Dynamic, Absolute and Kinematic Viscosity

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Dynamic, Absolute and Kinematic Viscosity

An introduction to dynamic, absolute and kinematic viscosity and how to convert between CentiStokes (cSt), CentiPoises (cP), Saybolt Universal Seconds (SSU), degree Engler and more
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The viscosity of a fluid is an important property in the analysis of liquid behavior and fluid motion near solid boundaries. The viscosity is the fluid resistance to shear or flow and is a measure of the adhesive/cohesive or frictional fluid property. The resistance is caused by intermolecular friction exerted when layers of fluids attempt to slide by one another. Viscosity is a measure of a fluid's resistance to flow The knowledge of viscosity is needed for proper design of required temperatures for storage, pumping or injection of fluids. Molasses is highly viscous Water is medium viscous Gases have a low viscosity There are two related measures of fluid viscosity - known as dynamic (or absolute) and kinematic viscosity.

Dynamic (absolute) Viscosity

Absolute viscosity or the coefficient of absolute viscosity is a measure of the internal resistance. Dynamic (absolute) viscosity is the tangential force per unit area required to move one horizontal plane with respect to the other at unit velocity when maintained a unit distance apart by the fluid. The shearing stress between the layers of non turbulent fluid moving in straight parallel lines can be defined for a Newtonian fluid as:

The dynamic or absolute viscosity can be expressed like = dc/dy where (1)

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= shearing stress = dynamic viscosity Equation (1) is known as the Newtons Law of Friction. In the SI system the dynamic viscosity units are N s/m2, Pa.s or kg/m.s where 1 Pa.s = 1 N s/m2 = 1 kg/m.s The dynamic viscosity is also often expressed in the metric CGS (centimeter-gram-second) system as g/cm.s, dyne.s/cm2 or poise (p) where 1 poise = 1 dyne s/cm2 = 1 g/cm.s = 1/10 Pa.s = 1/10 N.s/m2 For practical use the Poise is to large and it's usual divided by 100 into the smaller unit called the centiPoise (cP) where 1 p = 100 cP 1 cP = 0.01 poise = 0.01 gram per cm second = 0.001 Pascal second = 1 milliPascal second = 0.001 N.s/m2 Water at 68.4oF (20.2oC) has an absolute viscosity of one - 1 - centiPoise. Absolute Viscosity at Room Temperature (Pa.s) 1.983 x 10-5 1 x 10-3 1 x 10-1 1 x 100 1 x 101 1 x 102 1 x 1040

Liquid Air Water Olive Oil Glycerol Liquid Honey Golden Syrup Glass

Absolute or Dynamic Viscosity of some common Liquids

Kinematic Viscosity
is the ratio of absolute or dynamic viscosity to density - a quantity in which no force is involved. Kinematic viscosity can be obtained by dividing the absolute viscosity of a fluid with it's mass density =/ where = kinematic viscosity = absolute or dynamic viscosity = density In the SI-system the theoretical unit is m2/s or commonly used Stoke (St) where 1 St (Stokes) = 10-4 m2/s = 1 cm2/s Since the Stoke is an unpractical large unit, it is usual divided by 100 to give the unit called Centistokes (cSt) where 1 St = 100 cSt 1 cSt (centiStokes) = 10-6 m2/s = 1 mm2/s Since the specific gravity of water at 68.4oF (20.2oC) is almost one, the kinematic viscosity of water at 68.4oF is for all practical purposes 1.0 mm2/s (cSt). The kinematic viscosity of water at 68F (20C) is 1.0038 mm2/s (cSt). Kinematic Viscosities of Some common Liquids and Fluids (2)

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Conversion from absolute to kinematic viscosity can also be expressed as: = 6.7197 10-4 / where = kinematic viscosity (ft2/s) = absolute or dynamic viscosity (cP) = specific weight (lb/ft3) (2a)

Viscosity and Reference Temperatures

The viscosity of a fluid is highly temperature dependent and for either dynamic or kinematic viscosity to be meaningful, the reference temperature must be quoted. In ISO 8217 the reference temperature for a residual fluid is 100oC. For a distillate fluid the reference temperature is 40oC. For a liquid - the kinematic viscosity will decrease with higher temperature For a gas - the kinematic viscosity will increase with higher temperature

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Other Commonly used Viscosity Units

Saybolt Universal Seconds (or SUS, SSU) Saybolt Universal Seconds (or SUS) is used to measure viscosity. The efflux time is Saybolt Universal Seconds (SUS) required for 60 milliliters of a petroleum product to flow through the calibrated orifice of a Saybolt Universal viscometer, under carefully controlled temperature and as prescribed by test method ASTM D 88. This method has largely been replaced by the kinematic viscosity method. Saybolt Universal Seconds is also called the SSU number (Seconds Saybolt Universal) or SSF number (Saybolt Seconds Furol). Kinematic viscosity versus dynamic or absolute viscosity can be expressed as SSU = B / SG = B centiStokes where SSU = kinematic vicosity (SSU) B = 4.632 for temperature 100 oF (37.8 oC) B = 4.664 for temperature 210oF (98.9 oC) = dynamic or absolute viscosity (cP) SG = Specific Gravity centiStokes = kinematic viscosity (centiStokes) SSU at other temperatures Degree Engler Degree Engler is used in Great Britain as a scale to measure kinematic viscosity. Unlike the Saybolt and Redwood scales, the Engler scale is based on comparing a flow of the substance being tested to the flow of another substance - water. Viscosity in Engler degrees is the ratio of the time of a flow of 200 cubic centimetres of the fluid whose viscosity is being measured - to the time of flow of 200 cubic centimeters of water at the same temperature (usually 20oC but sometimes 50oC or 100oC) in a standardized Engler viscosity meter. (3)

Newtonian Fluids
Fluids for which the shearing stress is linearly related to the rate of shearing strain are designated as Newtonian Fluids.

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Newtonian materials are referred to as true liquids since their viscosity or consistency is not affected by shear such as agitation or pumping at a constant temperature. Fortunately most common fluids, both liquids and gases, are Newtonian. Water and oils are examples of Newtonian liquids.

Shear-thinning or Pseudoplastic Liquids

Shear-thinning or pseudoplastic liquids are those whose viscosity decreases with increasing shear rate. Their structure is time-independent.

Thixotropic Fluids
Thixotropic liquids have a time-dependent structure. The viscosity of a thixotropic liquid decreases with increasing time, at a constant shear rate. Ketchup and mayonnaise are examples of thixotropic materials. They appear thick or viscous but are possible to pump quite easily.

Dilatant Fluids
Shear Thickening Fluids or Dilatant Fluids increase their viscosity with agitation. Some of these liquids can become almost solid within a pump or pipe line. With agitation, cream becomes butter and Candy compounds, clay slurries and similar heavily filled liquids do the same thing.

Bingham Plastic Fluids

Bingham Plastic Fluids have a yield value which must be exceeded before it will start to flow like a fluid. From that point the viscosity will decrease with increase of agitation. Toothpaste, mayonnaise and tomato catsup are examples of such products.

Example - Converting between Kinematic and Absolute Viscosity for Air

Kinematic viscosity of air at 1 bar (105 Pa, N/m2) and 40oC is 16.97 cSt (16.97 10-6 m2/s). The density of air estimated with the Ideal Gas Law =p/RT where = density (kg/m3) p = absolute pressure (Pa, N/m2) R = individual gas constant (J/kg.K) T = absolute temperature (K) = (105 N/m2) / ((287 J/kg/K) ((273 oC) + (33 oC))) = 1.113 (kg/m3) Absolute viscosity can be expressed as = (1.113 kg/m3) (16.97 10-6 m2/s) = 1.88 10-5 (kg/m s, N.s/m2, P)

Viscosity of some Common Liquids

centiStokes (cSt) 1 4.3 15.7 20.6 43.2 Saybolt Second Universal (SSU, SUS) 31 40 80 100 200 Typical liquid Water (20oC) Milk SAE 20 Crankcase Oil SAE 75 Gear Oil No. 4 fuel oil Cream Vegetable oil

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centiStokes (cSt) 110

Saybolt Second Universal (SSU, SUS) 500

Typical liquid SAE 30 Crankcase Oil SAE 85 Gear Oil Tomato Juice SAE 50 Crankcase Oil SAE 90 Gear Oil SAE 140 Gear Oil Glycerine (20oC) SAE 250 Gear Oil Honey Mayonnaise Sour cream

220 440 1100 2200 6250 19,000

1000 2000 5000 10,000 28,000 86,000

Kinematic viscosity can be converted from SSU to Centistokes like Centistokes = 0.226 SSU - 195 / SSU where SSU < 100 Centistokes = 0.220 SSU - 135 / SSU where SSU > 100

Viscosity and Temperature

Kinematic viscosity of liquids like water, mercury, oils SAE 10 and oil no. 3 - and gases like air, hydrogen and helium are indicated below. Note that for liquids viscosity decreases with temperature for gases viscosity increases with temperature

Viscosity Measurements

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Three types of devices are used in viscosity measurements capillary tube viscometer Saybolt viscometer rotatiting viscometer
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