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LEVEL
OF ACIDITY IN YOUR WINE
By Dr. Frank Puzio
Acid measurements can be measured and adjusted accordingly using titration and pH
methods. Literature suggests that the total acidity endpoint of finished red wine should
be in a range of 0.55 – 0.60% TA and have a pH of 3.4 – 3.6.
Acid adjustment is one of the most important and most difficult decisions to calculate
quantitatively. Accuracy of acid adjustment will have a significant influence on the
ultimate taste of the finished wine and on pH. The right amount of acid helps provide a
pleasing bite or tang to the finished wine. Low levels of acid produce bland tasting
wines and high levels produce a harsh taste to the palate. Generally, California
grapes are deficient in acid and an adjustment is required with the addition of a natural
acid in grape called tartaric acid. There are also less dominant acids in grapes, malic
and citric, but tartaric has the most influence on taste. Publications advise avoiding
using acid blend products.
With the titration method discussed subjective color estimates are sometimes difficult
to estimate. pH measurement of acid is considered by some to be more accurate.
Optimum pH of finished red wine is 3.3 – 3.6. Accuracy has a profound influence on
final wine quality, it allows SO2 to be more effective as an antimicrobial agent, it
enhances fruity esters, optimizes color, and has a very positive influence on the
ultimate taste. Make note that a higher pH value is lower in acid.
If the pH of the must after crushing is higher than 3.5 (less acidic) delay beginning
yeast inoculation and fermentation until the acid level has been lowered (made more
acidic) by adjustments with tartaric acid to lower the pH reading to 3.5.
Provided compliments of www.HelpMyWineMaking.com 3
Measurement of Total Acidity (TA) with pH meter
Measuring acidity in wine using a pH meter is very similar to the titration method
but with a difference that does not rely on difficult to observe color changes to
determine endpoint.
Add 0.2N NaOH (sodium hydroxide) 1-2 drops at a time until the pH meter reads
8.2. 8.2 is the same pH at which phenolphthalein changes color (to pink).
If 0.1N reagent is used, divide the amount of NaOH used in half.
Place a 15cc sample of wine in a small beaker or Erlenmeyer flask.
Fill syringe with 0.2N NaOH
Record the exact cc amount of 0.2N NaOH used to reach end-point
neutralization. As with the titration method, for each cc of reagent used it equals
0.1% g/L TA. For example, if we used 6cc this equals 0.6% TA.
I used 0.1N NaOH, the cc’s used to reach 8.2 pH was 12 divided by 2 = 6 or .6%.
Follow the addition of tartaric calculations as outlined previously.
During fermentation there is sometimes a decrease in TA and an increase in pH.
Monitor the pH during fermentation especially with red wines and add tartaric
acid as needed to hold pH in line until fermentation is completed.
PLEASE NOTE:
This Primer Is Provided Free of Charge. Please respect the fact that this valuable
document was put together by Dr. Frank Puzio, an avid homemade wine enthusiast,
strictly for the benefit of other fellow wine makers to learn. Feel free to share it with
your wine making colleagues as you see fit but don’t copy it and call it your own.
If you learned something from this document and would like to pass on a comment
or a word of thanks please email Scott “The Wine Making Guy” at
Tips@HelpMyWineMaking.com and he’ll be sure to pass it along to Dr. Puzio!