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KINETICS AND EQUILIBRIUM Page 2
Evan P. Silberstein, 2003
Answer the questions below based on your reading and on your knowledge of chemistry.
1. For each oI the Iollowing, what eIIect would an increase in pressure have on equilibrium?
a. N
2
(!) 3H
2
(!) 2NH
3
(!)
b. 4H
2
(!) CS
2
(!) CH
4
(!) 2H
2
S(!)
c. CO(!) H
2
O(!) H
2
(!) CO
2
(!)
d. H
2
(!) F
2
(!) 2HF(!)
e. PCl
5
(!) PCl
3
(!) Cl
2
(!)
2. For each oI the Iollowing, what eIIect would an increase in temperature have on equilibrium?
a. N
2
(!) 3H
2
(!) 2NH
3
(!) H 92 kJ
b. C(") H
2
O(!) heat CO(!) H
2
(!)
c. PCl
3
(!) Cl
2
(!) PCl
5
(!) heat
d. 2SO
2
(!) O
2
(!) 2SO
3
(!) heat
e. H
2
O() H

(#$) OH

(#$) H 55.8 kJ
3. For the reaction, H
2
(!) I
2
(!) 2HI(!) |H 52.7 kJ|, what eIIect will each oI the Iollowing have on equilibrium?
a. Addition oI H
2
(!)
b. Removal oI I
2
(!)
c. Increase in temperature
d. Increase in pressure
e. Addition oI HI(!)
4. Explain LeChatelier`s principal based on collision theory.




5. II heat speeds up all reactions, both Iorward and reverse, why does it eIIect equilibrium?