------------------------------------------------------------------------------------------------------------------------------------------------------FLASH POINT: NOT DETERMINED. LOWER EXPLOSIVE LIMIT: NOT APPLICABLE. UPPER EXPLOSIVE LIMIT: NOT APPLICABLE AUTOIGNITION TEMPERATURE: NOT DETERMINED. EXTINGUISHING MEDIA: WATER, DRY CHEMICAL, CARBON DIOXIDE, AND FOAM. 1 MSDS 02-0002
SPECIAL FIRE FIGHTING PROCEDURES: FIREFIGHTERS SHOULD BE EQUIPPED WITH SELF CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING. UNUSUAL HAZARDS: DUST MAY BE EXPLOSIVE IF MIXED WITH AIR IN CRITICAL PROPORTIONS AND IN THE PRESENCE OF SOURCE OF IGNITION. ---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION VI: ACCIDENTAL RELEASE MEASURES ---------------------------------------------------------------------------------------------------------------------------------------------------------------STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: WEAR APPROPRIATE SAFETY EQUIPMENT. CONTAIN AND CLEAN UP SPILL IMMEDIATELY. PREVENT FROM ENTERING FLOOR DRAINS. SWEEP POWDERS CAREFULLY MINIMIZING DUSTING. SHOVEL ALL SPILL MATERIALS INTO DISPOSAL DRUMS AND FOLLOW DISPOSAL INSTRUCTIONS. SCRUB SPILL AREA WITH DETERGENT AND FLUSH WITH COPIOUS AMOUNTS OF WATER. ---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION VII: HANDLING AND STORAGE ---------------------------------------------------------------------------------------------------------------------------------------------------------------HANDLING: IN ACCORDANCE WITH GOOD INDUSTRIAL PRACTICES, HANDLE WITH CARE AND AVOID PERSONAL CONTACT. CONTAINERS SHOULD BE TRIPLE RINSED ACCORDING TO FEDERAL REGULATIONS AND/OR GOOD WASTE MANAGEMENT PRCATICES. FOR INDUSTRIAL USE ONLY. STORAGE: KEEP CONTAINERS CLOSED WHEN NOT IN USE. ---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION VIII: EXPOSURE CONTROL/PERSONAL PROTECTION ---------------------------------------------------------------------------------------------------------------------------------------------------------------ENGINEERING CONTROLS: LOCAL EXHAUST TO MINIMIZE EXPOSURE. RESPIRATORY PROTECTION: IF EXPOSURE TO DUST IS LIKELY, A NIOSH APPROVED DUST RESPIRATOR IS RECOMMENDED. EXPOSURE LIMITS: NOT ESTABLISHED. EYE PROTECTION: WEAR SAFETY GLASSES WITH SIDE SHIELDS OR SAFETY GOGGLES. SKIN PROTECTION: WEAR RUBBER GLOVES. OTHER PROTECTIVE MEASURES: WEAR APRON, COVERALLS, BOOTS AND LONG SLEEVE SHIRT TO PREVENT SKIN CONTACT. HYGIENIC PRACTICES: EYEWASH FOUNTAINS SHOULD BE EASILY ACCESSIBLE. SHOWER AFTER HANDLING THIS PRODUCT. WORK CLOTHES SHOULD BE WASHED BEFORE REUSE. BEFORE EATING, DRINKING, OR SMOKING, WASH HANDS AND FACE WITH SOAP AND WATER. ---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION IX: PHYSICAL AND CHEMICAL PROPERTIES ---------------------------------------------------------------------------------------------------------------------------------------------------------------APPEARANCE: POWDER ODOR: NONE SOLUBILITY IN WATER: SOLUBLE BOILING POINT: NOT APPLICABLE. MELTING POINT: NOT ESTABLISHED. -------------------------------------------------------------------------------------------------------------------------------------SECTION X: STABILITY AND REACTIVITY ---------------------------------------------------------------------------------------------------------------------------------------------------------------STABILITY: STABLE. CONDITIONS TO AVOID: NONE KNOWN. HAZARDOUS POLYMERIZATION: WILL NOT OCCUR. INCOMPATIBLE MATERIALS: NONE KNOWN.
MSDS 02-0002
HAZARDOUS DECOMPOSITION PRODUCTS: BURNING WILL PRODUCE OXIDES OF CARBON, NITROGEN AND SULFUR. ---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION XI: TOXICOLOGICAL PROPERTIES ---------------------------------------------------------------------------------------------------------------------------------------------------------------RAT, ORAL LD50: NOT ESTABLISHED RABBIT, SKIN: NOT ESTABLISHED RABBIT, EYES: NOT ESTABLISHED, PROBABLY IRRITATING. ADDITIONAL TOXICITY DATA: NOT KNOWN. ---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION XII: ECOLOGICAL INFORMATION ---------------------------------------------------------------------------------------------------------------------------------------------------------------NO INFORMATION IS CURRENTLY AVAILABLE. ---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION XIII: DISPOSAL CONSIDERATIONS ---------------------------------------------------------------------------------------------------------------------------------------------------------------WASTE DISPOSAL METHOD: THIS PRODUCT IS NOT TO BE CONSIDERED A HAZARDOUS WASTE UNDER RCRA (40 CFR 261).DISPOSAL MUST BE IN ACCORDANCE WITH APPLICABLE GOVERNMENTAL REGULATIONS. CONTAINER DISPOSAL INFORMATION: CONTAINERS SHOULD BE TRIPLE RINSED ACCORDING TO FEDERAL REGULATIONS AND/OR GOOD WASTE MANAGEMENT PRACTICE. ---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION XIV: TRANSPORTATION INFORMATION ---------------------------------------------------------------------------------------------------------------------------------------------------------------DOT PROPER SHIPPING NAME: NOT REGULATED. DOT TECHNICAL NAME: NOT APPLICABLE. DOT HAZARD CLASS: NOT APPLICABLE. HAZARD SUBCLASS: NOT APPLICABLE. DOT UN/NA NUMBER: NOT APPLICABLE. PACKING GROUP: NOT APPLICABLE. RESP. GUIDE PAGE: NOT APPLICABLE. DOT REPORTABLE QUANTITY: NOT APPLICABLE. DOT LABELS: NOT APPLICABLE. ---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION XV: REGULATORY INFORMATION ---------------------------------------------------------------------------------------------------------------------------------------------------------------SARA TITLE III SECTION 302: THIS PRODUCT DOES NOT CONTAIN ANY CHEMICALS REGULATED UNDER SECTION 302 AS EXTREMELY HAZARDOUS. SARA TITLE III SECTION 304 (CERCLA): THIS PRODUCT DOES NOT CONTAIN ANY CHEMICALS REGULATED UNDER SECTION 304 AS A HAZARDOUS SUBSTANCE FOR EMERGENCY RELEASE NOTIFICATION. SARA TITLE III SECTION 312 HAZARD RATING: ACUTE: YES CHRONIC: NO FLAMMABILITY: NO REACTIVITY: NO PRESSURE: NO SARA TITLE III SECTION 313: THIS PRODUCT IS NOT REPORTABLE FOR SARA 313. TSCA: THIS PRODUCT IS REGISTERED UNDER THE REGULATIONS OF THE TOXIC SUBSTANCES CONTROL ACT (TSCA). STATE RIGHT TO KNOW INFORMATION INGREDIENT ACID RED 266 CAS NUMBER 57741-47-6
MSDS 02-0002
---------------------------------------------------------------------------------------------------------------------------------------------------------------SECTION XVI: OTHER INFORMATION ---------------------------------------------------------------------------------------------------------------------------------------------------------------HMIS RATING: HEALTH - 2 FIRE - 1 REACTIVITY - 0 PERSONAL PROTECTION - F NFPA RATING: HEALTH - 1 FIRE - 1 REACTIVITY - 0 ------------------------------------------------------------------------------------------------------------------------------------------DISCLAIMER: KEYCOLOUR INC. BELIEVES ALL THE INFORMATION AND DATA GIVEN IS ACCURATE AS OF THE DATE OF PREPARATION AND IS OFFERED IN GOOD FAITH. THIS INFORMATION IS GIVEN WITHOUT WARRANTY OR REPRESENTATION SOLELY FOR YOUR CONSIDERATION, INVESTIGATION, AND VERIFICATION. SINCE CONDITIONS OF USE ARE BEYOND OUR CONTROL, KEYCOLOUR INC. EXPRESSLY DISCLAIMS ALL LIABILITY FOR THE USE OR HANDLING OF THIS PRODUCT.
MSDS 02-0002
HMIS RATINGS:
HEALTH:
FIRE: 1
REACTIVITY: 0

Product I.D.: Product Name: Product Description: Chemical Family: Effective Date: K301 ACID BROWN 282 CRUDE Acid Brown Colorant Powder Cr+3 compound < 85% Metallized azo dye July 3, 2009

Component Chromium as Cr+3 (Complexed in dye molecule) CAS Number 7440-47-3 Wt % 1 -10% OSHA - PEL 0.5 mg/m3 TWA ACGIH - TLV 0.5 mg/m3 TWA Recommended PEL Not applicable
1.00 Important Notice: UNPROTECTED CONTACT with Section 2 ingredients may be hazardous based on OSHA 29 CFR 1910.1200 & related appendices, unless noted otherwise for disclosure. Any not listed are confidential, non-hazardous, or below reportable limits. Confidential information is available to medical or emergency personnel. Use ALL PROTECTIVE EQUIPMENT & CLOTHING (Section 8) TO MINIMIZE or ELIMINATE CONTACT. Effects from UNPROTECTED may be unpredictable, depending on individual reactions. End-users are responsible for hazard determination and communication. 1 . 0 0 1.00

Emergency Overview: Mild eye and skin irritant. Respiratory effects not established. Eye Contact: Depending on degree of UNPROTECTED contact, vapors, mists, aerosols, splashes, droplets or dusts of product may cause health effects such as MILD IRRITATION, discomfort, redness, watering, itching, stinging. Heavy contact or for prolonged period may increase effects. Skin Contact:

K301 ACID BROWN 282 CRUDE Depending on degree of UNPROTECTED contact, vapors, mists, splashes, aerosols, or dusts of product may cause health effects in SENSITIVE or SENSITIZED individuals such as IRRITATION to skin, ALLERGIC REACTIONS, redness, rash, itching, burning feeling, drying, cracking, pain, swelling, or other effects. Prolonged or repeated contact may cause inflammation. Quantity absorption through skin may cause nausea, headache, or other effects. Inhalation: UNPROTECTED breathing of product vapors, mists, aerosols or dusts may cause symptoms including MILD IRRITATION of the nose, throat, lungs and mucous membranes, shortness of breath, sneezing, coughing, runny nose, nausea, headache. Prolonged or heavy exposure, or heating of liquid material may increase severity of symptoms. Hazard assessment is cautious, based on component information. Ingestion: Depending on amount swallowed, product can cause health effects including MILD IRRITATION of mouth, throat, esophagus, stomach, and gastrointestinal tract, upset stomach, abdominal discomfort, nausea, vomiting, gastrointestinal disturbances, diarrhea. Higher dose may increase irritation and severity of symptoms. Medical Conditions Aggravated by Exposure: UNPROTECTED or IMPROPERLY PROTECTED exposure to vapors, mists, aerosols, splashes or dusts of full strength product or its components by inhalation, eye contact, skin contact or swallowing MAY AGGRAVATE one or more of the following pre-existing medical conditions: Respiratory (breathing related) problems (asthma, allergies, etc.), skin conditions, or disorders, eye conditions or disorders, kidney disorders, liver disorders. Avoid ALL exposures. Individuals with any of the above-noted conditions, or with any known or suspected chemical sensitivities or allergies should avoid working with or being exposed to any chemicals. Skin Sensitization: Protect yourself and AVOID ALL EXPOSURES. As a precaution, persons known to be or suspected of being chemically sensitive or allergic should not work with chemicals. UNPROTECTED or IMPROPERLY PROTECTED exposure to product or its components may cause SKIN SENSITIZATION OR ALLERGIC REACTIONS in some individuals. Effects may include redness, swelling, itching, rash and hives. It may take repeated or prolonged exposure to cause health effects. SENSITIZATION or ALLERGIC REACTIONS ARE UNPREDICTABLE. If symptoms appear, IMMEDIATELY remove person from area of contact, follow Section 4 instructions, GET MEDICAL ATTENTION. Respiratory Sensitization: Respiratory sensitization caused by inhalation of product dust, vapors, mists or aerosols HAS NOT BEEN DETERMINED. As a precaution against aggravating existing respiratory conditions, hypersensitivity, allergic reactions, or other unforeseen health effects, be sure to read, understand and follow all supervisor instructions, and instructions for wearing Personal Protective Equipment and clothing in Section 8 of this MSDS. Avoid inhalation of product in any form. ALLERGIC REACTIONS and SENSITVITY depend on the individual, and CAN BE UNPREDICTABLE. Special Warnings: None for this material Unusual Health Hazards: None for this material Supplemental Hazard Information: No additional information available Notes to Physician: No notes available
Page 2 of 8

K301 ACID BROWN 282 CRUDE Cancer Information:
Chemical Name Chromium as Cr+3 (Complexed in dye molecule) CAS # 7440-47-3 WT % 1 - 10% IARC Group 3 Unclassifiable on human carcinogenicity NTP NONE OSHA NONE NIOSH NONE
Page 3 of 8
ACGIH NONE

Eye Contact: Immediately rinse with plenty of water for at least 15 minutes. Get immediate medical attention, as a precaution. Skin Contact: Immediately remove contaminated clothing. Wash affected area with soap and rinse with plenty of water. Get medical attention, as a precaution. Inhalation: Move person to fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration, and get emergency medical help immediately. Have this Material Safety Data Sheet available. Ingestion: Do not induce vomiting unless directed to do so by emergency medical personnel. Have this Material Safety Data Sheet available.

Flash Point: Not applicable Unusual hazards: None expected Other Hazards: None known Types of Extinguishers: CO2, dry chemical, foam, water fog or spray depending on type of fire Fire Fighting Directions: Wear self-contained breathing equipment and fire-proof clothing. Use water spray to cool fire exposed containers if they cannot be safely moved.

Special Precautions: None known. Follow general precautions shown below. Static Discharges: Take precautionary measures against static discharges when mixing, filling or otherwise dispensing any powders, combustibles, or flammable liquids. Containers should be properly grounded with metal straps, cables or other appropriate means to relieve static electricity build-up. Environmental Protection: Immediately dike liquid spills with inert absorbent material (sand, "Oil Dry" or other commercially available spill absorbent) to contain and soak up liquid. Prevent material from entering floor drains, sewers, or any bodies of water. For powder spills, use sweeping compound, sawdust, or other appropriate material to contain dust. If possible, recover any uncontaminated materials to re-use. Protective equipment and clothing: Wear all proper personal protective equipment and clothing to care for spill situation. See section 8 of this MSDS. Clean up:

K301 ACID BROWN 282 CRUDE After containing liquid spill by diking and soaking up with inert absorbent material, place in labeled container to be sealed for proper and regulated disposal. Only the slightest residue should remain. Try to save uncontaminated material for reuse whenever possible. For powders, use sweeping compound to minimize dust and pick up as much product as possible. Do not allow liquids to seep into drains, sewers, lakes, rivers, etc. Check Sections 1 and 2 for dye description or type. Solvent dye residue may be cleaned by scrubbing with detergent, depending on type. Do not add water to water-soluble dyes. Dye is concentrated. This will increase amount of color to remove. All cleaning or scrubbing liquids used should be absorbed and placed in labeled containers for correct disposal. Call emergency number for assistance if needed.
Page 4 of 8

Warnings and Precautions: No special precautions anticipated. Wear all PPE in section 8 as a precaution, and avoid physical contact with material. Personal Protection: Wear ALL proper personal protective equipment as outlined in section 8 of this MSDS. Storage & Temperature Conditions: Keep conditions cool, dry, out of direct sunlight, away from high heat, with at least minimal ventilation. Protect all products containing water from freezing.

Note: Selecting protective equipment & clothing: When choosing personal protective equipment and clothing, consider each worker environment, all chemicals being handled, temperature and all other conditions. Eye protection: Always wear indirectly vented, splash-proof chemical safety goggles under a clear face-shield. Face shield is not to be used without these goggles. Skin Protection: Always wear most impervious gloves such as nitrile or other proper chemical-resistant gloves for the job, along with proper coveralls, rubber or plastic apron, etc. Wash hands before eating, drinking or using restroom. Shower after each shift. Clean contaminated protective equipment and clothing before reusing. Respiratory Protection: Depending on materials handled, ALWAYS wear an appropriate NIOSH approved organic vapor/mist respirator, or dust respirator, with all proper filters as required whenever exposure to vapors or dusts is expected. After each shift or when equipment becomes contaminated, clean respirator in compliance with 29 CFR 1910.134. Eye Washes and Other Protection: Eye wash stations and drench showers should be located within 100 feet or 10-second walk of the work area per ANSI standard Z358.1-1990. Ventilation: Local exhaust should be used to maintain exposure limits below specified amounts recommended by OSHA, NIOSH, or ACGIH and to draw spray, aerosol, vapors, or dusts away from workers and prevent routine inhalation. At least 10 air changes per hour are recommended for good room ventilation. Airborne Exposure Limits:
Chemical Name Chromium as Cr+3 (Complexed in dye molecule) CAS # 7440-47-3 WT % 1 - 10% NIOSH - REL 0.5 mg/m3 TWA NIOSH - IDLH Not established OTHER OEL'S Not established

K301 ACID BROWN 282 CRUDE pH: % Water Content: % Total Solids / Non-Volatiles: % Total VOC: Color: Bulk Density (Solid): Form: Odor: Freezing/Melting Point: Specific Gravity (Liquid): Vapor Pressure: Water Solubility: Solvent Solubility: Other Properties: ~ 7.5 @ 1.0% 0 100 0 Brown Not established Powder None Not established Not established 0 Soluble Not applicable No further data
Page 5 of 8
Any quantity of VOC's reported here is calculated based on the U.S. EPA definition. State or local definitions may differ. To request additional Regulatory Compliance Data, call 312-666-2015.

Stability: Product is stable under normal, ambient (controlled) conditions concerning heat, moisture, pressure, ventilation and exposure to incompatible or reactive materials. Hazardous Polymerization: Product will not undergo polymerization. Conditions to Avoid: Incompatible materials, moisture Incompatible Materials: Strong oxidizing agents, strong reducing agents Hazardous Decomposition Products: In fire: Oxides of carbon, nitrogen, sulfur. Possible Hazard Reactions: None known

Oral LD50 (Rat): Eye Effects (Rabbit): Skin Effects (Rabbit): Mutagenicity: Inhalation LC50 (Rat): Skin Sensitization (Guinea Pig): Respiratory Sensitization: Additional Toxicity Data: No data currently available No data currently available No data currently available No data currently available No data currently available No data currently available No data currently available No data currently available

K301 ACID BROWN 282 CRUDE BOD: COD: Aquatic Toxicity: Biodegradability: Persistence: Ecotoxicity: Sewage Treatment: Other Data: No data currently available No data currently available No data currently available No data currently available No data currently available No data currently available Undetermined No additional data is available
Page 6 of 8

DOT Regulations (Ground): NOT REGULATED IATA Regulations (Air): NOT REGULATED

Component Chromium as Cr+3 (Complexed in dye molecule) CAS Number 7440-47-3 Weight % 1 - 10% Regulatory List 2, 8, 11: D007, 13: 0.1%, 15: DE, MA, MN, NJ, NY
Regulatory List Reference: NOTE: Regulations only apply when numbers listed below are shown on line(s) above this notation. Example A: 5, 8 (Indicates chemical is listed as an EPA HAP and a Marine Pollutant) Example B: 10: D007, 11: 5000 (Indicates chemical is a hazardous waste (Chromium), and is an EHS with RQ of 5000 lbs.) 1-Accidental Release Substance 2-CERCLA 304 Hazardous Substance (RQ) 3-Reserved 4-Clean Air Act-Sec. 111 Volatile Organic Compounds (VOC) 5-Clean Air Act-Sec. 112 Haz. Air Pollutant (HAP, HAP Code)

K301 ACID BROWN 282 CRUDE 6-Clean Air Act-Ozone Depleting Chemical (ODC) 7-Clean Water Act-RQ 8-Clean Water Act-Priority Pollutant (PP) RQ 9-Marine Pollutant (MP) 10-PSM Highly Hazardous Chemical 11-RCRA Hazardous Waste (RCRA Code) 12-SARA 302 Extremely Hazardous Substance (EHS) (RQ) 13-SARA 313 Toxic Release Inventory (TRI) (TR Conc., TR Threshold) 14-SOCMI Chemical 15-State Lists CA-California Proposition 65 NJ-New Jersey RTK Hazardous Substance List NJ-New Jersey TCPA Extremely Hazardous Substance List 16-Supplemental regulatory information (SRI) List revised 12/29/09 wln (Current list is not applicable to previously issued MSDS')
Page 7 of 8
SARA 311/312 Hazard Categories: Immediate / Acute Health Hazard: Chronic / Delayed Hazard: Fire Hazard: Sudden Release of Pressure Hazard: Reactivity Hazard: NATIONAL CHEMICAL INVENTORIES: AICS (Australia): ASIA-PAC (Asia-Pacific): DSL (Canada): ECL (Korea): EINECS (Europe): ENCS (Japan): IECSC (China): PICCS (Philippines): TSCA (US): OTHER: Supplemental Regulatory Information: For additional International, Federal or State regulatory compliance information not shown: Call 312-666-2015. Not yet determined Not yet determined Not yet determined Not yet determined Not yet determined Not yet determined Not yet determined Not yet determined Components Listed YES NO NO NO NO

Reason for Revision: Reviewed: Disclaimer: The information and recommendations contained herein are based upon data believed to be correct. However, no guarantee or warranty of any kind, expressed or implied, is made with respect to the information contained herein. This Material Safety Data Sheet was prepared to comply with the OSHA Hazard Communication Standard 29 CFR 1910.1200, and supersedes any previous information. Previously dated sheets are invalid and inapplicable. END OF MSDS None at this time wln 070306

K301 ACID BROWN 282 CRUDE
Page 8 of 8
TRADE NAME: ACID RED 357 CRUDE PRODUCT ID: 601-357-80 EMERGENCY PHONE: Call CHEMTEL 800.255.3924 ________________________________________________________________________________ ____ M A T E R I A L S A F E T Y D A T A S H E E T
________________________________________________________________________________ ____ N O T E: DO NOT DETACH THIS GUIDANCE COVER SHEET FROM THE REST OF THIS DOCUMENT. This page indicates the Keycolour Trade Name and Product ID. This identifying information must be referenced when ordering products or making inquiries. ________________________________________________________________________________ ____ A) YOUR CERTIFICATION OF COMPLIANCE UNDER FEDERAL AND STATE REGULATIONS IMPORTANT NOTE: THIS DOCUMENT IS YOUR OFFICIAL CERTIFICATION OF COMPLIANCE as stated in each applicable section. It is compiled in accordance with OSHA's Hazard Communication standard (29 CFR 1910.1200), and other federal and state regulations. NOTE: NO ADDITIONAL COMPANY CERTIFICATION OF COMPLIANCE IS REQUIRED WHEN COMPLIANCE IS INDICATED IN THE APPROPRIATE SECTION OF THIS DOCUMENT. To avoid use of outdated information, please completely destroy ALL previously dated MSDS' that are on file. ________________________________________________________________________________ ____ B) ABOUT THE FORMAT OF THIS MATERIAL SAFETY DATA SHEET New and updated MSDS' are presented in the ANSI Z400.1 Sixteen-section format. All available information is included in systematic updates. ________________________________________________________________________________ ____ C) ABOUT THE PURPOSE AND AVAILABILITY OF THIS DOCUMENT Under the federal OSHA Hazard Communication Standard and some State Right to Know laws, employers using this product in their operation must make this MSDS available
to all employees handling this product in any manner. The MSDS readily available for review by all persons concerned.
must be
This MSDS is designed to effectively communicate Health and Physical Hazards to the material handler and all other responsible persons concerned with Health and Environmental protection and regulatory compliance. Distributors receiving this MSDS are obligated to readily provide a copy to their customers, affiliates, and agents. ________________________________________________________________________________ ____ D) THE PRODUCT USER RESPONSIBILITY NOTICE This type of document cannot cover all possible unique situations. It is the product user's responsibility to provide a safe workplace, and to pass on all Health, Safety and Environmental information to all employees and customers that may handle this product. Under 29 CFR 1910.1200, all product users and handlers must be informed of U.S. OSHA requirements, and the need to be familiar with them. ________________________________________________________________________________ ____ <<<<<<<<<< MATERIAL SAFETY DATA SHEET >>>>>>>>>> ________________________________________________________________________________ __ Effective Date: 06-08-09 Supersedes: 06-10-05 Product Code: K605 ________________________________________________________________________________ __ SECTION 1: <CHEMICAL IDENTIFICATION> C.I. Name : C.I. Number : CAS Number : Chemical Family: Physical Form : NA NA 73507-64-9 Chromium Complex Dye Powder
________________________________________________________________________________ __ SECTION 2: <INFORMATION ON INGREDIENTS> Component Name % CAS Number PEL TLV
Acid Red 357 100
73507-64-9
NE
NE
________________________________________________________________________________ __ SECTION 3: <HAZARD IDENTIFICATION and EMERGENCY OVERVIEW> HMIS Ratings: Protection F,n gastric disturbances; inhalation may cause respiratory irritation. Possible Exposures: Eyes, Skin, Breathing dust, Accidental swallowing Possible Health Effects: Eye Contact: Irritating to eyes Skin Contact: Irritating to skin Breathing Dust: NE. Take precautions. Swallowing: NE. Take precautions. Sensitization: NK Target organs: NK Cancer Information: Product and components not known to us to be Carcinogens NTP : NK Group IARC : NK Group OSHA : NR See above Medical conditions worsened by exposure: Persons with breathing and lung problems can be affected by any type of dusty material. Persons with asthma, allergies or other breathing-related problems should not handle, nor be exposed to dusty products or dusty conditions, as a precautionary measure. Unusual Hazards: Avoid dusting. Ground containers when dispensing product. Dust can form explosive mixtures with air. Precautions: Wear protective equipment and follow hygienic recommendations indicated in Section 8 of this MSDS. ________________________________________________________________________ SECTION 4: <FIRST AID INSTRUCTIONS> Eye contact: Immediately rinse with plenty of clean flowing water for at least 20 minutes, holding eyelids open to rinse completely. Call a doctor and get medical help quickly, as a precaution. Health 1 Flammability 0 Reactivity 0
Emergency Overview: Irritating to eyes and skin. Ingestion may result in
Skin contact: Remove affected clothing, wash affected area with plenty of soap & water. Rinse with plenty of water. Wash work clothes before wearing again. If any redness, swelling, itching or pain of skin starts, see doctor as a precaution. Breathing product dust: Move person to fresh air. If person has difficulty breathing, give oxygen. If not breathing, give artificial respiration. Get emergency medical help immediately. Call 911. Swallowing: Do not induce vomiting. doctor and get emergency medical help quickly. Flush mouth with water. Call a
________________________________________________________________________________ ___ SECTION 5: <FIRE FIGHTING INSTRUCTIONS> Flash point : NA Types of extinguishers : Water Spray, dry chemical, CO2, foam Fire-fighting directions: Wear self-contained breathing apparatus to protect against possibly toxic fumes. Wear full fire-protective clothing
________________________________________________________________________________ ___ SECTION 6: <ACCIDENTAL SPILL or RELEASE INSTRUCTIONS> Wear a NIOSH approved dust respirator, along with all protective clothing and equipment as described in Section 8 of this MSDS. Read & follow Section 8. Contain and clean up spill immediately. Try to salvage as much clean material as possible. Sweep powders carefully, using an absorbent (such as sweeping compound) to keep down the dust in the area. Scoop material and absorbent into disposal drum, seal and label. RCRA Status: See Regulatory Information, Section 15. Environmental protection: Prevent material from entering floor drains or sewers. Do not release to sewers, streams, rivers or to any other bodies of water. If
entry has occured or soil/vegetation has been contaminated, advise proper government authorities. Check Section 13, "Disposal Considerations/Environmental Protection Procedures" for more information. ________________________________________________________________________________ ___ SECTION 7: <HANDLING and STORAGE> Protect product from moisture, store in cool, dry place under low relative humidity, away from excessive heat. Store in original or equivalent water-proof containers. Reseal containers tightly after each use. Keep out of direct sunlight. Avoid contact with eyes. Shelf life: Indefinite when stored carefully as instructed above. ________________________________________________________________________________ ___ SECTION 8: <EXPOSURE CONTROLS and PERSONAL PROTECTION> Note: When selecting personal protective equipment and clothing, follow all manufacturers specifications and recommendations that apply to your operation and processing conditions. Take into consideration worker environments and all chemicals and mixtures being handled or processed. Apply OSHA workplace regulations in CFR Title 29 part 1910.1200, and cited and crossreferenced regulations and standards. State and local regulations may also apply. Eye Protection: Wear splash-proof chemical safety goggles. Precaution: Contact lenses should not be worn when working with chemicals. Skin Protection: Wear chemically impervious gloves, selected with your specific processing conditions and chemicals to be handled in mind. Wear coveralls and boots to minimize skin contact. As precautions, wash hands and face with mild soap and water before eating, drinking, smoking or using restroom. After each shift, clean all protective equipment, wash all work clothes and shower well. Lung, Throat and Nasal Protection: Wear NIOSH approved dust respirator for your particular operation and material being handled. Clean respirator with soap and water after each shift.
Other Protection: Eye wash fountains and drench showers should be located within 100 feet or a 10-second walk of the work area per ANSI Z358.1-1990. Ventilation: Local exhaust is recommended. ________________________________________________________________________________ __ SECTION 9: <PHYSICAL and CHEMICAL PROPERTIES> Description : Melting Point : Water Solubility: pH : Bulk density : % Total VOC's : % Non-Volatiles : % Water : Powder, odorless NE Soluble NE NE 0 100 0
________________________________________________________________________________ __ SECTION 10: <STABILITY and REACTIVITY> Stability : Stable Conditions to avoid : NK Incompatible Materials : Oxidizing and reducing agents. Hazardous decomposition products: Burning can produce oxides of carbon, nitrogen, or other toxic or possibly harmful fumes. ________________________________________________________________________________ __ SECTION 11: <TOXICOLOGY INFORMATION> Oral LD50 (Rat): > NE Dermal LD50 (Rat): NE Inhalation LC50 (Rat): NE Eye effects (Rabbit) : Irritating to eyes Skin Effects (Rabbit): NE. Take precautions. Breathing Effects: NE. Take precautions. General Precautions: Practice good industrial hygiene, handle with care, avoid personal contact. Do not get in eyes or on skin, do not breathe product dust, do not swallow. Wash hands with soap and water, and rinse well after handling. Shower after each shift. Wash all work clothes and equipment after each shift.
Mutagenicity: NK Reproductive Effects: NK ________________________________________________________________________________ SECTION 12: <ECOLOGICAL DATA> Mobility: Soluble in water. Pesistence and degradability: This product is not readily biodegrageable. Other adverse effects: WGK(Germany) Water pollution class: 2-hazardous to water (self assessment). ________________________________________________________________________________ SECTION 13: <DISPOSAL CONSIDERATIONS AND ENVIRONMENTAL PROTECTION PROCEDURES> Disposal Methods: It is recommended that you select an alternative below according to the following order of preference, depending on environmental impact: 1) Recycle or rework material if at all possible 2) Incinerate material at an approved facility 3) Treat at an acceptable waste treatment facility, or municipal waste treatment plant after proper testing & approval of waste samples. If disposed of in original unused form, material should be treated and disposed of at an approved site or facility, in compliance with applicable federal, state & local environmental regulations. Contact proper government agencies for additional directions. All waste material & waste water should be disposed of correctly, under all federal, state, city and county laws. RCRA Status: See Section 15, Regulatory Information Do not release any chemicals, dyes or other color solutions into any sewer, or any river, stream, lake pond nor onto any other types of watercourses, waterways, or systems without proper government permission at all levels. Container reuse: An "empty" container can contains product residue and should not be reused. If not professionally cleaned and reconditioned, crushing or
other means is recommended to prevent unauthorized reuse. ________________________________________________________________________________ SECTION 14: SHIPPING AND TRANSPORT INFORMATION DOT Status (Highway and rail): NR IATA Status (Air): NR ________________________________________________________________________________ SECTION 15: REGULATORY INFORMATION AICS (Australia): Listed Cal Prop. 65: To the best of present knowledge, based on information available on date of this entry, we are not aware of substances present in this product listed by California as causing cancer or reproductive toxicity. CERCLA(40CFR 302.4): NH Clean Air Act: Title III (HAP's): NK Title (V-VOC's): Check Sections 2, 3 and 9 Title VI (ODC's): Not containing nor manufactured with class I or II ODC's. CONEG-Typical Metals present in PPM: These figures are typical results determined by random sample analysis and should not be construed as limits for this material. Cadmium : NE Chromium : NE (Total including Hexavalent Cr=6) Lead : NE Mercury : NE DSL (Canada): Listed ECL (Korea): KE-20730 EINECS (Europe): NC ENCS (Japan): NC FDA Status: NL NEPA (China): NC Other Typical Metals Data in PPM: NK PICCS (Philippines): Listed RCRA: Not hazardous in purchased form. SARA 311/312: Immediate/Acute Health Hazard : Delayed/Chronic Health Hazard : Fire Hazard : Sudden release of pressure hazard: Reactivity Hazard : SARA 313: Chromium Compounds, Threshold: 1% TSCA: Listed
yes no no no no
_______________________________________________________________________________
SECTION 16: <OTHER INFORMATION> Effective date: Enter current component data V-075330-10312001-lkb V-001099-09172002 Acronym List AICS = Australian Inventory of Chemical Substances ANSI = American National Standards Institute CFR = Code of Federal Regulations CERCLA = Comprehensive Environmental Responsibility, Compensation and Liability Act (U.S. EPA) CONEG = Coalition of Northeast Govenors CWA = Clean Water Act (U.S. EPA) DOT = Department of Transportation (U.S.A.) DSL = Domestic Substance List (Canada) ECL = Existing Chemicals List (Korea) EINECS = European Inventory of Existing Chemical Substances (European Union) ELINCS = European Listing of Notified of Chemical Substances (European Union) ENCS = Existing and New Chemical Substances (Japan) EPA = Environmental Protection Agency (U.S.A.) FDA = Food & Drug Administration (U.S.A.) HAP's = Hazardous Air Pollutants (U.S. EPA) IATA = International Air Transport Association NA = Not applicable to this material NC = Not certain, undetermined as of this writing ND = No data is currently available, user may test at own discretion NE = Not established, no testing is planned NEPA = National Environmental Protection Agency (China) NH = Not hazardous under cited regulations NIOSH = National Institute for Occupational Safety and Health NK = Substance not known to be present, effect not known to be caused NL = Not listed or approved under these agencies or regulations NR = Not regulated or reportable under applicable regulations RCRA = Resource Conservation and Recovery Act (U.S. EPA) SARA = Superfund And Reauthorization Act (U.S. EPA) TSCA = Toxic Substance Control Act (U.S. EPA) USDA = United States Department of Agriculture The information and recommendations contained herein are based upon data believed to be correct. However, no guarantee or warranty of any kind expressed or implied, is made with respect to the information contained herein. This Material Safety Data Sheet was prepared to Hazard Communication Standard 29 CFR 1910.1200, and supersedes any previous information. Previously dated sheets are invalid & inapplicable. comply with the OSHA
END OF MSDS

I. PRODUCT IDENTIFICATION TRADE NAME--------- ACID RED 419 CHEMICAL NAME-----CHEMICAL FAMILY---COLOR INDEX #-----C. A. S. #--------LAST REVISION DATE. N/A ACID DYES ACID RED 419 N/A 4/29/2009
II. HAZARDOUS COMPONENTS COMPONENT PERCENT ----- None III. PHYSICAL DATA BOILING POINT--N/A VAPOR PRESSURE--N/A VAPOR DENSITY---N/A VOLATILITY----- N/A FREEZE POINT--- N/A MELTING POINT---N/A IV. FIRE AND EXPLOSION DATA FLASH POINT N/A FILAMMABLE LIMITS. N/A IN CASE OF FIRE-----DRY CHEMICAL, CO2, WATER SPRAY OR REGULAR FOAM. MOVE CONTAINERS FROM FIRE AREA IF YOU CAN DO IT WITHOUT RISK. APPLY COOLING WATER TO SIDES OF CONTAINERS THAT ARE EXPOSED TO FLAMES UNTIL WELL AFTER FIRE IS OUT. SOLUB. IN WATER--SOLUBLE IN WATER ODOR--- NONE APPEARANCE--DARK POWDER SPECIFIC GRAV-- N/A EVAP. RATE--- N/A pH OF PRODUCTN/A
VENTILATION----Local Exhaust. OTHER PROTECTION--- DELUGE SAFETY SHOWER AND EYE WASH STATION SHOULD BE LOCATEI NEAR WORK AREA.
S. A. R. A.--- NOT REPORTABLE T.S.C.A---- IN COMPLIANCE 0. S. H. A. HAZARD CLASSIFICATION: ACUTE:NO CHRONIC: NO FLAMMABLE: NO REACTIVE: NO OXIDIZER: NO HEALTH H.M.I.S. CLASSIFICATION: N.F.P.A CODES: 1 1 FLAMMABILITY 1 1 REACTIVITY 1 1 PERSONAL PROT. F N
XIII. STATES RIGHT TO KNOW LAWS HAZARDOUS MATERIALS ** NONE*** INGREDIENTS STATE INFORMATION * * N O N E * * ***NON-HAZARDOUS MATERIALS * STATE INFORMATION:::: INGREDIENTS :::PROPRIETARY ACID DYES ::: MA. N.J, PA, CA GLAUBERS SALT 7767-86-68 MA, N.J, PA, CA XIV. OTHER INFORMATION
ALL INFORMATION AND DATA APPEARING ON THIS M. S. D. S. ARE BELIEVED TO BE RELIABLE & ACCURATE. HOWEVER, IT IS THE USER'S RESPONSIBILITY TO DETERMINE THE SAFETY, TOXICITY, AND SUITABILITY FOR HIS OWN USE OF THE PRODUCT DESCRIBED. SINCE THE ACTUAL USE BY OTHERS IS BEYOND OUR CONTROL, NO GUARANTEE, EXPRESSED OR IMPLIED, IS MADE BY KEYCOLOUR INC..USER ASSUMES ALL RISK AND RESPONSIBILITY.

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************* MATERIAL SAFETY DATA SHEET *************

PAGE- 2 (CONTINUED NEXT PAGE)

SKIN-------IMPERVIOUS GLOVES AND APPROPRIATE EQUIPMENT TO PREVENT PROBABILITY OF PERSONAL CONTACT.

EYES----SIDE-SHIELD SAFETY GLASSES.

PAGE- 3 (CONTINUED NEXT PAGE)

DOT IDENTIFICATION # .. COMMODITY CLASS---- INK MATERIAL

XII. REGULATORY INFORMATION

MATERIAL SAFETY DATA SHEET (END) **************************

MATERIAL SAFETY DATA SHEET

EMERGENCY PHONE NUMBER:

MATERIAL SAFETY DATA SHEET KEYCOLOUR INC.

EMERGENCY PHONE NUMBER:

SECTION 1: PRODUCT IDENTIFICATION

SECTION 2: HAZARD IDENTIFICATION AND EMERGENCY OVERVIEW

SAFETY DATA SHEET (continued)

SECTION 3: OSHA HAZARDOUS INGREDIENTS

SECTION 4: FIRST AID INSTRUCTIONS

SAFETY DATA SHEET (continued)

SECTION 5: FIRE FIGHTING INSTRUCTIONS

SECTION 6: ACCIDENTAL SPILL OR RELEASE INSTRUCTIONS

SAFETY DATA SHEET (continued)

SECTION 7: HANDLING AND STORAGE

SECTION 8: EXPOSURE CONTROLS AND PERSONAL PROTECTION

SAFETY DATA SHEET (continued)

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

All Data shown above are typical values, not specifications.

SECTION 10: STABILITY AND REACTIVITY

SECTION 11: TOXICOLOGICAL INFORMATION

Other Tox Data

SAFETY DATA SHEET (continued)

SECTION 12: ECOLOGICAL DATA

*** No Data ***

SECTION 13: DISPOSAL AND ENVIRONMENTAL CONSIDERATION

SECTION 14: SHIPPING AND TRANSPORTATION INFORMATION

SECTION 15: REGULATORY INFORMATION

SAFETY DATA SHEET (continued)

SECTION 16: OTHER INFORMATION

MATERIAL SAFETY DATA SHEET

EMERGENCY PHONE NUMBER:

STATE RIGHT TO KNOW INFORMATION INGREDIENT ACID BLUE 40

CAS NUMBER 6424-85-7

EMERGENCY PHONE NUMBER:

INGREDIENT XANTHENE DYE

CAS NUMBER 3520-42-1

MATERIAL SAFETY DATA SHEET

EMERGENCY PHONE NUMBER:

For 24 hours emergency Chemtrec :: 800-424-9300

************* MATERIAL SAFETY DATA SHEET *************

PAGE- 2 (CONTINUED NEXT PAGE)

SKIN-------IMPERVIOUS GLOVES AND APPROPRIATE EQUIPMENT TO PREVENT PROBABILITY OF PERSONAL CONTACT.

EYES----SIDE-SHIELD SAFETY GLASSES.

PAGE- 3 (CONTINUED NEXT PAGE)

DOT IDENTIFICATION # .. COMMODITY CLASS---- INK MATERIAL

XII. REGULATORY INFORMATION

No labelling is required in accordance with the EEC directives. T.S.C.A---- IN COMPLIANCE

MATERIAL SAFETY DATA SHEET (END) **************************

CHEMTREC (24HOUR) 800-424-9300

EMERGENCY PHONE NUMBER:

SECTION 1: PRODUCT IDENTIFICATION

SECTION 2: OSHA HAZARDOUS INGREDIENTS

Component Acid Blue 113

CAS Number 3351-05-1

OSHA - PEL 15 mg/m3 TWA Total dust 5 mg/m3 Respirable

* MATERIAL SAFETY DATA SHEET *

* No Data *

* MATERIAL SAFETY DATA SHEET *

* No Data *

* MATERIAL SAFETY DATA SHEET *