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according to Regulation (EC) No. 1907/2006 Version 5.0 Revision Date 19.09.2012 Print Date 14.01.2014 GENERIC EU MSDS - NO COUNTRY SPECIFIC DATA - NO OEL DATA

1. 1.1

IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING Product identifiers Product name Product Number Brand CAS-No. : : : :

Malachite Green Carbinol hydrochloride
213020 Aldrich 123333-61-9


Relevant identified uses of the substance or mixture and uses advised against Identified uses : Laboratory chemicals, Manufacture of substances


Details of the supplier of the safety data sheet Company : Sigma-Aldrich Pte Ltd 1 Science Park Road #02-14 The Capricorn Singapore Science Park Road II SINGAPORE 117528 SINGAPORE +65 6779 1200 +65 6779 1822

Telephone Fax 1.4

: :

Emergency telephone number Emergency Phone # : 1-800-262-8200

2. 2.1

HAZARDS IDENTIFICATION Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008 [EU-GHS/CLP] Acute toxicity, Oral (Category 3) Serious eye damage (Category 1) Reproductive toxicity (Category 2) Acute aquatic toxicity (Category 1) Chronic aquatic toxicity (Category 1) Classification according to EU Directives 67/548/EEC or 1999/45/EC Toxic if swallowed. Risk of serious damage to eyes. Possible risk of harm to the unborn child. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.


Label elements Labelling according Regulation (EC) No 1272/2008 [CLP] Pictogram Signal word Hazard statement(s) H301 H318 H361 H410 Precautionary statement(s) P273 Danger Toxic if swallowed. Causes serious eye damage. Suspected of damaging fertility or the unborn child. Very toxic to aquatic life with long lasting effects. Avoid release to the environment.
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Aldrich - 213020

Refer to special instructions/ Safety data sheets. gloves and eye/face protection.3 3.93 g/mol Concentration - Toxic if swallowed. 4. If swallowed. Very toxic to aquatic organisms. This material and its container must be disposed of as hazardous waste. Hazard symbol(s) R-phrase(s) R25 R41 R63 R50/53 S-phrase(s) S26 S36/37/39 S46 S60 S61 2. Remove contact lenses. may cause long-term adverse effects in the aquatic environment. If inhaled If breathed in. Risk of serious damage to eyes. Possible risk of harm to the unborn child. none According to European Directive 67/548/EEC as amended. In case of skin contact Wash off with soap and plenty of water.1 Other hazards . seek medical advice immediately and show this container or label.213020 Page 2 of 7 . In case of contact with eyes. Dispose of contents/ container to an approved waste disposal plant. In case of eye contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.none COMPOSITION/INFORMATION ON INGREDIENTS Substances Synonyms : Malachite Green Basic Green 4 C23H26N2O · HCl 382.1 FIRST AID MEASURES Description of first aid measures General advice Consult a physician. If not breathing. 123333-61-9 4. Show this safety data sheet to the doctor in attendance. rinse immediately with plenty of water and seek medical advice. Avoid release to the environment.P280 P301 + P310 P305 + P351 + P338 P501 Supplemental Hazard Statements Wear protective gloves/ eye protection/ face protection. Take victim immediately to hospital. Aldrich . Wear suitable protective clothing. move person into fresh air. give artificial respiration. Rinse mouth with water. IF IN EYES: Rinse cautiously with water for several minutes. If swallowed Never give anything by mouth to an unconscious person. Consult a physician. IF SWALLOWED: Immediately call a POISON CENTER or doctor/ physician. if present and easy to do. 3. Consult a physician. Continue rinsing. Consult a physician. Formula Molecular Weight Component : : Malachite Green hydrochloride CAS-No.

including any incompatibilities Store in cool place.4. Conditions for safe storage. mist or gas.3 5. Discharge into the environment must be avoided. and toxicological properties have not been thoroughly investigated. Specific end uses no data available EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Components with workplace control parameters 6.2 5.2 7. HANDLING AND STORAGE Precautions for safe handling Avoid contact with skin and eyes.2 Most important symptoms and effects. Reference to other sections For disposal see section 13.Normal measures for preventive fire protection.3 6.213020 Page 3 of 7 . Avoid dust formation. Sweep up and shovel. dry chemical or carbon dioxide.4 Special hazards arising from the substance or mixture Carbon oxides. Hydrogen chloride gas Advice for firefighters Wear self contained breathing apparatus for fire fighting if necessary. Indication of any immediate medical attention and special treatment needed no data available FIREFIGHTING MEASURES Extinguishing media Suitable extinguishing media Use water spray.2 6. Provide appropriate exhaust ventilation at places where dust is formed. Keep in suitable. Methods and materials for containment and cleaning up Pick up and arrange disposal without creating dust. physical. Personal protective equipment Eye/face protection Face shield and safety glasses Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Further information no data available ACCIDENTAL RELEASE MEASURES Personal precautions. Evacuate personnel to safe areas. alcohol-resistant foam. Avoid breathing dust. Wash hands before breaks and immediately after handling the product. eyes and clothing. Do not let product enter drains.1 7. 6. protective equipment and emergency procedures Wear respiratory protection. the chemical. both acute and delayed To the best of our knowledge. Aldrich . Keep container tightly closed in a dry and well-ventilated place.1 5.3 5. closed containers for disposal. 5.3 8.2 Exposure controls Appropriate engineering controls Avoid contact with skin.4 7. 7.1 6. Ensure adequate ventilation. Environmental precautions Prevent further leakage or spillage if safe to do so. Avoid formation of dust and aerosols. nitrogen oxides (NOx).1 8. Avoid breathing vapors. 4. 8.

Respiratory protection Where risk assessment shows air-purifying respirators are appropriate use a full-face particle respirator type N100 (US) or type P3 (EN 143) respirator cartridges as a backup to engineering controls. Wash and dry hands. 9. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it.213020 . gas) no data available k) l) n) o) p) q) r) s) t) 9. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).Skin protection Handle with gloves. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. If the respirator is the sole means of protection. Body Protection Complete suit protecting against chemicals. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. use a full-face supplied air respirator.2 no data available no data available no data available no data available no data available no data available no data available no data available no data available no data available m) Relative density Other safety information no data available Page 4 of 7 Aldrich . 9. Gloves must be inspected prior to use.1 PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties a) b) c) d) e) f) g) h) i) j) Appearance Odour Odour Threshold pH Melting point/freezing point Initial boiling point and boiling range Flash point Evaporation rate Upper/lower flammability or explosive limits Vapour pressure Vapour density Water solubility Partition coefficient: noctanol/water Autoignition temperature Decomposition temperature Viscosity Explosive properties Oxidizing properties Form: solid no data available no data available no data available no data available no data available no data available no data available no data available Flammability (solid.

11. and toxicological properties have not been thoroughly investigated.no data available TOXICOLOGICAL INFORMATION Information on toxicological effects Acute toxicity no data available Skin corrosion/irritation no data available Serious eye damage/eye irritation no data available Respiratory or skin sensitization no data available Germ cell mutagenicity no data available Carcinogenicity IARC: No component of this product present at levels greater than or equal to 0. the chemical. May cause respiratory tract irritation.1 10. Additional Information RTECS: Not available Aldrich . physical.4 10.10.6 STABILITY AND REACTIVITY Reactivity no data available Chemical stability no data available Possibility of hazardous reactions no data available Conditions to avoid no data available Incompatible materials Strong oxidizing agents Hazardous decomposition products Other decomposition products . Toxic if swallowed.repeated exposure no data available Aspiration hazard no data available Potential health effects Inhalation Ingestion Skin Eyes May be harmful if inhaled.213020 Page 5 of 7 . May cause skin irritation.5 10. Signs and Symptoms of Exposure To the best of our knowledge. Causes eye burns.single exposure no data available Specific target organ toxicity .1 Reproductive toxicity Suspected human reproductive toxicant Specific target organ toxicity .3 10. possible or confirmed human carcinogen by IARC. 10.1% is identified as probable.2 10. May be harmful if absorbed through skin. 11.

1 14. ORGANIC.6 15.2 Safety.1 IMDG: III IMDG Marine pollutant: yes IATA: 6.S. Aldrich . License granted to make unlimited paper copies for internal use only. n. IMDG: 6.3 14.2 TRANSPORT INFORMATION UN number ADR/RID: 2811 IMDG: 2811 IATA: 2811 UN proper shipping name ADR/RID: TOXIC SOLID. (Malachite Green hydrochloride) Transport hazard class(es) ADR/RID: 6.5 12. LLC. 16. N.1 IATA: III IATA: no 14. Contaminated packaging Dispose of as unused product.s.1 14.213020 Page 6 of 7 . 1907/2006.5 14.12. Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. Contact a licensed professional waste disposal service to dispose of this material. health and environmental regulations/legislation specific for the substance or mixture no data available Chemical Safety Assessment no data available OTHER INFORMATION Further information Copyright 2012 Sigma-Aldrich Co. (Malachite Green hydrochloride) IMDG: TOXIC SOLID. (Malachite Green hydrochloride) IATA: Toxic solid. DISPOSAL CONSIDERATIONS Waste treatment methods Product Offer surplus and non-recyclable solutions to a licensed disposal company. 13.1 12. 12.1 Packaging group ADR/RID: III Environmental hazards ADR/RID: yes Special precautions for user no data available REGULATORY INFORMATION This safety datasheet complies with the requirements of Regulation (EC) No. 15.1 15.6 ECOLOGICAL INFORMATION Toxicity no data available Persistence and degradability no data available Bioaccumulative potential no data available Mobility in soil no data available Results of PBT and vPvB assessment no data available Other adverse effects Very toxic to aquatic life with long lasting effects.S. 14. N. ORGANIC.4 14. organic.o.2 12.O.3 12.4 12.O. 13.

com and/or the reverse side of invoice or packing slip for additional terms and conditions of sale. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. Aldrich . It does not represent any guarantee of the properties of the product. See www. Sigma-Aldrich Corporation and its Affiliates shall not be held liable for any damage resulting from handling or from contact with the above product.sigmaaldrich.213020 Page 7 of 7 .The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide.