UNIVERSITY OF CAMBRIDGE INTERNATIONAL EXAMINATIONS

General Certificate of Education Ordinary Level

CHEMISTRY
5070/01


Paper 1 Multiple Choice

October/November 2004

1 hour
Additional Materials: Multiple Choice Answer Sheet
Soft clean eraser
Soft pencil (type B or HB is recommended)





READ THESE INSTRUCTIONS FIRST

Write in soft pencil.
Do not use staples, paper clips, highlighters, glue or correction fluid.
Write your name, Centre number and candidate number on the answer sheet in the spaces
provided unless this has been done for you.

There are forty questions on this paper. Answer all questions. For each question there are four possible
answers A, B, C, and D.
Choose the one you consider correct and record your choice in soft pencil on the separate answer sheet.

Read the instructions on the Answer Sheet very carefully.

Each correct answer will score one mark. A mark will not be deducted for a wrong answer.
Any rough working should be done in this booklet.
A copy of the Periodic Table is printed on page 16.
You may use a calculator.






















This document consists of 16 printed pages.
IB04 11_5070_01/2RP
UCLES 2004

[Turn over

2

UCLES 2004 5070/01/O/N/04
1 A pale green solution X gives a green precipitate with excess aqueous sodium hydroxide.

An alkaline gas is only given off when the mixture is warmed with powdered aluminium.

Which ions does X contain?
A ammonium and copper(II)
B ammonium and iron(III)
C copper(II) and nitrate
D iron(II) and nitrate


2 The diagram shows the chromatogram of four different sugars using the same solvent.

Glucose has an R
f
value of 0.5.

Which sugar is glucose?





















3 A liquid boils at a temperature of 100
o
C.

Which other property of the liquid proves that it is pure water?
A It does not leave a residue when boiled.
B It freezes at 0
o
C.
C It is neither acidic nor alkaline.
D It turns white anhydrous copper(II) sulphate blue.


A B C D
solvent front
base line
3

UCLES 2004 5070/01/O/N/04 [Turn over
4 The diagram shows apparatus used to separate hexane (boiling point, 70
o
C) and heptane
(boiling point, 98
o
C).

water out
thermometer
water in
distillate
heat
T


Which graph would be obtained if the temperature at point T was plotted against the total volume
of distillate collected?

























70
80
90
100
total volume
of distillate
temperature /
o
C
70
80
90
100
total volume
of distillate
temperature /
o
C
70
80
90
100
total volume
of distillate
temperature /
o
C
70
80
90
100
total volume
of distillate
temperature /
o
C
A B
C D
4

UCLES 2004 5070/01/O/N/04
5 In which conversion do H
2
O molecules lose speed?

steam
water ice


A ice water
B ice steam
C steam ice
D water steam


6 Two particles X and Y have the composition shown in the table.

particle number of electrons number of neutrons number of protons
X 10 8 8
Y 18 18 17

The particles X and Y are
A metal atoms.
B non-metal atoms.
C negative ions.
D positive ions.


7 What is the nucleon number of the isotope of uranium,
235
92
U?
A 92 B 143 C 235 D 327


8 Which of the following is a compound?
A air
B carbon
C oxygen
D steam


5

UCLES 2004 5070/01/O/N/04 [Turn over
9 The experiment shown is used to test potassium bromide crystals.

electrodes
beaker
lamp
potassium
bromide crystals


The lamp does not light.

Distilled water is then added to the beaker and the lamp lights.

Which statement explains these results?
A Electrons are free to move in the solution when potassium bromide dissolves.
B Metal ions are free to move when potassium bromide melts.
C Metal ions are free to move when potassium reacts with water.
D Oppositely charged ions are free to move in the solution when potassium bromide dissolves.


10 Which compound has both ionic and covalent bonds?
A ammonium chloride
B carbon dioxide
C ethyl ethanoate
D sodium chloride


11 'Cracking' of hydrocarbons breaks them into smaller molecules.

Which example of 'cracking' would produce the largest volume of products from one mole of
hydrocarbon? Assume that all measurements are made at the same temperature and pressure.
A C
6
H
14
(g) 3C
2
H
4
(g) + H
2
(g)
B C
8
H
18
(g) 2C
3
H
8
(g) + C
2
H
2
(g)
C C
10
H
22
(g) C
8
H
18
(g) + C
2
H
4
(g)
D C
12
H
26
(g) C
8
H
18
(g) + 2C
2
H
4
(g)


6

UCLES 2004 5070/01/O/N/04
12 When 20 cm
3
of a gaseous alkene burns in an excess of oxygen, 60 cm
3
of carbon dioxide are
formed. Both volumes are measured at r.t.p.

What is the formula of the alkene?
A C
3
H
6

B C
3
H
8

C C
6
H
12

D C
6
H
14



13 'Meta-fuel', C
8
H
16
O
4
, is a fuel used in camping stoves.

What is the equation for its complete combustion?
A C
8
H
16
O
4
+ 2O
2
8C + 8H
2
O
B C
8
H
16
O
4
+ 5O
2
8CO + 8H
2
O
C C
8
H
16
O
4
+ 10O
2
8CO
2
+ 8H
2
O
D C
8
H
16
O
4
+ 8O
2
4CO
2
+ 4CO + 8H
2
O


14 Dilute sulphuric acid is electrolysed using inert electrodes.

Which equation represents the reaction at the anode (+ve)?
A O
2
2

O
2
+ 2e

B 2H
+
+ 2e

H
2

C 4OH

O
2
+ 2H
2
O + 4e

D SO
2
4

O
2
+ SO
2
+ 2e

15 What are the products when concentrated aqueous lithium chloride is electrolysed?

at the anode (positive) at the cathode (negative)
A chlorine hydrogen
B chlorine lithium
C oxygen hydrogen
D oxygen lithium


7

UCLES 2004 5070/01/O/N/04 [Turn over
16 A solid deposit of element R is formed at the cathode(-ve) when an aqueous solution containing
ions of R is electrolysed.

Which statement about element R must be correct?
A R forms negative ions.
B R ions gain electrons at the cathode.
C R ions lose electrons at the cathode.
D R is above hydrogen in the reactivity series.


17 Apparatus was set up as shown.

metal
Y
metal
X
flow of electrons
electrolyte


For which pair of metals would electrons flow in the direction shown?

metal X metal Y
A copper zinc
B iron aluminium
C iron magnesium
D zinc silver


8

UCLES 2004 5070/01/O/N/04
18 The table shows the energy released by the complete combustion of some compounds used as
fuels.

compound formula M
r
H in kJ / mol
methane CH
4
16 880
ethanol C
2
H
5
OH 46 1380
propane C
3
H
8
44 2200
heptane C
7
H
16
100 4800

Which fuel produces the most energy when 1 g of the compound is completely burned?
A ethanol
B heptane
C methane
D propane


19 Which reaction is the fastest?

water at
60 C
water at
30 C
water at
30 C
water at
60 C
dilute
hydrochloric
acid
lumps of
calcium
carbonate
dilute
hydrochloric
acid
powdered
calcium
carbonate
concentrated
hydrochloric
acid
lumps of
calcium
carbonate
concentrated
hydrochloric
acid
powdered
calcium
carbonate
experiment A experiment B
experiment C experiment D



9

UCLES 2004 5070/01/O/N/04 [Turn over
20 The diagram shows the reaction pathway for a reaction without a catalyst.

energy
reaction pathway


Which diagram shows the pathway resulting from the addition of a catalyst to the reaction?

energy
reaction pathway
A
energy
reaction pathway
B
energy
reaction pathway
C
energy
reaction pathway
D



21 Nitrogen reacts with oxygen.

N
2
(g) + O
2
(g) 2NO(g) H = +170 kJ / mol

At equilibrium, which statement is true?
A The concentration of nitrogen present will change with time.
B The forward and backward reaction are taking place at the same rate.
C The forward reaction releases heat energy.
D There are more molecules on the left hand side of the equation than on the right.


10

UCLES 2004 5070/01/O/N/04
22 Which series of changes includes both oxidation and reduction?
A C CO CO
2

B PbO
2
PbO Pb
C N
2
NH
3
NO
D C
2
H
2
C
2
H
4
C
2
H
6



23 The table gives information about three indicators.

indicator colour at pH 1
pH at which
colour changes
colour at pH 12
thymol blue red 3 yellow
congo red blue 5 red
phenolphthalein colourless 10 red

Which colours would be obtained when each indicator was added separately to pure water?

thymol blue congo red phenolphthalein
A red blue red
B yellow blue colourless
C yellow blue red
D yellow red colourless


24 Which reactants could be used safely to prepare potassium chloride?
A aqueous potassium hydroxide and dilute hydrochloric acid
B aqueous potassium sulphate and aqueous sodium chloride
C potassium and aqueous sodium chloride
D potassium and dilute hydrochloric acid


11

UCLES 2004 5070/01/O/N/04 [Turn over
25 In an experiment 5 cm
3
of 1.0 mol / dm
3
sodium hydroxide are gradually added to
10 cm
3
of 1.0 mol / dm
3
hydrochloric acid containing methyl orange.

10cm
3
of 1.0 mol / dm
3
HCl
and methyl orange
stirrer
5cm
3
of 1.0 mol / dm
3
NaOH


Which change occurs in the mixture?
A The concentration of the H
+
ions increases.
B The methyl orange changes colour.
C More water molecules are formed.
D A precipitate is formed.


26 X and Y are diatomic elements. X is less reactive than Y.

What are elements X and Y?

X Y
A bromine iodine
B iodine bromine
C potassium sodium
D sodium potassium


27 Element Z has the following properties.

It has a high melting point.
Its presence can lower the activation energy for a reaction.

What type of element is Z?
A a halogen
B an alkali metal
C a noble gas
D a transition metal


12

UCLES 2004 5070/01/O/N/04
28 All ammonium salts on heating with sodium hydroxide produce ammonia gas.
From which ammonium salt can the greatest mass of ammonia be obtained?
A 0.5 mol (NH
4
)
3
PO
4

B 0.5 mol (NH
4
)
2
SO
4

C 1.0 mol NH
4
Cl
D 1.0 mol NH
4
NO
3



29 The position of metal M in the reactivity series is shown.

K, Na, M, Al, Zn, Fe, Pb, Cu, Ag

Which method will be used to extract M from its ore?
A electrolysis of its molten oxide
B electrolysis of its aqueous sulphate
C reduction of its oxide by heating with hydrogen
D reduction of its oxide by heating with coke


30 Two elements are in the same group of the Periodic Table.

Which property will be the same for both elements?
A the charge on their ions
B their electronic structure
C their melting point
D their reactivity with water or acids


31 How does the mass of a sample of copper(II) oxide change when it is heated in hydrogen and in
oxygen?


mass after heating
in hydrogen
mass after heating
in oxygen
A decreases decreases
B decreases unchanged
C unchanged decreases
D unchanged unchanged


13

UCLES 2004 5070/01/O/N/04 [Turn over
32 From which reaction is a gas produced?
A adding calcium to water
B adding dilute hydrochloric acid to silver
C adding dilute sulphuric acid to copper
D electrolysing aqueous copper(II) sulphate, using copper electrodes


33 The diagram shows a boat made from iron.

Some magnesium blocks are attached to the iron below the water line.

water line
magnesium blocks


Why does the magnesium stop the iron from rusting?
A Magnesium reacts in preference to the iron.
B Magnesium reacts to form a protective coating of magnesium oxide on the iron.
C The magnesium forms an alloy with the iron.
D The magnesium stops oxygen in the water from getting to the iron.


34 A catalytic converter in a car exhaust system changes pollutants into less harmful products.

Which change does not occur in a catalytic converter?
A carbon dioxide carbon
B carbon monoxide carbon dioxide
C nitrogen oxides nitrogen
D unburned hydrocarbons carbon dioxide and water


35 The equation shows a reaction in the Contact process.

2SO
2
(g) + O
2
(g) 2SO
3
(g) H = 98 kJ / mol

Which change would move the position of equilibrium to the left?
A adding more O
2

B increasing the pressure
C increasing the temperature
D removing SO
3
from the reacting mixture
14

UCLES 2004 5070/01/O/N/04
36 Poly(ethene) can be manufactured by the process below.

decane ethene poly(ethene)
cracking polymerisation


Which diagram shows the change in molecular size during this process?



















37 Compound Q has the structure shown.

H
H
H
H H H
H
H H H
C C C C
O


Which structure is an isomer of Q?





















start finish
molecular
size
A
start finish
molecular
size
B
start finish
molecular
size
C
start finish
molecular
size
D
H
H
H
H H H
H
H
H H
C
C
C C
O
H H
C
C
C
C H H
H H
H H H H
O
C C C
H H H H
C H
H
H H H
H
O
H H H
C
H H H
C C O H H
H
C
H
A B
C D
15

UCLES 2004 5070/01/O/N/04
38 Compound X has the molecular formula C
2
H
6
O.

X can be made by a fermentation process.
X can be oxidised to Y.
X can react with Y to form Z and water.

To which homologous series do X, Y and Z belong?

X Y Z
A alcohols carboxylic acids esters
B alcohols esters carboxylic acids
C carboxylic acids alcohols esters
D carboxylic acids esters alcohols


39 The list shows reactions in which ethanol is either a reactant or a product.

1 combustion of ethanol
2 conversion of ethene to ethanol
3 fermentation of glucose
4 oxidation of ethanol to ethanoic acid

In which reactions is water also either a reactant or a product?
A 1, 3 and 4 only
B 2, 3 and 4 only
C 1, 2 and 4 only
D 3 only


40 A vegetable oil is polyunsaturated.

Which statement about this vegetable oil is correct?
A It has double bonds between carbon and hydrogen atoms.
B It reacts with hydrogen to form a solid compound.
C It reacts with steam to form margarine.
D It turns aqueous bromine from colourless to brown.


16


University of Cambridge International Examinations is part of the University of Cambridge Local Examinations Syndicate (UCLES), which is itself a department
of the University of Cambridge.
5070/01/O/N/04


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