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This document contains a chemistry assessment test with multiple choice and short answer questions.
1. The test covers topics such as isotopes, organic compounds, electronic configurations, hydrogen atom energy levels, conductivity, bonding, phase diagrams, equilibrium, kinetics and solubility.
2. It consists of 3 sections with varying point values and number of questions in each section. Section A has short answer and multiple choice questions. Section B requires explaining mass spectrometry data and drawing orbital diagrams. Section C involves drawing Lewis structures, explaining differences in bond angles and proposing a reaction mechanism.
3. The questions assess a range of chemistry concepts and require calculations, labeling diagrams and explaining chemical phenomena. Success on the test requires understanding of
This document contains a chemistry assessment test with multiple choice and short answer questions.
1. The test covers topics such as isotopes, organic compounds, electronic configurations, hydrogen atom energy levels, conductivity, bonding, phase diagrams, equilibrium, kinetics and solubility.
2. It consists of 3 sections with varying point values and number of questions in each section. Section A has short answer and multiple choice questions. Section B requires explaining mass spectrometry data and drawing orbital diagrams. Section C involves drawing Lewis structures, explaining differences in bond angles and proposing a reaction mechanism.
3. The questions assess a range of chemistry concepts and require calculations, labeling diagrams and explaining chemical phenomena. Success on the test requires understanding of
This document contains a chemistry assessment test with multiple choice and short answer questions.
1. The test covers topics such as isotopes, organic compounds, electronic configurations, hydrogen atom energy levels, conductivity, bonding, phase diagrams, equilibrium, kinetics and solubility.
2. It consists of 3 sections with varying point values and number of questions in each section. Section A has short answer and multiple choice questions. Section B requires explaining mass spectrometry data and drawing orbital diagrams. Section C involves drawing Lewis structures, explaining differences in bond angles and proposing a reaction mechanism.
3. The questions assess a range of chemistry concepts and require calculations, labeling diagrams and explaining chemical phenomena. Success on the test requires understanding of
S#MM$TI%E $SSESSMENT "IRST TERM ST&M 2'1( LOGO DAN NAMA SEKOLAH
Se)*+on $ [15 marks] Answer all questions in this section. 1 C and C atoms are isotopes of caron! "#ic# of t#e fo$$o%in& is t#e same for t#e isotopes' $ Stai$it( , N)c$ear c#ar&e C N)c$eon n)mer - *e$ati+e isotopic mass
2 "#ic# of t#e fo$$o%in& )nkno%n or&anic compo)nd %i$$ re$ease a spectr)m as t#e one s#o%n ao+e' $ C , H - , C - H 1. C C 1/ H 0/ - C 1/ H 00 ( 1anadi)m #as t#e e$ectronic confi&)ration of 1s 0 0s 0 0p . 2s 0 2p . 2d 2 ,s 0 ! "#ic# ion does no* e3ist' $ 1O , 2. , 1O 2 . C 1O 0 4 - 1O 2/ 0 10 . 1, . *e$ati+e intensit( m5e / 0/ ,/ ./ -/ 1// 10/ 1,/ 1./
0 6#e ener&(7$e+e$ dia&ram for a #(dro&en atom s#o%s se+era$ e$ectronic transitions %it# fre8)encies f19 f29 f39 f4 and f5! "#ic# of t#e fo$$o%in& statements is 5 are *rue of t#e ao+e dia&ram' I f1 represents t#e con+er&ence $imit of t#e L(man series! II f19 f2 and f3 represent $ines in t#e L(man series! III f4 and f5 are )sed to ca$c)$ate t#e difference et%een t#e ener&( $e+e$s of n : 2 and n : ,! I% 6#e e$ectronic transition of f3 &i+es a $ine spectr)m t#at corresponds to t#e re&ion of +isi$e $i&#t! $ I and II , I and I% C II and III - III and I% 1 ;ased on t#e and t#eor(9 t#e cond)cti+it( of meta$ is d)e to de$oca$i<ed e$ectrons in t#e cond)ction and! Ho% man( e$ectrons are fo)nd in t#e cond)ction and of a 1/!/ & ma&nesi)m meta$ strip' [*e$ati+e atomic mass of M& is 0,!/= A+o&adro constant is .!/0 3 1/ 02 mo$ 71 ] $ 0!51 3 1/ 02 , 5!/0 3 1/ 02 C 0!51 3 1/ 0, - 2!/1 3 1/ 0, 6 "#ic# of t#e fo$$o%in& #as +an der "aa$s forces' $ S)$p#)r! , Diamond! C Sodi)m c#$oride! - Ma&nesi)m o3ide! 2 Ener&( n : 1 n : 0 n : 2 n : , n : > f1 f2 f3 f4 f5
2 "#ic# species is dra%n %it# t#e correct s#ape' $ [ ? @ ? @ ? ] 7 , O O 07 S O O C
;
A A A
- H
B
H H
3 6#e dia&ram ao+e s#o%s t#e od(7centred c)ic str)ct)re of a )nit ce$$! Ho% man( atoms are t#ere in t#e )nit ce$$ ao+e' $ 1 , 0 C 2 - , 9 6#e ;o$t<mann distri)tion c)r+es at temperat)re 6 1 and 6 0 are s#o%n e$o%! At temperat)re 6 1 9 I t#e acti+ation ener&( is $o%er! II more mo$ec)$es #a+e $o%er ener&(! III t#e tota$ n)mer of mo$ec)$es remain constant! I% t#e ma3im)m point of t#e c)r+e is disp$aced to t#e ri&#t! $ I and II , I and I% C II and III - III and I% , Araction of mo$ec)$es 6 1 6 0 E a Ener&(
1' A p#ase dia&ram of %ater is s#o%n e$o%!
O
"#at can (o) ded)ced from t#e p#ase dia&ram' $ An increase in press)re %i$$ decrease t#e free<in& point of %ater! , An increase in press)re %i$$ decrease t#e oi$in& point of %ater! C ?ce s)$imes at a press)re #i&#er t#an .11 Ba! - "ater e3ists as $i8)id at a press)re of .11 Ba and temperat)re of 0C-K! 11 6#e kinetic data for t#e reaction A 4 0; D C at a certain temperat)re is s#o%n in t#e fo$$o%in& ta$e! E3periment ?nitia$ cencentration ?nitia$ rate of reaction [A] o [;] o 1 a r 0 0a ,r 2 a 0 r "#at is t#e rate of t#e reaction' $ k[A] 0 , k[;] 0 C k[A][;] 0 - k[A] 0 [;] 12 A 0!/ dm 2 stoppered f$ask at 6 o C contains /!5/ mo$ of SO 0 9 /!/1/ mo$ of O 0 and ,!. mo$ of SO 2 at e8)i$iri)m! Ca$c)$ate K c for t#e fo$$o%in& e8)i$iri)m at 6 o C! 0SO 0 E&F 4 O 0 E&F 0SO 2 E&F $ 5!C 3 1/ 75 dm 2 mo$ 71 , C!0 3 1/ 0 dm 2 mo$ 71 C -!5 3 1/ 2 dm 2 mo$ 71 - 1!G 3 1/ , dm 2 mo$ 71 5 Bress)re 5 Ba 6emperat)re 5 K 0G2!1. A C ; .11
1( "#ic# )nder$ined mo$ec)$e reacts as a Le%is ase' $ K 0 O 4 SO 2 D K 0 SO , , ;A 2 4 NH 2 D H 2 N!;A 2 C OH 7 4 CO 0 D HCO 2 7 - CH 2 C$ 4 AeC$ 2 D CH 2 4 4 AeC$ , 7 10 6#e so$)i$it( prod)ct9 K sp of ma&nesi)m #(dro3ide in p)re %ater at 05 o C is 0!/ 3 1/ 711 mo$ 2 dm 7C ! "#at is t#e so$)i$it( of ma&nesi)m #(dro3ide %#en an e3cess of so$id ma&nesi)m #(dro3ide is s#aken in 1 dm 2 of /!1 mo$ dm 72 sodi)m #(dro3ide' $ 0!/ 3 1/ 712 mo$ dm 72 , ,!/ 3 1/ 710 mo$ dm 72 C ,!/ 3 1/ 711 mo$ dm 72 - 0!/ 3 1/ 7C mo$ dm72
11 6#e p#ase dia&ram of a mi3t)re of t%o $i8)ids B and H is as fo$$o%sI "#at co)$d B and H e' B H $
6ric#$oromet#ane Bropanone , ;en<ene Met#($en<ene C Et#ano$ "ater - Caron dis)$p#ide Bropanone . 1apo)r press)re 5 atm B H 1!/ 1!/ Mo$e fraction
SECTION , [15 marks] Answer all 8)estions in t#is section! 16 6#e mass spectr)m of a &aseo)s compo)nd is s#o%n e$o%! 4a5 "rite t#e form)$a of ions responsi$e for eac# of t#e peaks $ae$$ed A9 ;9 C and D! [0 marks] A I 77777777777777777777777777777 ;I 777777777777777777777777777777777 CI 777777777777777777777777777777 DI 777777777777777777777777777777777 465 EiF "rite a possi$e form)$a for t#e compo)nd %it# m5e +a$)e of C0 [0 marks] 777777777777777777777777777777777777777777777777777777777777777777777777777777777777777777 EiiF Name t#e compo)nd 7777777777777777777777777777777777777777777777777777777777777777777777777777777777777777777 4)5 6#e fo)r nat)ra$$( occ)rrin& sta$e isotopes of iron are &i+en in t#e ta$e e$o%! Determine t#e re$ati+e atomic mass of iron! [0 marks] *e$ati+e atomic mass 52!C, 55!C2 5.!C, 5G!C2 *e$ati+e a)ndance 5 J 5!-0 C1!-/ 0!1/ /!0- G Bercenta&e a)ndance
17. 6#e dia&ram e$o% represents t#e ener&( $e+e$s of t#e orita$s in atoms of t#e t#ird period! (aF ?ndicate t#e t(pe of orita$s at eac# ener&( $e+e$ e$ectrons in t#e dia&ram ao+e! [0 marks] 465 Dra% and $ae$ a$$ t#e possi$e s#apes of orita$s at t#e ener&( $e+e$9 n : 0! [, marks] 4)5 ?n t#e ao+e dia&ram9 mark t#e +a$ence e$ectron confi&)ration for p#osp#or)s9 )sin& arro%s to represent e$ectrons in t#e dia&ram ao+e! [2 marks]
- Ener&(
SECTION C [2/ marks] Ans%er an( *7o 8)estions in t#is section! 13 4a5 Ammonia is a co$o)r$ess &as %it# a p)n&ent sme$$! ?t reacts %it# #(dro&en ions in acids to form ammoni)m ions9 NH , 4 ! Dra% a Le%is str)ct)re for ammonia and t#e ammoni)m ion! [0 marks] 465 6#e H@N@H ond an&$es in ammonia and ammoni)m ion are 1/GK and 1/C!5K respecti+e$(! E3p$ain t#e difference in t#ese ond an&$es! [, marks] 4)5 6#e reaction et%een f$)orine and nitro&en dio3ide %as carried o)t at 6 K! A 0E&F 4 0NO 0E&F 0NO 0 A E&F 6#e fo$$o%in& data %ere otained %#en t#e reaction %as carried o)t )sin& different concentrations of t#e &ases! "#at is t#e order of t#e reaction %it# respect to EiF f$)orine and nitro&en dio3ide' [, marks] EiiF "rite t#e rate e8)ation for t#e reaction! [ 1 mark ] EiiiF Bropose a possi$e mec#anism for t#is reaction! [, marks] 19! 4a5 Nitro&en mono3ide9 NO can e prepared from t#e reaction et%een nitro&en and o3(&en! N 0E&F 4 O 0E&F 0NO E&F / LH : 41-/!5 kM State #o% EiF K c and EiiF t#e amo)nt of NO %i$$ c#an&e %#en an e8)i$iri)m mi3t)re of N 0 9 O 0 and NO is s)Nected to t#e fo$$o%in& c#an&es! EiF More O 0 is added EiiF 6#e +o$)me is increased EiiiF 6#e temperat)re is decreased Ei+F A cata$(st is )sed [- marks] 465 Caron mono3ide can e )sed to red)ce steam to #(dro&en! CO E&F 4 H 0 O E&F H 0E&F 4 CO 0E&F 0!0/ mo$ of CO E&F and 1!G1 mo$ of H 0 O are p$aced in an empt( 1!// dm 2 f$ask at 6 KC! After e8)i$iri)m %as reac#ed9 t#e concentration of CO %as /!G- mo$ dm 72 ! Ca$c)$ate EiF t#e concentration of H 0 O E&F at e8)i$iri)m [0 marks] EiiF t#e +a$)e of K c at 6 KC for t#e ao+e reaction [0 marks] EiiiF t#e +a$)e of K c at 6 KC for t#e reaction9 H 0E&F 4 CO 0E&F CO E&F 4 H 0 O E&F [2 marks] C
2'! 4a5 EiF "#at do (o) )nderstand ( t#e term so$)i$it( prod)ct' [0 marks] EiiF "rite an e3pression for t#e so$)i$it( prod)ct of ma&nesi)m #(dro3ide9 M&EOHF 0 ! [0 marks] 465 A 05!/ cm 2 samp$e of sat)rated9 a8)eo)s ma&nesi)m #(dro3ide re8)ired 1C!0 cm 2 of /!/5/ mo$ dm 72
#(droc#$oric acid for ne)tra$isation! Ca$c)$ate EiF t#e #(dro3ide ion concentration of t#e sat)rated so$)tion9 [0 marks] EiiiF a +a$)e for t#e so$)i$it( prod)ct of ma&nesi)m #(dro3ide9 statin& t#e )nits! [0 marks] 4)5 6#e )ffer s(stem9 H 0 BO , 7 5 HBO , 07 in $ood #e$ps to keep t#e pH of $ood at ao)t G!,/! EiF Ca$c)$ate t#e [H 0 BO , 7 ] 5 [ HBO , 07 ] ratio at t#e norma$ pH of $ood! [K a H 0 BO ,
7 I .!0 3 1/ 7- mo$ dm 72 ] [2 marks] EiiF Osin& a s)ita$e e8)ation9 e3p$ain %#at #appens %#en= ?F a sma$$ amo)nt of stron& acid is added to t#is )ffer s(stem! ??F a sma$$ amo)nt of stron& ase is added to t#is )ffer s(stem! [, marks] END OF QUESTION PAPER 1/