IITJEEMains2014 CodeE Solution

IITJEE MAIN | PHYSICS, CHEMISTRY AND MATHEMATICS
Paper 2014

www.topperlearning.com 1
IITJEE (MAIN) 2014
(Physics, Chemistry and Mathematics)
Code - E
SOLUTIONS

PARTA : PHYSICS

1. Correct option (1)
The current voltage relation is I = (e
1000V/T
1) m A (1)

1000 V/ T
1000 V/ T
When I 5mA
5 mA = (e 1)
e 6mA
=
=

Differentiating equation (1), we get
1000 V/ T
1000 V/ T
1000
dI = (e ) dV
T
On substituting the values, e 6 mA ,T= 300K , dV= 0.01
1000
= (6 mA) (0.01)
300
=0.2 mA
=

Therefore the error in the value of current is m A = 0.2 mA.


H is the height of the tower.

Paper 2014

1
2 2
2
u
Time taken by the particle to reach highest point of its path is t
g
We know that v u 2gh
So speed on reaching ground ,v = u 2gh
Now v = u + at ( for particle thrown upwards)
v = -u + gt (For spee
=
= +
+
2
2
d of particle reaching to ground)
u 2gh -u + gt
On solving, we get
u u 2gH
t =
g
+ =
+ +

2
1
2
2
Given that time taken by particle to hit ground is n times that
taken by it to reach the highest point of its path.
u u 2gH
t = = n t
g
u u 2gH u
= n
g g
On solving the equation, we get
2gH = n(n-2)u
+ +
+ +

3. Correct Option (2)

Paper 2014

2
2
Acceleration a = R
Now, For the block of mass m, mg -T = ma ---------- equation(1)
Tension T perpendicular distance R I
i e T R mR ......(2)
a
T R mR ma R
R
or T = m a ......(3)
Substituting equation
o
= o
= o
= =
(3) in equation (1), we get
mg -T = ma
mg -ma = ma
mg = 2 ma
g
a=
2


3
2 2
2
x
Given y =
6
dy x x
On differentiating 3 =
dx 6 2
dy x

dx 2
Let be the angle at which block start slipping.
Under the condition of limiting equilibrium, we have
tan
=
=
u
= u

Paper 2014

2
3
where is the coefficient of friction = 0.5
From the figure, we get that
dy
tan =
dx
Substituting in tan
dy
0.5
dx
x
0.5 =
2
x = 1
x 1
Now, putting value of x in y = , y
6 6
The maximum horizontal dis
u
= u
=
=
tance from origin where the block can be placed
without slipping is x=1
Hence, vertical height
1
y =
6

2
L
2
0
L L
2
0 0
2
Let the rubber band be stretched by a distance 'x'.
The magnitude of restoring force is F =ax bx
The work done in stretching the rubber-band
dW = F.dx
W (ax bx ) dx
ax dx + bx dx
L
a
+
= +
=
=
} }
}
} }
3
2 3
L
+ b
2 3
aL bL
The work done in stretching the rubber-band by L is +
2 3

Paper 2014


Conical pendulum is rotating with an angular velocity with the vertical axis.
Torque changes angular momentum
radial
Angular momentum of the pendulum about the suspension point 'O' is
L = m(r v)
r can be resolved into two components, radial components and axial components.
Due to r , L will be axial and due
axial
to r , L will be radially outwards.

Here the angular momentum is not conserved.
So magnitude of net angular momentum will be constant |L| = |m(r v)| but its direction
changes as shown in the figure.

Let the four particles of mass M be placed at the four corners of a square as they are
equidistant from each other as shown in the figure.
The x be the distance between the masses and using Pythagoras theorem we can find x as

2 2 2
x R R
x 2 R
= +
=

Under the action of mutual gravitational attraction, they move along the circle of radius R.
The necessary centripetal force of attraction is provided by gravitational force.
Let us consider a single particle acted upon by three other adjacent particles.

Paper 2014

The two forces acting on that will be the sum of resultant of the force due to adjacent two
masses and that of the third one diagonally opposite to it.

( )
( )
( )
= +
+ +
=
=
+ =
2
diagonally opposite mass
2 2
2
2
2 2
2 2
2
diagonally opposite mass 2
2 2 2
2 2
Mv
F' F
R
F' = F F 2FFcos90
F' = 2 F
GM
= 2
x
GM GM
F' = 2 2
2R
2R
GM
F
2R
GM GM Mv
2
2R R
2R

2 2
2
GM 1 1 Mv
R 4 R
2
On solving for v, we get
GM 2 4
v=
R
4 2
1 GM
= (1+2 2 )
2 R
(
+ =
(

| |
+
|
|
\ .

As length is kept constant, we have
11
L
Strain = Q
L
Strain = Q
Coefficient of thermal expansion
and Q Temperature change
Thermal stress generated = strain
Pressure =stress = strain
= 2 x 10 Q

A
= o A
o A
o =
A =

o A
11 -5
8
8
= 2 x 10 1.1 x 10 100
= 2.2 10 Pa
Pressure to be applied = 2.2 10 Pa

Paper 2014


On equating the pressure at A from both L.HS and R.H.S, we get

1 1 2 2 3 2 4 1
1 1 4 1 2 2 3 2
1
1
2
3
3
4
1 1 2 2
h d g h d g h d g h d g
h d g h d g h d g h d g ......(1)
h R Rcos(90 )
h (R R sin )
h R sin
h Rsin(90 )
h =Rcos
h =R-R cos
Substituting in (1), we get
(R R sin )d g (R-R cos )d g R sin d g Rcos d
= + +
= +
= o
= o
= o
= o
o
o
o o = o + o
1 2
1
2
g
(R cos R sin )d g (Rcos R sin )d g
d cos sin 1 tan
=
d cos sin 1 tan
o o = o+ o
o+ o + o
=
o o o

10. Correct option- No option matches the correct answer

When the bubble detaches, force of surface tension will act on complete circumference and
the resultant will be in the downward direction.
The Bubble will detach if

Paper 2014

Buoyant force Surface Tension Force
3
w
Buoyant force = density (cross sectional area) g
4
Buoyant force R g
3
r
From figure, sin =
R
Surface Tension Force = T dlsin
r
= T 2 r
R
On equating both f

= t
u
u
t
}
3
w
4
2 w
2 w
2 w
orces, we get
4 r
R g T 2 r
3 R
2R g
r
3T
2 g
r R
3T
2 g
The value of r just before bubbles detach is R .
3T

t = t


2
c B S
C B S
C B S
1 2
Given
A A A 4 cm
L 46 cm L 13 cm L 12 cm
K 0.92 K 0.26 K 0.12 (in CGS units)
KA(T T )
Q
l
= = =
= = =
= = =
=

Paper 2014

c B S
C C 1 2 S S 1 2 B B 1 2
C B S
c
Now,
Q Q Q
K A (T T ) K A (T T ) K A (T T )
=
L L L
0.92 4(100 T) 0.26 4(T 0) 0.12 4(T 0)
=
46 13 12
200 - 2T = 2T +T
T = 40 C
Hence, rate of heat flow through copper rod is
0.92 4(100 40)
Q 4
46
= +

+

+

= = .8 cal/s

( )
( )
Change in internal energy is given as,
f
U = nR T
2
For diatomic gas molecule, f = 5
For cyclic process U = 0
Process CA:
5
U = 1 R 400 600 U =-500 R
2
Process AB:
5
U = 1 R 800 400 U =+1000 R
2
Process BC:
A A
A
A A
A A
A ( )
5
U = 1 R 600 800 U =-500 R
2
A


Paper 2014

( )
( )
( )
1 1 2 2
1 atm
2 atm
2
Let length of the air colunm above mercury in the tube be x.
For the air colunm trapped in tube,
P V P V ......(1)
P P gh g 76
P P g 54 x
= g 76 g 54 x
P = g 22 x
=
= = =
=

+

1
2
V Area of cross section length of air colunm
V A 8
V A x
=
=
=

( )( ) ( )( )
( )
2
2
2
Now substituting all these values in eq(1), we get
76 g 8A g 22 x xA
608 gA 22 gAx x gA (Divide by gA)
x 22x 608 0
x 22x 38 16 0
Solving this, we get
x =16 cm
= +
= +
+ =
+ =

( )
( )
x Acos t The particle starts from rest
Displacement in time t is = A - x =A -Acos t
For t = :
a =A -Acos
a = A 1-cos ......(1)
= e
e
t
et
et

( )
( )
For t = 2 + :
2a+a =A -Acos2
3a = A 1-cos2 ......(2)
t t t
et
et

( )
2 2
Now, by taking ratio of eq(1) and (2), we get
1-cos 1
1-cos2 3
1-cos 1-cos 1
2sin 3 2 1-cos
et
=
et
et et
= =
et et

Paper 2014

( )
( )( )
( )
2
Let cos x
1-x 1-x 1
2 1-x 1 x 3 2 1-x
1 1
2 1+x 3
2 2x 3
1
x cos
2
et =
= =
+
=
+ =
= = et

2
3 T 3
T 6
Hence, time period of the motion is 6 .
t t t | |
et = t =
|
\ .
= t
t

From (1);
1
a = A 1- A=2a
2
Hence, amplitude of the motion is 2a.
| |

|
\ .

15. Correct option: (3)
( )
( )
( )
( )
2n 1 v
f
4L
L 85 cm =0.85 m
For frequencies below 1250 Hz
2n 1 v
f 1250 Hz
4L
2n 1 340
1250 Hz
4 0.85
2n 1 12.5 Hz
n 6.75
n 6
Number of possible natural oscillations having frequency below 1250 Hz is 6.
=
=
= s
s
s
=

Paper 2014

A
0
2
V 2
2
V 0
2
3
A 0
0
A 0
Potential difference dV = -E.dx
E 30x i
dV = -E.dx
dV 30x dx
x
V V 30
3
V V 80 J
=
=
(
=
(

=
} }


0
0
0
4 12
7 2
E
E
K K
EK
3 10 2.2 8.85 10
6 10 C/m
o
= =
c
o = c
o =
o ~

( ) ( ) ( ) ( )
Power P = VI
Total power:
P = 15 40 5 100 5 80 1 1000
P VI 2500 W
2500
I 11.36 A
220
Hence, minimum capacity of the main fuse should be 12 A.
+ + +
= =
= =

2
ext
0
ext
2
ext
0
Work W
Power
Time t
W F .dx
F BIL
1
P F .dx
t
= =
=
=
=
}
}

Paper 2014


( )( )( )
( )( )( )
2
4 0.2x
0
2
4 0.2x
3
0
2
0.2x
0
2
0.2x
0
0.4
1
P 3 10 e 10 3 dx
t
1
= 3 10 e 10 3 dx
5 10
=1.8 e dx
e
=1.8
0.2
=9 1 e
P 2.97 W

(

(

=
}
}
}

3 1 3 1
The coerctivity of 3 10 Am of a magnet implies that magnetic intensity H = 3 10 Am
is required in opposite direction to demagnetise it.

-1
Number of turns per unit length of the solenoid
100
n = 1000 turns m
0.1 m
=

0
0
3
For solenoid
B
= H
Now, B = nI
H = nI
H 3 10
I = 3 A
n 1000
= =

After changing the switch, the circuit will acts as an L-R discharging circuit.
Applying Kirchhoffs loop equation in the circuit, we get

+ =
=
=
R L
R L
R
L
V V 0
V V
V
1
V

During the propagation of electromagnetic waves in a medium, the energy density of both
the electric as well as magnetic field is the same.

Paper 2014

According to the Lens Makers formula

( )
21
1 2
1 2 1 2
1 2 1 2
1 1 1
n 1
f R R
When crown glass is kept in air, its focal length is f
1 3/2 1 1 3 2 1 1
1
f 1 R R 2 R R
1 1 1 1 1 1 1 1
Let
f 2 R R 2R R R R
| |
=
|
\ .
| | | | | | | |
= =
| | | |
\ . \ .
\ . \ .
| | | |
= = =
|
\ . \
1 1 2 1 2
1 1 2
f 2R ...... (1)
4
When crown glass is kept in liquid with n , we get
3
1 3/2 1 1 9 1 1
1 1
f 4/3 R R 8 R R
1 1 1 1
f 8 R R
|
.
=
=
| | | | | | | |
= =
| | | |
\ . \ .\ . \ .
|
=
\
1
1
8R
f 8R 4f ...... (2)
|
=
|
.
= =

2 1 2 1 2
2 1 2
2
5
When crown glass is kept in liquid with n , we get
3
1 3/2 1 1 9 1 1
1 1
f 5/3 R R 10 R R
1 1 1 1 1
f 10 R R 10R
f 10R 5f .
=
| | | | | | | |
= =
| | | |
\ . \ .\ . \ .
| |
= =
|
\ .
= =
1 2
..... (3)
From (1), (2) and (3), we get
f f , and f becomes negative >

We know that, whether the light will refract out to the second medium or totally internally
reflect back in the first medium depends on the critical angle.
Now, critical angle for water to air medium is given as

c
water
1
sin
n
u =
We know that, for a light of higher wavelength, i.e., lower frequency the refractive index is
less. This will make uc greater for these light rays.
When these light rays travel from water to air, they do not suffer total internal reflection
and refract out in the air medium.

Paper 2014

The initial intensities of the two beams are IA and IB respectively.
The two beams have mutually perpendicular planes of polarization.

When the Polaroid is rotated through 30, the intensities of both the beams become equal.
If u = 30 for beam A, then u = 60 for beam B.

Then from Malus law, we get

2 2
A A A A
2 2
B B B B
3
I' I cos I cos 30 I
4
1
I' I cos I cos 60 I
4
= u = =
= u = =

Since IA = IB, the ratio is

A B
A B
A
B
I' I'
3 1
I I
4 4
I 1 4 1
I 4 3 3
=
=
= =

The radius r of the path taken by an electron of mass m and charge e inside a magnetic
field is

mv mv
r
qB eB
= =

2 2 2 2 2
2 2 2
2
2 2 2
2
m v r e B
r e B
mv
m
1 r e B
mv
2 2m
=
=
=

This energy will be in joules. Hence, energy in eV will be given as

2 2 2
2
2 2
1 r e B 1
mv eV
2 2m e
r eB
eV
2m
=
=

Therefore, we have

( ) ( )
2 2
3 19 4
2
31
30
2
30
10 10 1.6 10 3 10
1
mv
2 2 9.1 10
1 1.44 10
mv 0.79 eV
2 1.82 10

= =

The transition of electron is between 3 2 states

Paper 2014

Thus, we have

2 2
1 1 1 1 5
E 13.6 13.6 13.6 1.89 eV
2 3 4 9 36
| | | |
= = = =
| |
\ . \ .

Thus, the work function of the metal will be
1.89 eV 0.79 eV 1.1 eV |= =

The spectral formula is given as

2
2 2
2
2 2
2
1 1 1
Rz
p n
p 1 and n 2
1 1 1
Rz
1 2
1 3
Rz
4
| |
=
|
\ .
= =
| |
=
|
\ .
=

Now, for Hydrogen 1H
1
, we have

( )
2
1
1 3 3
R 1 R
4 4
= =

For Deuterium 1H
2
, we have

( )
2
2 1
2 1
1 3 3 1
R 1 R
4 4
= = =

=

For Helium 2He
4
, we have

( )
2
3 1
1 3
1 3 3 4
R 2 R 4
4 4
4
= = =

=

For Lithium 3Li
6
, we have

( )
2
4 1
1 4
1 3 3 9
R 3 R 9
4 4
9
= = =

=

Therefore, we have

1 2 3 4
4 9 = = =

A diode is said to be forward biased when the positive side (p) is at a higher potential than
the negative side (n).

Paper 2014


List I List II
(a) Infrared waves (i) To treat muscular strain
(b) Radio waves (ii) For broadcasting
(c) X-rays (iii) To detect fracture of bones
(d) Ultraviolet rays (iv)
Absorbed by the ozone layer of the
atmosphere

30. Correct option (B)
The student measures the value as 3.50 cm. This indicates that there is an uncertainty in
the second digit after the decimal point.
Hence, the least count of the instrument should be 0.01 cm = 0.1 mm.

A meter scale has a least count of 1 mm. Hence, the instrument cannot be a meter scale.

Least count of a vernier calliper is calculated as
L.C one main scale division One vernier scale division =
Now, for the given vernier calliper there are 10 divisions in 1 cm on the main scale.
Hence, one main scale division is 1 mm
Now, 10 divisions on the vernier scale coincide with 9 divisions on the main scale. Thus, 10
divisions on vernier scale correspond to 9 mm.

Thus, one vernier scale division is 9/10 = 0.9 mm

Hence, the least count of the vernier calliper is

L.C 1 mm 0.9 mm
0.1 mm
0.01 cm
=
=
=

Least count of a screw gauge is

Pitch
L.C
Number of divisions on the circular scale
=
Hence, for a screw gauge with pitch 1 mm and 100 divisions, we have

1 mm
L.C 0.01 mm
100
= =
And, for a screw gauge with pitch 1 mm and 50 divisions, we have

1 mm
L.C 0.02 mm
50
= =
Hence, the instrument has to be a vernier calliper.

Paper 2014

PARTB : CHEMISTRY

Z = 37
Rb is in fifth period.
Electronic configuration: 1s
2
2s
2
2p
6
3s
2
3p
6
3d
10
4s
2
4p
6
5s
1
So last electron enters 5s orbital
Hence n = 5, l = 0, m = 0, s = + 1/2 -1/2

Compressibility factor (Z)
PV
RT

(For one mole of real gas)
van der Waal equation is given by,
( )
| |
|
|
\ .
a
P+ v-b = RT
2
V

At low pressure; V b ~ V
| |
|
|
\ .
a
P+ V = RT
2
V

PV +
a
V
=RT
PV = RT -
a
V

PV
RT
= 1 -
a
VRT

Therefore, Z = 1 -
a
VRT

In CsCl, Cl
-
lies at corners of simple cube and Cs
+
at the body centre.
Hence, along the body diagonal, Cs
+
and Cl
-
touch each other so,
2r +2r += 3 a
- cs
CI

2
3 a
r +r +=
- cs
CI

Paper 2014


As per the question.
Normality Volume
H2SO4 N
5

60mL
NaOH
10
N

20mL

Mass of organic compound is = 1.4 g
( ) ( ) ( )
n = n + n
geq geq geq
H SO NaOH NH
4 2 3

( )
1 60 1 20
x = x + n
geq
NH 5 1000 10 1000
3

( )
6 1
= + n
geq
NH 500 500
3

( )
5 1
n = =
geq
NH
500 100
3

( ) ( ) ( )
1
n = n = n =
geq
mol mol NH N NH 100
3 3

(Mass)N =
14
100
= 0.14 g
Percentage of 'N' =
0.14
1.4
x 100 = 10%

Paper 2014


For 0.2 M solution,
R = 50 O

o = 1.4 S m
1
= 1.4 10
2
S cm
1

1 1
= = cm
-2
1.4x10

Now, R =
l
l R
-2
= =50 x 1.4 x10

For 0.5 M solution,
R = 280 O

o= ?
l
a
= 50 x 1.4 x10
-2
l
R =
a

1 1 l
x x
R a

1
-2
= x 50 x 1.4 x 10
280

1
-2
= x 70 x 10
280

= 2.5 x 10
-3
S cm
-1
x 1000
ow, =
m
M

-3
2.5 x 10 x 1000
=
0.5

= 5 S cm
2
mol
-1
= 5 x 10
-4
S m
2
mol
-1

Paper 2014


C H OH + 3O 2CO + 3H O
2 2 2 2 5 (l) (g) (g) (l)
Bomb calorimeter gives AU of the reaction. Hence, as per the question,
AU = - 1364.47 kJ mol
-1
Ang = -1
AH = AU + AngRT
1 x 8.314 x 298
=-1364.47-
1000

= - 1366.93 kJ mol
-1

According to Debye Huckle onsager equation,
= - A C
c

Here, A = B
Therefore,
= - B C
c

= i CRT

C H OH=1 x 0.500 x R x T=0.5 RT
2 5

(PO ) =5 x 0.100 x R x T=0.5 RT
4 Mg3 2

=2 x 0.250 x R x T=0.5 RT
KBr

= 4 x 0.125 x R x T=0.5 RT
Na PO
4 3

1
SO + O SO
2 2 3 (g) (g) (g)
2

Kp = KC (RT)
X
X =n
g
= no. of gaseous moles in product no. of gaseous moles in reactant
| |
|
\ .
1 3 -1
= 1- 1+ =1- =
2 2 2

Paper 2014


2A + B C + D

Rate of Reaction =
-1 d[A] d[B]
= -
2 dt dt

=
d[C] d[D]
=
dt dt

Let rate of Reaction = k[A]
x
[B]
y
d[C]
y x
Or = k[A] [B]
dt

Now from table,
1.2 103 = k [0.1]
x
[0.1]
y
...(i)
1.2 103 = k [0.1]
x
[0.2]
y
...(ii)
2.4 103 = k [0.2]
x
[0.1]
y
...(iii)

Dividing equation (i) by (ii)
y -3 x
1.2 x 10 k[0.1] [0.1]
=
y x
-3
k[0.1] [0.2]
1.2 x 10

(
(

y
1
1 =
2

y =0

Now dividing equation (i) by (iii)
y -3 x
1.2 x 10 k[0.1] [0.1]
=
y x
-3
k[0.2] [0.1]
2.4 x 10

( (
( (

-1 x
1 1
=
2 2

x =1

.
d[C]
1 0
Hence = k[A] [B]
dt

Paper 2014


Decreasing order of strength of oxoacids:
HClO4> HClO3> HClO2> HOCl
The given acids will get ionised as follows:
HClO4 ClO4
-
+ H
+
HClO3 ClO3
-
+ H
+
HClO2 ClO2
-
+ H
+
HOCl ClO
-
+ H
+
The structures of conjugate bases are as follows:

The resonance structure for ClO4
-
is as follows:

-
is as follows:

-
is as follows:

From the above resonating structures, negative charge is more delocalized on ClO4
-
due to
resonanace.
The resonanace stability order of conjuhate base is,

ClO4
-
> ClO3
-
> ClO2
-
> ClO
-

Therefore, the acidic strength oreder is,

HClO4 > HClO3 > HClO2 > HOCl

Paper 2014

Only Ca
2+
can not be dischrged as Ca at cathode on electrolysis as in Ca
2+
case, H2 gas
gets discharged at cathode.

This is due to the fact that, higher the position of element in the electrochemical series,
more difficult is the reduction of its cations. If Ca
2+
is electrolysed then water is reduced
in preference to it. Therefore, Ca
2+
can not be reduced electrolytically from an aqueous
solutions.
The chemical equations for cathode are as follows:

In case of Ag
2+
At cathode: Ag
2+
+ e
-
Ag

In case of Ca
2+
At cathode: H2O + e
-
H2 + OH
-

In case of Cu
2+
At cathode: Cu
2+
+ 2e
-
Cu

In case of Cr
3+
At cathode: Cr
3+
+ 2e
-
Cr

Given:
Ligands L1 L2 L3 L4
Wavelength
() absorbed
region
Red Green Yellow Blue

Now,
Increase in the order of energy of wavelengths absorbed reflect in the greater extent of
crystal-field splitting which in turn reflect into higher field strength of the ligand.
The order of energy of the different regions are as follows:

Red(L1)< Orange< Yellow(L3)< Green(L2)< Blue(L4)< Violet

The ligand which absorb lower energy light has lower strength.
Therefore, the order for the strength of ligand is as follows:

L1<L3< L2< L4

Paper 2014

Nitric oxide (NO) is paramagnetic in gaseous state. The electronic configuration of NO is
as follows:
1s
2
1s*
2
2s
2
2s *
2
2pz
2
2pz*
2
2px
2
= 2py
2
2px*
1

NO is paramagnetic since it has one unpaired electron in its outermost shell.

Reducing agent gets oxidised itself by releasing electrons.

The oxidation number of oxygen in the reactants and product are shown as a power in
brackets in the given following reactions:
(a) H2O2
(-1)
+ 2H
+
+2e
-
2H2O
(-2)

(b) H2O2
(-1)
2e
-

(0)
2
O + 2H
+

(c) H2O2
(-1)
+ 2e
-

(-2)
-
2 OH
(d) H2O2
(-1)
+ 2OH
-
- 2e-
(0)
2
O + 2H2O

From the oxidation numbers of oxygen in the above reactions, H2O2 acts as reducing
agent in (b) and (d) reactions where oxidation number of oxygen shifts to positive side.

It is a fact that CsI3 contains one Cs
+
ion and I3
-
ions.

The mass ratio of O2 to N2 is given as 1:4.
Let the mass of O2 = x
Hence, the mass of N2 = 4x
Number of moles of O2 =
32
x

Number of moles of N2 =
4
28 7
x x
=

Now, ratio of moles of O2 to N2 =
32
x
:
7
x
= 7:32
Therefore, the ratio of number of molecules of O2 to N2 = 7:32

Paper 2014


0
2+ 0
+1.51V -1.18V 2+
2+
0
Mn E 1.18V
2( Mn ) E 1.51V
Mn Mn
Therefore, for 3Mn Mn +2
E 1.18V-( 1.51V)
= - 2.69 V
=
=+

= +
2+ -
3+ -
3+
3+
2+
Mn +2e
Mn +e
Mn
Mn
for Mn disproportionation

Since -2.69 V < 0, reaction is non-spontaneous.

The correct option (option 4) is as follows:
2
0 0
O CO CO
Heat 600 C 700 C
FeO Fe
3 4
Fe Fe O is a correct series of reaction.
2
O
Heat
3 4
Fe Fe O is a combustion reaction of Fe.
0 0
CO CO
600 C 700 C
FeO Fe
3 4
Fe O

This series of reactions correspond to the production of Fe by reduction of Fe3O4.

The other options are as follows:
(1) Fe + H2SO4 FeSO4 + H2,
2FeSO4 + H2SO4 + O2 Fe2(SO4)3 +H2O
Fe2(SO4)3
A
Fe2O3(s) + 3SO3 | (This reaction is given incorrectly).

(2) Fe
2
O
A
FeO (The products can be Fe2O3 or Fe3O4)
FeO
2 4
dil. H SO
FeSO4 + H2O
2FeSO4
A
Fe2O3 + SO2 + SO3

(3) Fe
2
Cl
A
FeCl3
A, A
ir
no reaction (it cannot give FeCl2)

Paper 2014

Option (1) Li2O + 2KCl 2LiCl + K2O
The compound K2O cannot be generated.

Option (2) [CoCl(NH3)5]
+
+5H
+
Co
2+
+ 5NH4
+
+ Cl
-
This is a correct option. The complex [CoCl(NH3)5]
+
decomposes under acidic medium.
All ammine complexes can be decomposed by adding H
+
.

Option (3) [Mg(H2O)6]
2+
+ (EDTA)
4-

excess NaOH
[Mg(EDTA)]
2+
+ 6H2O

The formula of the complex in the product must be [Mg(EDTA)]
2-

Option (4) CuSO4 + 4KCN K2[Cu(CN)4] + K2SO4
It is an incorrect option. The correctly balanced reaction is as follows:
2CuSO4 + 10 KCN 2 K3[Cu(CN)4] + 2K2SO4 + (CN)2|

51. Correct option: ( 2)
In SN
2
, the order of reactivity depends on the stearic hindrance.
So as the stearic hindrance around the electrophilic carbon increases in the order CH3X
> 1
0
>2
0
>3
0
. Thus the order of reactivity in SN
2
reactions is: CH3Cl > (CH3)CH2
Cl >
(CH3)2CH

Cl > (CH3)3CCl

When aliphatic primary amine is treated with chloroform and ethanolic potassium
hydroxide alkyl isocyanide is obtained.

R NH2 + CHCl3 R CH2 NC

Pyridinium chlorochromate is the mild oxidising agent and converts the alcohol to
aldehyde.

R CH2 - OH R-CHO


2-Butyne

Paper 2014



In aliphatic amines, the order of basic strength in aqueous solution is as follows:

Since pKb = - log Kb

So (CH3)2NH will have smallest pKb value.

In quinol and thioquinol, the OH and SH groups do not cancellise their dipole moment
because they exist in different conformations.

Same as in thioquinol.

Paper 2014


Dacron is a condensation polymer of ethylene glycol and terepthalic acid.

Quinoline is an alkaloid. DNA contains ATGC bases Adenine, Thymine, Guanine and
Cytocine.


PARTC : MATHEMATICS

61.Correct Option: (2)
( )
{ }
( ) { }
{ }
( ) { }
{ }
n
2 n n n 2
2 3
Let us rewrite the given equation as
X 1 3 3n 1,n N
3 C C ... 3 ,n N expanding by binomial expansion
Divisible by 9
Now let us consider the set Y
Given that
Y= 9 n 1 ,n N
All multiples of 9
Thus,
= + e
= + + + e (

=
e
=
X Y
X Y=Y
_

Paper 2014


( )
1 2 1 2
min
We know that z z z z
1
Now consider z+
2
1 1
z z+
2 2
1 1
z+ 2
2 2
3
z
2
Minimum value lies in the interval 1,2
+ >
s
>
=

( ) ( )
{ } { }
{ }
{ } { }
{ }
{ }
( ) ( )
2
2
2 2
2
2
2
2
2
3 x x 2 x x a 0
2
3 x x a
3
1 1
3 x a
3 3
1 1 2
0 x 1 and x
3 3 3
1 4
0 3 x
3 3
1 1 1
3 x 1
3 3 3
For non-interval solution 0<a 1 and a 1,0 0,1
+ + = ( (

| |
=
|
\ .
| |
=
|
\ .
s < s <
| |
s <
|
\ .
| |
s <
|
\ .
< e

Paper 2014


From the given quadratic equation, we have
q r
+ = ;
p p
Given p,q,r in A.P.
2q=p+r....(1)
Also, given that
1 1
4
4
o | o| =
+ =
o |
o + |
=
o|

( )
2
q
p
4
r
p
q
4
r
q 4r and p= 9r
4
=
=
o | = o + | o|

2
2
2 2
q r
4
p p
q 4pr
p
16r 36r 2 13
9r 9
| |
o | =
|
\ .
o | =
+
o | = =

Paper 2014


( ) ( )
( ) ( ) ( )
( ) ( ) ( )
( ) ( ) ( )
2 2
2 2 3 3
2 2 3 3 4 4
2
2
2 2
2 2 2
Consider the determinant
3 1+f 1 1+f 2
1+f 1 1+f 2 1+f 3
1+f 2 1+f 3 1+f 4
1+1+1 1+ + 1+ +
1+ + 1+ + 1+ +
1+ + 1+ + 1+ +
1 1 1 1
1 1
1 1 1 1
1 1
Equating this with the given equation,
we ha
o | o |
= o | o | o |
o | o | o |
o o
= o | | |
o |
(
= o | o |

ve K=1

( )
( ) ( )
( ) ( )
( )
1 1
1 1
1 1
1 1
BB' B A A' ' since B A A'
A A' A A' '
A A' A' ' A '
A A' A A '

( = =

=
=
=

( )
( ) ( )
( )
( )
1 1
1 1
1
1
A A A' A ' since A' A=A A'
A A A' A '
I A' A '
A' A'
I

= (

(
=

=
=
=

Paper 2014


( ) ( )
( ) ( ) ( ) ( ) ( )
( )
18
2
2 3 4
2 18 18 18 18 18
0 1 2 3 4
3
18 3 18 2 18
3 2 1
1 ax bx 1 2x
1 ax bx C C 2x C 2x C 2x C 2x ...
Therefore, coefficient of x
C 2 a C 2 2b C 0
18 17 16 4a 18 17
8 36b 0
6 2
51 16 8 a 36 17 36b 0
6528 a 36 17 36b 0
51a 3b 54
+ +
= + + + +
= + =

+ =
+ =
+ =
= 4
By checking the options it is clear that,
option (2) satisfies the above equation.

( ) ( ) ( ) ( ) ( ) ( ) ( )
( ) ( ) ( ) ( ) ( )
( ) ( ) ( ) ( ) ( ) ( ) ( )
9 1 8 2 7 9 9
2 7 3 6 9
8 10
9 1 8 2 7 9 10
9
Let s= 10 2 11 10 3 11 10 ... 10 11 k 10 ,
11
x 11 10 2 11 10 3 11 10 ... 9 11 11
10
Subtracting the above two equations, we have
11
1 x 10 11 10 11 10 ... 11 11
10
11
10 1
10
1
x
10
+ + + + =
= + + + + +
| |
= + + + +
|
\ .
| |

\
= ( )
10
10 Sum of n terms in
11
11
Geometric progression
1
10

`
|
.
(
)

(

{ }
( )
( )
10 10
10
9
10
10 10 10
10
11
9
11
10 11
1 10
x 10 11
10 1 10
1
x 10 11 11
10
1
x 10
10
x 10
Given that 10 k 10
Thus,we have
k=100
= +
=
=
=

Paper 2014

2
Let a, ar and ar be three positive integers in a G.P.
Now consider the middle term, which is ar
Given that the middle term is doubled.
Therefore, the new middle term is 2ar,
Hence the three terms, a, 2ar
2
2
2
2
and ar form an AP
4ar=a+ar
4r 1 r
r 4r 1 0
4 2 3
r
2
r 2 3 or r 2 3
Since r>1, GP is increasing, we have r 2 3
= +
+ =
=
= + =
= +

( )
( ) ( ) ( )
2
2
x 0
2 2
2 2
x 0 x 0
sin cos x
We need to evaluate the expression lim
x
sin 1 sin x sin cos x
lim lim
x x

t
t t
=

( )
( )
( )
( )
( )
( )
( )
2
2
x 0
2
2
x 0
2
2
2 2
x 0
2
2
2 2
x 0 x 0
2
2
2 2
x 0 x 0
2
2
x 0 x 0
sin sin x
lim
x
sin sin x
lim sin sin
x
sin sin x
sin x
lim
sin x x
sin sin x
sin x
lim lim
sin x x
sin sin x
sin x
lim lim
sin x x
sin sin x
sinx
lim lim
x sin x

t t
=
t
( = t u = u

t
t
=
t
t
t
=
t
t
= t
t
t
| |
= t
|
t
\ .
2
2
0
sin
1 1 lim 1
u
u (
= t =
(
u

= t

Paper 2014

71. Correct Option: (2)
Since g(x) is the inverse of f(x),
( )
( )
5
5
1
' ( )
'( )
1
' ( ) 1
1
1
=
= = +
+
g f x
f x
g f x x
x

Assuming ( ) x g y =
| |
{ }
5
5
'( ) 1 ( )
'( ) 1 ( )
= +
= +
g y g y
g x g x

Consider
( ) ( ) ( )
( )
( ) ( ) ( )
( ) ( ) ( )
( )
f x 2g x h x
Since f and g are continuous and differentiable in 0,1
h x is also continuous and differentiable.
Also we have
h 0 f 0 2g 0 2 0 2
and
h 1 f 1 2g 1 6 2 2 2
Thus, h x satisfies the conditions of Rolles T
=
(

= = =
= = =
( ) heorem in 0,1

Using Rolle's Theorem,
(1) (0) 6 2
'( ) 4
1 0 1 0
(1) (0) 2 0
'( ) 2
1 0 1 0

= = =

= = =

f f
f c
g g
g c

Hence, '( ) 2 '( ) = f c g c

Paper 2014


Given,

2
( ) log
'( ) 2 1 0 at 1, 2
= + +
= + + = =
f x x x x
f x x x
x
o |
o
|

Hence, at 1 x = ,
2 1 0
2 1 -----Equation 1
o |
o |
+ =
+ =

And at 2 x = ,
4 1 0
2
8 2 -----Equation 2
o
|
o |
+ + =
+ =

Solving equations 1 and 2, we get
1
2,
2
o | = =

Paper 2014


Let ( )
1
x
x
f x e
+
=
'( ) = f x
1
2
1
(1 )
x
x
e
x
| |
+
|
\ .

1
x+
x
1 1 1
x+ x+ x+
x x x
2
1 1 1
x+ x+ x+
x x x
2
1
Let I= 1+x e dx
x
Rewrite the given integrand as:
1 1
1+x e =e +x(1 )e
x x
Thus, we have,
1 1
1+x e dx= e +x(1 )e
x x
| |
|
\ .
| | | | | |
| | |
\ . \ . \ .
| | | | | |
| | |
\ . \ . \ .
| |
|
\ .
| |

|
\ .

| |

`
|
\ .

)
}
}
( )
1 1
1
x+ x+
x+
x x
x
2
dx
We know that xf'(x)+f(x) dx=xf(x)+c
Thus,
1
= e +x(1 )e dx=xe +c
x
| | | |
| |
\ . \ .

`

)
}
}
}
I

2
0
0
3
0
3
3
0
3
1 4sin 4sin
2 2
2sin 1
2
(1 2sin ) (2sin 1)
2 2
4cos 4cos
2 2
4 3 3
4 0 4
3 2 2 3
4 3 4
3
+
=
= +
( (
= + +
( (

| |
= + + + +
|
|
\ .
=
}
}
} }
x x
dx
x
dx
x x
dx dx
x x
x x
t
t
t
t
t
t
t
t
t t
t
t

Paper 2014

2 2 2
1 and 1 intersect at 0,1 x y y x x + = = =

Area of the shaded region =Area of semi-circle plus area bounded by parabola and y-axis
Area of the shaded region =
1 2
1
(1)
2

+
}
ydx
t

2
Since y 1 x y 1 x = =
Thus, we have,

| |
1 2
1
1 2
0
1
3
2
0
(1)
Area (1 )
2
(1)
2 (1 ) the parabola is symmetric about x-axis
2
2(1 )
( 1)
3
2
2
4
(0 ( 1))
2 3
4
2 3
= +
= +
(
(
= +
(

= +
= +
}
}
x dx
x dx
x
t
t
t
t
t

Paper 2014


Given,
Given equation is:
1
'( ) ( ) 200
2
Rewriting the above equation, we have
1
'( ) ( ) 200....(1)
2
This is a linear differential equation of the form
dy
, where P and Q are functions of x.
dx
From equati
=
=
+ =
p t p t
p t p t
Py Q
1
2
1
on (1), we have, P and Q 200
2
The integrating factor I.F. = e
= =
}
=
t
Pdt
e

Hence,
Pdx Pdx
1 1
2 2 2
2
The solution is of the form,
ye e
Thus, we have,
( ) 200 400
( ) 400

} }
= +
= = +
= +
}
}
t t t
t
Q dx c
p t e e dt e c
p t ce

Since, p (0) = 100,
=>100 = 400 + c
C = -300
Hence,
2
( ) 400 300
t
p t e =

Paper 2014


S is the mid-point of QR.
Hence, S =
7 6 3 1 13
, ,1
2 2 2
+ | | | |
=
| |
\ . \ .

Slope of PS =
2 1 2
13
9
2
2

Equation of the line passing through (1,-1) and parallel to PS is
2
( 1) ( 1)
9
9 9 2 2
2 9 7 0
y x
y x
x y
=
+ = +
+ + =

The point of intersection of the lines 4 2 0 and 5 2 0 is given by
4 1
2 2 4 5 8 10
2( )
2
5 4
2
ax ay c bx by d
x
ad bc ad bc ab ab
ad bc
x
ab
bc ad
y
ab
+ + = + + =
= =

As the point of intersection is in the fourth quadrant, x is positive and y is negative. Also
the distance from the axes is same.
Hence, x = -y

2( ) (5 4 )
2 2
2 2 5 4
3 2 0
ad bc bc ad
ab ab
ad bc bc ad
bc ad

=

= +
=

Paper 2014



Let us rewrite the given equation of the ellipse.
2 2
2 2
2 2
2 2
2 2
2 2
x 3y 6
x 3y 6
6 6 6
x y
1
6 2
Now compare the above equation with the
x y
general equation of the ellipse 1
a b
a 6;b 2
+ =
+ =
+ =
+ =
= =

Equation of a line through (h, k) & perpendicular to line joining it to origin is
2 2
2 2 2 2
2 2
2
2 2 2
2
( ) ( )
Since the above line is tangent to the ellipse,
it should satisfy the following condition.
C
Substituting the values of C, , and , we have
6 2
=
+
= +
= +
| | +
= +
|
\ .
h
y k x h
k
h h k
y x
k k
a m b
a m b
h k h
k k
( )
2
2 2 2 2
6 2 + = + x y x y

Paper 2014



2 2
2 2 2
2 2
2 2
2 2
( 1) ( 1) 1
Radius of M=
M touches P externally
(0-1) ( 1) (1 )
1 1 2 1 2
If y > 0,
y 2 2 1 2
4 1
1
4
If y < 0,
y 2 2 1 2
1 2
Which is not possible
1
4
P x y
y
y y
y y y y
y y y
y
y
y y y
y
+ =
+ = +
+ + = + +
+ = + +
=
=
+ = +
=
=

Paper 2014

Let the equation of the tangent to
2
1
4 be y=mx+
m
y x =
The above tangent is also a tangent to
2
32 = x y
( )
2
2
2
2
3
3
32
1
32 mx+
m
32
32 0
Since roots are equal, the discriminant is zero.
Thus,
32
0 32 4 0
32 4
1
8
1
2
=
| |
=
|
\ .
+ + =
= =
=
=
=
x y
x
x mx
m
D m
m
m
m
m


Paper 2014

( ) ( )
( )
Let B' a,b,c be the image of the point B 1,3,4
The direction ratios of the line BB' is
1 3 4
2 1 1
Any point on the line BB' is of the form
a=2 1, 3 , 4
Let P x,y,z mid point of the line BB'.
Thu

= = =
+ = = +
a b c
b c

( )
2 1 1 3 3 4 4
s, , ,
2 2 2
1, 3 , 4
2 2
Since the point P lies in the plane, 2 3 0, we have
2 1 3 4 3 0
2 2
+ + + + + | |
|
\ .
| |
+ +
|
\ .
+ + =
| | | |
+ + + + =
| |
\ . \ .
P
P
x y z

2 2 3 4 3 0
2 2
3 6 0
2
Substituting the value of in
1 3 4
2 1 1
we have
3, 5, 2
Hence the equation of the required line is
3 5 2
3 1 5
+ + + + + =
+ =
=

= = =
= = =
+
= =
a b c
a b c
x y z

Paper 2014


( ) ( )
2 2 2
2 2 2
1 2 1 2 1 2
2 2 2 2 2 2
1 1 1 2 2 2
0..................( )
....................( )
( ) 0
2 ( ) 0
0
So direction ratios are -1, 0, 1 -1, 1, 0
cos
1 0 0
cos
2
l m n i
l m n ii
l m l m
m m l
m or l m
and
a a b b c c
a b c a b c
u
u
+ + =
= +
=
+ =
= =
| |
+ +
| =
|
+ + + +
\ .
+ +
=
1
2 2
3
t
u
=
=

( )
( ) { } ( )
( ) ( ) { } ( )
{ } ( ) ( )
( )
( )
2
LHS = a b b c c a
p b c c a p a b
p b c . c a
p.c b p. b c . c a
a b c b a b c c . c a p a b
a b c b c a 0 a b b 0
a b c b c a a b c
where
where
RHS
(

(
= =

=
=
( (
= =

( (
= =

(
= =

=
2
a b c
1
(

=

Paper 2014

1 1 5
( ) ( ) 1
6 6 6
1 1 3
( ) ( ) 1
4 4 4
Now, ( ) ( ) ( ) ( )
5 3 1
( )
6 4 4
5 3 1 1
( )
6 4 4 3
P A B P A B
P A P A
P A B P A P B P A B
P B
P B
= = =
= = =
= +
= +
= + =

Thus, we observe that ( ) ( ) P A P B = .
Hence, events A and B are not equally likely.
Also,
3 1 1
( ) ( ) ( )
4 3 4
P A P B P A B = = =
Thus, events A and B are independent.

Solution:
( )
( )
( )
( )
2
2
2
2
2 2 2 2
2
2 2 2 2
2
2
2
,
2 4 6 .......... 100 2 4 6 ...... 100
50 50
50
2 100
4(1 2 3 .......... 50
2
50 50
50 (50 1) (2 50 1)
6
4 51
50
50 51 101
4 51
50 6
3434 2601
833
i
x
Variance x
N
o
o
o
=
+ + + + + + + + | |
=
|
\ .
+
+ + + +
=
+ + | |
|
=
|
|
\ .
| |
=
|
\ .
=
=

Paper 2014

Solution:
( )
( ) ( )
( ) ( )
4 4 6 6
4 6
2 2 2 2
2 2 2 2
1
( ) sin cos
1 1
( ) ( ) sin cos sin cos
4 6
1 1
1 2sin cos 1 3sin cos
4 6
1 1 1 1
sin cos sin cos
4 2 6 2
1 1
4 6
1
12
k k
k
f x x x
k
f x f x x x x x
x x x x
x x x x
= +
= + +
=
= +
=
=

t = 1 second

From the figure, we have
( )
( )
20 20
tan 45 1 20
20 1 20
tan30
20 3
20 3 1
. . 20 3 1 /
o
o
a
a a
and
a b b
b
i e Speed m s
= = =
= =
+ +
=
=

Paper 2014

p q
q p q ( ) p q p q
F F T F T T
F T F T F F
T F T T F F
T T F F T T

Thus, ( ) p q is equivalent to p q

IITJEEMains2014 CodeE Solution

Transféré par

Informations du document

Description originale:

Titre original

Copyright

Formats disponibles

Partager ce document

Partager ou intégrer le document

Options de partage

Avez-vous trouvé ce document utile ?

Ce contenu est-il inapproprié ?

Droits d'auteur :

Formats disponibles

IITJEEMains2014 CodeE Solution

Transféré par

Droits d'auteur :

Formats disponibles

IITJEE MAIN | PHYSICS, CHEMISTRY AND MATHEMATICS

Vous aimerez peut-être aussi